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Air-Broadened Line Shapes in the 2n3 R Branch of 12ch4 Between 6014 and 6100 cm-1

Complete and accurate information on line shape parameters of 2?3 methane transitions for air broadening as a function of temperature is critical not only for the correct interpretation of the observed atmospheric spectra but also for the development of a reliable theoretical model. For this reason, we obtained a series of high-resolution, high S/N spectra of high-purity 12CH4 and 12CH4 broadened with dry air at temperatures in the 130 to 295 K range using the Bruker IFS 125HR Fourier transform spectrometer at JPL. Two absorption cells were used in the experiment, a White cell with path length of 13 m for room temperature spectra and a 21 m Herriott cella for cold sample spectra. The 15 spectra used in the analysis consisted of 3 low pressure (0.26 to 2.57 Torr) spectra with pure 12CH4 and 12 air-broadened spectra with total sample pressures of 79-805 Torr and volume mixing ratios of methane between 0.23 and 1%. A multispectrum least-squares fitting techniqueb was employed to fit all 15 spectra simultaneously. Preliminary results for select R(J) manifolds will be presented.

V Malathy Devi

Tidal Tomography Reveals a Thermal Anomaly Beneath Mars’s Crustal Dichotomy

Mars undergoes seasonal tidal forcing as a result of its eccentric orbit and the tilt of its rotation axis relative to the Sun1. Response to this forcing produces temporal variations in the Martian gravity field and is sensitive to the internal structure of the planet2,3,4. Using tracking data from the Mars Global Surveyor (MGS), Mars Odyssey (ODY) and Mars Reconnaissance Orbiter (MRO) spacecraft5,6,7, we demonstrate that degree-3 components of the time-variable gravity field of Mars differ by up to 300% from predictions for a spherically symmetric planet8,9,10. These deviations can be explained if the effective shear modulus of the mantle varies by >20% over a roughly north–south pattern that closely aligns with the surface expression of the Martian crustal dichotomy11. On the basis of this correlation, we infer preservation of a 200–400 °C thermal anomaly in the present-day mantle below the southern highlands of Mars. This temperature variation could reflect regional mantle convection12,13 or insulation by the thick southern highlands crust of Mars that has persisted over several billion years14,15.

Mars

Research Reports: 2001 NASA/ASEE Summer Faculty Fellowship Program

For the thirty-seventh consecutive year, a NASA/ASEE (American Society for Engineering Education) Summer Faculty Fellowship Program was conducted at Marshall Space Flight Center (MSFC). The program was conducted by The University of Alabama in Huntsville and MSFC during the period May 29 - August 3, 2001. Operated under the auspices of the American Society for Engineering Education, the MSFC program, as well as those at other NASA Centers, was sponsored by the University Affairs Office, NASA Headquarters, Washington, DC. The basic objectives of the programs, which are in the thirty-seventh year of operation nationally, are (1) to further the professional knowledge of qualified engineering and science faculty members; (2) to stimulate an exchange of ideas between participants and NASA; (3) to enrich and refresh the research and teaching activities of the participants' institutions; and (4) to contribute to the research objectives of the NASA Centers. The Faculty Fellows spent ten weeks at MSFC engaged in a research project compatible with their interests and background and worked in collaboration with a NASA MSFC colleague. This document is a compilation of Fellows' reports on their research during the summer of 2001.

Avionics

Calculations of the Moon's Thermal History at Different Concentrations of Radioactive Elements, Taking Into Account Differentiation on Melting

