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At least 73 records · Page 4

The structure of particle cloud premixed flames

The structure of premixed flames propagating in combustible systems containing uniformly distributed volatile fuel particles in an oxidizing gas mixture is analyzed. This analysis is motivated by experiments conducted at NASA Lewis Research Center on the structure of flames propagating in combustible mixtures of lycopodium particles and air. Several interesting modes of flame propagation were observed in these experiments depending on the number density and the initial size of the fuel particle. The experimental results show that steady flame propagation occurs even if the initial equivalence ratio of the combustible mixture based on the gaseous fuel available in the particles, phi sub u, is substantially larger than unity. A model is developed to explain these experimental observations. In the model, it is presumed that the fuel particles vaporize first to yield a gaseous fuel of known chemical composition which then reacts with oxygen in a one-step overall process. The activation energy of the chemical reaction is presumed to be large. The activation energy characterizing the kinetics of vaporization is also presumed to be large. The equations governing the structure of the flame were integrated numerically. It is shown that the interplay of vaporization kinetics and oxidation process can result in steady flame propagation in combustible mixtures where the value of phi sub u is substantially larger than unity. This prediction is in agreement with experimental observations.

Seshadri, K.↗

Premixed flame propagation in combustible particle cloud mixtures

The structures of premixed flames propagating in combustible systems, containing uniformly distributed volatile fuel particles, in an oxidizing gas mixtures is analyzed. The experimental results show that steady flame propagation occurs even if the initial equivalence ratio of the combustible mixture based on the gaseous fuel available in the particles, phi(u) is substantially larger than unity. A model is developed to explain these experimental observations. In the model it is presumed that the fuel particles vaporize first to yield a gaseous fuel of known chemical composition which then reacts with oxygen in a one-step overall process. It is shown that the interplay of vaporization kinetics and oxidation process, can result in steady flame propagation in combustible mixtures where the value of phi(u) is substantially larger than unity. This prediction is in agreement with experimental observations.

Seshadri, K.↗

Dense hydrogen layers for high performance MagLIF

We report that Magnetized Liner Inertial Fusion (MagLIF) experiments driven by the Z machine produce >10 13 deuterium-deuterium fusion reactions. Simulations indicate high yields and gains (1000) with increased current and deuterium-tritium layers for burn propagation. Such a coating also isolates the metal liner from the gaseous fuel, which should reduce mixing of liner material into the fuel. However, the vapor density at the triple point is only 0.3 kg/m3, which is not high enough for MagLIF operation. We present two solutions to this problem. First, a fuel wetted low-density plastic foam can be used to form a layer on the inside of the liner. The desired vapor density can be obtained by controlling the temperature. This does however introduce carbon into the layer which will enhance radiation losses. Simulations indicate that this wetted foam layer can significantly contribute to the fusion yield when the foam density is less than 35 kg/m 3 . Second, we show that a pure frozen fuel layer can first be formed on the inside of the liner and then low temperature gaseous fuel can be introduced just before the implosion without melting a significant amount of the ice layer. This approach is the most promising for MagLIF to produce high yield and gain.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Premixed Atmosphere and Convection Influences on Flame Inhibition and Combustion (Pacific)

Flame spread over flat solid fuel beds is a useful paradigm for studying the behavior of more complex two-phase nonpremixed flames. For practical applications, two of the most important elements of flame spreading are the effects of (1) the ambient atmosphere (e.g. pressure and composition) and (2) the flow environment on the spread rate and extinction conditions. Concerning (1), studies of flame spread in vitiated air and non-standard atmospheres such as those found in undersea vessels and spacecraft are particularly important for the assessment of fire hazards in these environments as well as determination of the effectiveness of fire suppressants. Concerning (2), the flow environment may vary widely even when no forced flow is present because of buoyancy effects. Consequently, the goal of this work is to employ microgravity (micro g) experiments to extend previous studies of the effects of ambient atmosphere and the flow environment on flame spread through the use of microgravity (micro g) experiments. Because of the considerable differences between upward (concurrent-flow) and downward (opposed-flow) flame spread at 1g (Williams, 1976, Fernandez-Pello, 1984), in this work both upward and downward 1g spread are tested. Two types of changes to the oxidizing atmosphere are considered in this work. One is the addition of sub-flammability-limit concentrations of a gaseous fuel ('partially premixed' atmospheres). This is of interest because in fires in enclosures, combustion may occur under poorly ventilated conditions, so that oxygen is partially depleted from the air and is replaced by combustible gases such as fuel vapors, H2 or CO. Subsequent fire spread over the solid fuel could occur under conditions of varying oxygen and gaseous fuel content. The potential significance of flame spread under vitiated or partially premixed conditions has been noted previously (Beyler, 1984). The second change is the diluent type, which affects the radiative properties of the mixture as well as the Lewis number (Le) of the reactants in the atmosphere, which for oxygen is defined as the thermal diffusivity of the bulk mixture divided by the mass diffusivity of oxygen into the bulk mixture. Understanding the effect of diluent type is desirable because in some undersea and spaceborne habitations, it is desirable to use diluent gases other than nitrogen. Prior experiments have shown that both radiation (Bhattacharjee and Altenkirch, 1993) and Lewis number (Zhang et al, 1992) effects are important in flame spreading problems.