Calculations of the thermal history of the moon were carried out by solving the thermal conductivity equation for the case in which the heat sources are the long-lived radioactive elements Th, U, and K 40 . The concentrations of these elements were adjusted to give four variations of the heat flow: 1.35 x 10 -8 and 0.91 x 10 -6 cal cm -2 s -1 (I and I**), 0.61 x 10 -6 (variant II, the terrestrial mixture of Lyubimova and Starkova), and 0.236 x 10 -6 (variant III, the chondrite model of Urey and MacDonald). In the same calculations, we considered layering of the differentiated material with transport to the surface of the radioactive elements after the temperature of the layer rose to 200 K above the melting temperature, which is considered in five variants that differ in the amount of transported radioactive elements: 100 percent ( n = 1), 80 percent n = 0.8), 40 percent, 20 percent ( n = 0.6, 0.4, 0.2). During fusion the heat capacity and heat conductivity were changed. We considered two variants of an initially cold (273 K) and hot (900 K) Moon. Calculations show that the interior of the Moon was heated to melting during the first 0.7 to 2.3 x 10 9 years. The maximum fusion involved practically the entire Moon to a distance from 15 to 45 km beneath the surface, and started 3.5 to 4.0 x 10 9 years ago (I, I**), or 2.5 to 3.0 x 10 9 years ago (II, III) and continued for 1 to 2 x 10 9 years. Today the Moon is cooling. The current thickness of the solid crust is from 150 to 200 km and the heat flow exceeds the stationary value 1.5 fold. Apparently the most realistic variant is II (terrestrial mixture) for an initially hot Moon, and gives, regardless of the moderate concentration of radioactive elements, a heat flow of 0.9 to 0.95 x 10 -6 cal cm -2 s -1 , which agrees with the radioastronomical measurements of Troitsky and Krotikov and with the Apollo 15 data.

O I Ornatskaya

Reliability Models and Demonstration of a Fault-Tolerant Motor Concept for Vertical Takeoff and Landing Vehicles

This report documents the completion of the Revolutionary Vertical Lift Technology Project Annual Performance Indicator 24-3.2.4.1: “Apply and document reliability prediction for high reliability motor concept.” Two modeling tools were completed for calculation of reliability of fault-tolerant (FT) motors, and key FT operations of a modular FT motor were demonstrated experimentally. The two models are complementary tools for the stakeholder and user community. Both models employ Markov chain theory. The first model is a time-homogeneous Markov chain model, and the second is a time-inhomogeneous Markov-Weibull model. This report’s main sections are as follows: 1.0 Introduction, 2.0 Theory, 3.0 Motor Reliability Models, 4.0 Validation of FT Operation by Hardware Demonstration, and 5.0 Concluding Remarks. Novel contributions to the field include development of a modular FT motor concept for electrified vertical takeoff and landing (eVTOL) application, solution methods to solve the reliability calculations, development of figures of merit, and the introduction of “linked chains” to formulate a building-block approach for time-inhomogeneous Markov-Weibull modeling of motor reliability. Example case studies have been completed, and results are provided and discussed herein. A four-module FT motor concept was developed to a preliminary-design level of detail. This eVTOL FT motor concept was designed for galvanic, magnetic, and thermal isolation of stator winding faults. The reliability of the concept motor was calculated using a time-inhomogeneous Markov chain model. Employing average failure rate as a metric, 570 times greater reliability was achieved as compared to a baseline motor without fault tolerance. A demonstrator motor was built and tested. The testing demonstrated the key features of FT operation and validated the essential premises of the FT motor concepts presented herein. The experiments included successful demonstration of the feasibility of the following four key FT features: (1) terminal open-circuit operation, (2) thermal isolation after fault, (3) terminal short-circuit operation, and (4) internal short-circuit operation. These works indicate that FT modular motor drives offer promise for addressing the daunting reliability gap that electric aircraft propulsor drives are facing relative to the best conventional motor drive technology that is available today.

Electric Motor

Development of a battery status monitor

A prototype battery status monitor system has been developed. The functions of the system are: (1) to provide the energy status of the battery, (2) to measure and transmit basic battery parameters, (3) to process these measurements required to determine abnormal functioning of the battery, and (4) to transmit warning signals of the abnormal condition along with a go/no go signal. The system was developed for use with the space shuttle.

Zimmerman, R. I.