Honda, Linton K.↗

Planar Strain-Rate-Free Diffusion Flames: Initiation, Properties, and Extinction

An effectively strain-rate-free diffusion flame constitutes the most vigorous laminar combustion of initially unmixed reactive gases. Such a diffusion flame is characterized by a relatively long residence time and by a relatively large characteristic length scale. If such a flame were also planar, providing high symmetry, it would be particularly suitable for experimental and theoretical investigations of key combustion phenomena, such as multicomponent diffusion, chemical kinetics, and soot inception, growth, and oxidation. Unfortunately, a planar strain-rate-free diffusion flame is highly disrupted in earth-gravity (e.g., in a counterflow-diffusion-flame apparatus) because of the very rapid onset (approx. 100 ms) of gravity-induced instability. Accordingly, a specially dedicated apparatus was designed, fabricated, and initially checked out for the examination of a planar strain-rate-free diffusion flame in microgravity. Such a diffusion flame may be formed within a hollowed-out squat container (initially configured as 25 cm x 25 cm x 9 cm), with isothermal, noncatalytic, impervious walls. At test initiation, a thin metallic sheet (approx. 1 mm in thickness) that separates the internal volume into two equal portions, each of dimensions 25 cm x 25 cm x 4.5 cm, is withdrawn, by uniform translation (approx. 50 cm/s) in its own plane, through a tightly fitting slit in one side wall. Thereupon, diluted fuel vapor (initially confined to one half-volume of the container) gains access to diluted oxygen (initially with the same pressure, density, and temperature as the fuel, but initially confined to the other half-volume). After a brief delay (approx. 10 ms), to permit limited but sufficient-for-flammability diffusional interpenetration of fuel vapor and oxidizer, burning is initiated by discharge of a line igniter, located along that side wall from which the trailing edge of the separator withdraws. The ignition spawns a triple-flame propagation across the 25 cm x 25 cm centerplane. When a diffusion flame is emplaced in the centerplane, any subsequent travel, and change in temperature, of that planar diffusion flame may be tracked, along with the effectively spatially uniform but temporally evolving pressure within the container. Eventually, nearly complete depletion of the stoichiometrically deficient reactant, along with heat loss to the container surfaces, effects extinction. These data afford an opportunity to check theoretical models of diffusion and chemical kinetics under conditions ranging from intense burning to flame out, or, alternatively, to evolve simple empirical representations of these phenomena. Thus, the project sought to utilize microgravity testing to elucidate commonly encountered phenomenology, arising in the commonly-encountered mode of combustion (whether related to heating, manufacturing, boiling, and propulsion, or to uncontrolled, free-burning fire in structures and wildland vegetation), of those commonly utilized fuels usually categorized as gaseous fuels (such as hydrogen, natural gas, and propane, which are gaseous under atmospheric conditions).

Fendell, Francis↗

Numerical modeling of hydrogen mixing in a direct-injection engine fueled with gaseous hydrogen

Hydrogen is considered as one of the most promising options to achieve effective decarbonization of the energy and transportation sectors. As such, it has recently been receiving increasing attention because of its promising potential as an energy carrier for advanced energy and propulsion systems. With a focus on internal combustion engines, direct injection (DI) of gaseous hydrogen during the compression stroke offers great potential for high engine efficiency and specific power while reducing the risk of backfiring and pre-ignition issues. Therefore, many experimental and numerical efforts have recently been dedicated to understanding the physical and chemical behaviors of hydrogen in engine during mixing and combustion. This study focuses on computational fluid dynamics (CFD) modeling of the hydrogen DI process in a hydrogen optical research engine. Under the conditions studied, gaseous hydrogen is injected into the combustion chamber via a centrally located single-hole injector at a pressure of 100 bar. Two configurations, namely low-and high-tumble, are investigated to understand the impact of different in-cylinder flow patterns on the fuel-air mixture preparation. Simulations are carried out using the commercial CFD software CONVERGE. Here, the in-cylinder turbulence is modeled with an unsteady Reynolds-averaged Navier-Stokes (URANS) formulation closed by the renormalization group (RNG) k-ε model. Several numerical methods and model constants, including but not limited to turbulent Schmidt number, are evaluated. The numerical results are systematically compared against experimental measurements of velocity and hydrogen concentration fields on the vertical center plane to assess the performance of the CFD model, unveil the physics of hydrogen mixing, and establish best practices for modeling hydrogen DI under relatively high injection pressure conditions.

33 ADVANCED PROPULSION SYSTEMS↗

Multi-dimensional modeling of mixture preparation in a direct injection engine fueled with gaseous hydrogen

With the recent advances of direct injection (DI) technology, introducing hydrogen into the combustion chamber through DI is being considered as a viable approach to circumvent backfire and pre-ignition encountered in early generations of hydrogen engines. As part of a broader vision to develop a robust numerical model to study hydrogen spark ignition (SI) combustion in internal combustion (IC) engines, the present numerical investigation focuses on mixture preparation in a hydrogen DI SI engine. This study is carried out with a single hole injector with gaseous hydrogen injected at 100 bar injection pressure. Simulations are carried out for high and low tumble configurations and validated against optical data acquired from planar laser induced fluorescence (PLIF) measurements. Varying mesh configurations are investigated for the impact on in-cylinder mixture distribution. A particular emphasis is placed on the effect of nozzle geometry and mesh orientation near the wall. Overall, the computational model is found to predict the mixture distribution in the combustion cylinder reasonably well. The results showed that the alignment of mesh with the flow direction is important to achieve good agreement between numerical analysis and optical measurement data.

08 HYDROGEN↗

Design and evaluation of combustors for reducing aircraft engine pollution

Efforts in reducing exhaust emissions from turbine engines are reported. Various techniques employed and the results of testing are briefly described and referenced for detail. The experimental approaches taken to reduce oxides of nitrogen emissions include the use of: (1) multizone combustors incorporating reduced dwell times, (2) fuel-air premixing, (3) air atomization, (4) fuel prevaporization, and (5) gaseous fuel. Since emissions of unburned hydrocarbons and carbon monoxide are caused by poor combustion efficiency at engine idle, the studies of fuel staging in multizone combustors and air assist fuel nozzles have indicated that large reductions in these emissions can be achieved. Also, the effect of inlet-air humidity on oxides of nitrogen was studied as well as the very effective technique of direct water injection. The emission characteristics of natural gas and propane fuels were measured and compared with those of ASTM-Al kerosene fuel.

Jones, R. E.↗

Characteristics of response factors of coaxial gaseous rocket injectors

The results of an experimental investigation undertaken to determine the frequency dependence of the response factors of various gaseous propellant rocket injectors subject to axial instabilities are presented. The injector response factors were determined, using the modified impedance-tube technique, under cold-flow conditions simulating those observed in unstable rocket motors. The tested injectors included a gaseous-fuel injector element, a gaseous-oxidizer injector element and a coaxial injector with both fuel and oxidizer elements. Emphasis was given to the determination of the dependence of the injector response factor upon the open-area ratio of the injector, the length of the injector orifice, and the pressure drop across the injector orifices. The measured data are shown to be in reasonable agreement with the corresponding injector response factor data predicted by the Feiler and Heidmann model.

Janardan, B. A.↗

Dual membrane hollow fiber fuel cell and method of operating same

A gaseous fuel cell is described which includes a pair of electrodes formed by open-ended, ion-exchange hollow fibers, each having a layer of metal catalyst deposited on the inner surface and large surface area current collectors such as braided metal mesh in contact with the metal catalyst layer. A fuel cell results when the electrodes are immersed in electrolytes and electrically connected. As hydrogen and oxygen flow through the bore of the fibers, oxidation and reduction reactions develop an electrical potential. Since the hollow fiber configuration provides large electrode area per unit volume and intimate contact between fuel and oxidizer at the interface, and due to the low internal resistance of the electrolyte, high power densities can be obtained.