Effect of Barely Visible Impact Damage on Thermoplastic Welded Structure

Spirit Aerosystems recently conducted screening tests on thermoplastic skin/stringer panels manufactured with Automated Fiber Placement (AFP) and stamp forming which were joined using Spirit’s Co-Fusion process. Skin and stringer gauge were both set to 0.168 cm. The resulting panel design is 48 cm tall, 49 cm wide, and has 3 stringers welded at a 21.5 cm pitch. Barely Visible Impact Damage (BVID) and Residual Compressive Strength were chosen to conduct a damage tolerance study. Zee stringers, made with IM8/PEKK-FC material, were Co-Fusion welded to a T1100/TC1225 skin. Out of these 5 panels, 1 was chosen to be a BVID survey panel, 1 for pristine compressive strength determination, and 3 to be impacted to create BVID followed by testing for residual compressive strength. On the survey panel, impacts ranged in energy from 40J – 65J and dent depth measurements were conducted at 24 hours, 48 hours, and two weeks after impacting. The residual compressive strength panel failed near the predicted load of 214 MPa. For the residual compressive strength panels, BVID was created at two different mid-bay locations: 1) striking the OML coincident with the stringer and 2) striking the skin IML 2.5 cm away from the stringer flange. Pulse Echo Ultrasonic Testing was used to inspect the panels before and after creating BVID.

HiCAM

Biobased Polybenzoxazine Derived from Furfurylamine and Piceol with Low Cure Temperature and Advanced Properties for Composite Matrices

A novel benzoxazine made from furfurylamine, paraformaldehyde, and piceol, Bz-FA-HA, is assessed for applications in fiber reinforced (FR) composites. Piceol is a biobased phenolic compound derived from the roots of Norwegian spruce trees and contains a methyl ketone group at the para position. Bz-FA-HA is a liquid at room temperature, has a viscosity of < 1 Pa.s at temperatures above 90 °C, and a Tonset of cure at 132 °C. The carbonyl is found to react with the furan ring, yielding a crosslinking reaction, when cured above 180 °C as indicated by differential scanning calorimetry and thermogravimetric analysis coupled with Fourier transform infrared spectroscopy. Poly(Bz-FA-HA) has a Tg > 350 °C, attributed to the crosslinking reaction. Furthermore, the storage modulus is > 3 GPa, regardless of cure temperature. Poly(Bz-FA-HA) has a char yield at 800 °C of 65.0 % (62.3 % at 1000 °C), and a Tonset of decomposition of 357 °C in nitrogen. The resulting carbon formed during pyrolysis shrinks during the carbonization reaction and scanning electron microscopy imaging shows a cross-section with micro cracks. The high processability, advanced mechanical properties, and exceptional char yield make it a promising candidate as the matrix for FR composites.

Benzoxazine

First N 2 Profile for Venus’ Deep Lower Atmosphere

We present the first N 2 profile for Venus’ deep lower atmosphere (<15 km) and a constrained isotopic composition for cloud N 2 [1]. This work directly addresses unresolved questions for Venus using legacy observations. Prior to this work, there were no reported measurements for N 2 abundances at <15 km and the isotopic composition remained unconstrained [2]. The N 2 parameters are critical to understanding the evolution and thermal properties of the atmosphere [3-7]. Our N 2 results were obtained by re-analysis of data acquired in 1978 by the Pioneer Venus Large Probe Neutral Mass Spectrometer (LNMS) [8]. The archived mass spectra from 64.2 to 0.2 km were treated using the analytical procedures specifically developed for the LNMS [9-11]. Judicious peak fitting permitted disambiguation of (A) N 2 + and CO + at 28 u and (B) 14 N 15 N+, 13 CO + , and C 2 H 5 + at 29 u. Quality controls included comparing the (A) LNMS CO + /CO 2 + ratios to the NIST database and literature and (B) fitted counts for CO + to the expected counts of CO + calculated from C 18 O + and 13 CO + using the LNMS 16 O/ 18 O and 12 C/ 13 C ratios (obtained from CO 2 ). Our results show that N 2 is uniformly mixed across the deep lower atmosphere between ~0.2 and 15 km (2.49 ± 0.10 v%). In contrast, N 2 is non-uniformly mixed across the sub-cloud atmosphere and clouds (~15–59 km), where N 2 abundances increase by ~ 2-fold between ~15 km (2.45 ± 0.32 v%) and ~59-51 km (5.21 ± 0.18 v%). Using the cloud data, we also obtained a constrained 15 N/ 14 N ratio (2.93×10 -3 ± 0.13×10 -3 ) and δ 15 N value (-204 ± 35‰). Thus, the LNMS results [1] suggest that (A) the atmosphere is unstable at <15 km, (B) N 2 is not well-mixed >15 km, and (C) the cloud δ 15 N falls between Earth and the solar wind [12, 13]. Comparisons of the N 2 abundances and isotopic compositions for nitrogen, carbon, and oxygen to other Venus measurements will be discussed.