Ingham, J. D.↗

Performance and Emissions of an SI Engine Fueled With DME-Propane Blends

Dimethyl Ether (DME) is an alternative fuel that can be produced renewably and has the potential for lower CO and NOx emissions than conventional petroleum-based fuels. Blending DME with another gaseous fuel such as propane, which has a lower knock tendency than gasoline, can allow this fuel to be leveraged on SI engines. In this study, the use of DME-propane blends on a spark ignition (SI) engine was studied via computer simulations in order to understand the impact on engine performance and emissions and to identify the knock limitations of using such fuel blends. A 2L Hyundai SI engine was modeled in GT Power and the model was validated by comparing it with computational fluid dynamics (CFD) simulation results. Starting from pure propane, DME was added incrementally until knock was observed in the engine. Results indicate that it is feasible to run propane with DME percentages up to 35% before severe knock impacts were observed. The BTE was higher, but the BSFC also increased for DME-propane blends as compared to gasoline. Here, an increase in NOx emissions was detected along with a significant decrease in CO emissions. CO 2 emissions declined for propane as compared to gasoline but increased with the addition of DME.

alternative fuels↗

The UF6 Breeder - A solution to the problems of nuclear power

One of the major advantages of uranium hexafluoride reactors for power generation is the simplified fuel reprocessing scheme which the gaseous fuel makes possible. Critical experiments related to the development of the reactors for electric power generation are discussed along with UF6 breeder reactor studies. Previous energy conversion studies are reported, taking into account gas turbine power plants, thermionic conversion, and MHD conversion. Thermodynamic cycle analyses show that high efficiencies can be achieved using UF6 as the working fluid for Rankine or Brayton cycles without requiring excessive temperatures.

Williams, J. R.↗

Study of industry requirements that can be fulfilled by combustion experimentation aboard space station

The purpose of this study is to define the requirements of commercially motivated microgravity combustion experiments and the optimal way for space station to accommodate these requirements. Representatives of commercial organizations, universities and government agencies were contacted. Interest in and needs for microgravity combustion studies are identified for commercial/industrial groups involved in fire safety with terrestrial applications, fire safety with space applications, propulsion and power, industrial burners, or pollution control. From these interests and needs experiments involving: (1) no flow with solid or liquid fuels; (2) homogeneous mixtures of fuel and air; (3) low flow with solid or liquid fuels; (4) low flow with gaseous fuel; (5) high pressure combustion; and (6) special burner systems are described and space station resource requirements for each type of experiment provided. Critical technologies involving the creation of a laboratory environment and methods for combining experimental needs into one experiment in order to obtain effective use of space station are discussed. Diagnostic techniques for monitoring combustion process parameters are identified.

Priem, Richard J.↗

Fuel Cell Power Plant Initiative: Preliminary Design of a Fixed-Base LFP/SOFC Power System - Volume 2

This report documents the preliminary design for a military fixed-base power system of 3 MWe nominal capacity using Westinghouse's tubular Solid Oxide Fuel Cell [SOFC] and Haldor Topsoe's logistic fuels processor [LFP]. The LFP provides to the fuel cell a methane rich sulfur free fuel stream derived from either DF-2 diesel fuel, or JP-8 turbine fuel. Fuel cells are electrochemical devices that directly convert the chemical energy contained in fuels such as hydrogen, natural gas, or coal gas into electricity at high efficiency with no intermediate heat engine or dynamo. The SOFC is distinguished from other fuel cell types by its solid state ceramic structure and its high operating temperature, nominally 1000'C. The SOFC pioneered by Westinghouse has a tubular geometry closed at one end. A power generation stack is formed by aggregating many cells in an ordered array. The Westinghouse stack design is distinguished from other fuel cell stacks by the complete absence of high integrity seals between cell elements, cells, and between stack and manifolds. Further, the reformer for natural gas [predominantly methane] and the stack are thermally and hydraulically integrated with no requirement for process water. The technical viability of combining the tubular SOFC and a logistic fuels processor was demonstrated at 27 kWe scale in a test program sponsored by the Advanced Research Projects Agency [ARPA) and carried out at the Southern California Edison's [SCE] Highgrove generating station near San Bernardino, California in 1994/95. The LFP was a breadboard design supplied by Haldor Topsoe, Inc. under subcontract to Westinghouse. The test program was completely successful. The LFP fueled the SOFC for 766 hours on JP-8 and 1555 hours of DF-2. In addition, the fuel cell operated for 3261 hours on pipeline natural gas. Over the 5582 hours of operation, the SOFC generated 118 MVVH of electricity with no perceptible degradation in performance. The LFP processed military specification JP-8 and DF-2 removing the sulfur and reforming these liquid fuels to a methane rich gaseous fuel. Results of this program are documented in a companion report titled 'Final Report-Solid Oxide Fuel Cell/ Logistic Fuels Processor 27 kWe Power System'.