deep lower atmosphere

Design, Testing and Evaluation of Latching End Effector

The Latching End Effector (LEE) forms part of the Space Station Remote Manipulator System (SSRMS) for which Spar Aerospace Ltd, Space Systems Division is the prime contractor. The design, testing and performance evaluation of the Latching End Effector mechanisms is the subject of this paper focusing on: (1) ambient, thermal and vibration testing; (2) snare/rigidize performance testing and interaction during payload acquisition; and (3) latch/umbilical test results and performance.

B Walker

Development and Experimental Validation of a Path-Dependent Spin Forming Finite Element Model

Spin forming is an advanced manufacturing process widely used in the aerospace and defense sectors to produce lightweight, high-strength cylindrical components with tight dimensional tolerances. This study explores the applicability of the path-dependent Mechanical Threshold Stress (MTS) constitutive model by simulating the evolution of geometry, machining forces, and plastic deformation during the spin forming of a 10-mm thick 6061-O aluminum cylinder. While numerical modeling of spin forming has advanced substantially over the past decade, systematic verification and experimental validation of material models remain limited, particularly in predicting through-thickness process evolution. The MTS model, incorporating a Voce hardening rule, is employed for its ability to represent cyclic loading, rapidly varying temperature fields, and strain rates characteristic of spin forming. Numerical convergence analysis indicates discretization uncertainties between 0.3% and 9.2% for key quantities of interest. Experimental validation demonstrates that the MTS model, when implemented with a verified mesh, accurately reproduces both elastic and plastic behavior of 6061-O aluminum, predicting peak roller loads within 11–18% of measurements, geometric tolerances within 3%, and plastic strain distributions within 10% of experimental values. Collectively, these results establish a validated computational framework for predictive spin-forming simulations with quantified confidence, providing a foundation for extension to other alloys, geometries, and forming conditions.

Spin forming

Utilization of a bipolar lead acid battery for the advanced launch system

The development of a battery comprised of bipolar lead acid modules is discussed. The battery is designed to satisfy the requirements of the Advanced Launch System (ALS). The battery will have the following design features: (1) conventional lead acid chemistry; (2) thin electrode/active materials; (3) a thin separator; (4) sealed construction (gas recombinant); and (5) welded plastic frames for the external seal.

Gentry, William O.

Ground-Based Microwave Measurements of ClO and O3 Over Scott Base, Antarctica

We present measurements from a new microwave instrument that has been deployed at Scott Base, Antarctica, primarily to measure ClO. The new instrument allows for the extension of the time series of lower stratospheric ClO measurements begun in 1996 at this site, while some of the technical improvements offer the possibility of making additional measurements. We show measurements of ClO and O 3 in both the upper and lower stratosphere near both the fall and spring equinox and document the diurnal variations of these measurements throughout the season. The ground-based measurements are compared with Aura Microwave Limb Sounder (MLS) measurements, which are available twice per day, and with a NASA Goddard 2D model (GSFC2D) simulation. We show that, in agreement with the GSFC2D model diurnal variations, upper stratospheric ClO mixing ratios gradually increase throughout the daylight hours, while in the lower stratospheric austral spring, when heterogeneous chemistry associated with polar stratospheric clouds occurs, daily maximum ClO mixing ratios of near 2 ppbv occur near noon. We also show measurements of stratospheric O 3 , primarily in the upper stratosphere, which, while exhibiting a low bias of ∼15%–20% relative to Aura MLS, show temporal variations in good agreement with MLS.

stratospheric ozone

GOPEX at the Starfire Optical Range

The Starfire Optical Range successfully conducted laser upink experiments to the Galileo spacecraft during the early morning hours of December 9, 10, 11, and 12, 1992, when the spacecraft was at ranges between 700,000 and 3 million km from Earth. Analysts at JPL have reported as many as 79 pulse detections by the spacecraft. The best weather conditions occurred on the second night when 37 pulses were detected with as many as five on one frame. Signal levels at the spacecraft generally agree with predictions.