Veyo, S.E.↗

25-Pin metallic fuel performance benchmark case based on the EBR-II X430 experiments series

A metallic fuel benchmark case was developed for the fuel performance code BISON based on 25 uranium-zirconium and uranium-plutonium-zirconium pins of the Experimental Breeder Reactor II X430 experiment series. Results of the benchmarks were compared with measurements and calculations made at the time of the experiment as well as subsequent measurements reported in 2019. The comparisons were used to quantify the accuracy of the BISON predictions and to identify patterns in the BISON differences.BISON predicted burnup, plenum pressure, and fission gas release fractions accurately. BISON temperature predictions were somewhat cooler than the temperatures determined at the time of the experiment but appeared to be reasonably accurate considering uncertainties in the legacy temperature calculations, uncertainties in the legacy linear heat rate calculations, and the high sensitivities of the BISON-predicted temperatures to BISON inputs. Fuel axial elongation predictions had errors correlated to fuel composition; BISON tended to underpredict the elongation of binary fuels and overpredict the elongation of ternary fuels. BISON cladding radial dilation predictions were also significantly lower than legacy PIE measurements.Recommendations were made to improve the BISON fuel gaseous swelling model to account for fuel composition, to add additional capabilities to the coolant channel temperature model to ease benchmark development, and to continue developing benchmark cases based on a wide range of experiments in several reactors. Once a wide array of benchmarks is developed, an attempt can be made to enhance or calibrate BISON models to improve the cladding dilation predictions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Advanced Anode for Internal Reforming and Thermal Management in Solid Oxide Fuel Cells

Solid oxide fuel cell (SOFC) is an efficient and clean electrical power generation system compared to conventional combustion based technologies with energy efficiency reaching as high as 85-90% in co-generation mode (electricity and heat). Other advantages of SOFCs are hybridization, modularity of construction, small CO 2 foot print per kWh of generated electricity and fuel flexibility. Hydrocarbons present in the gaseous fuel is utilized in SOFCs by internal or external reforming. There are two different internal reforming concepts: Direct Internal Reforming (DIR) and Indirect Internal Reforming (IIR). For DIR operation, the endothermic reforming reaction and the exothermic reaction from the oxidation reaction are operated together in the single unit eliminating the requirement for a separate fuel reformer. This configuration also simplifies the overall system design, making SOFC more attractive and efficient means of producing electrical power. The main advantage of the DIR type of operation is that the H 2 or CO consumption by the electrochemical reaction could directly promote the conversion of methane at the anode side of the fuel cell resulting in high conversion and high efficiency. The DIR operation, however, requires an anode material that has desired dual catalytic (hetero and electro) properties for reforming reaction and electrochemical reactions. The anode materials also need to remain resistant to carbon formation at the operating temperature and atmosphere with stable cell performance. Another requirement is to match the reforming reactions and electrochemical reactions to avoid local cooling or overheating, which can result in mechanical failure due to thermally induced stresses. Direct internal reforming (DIR) of hydrocarbon fuels simplifies the overall SOFC system design making it more attractive and efficient for producing electrical power. Low cost alloy anodes for distributed internal reforming of methane and other hydrocarbon fuels offer increased fuel-flexibility, reliability, and long term performance stability of solid oxide fuel cells (SOFC). The research program examined modification of the chemical compositions and microstructure of high entropy alloy (HEA) anode materials using thermochemical calculations and process simulation and modeling to achieve distributed reforming over the entire anode to eliminate hot zones. Cell fabrication and testing of the HEA anodes using button cell configuration has been performed to demonstrate the advantages of new anode over traditional Ni-YSZ anodes for distributed reforming and carbon free operation. Technical accomplishments include identification and synthesis of HEA carbon-resistant anode, demonstration of reduction in reforming rate confirmed by GC and modelling data validating effectiveness for thermal management in cell/stacks, electrochemical testing of HEA anode in single cell (HEA-GDC||YSZ||LSM-YSZ) and Characterization of pretest and posttest anode materials by TEM and SEM-EDS confirming carbon-free operation.

30 DIRECT ENERGY CONVERSION↗

Measurements of acoustic responses of gaseous propellant injectors

Results are presented for an investigation intended to provide experimental data that can quantitatively describe the way in which various coaxial injector designs affect the stability of gaseous propellant rocket motors. The response factors of configurations that simulate the flow conditions in a gaseous-fuel injector element and a gaseous-oxidizer injector element are measured by using a modified impedance-tube technique and under cold-flow conditions simulating those observed in rocket motors with axial instability. The measured injector response factor data are presented and discussed. It is shown that there is reasonable agreement between the measured injector response factors and those predicted by the Feiler and Heidmann model (1967), and that the orifice length can be varied to shift the resonant frequency of the injector without any change in the magnitude of the response factor at resonance. A change in the injector open-area ratio is found to have a significant effect on the characteristics of the injector response factor.

Janardan, B. A.↗