R Q Fugate

The 1988 Goddard Space Flight Center Battery Workshop

This document contains the proceedings of the 21st annual Battery Workshop held at Goddard Space Flight Center, Greenbelt, Maryland on November 1-3, 1988. The Workshop attendees included manufacturers, users, and government representatives interested in the latest developments in battery technology as they relate to high reliability operations and aerospace use. The subjects covered included battery testing methodologies and criteria, life testing of nickel-cadmium cells, testing and operation of nickel-hydrogen batteries in low earth orbit, and nickel-hydrogen technology issues and concerns.

Yi, Thomas Y.

1998 NASA Seal/Secondary Air System Workshop

The 1998 NASA Seal/Secondary Air System Workshop was divided into three major areas with limited materials presented in Volume II: (1) overviews of the (NASAs high speed research (HSR) and DOE's advanced turbine engine systems (ATS)) gas turbine programs and the general aviation program (GAP) with emphasis on sealing methods and results; (2) sealing concepts and methods and results including experimental facilities and numerical predictions; and (3) reviews of the numerical engine simulation and aerospace vehicles and concepts (Trailblazer, Bantam, and X-38).

Bruce Steinetz

NIAC Phase I Final Report Lunar South Pole Oxygen Pipeline (LSPOP)

The Lunar South Pole Oxygen Pipeline (LSPOP) Phase I NIAC, is to analyze the feasibility of constructing a pipeline at the Moon’s South Pole for transporting gaseous oxygen from point of generation to point of use. A lunar pipeline has never been pursued and will revolutionize lunar surface operations for the Artemis program and reduce cost and risk. Our starting concept is for a 5 km pipeline to transport oxygen gas from an oxygen production source, for example from our molten regolith electrolysis (MRE, currently at TRL 5, see references[1],[2],[3],[4],[5],[6] for technical discussions of the MRE process) extraction site, or any other source, to an oxygen storage/liquification plant near a lunar base. The pipeline is designed to: 1) be constructed robotically from regolith-derived metals with minimal material transferred from Earth, 2) be repairable robotically, 3) have an oxygen flow rate of ~2 kg/hour, which is commensurate with the NASA initial projected need of 10,000 kg/year, 4) operate with minimal power over the lifetime of the pipeline, with a goal of high operational reliability and the ability to survive in the lunar environment for > 10 years. We compare this concept to a pipeline concept with pipe produced on Earth and then transported to and assembled on the Moon. Both approaches will use earth-based compressors, valves, and fittings which are integrated into the pipeline on the Moon.

NIAC Phase I

The Evolution in Coma Molecular Composition of Comet C/2017 K2 (PanSTARRS) Across the H 2 O Sublimation Zone: ALMA Imaging of an H 2 O-Dominated Coma

We report a survey of molecular emission from cometary volatiles using the Atacama Large Millimeter/Submillimeter Array (ALMA) toward comet C/2017 K2 (PanSTARRS) carried out on UT 2022 September 21, 22, and 23 at a heliocentric distance r H 3 OH, and H 2 CO (along with continuum emission from dust) sampled molecular chemistry in C/2017 K2 at the inner edge of the H 2 O sublimation zone, the region from r H 2 O begins vigorously subliming and increasingly dominating comet activity, discerning parent from daughter or extended source species. This work presents spectrally integrated flux maps, production rates, and parent scale lengths for each molecule. CH 3 OH, CO, and HCN were produced within ~250 km of the nucleus, potentially including contributions from sublimation of icy grains. CS was consistent with production from CS 2 photolysis, and H 2 CO required production from extended sources in the coma. An ortho-to-para ratio of 2.9 ± 0.4 for H 2 CO was derived from simultaneously measured transitions of each spin species. The continuum was extended and spatially resolved, consistent with thermal emission from dust in the coma. Analysis of the continuum visibilities provided an upper limit on the nucleus diameter d <6.6 km and coma dust masses of (1.2-2.4) times10 11 kg.

Nathan X Roth