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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Merging Ocean Color Data From Multiple Missions

Oceanic phytoplankton may play an important role in the cycling of carbon on the Earth, through the uptake of carbon dioxide in the process of photosynthesis. Although they are ubiquitous in the global oceans, their abundances and dynamics are difficult to estimate, primarily due to the vast spatial extent of the oceans and the short time scales over which their abundances can change. Consequently, the effects of oceanic phytoplankton on biogeochemical cycling, climate change, and fisheries are not well known. In response to the potential importance of phytoplankton in the global carbon cycle and the lack of comprehensive data, NASA and the international community have established high priority satellite missions designed to acquire and produce high quality ocean color data (Table 6.1). Ten of the missions are routine global observational missions: the Ocean Color and Temperature Sensor (OCTS), the Polarization and Directionality of the Earth's Reflectances sensor (POLDER), Sea-viewing Wide Field-of-view Sensor (SeaWiFS), Moderate Resolution Imaging Spectrometer-AM (MODIS-AM), Medium Resolution Imaging Spectrometer (MERIS), Global Imager (GLI), MODIS-PM, Super-GLI (S-GLI), and the Visible/Infrared Imager and Radiometer Suite (VIIRS) on the NPOESS Preparatory Project (NPP) and the National Polar-orbiting Operational Environmental Satellite System (NPOESS). In addition, there are several other missions capable of providing ocean color data on smaller scales. Most of these missions contain the spectral band complement considered necessary to derive oceanic chlorophyll concentrations and other related parameters. Many contain additional bands that can provide important ancillary information about the optical and biological state of the oceans.

Gregg, Watson W.↗
NASA NTRS2001

Merging Ocean Color Data from Multiple Missions

Oceanic phytoplankton may play an important role in the cycling of carbon on the Earth, through the uptake of carbon dioxide in the process of photosynthesis. Although they are ubiquitous in the global oceans, their abundances and dynamics are difficult to estimate, primarily due to the vast spatial extent of the oceans and the short time scales over which their abundances can change. Consequently, the effects of oceanic phytoplankton on biogeochemical cycling, climate change, and fisheries are not well known. In response to the potential importance of phytoplankton in the global carbon cycle and the lack of comprehensive data, the National Aeronautics and Space Administration (NASA) and the international community have established high priority satellite missions designed to acquire and produce high quality ocean color data. Seven of the missions are routine global observational missions: the Ocean Color and Temperature Sensor (OCTS), the Polarization and Directionality of the Earth's Reflectances sensor (POLDER), Sea-viewing Wide Field-of-view Sensor (SeaWiFS), Moderate Resolution Imaging Spectrometer-AM (MODIS-AM), Medium Resolution Imaging Spectrometer (MERIS), Global Imager (GLI), and MODIS-PM. In addition, there are several other missions capable of providing ocean color data on smaller scales. Most of these missions contain the spectral band complement considered necessary to derive oceanic pigment concentrations (i.e., phytoplankton abundance) and other related parameters. Many contain additional bands that can provide important ancillary information about the optical and biological state of the oceans. Any individual ocean color mission is limited in ocean coverage due to sun glint and clouds. For example, one of the first proposed missions, the SeaWiFS, can provide about 45% coverage of the global ocean in four days and only about 15% in one day.

Gregg, Watson W.↗
DOE OSTI2023

Arctic Permafrost Thawing Enhances Sulfide Oxidation

Permafrost degradation is altering biogeochemical processes throughout the Arctic. Thaw-induced changes in organic matter transformations and mineral weathering reactions are impacting fluxes of inorganic carbon (IC) and alkalinity (ALK) in Arctic rivers. However, the net impact of these changing fluxes on the concentration of carbon dioxide in the atmosphere (pCO 2 ) is relatively unconstrained. Resolving this uncertainty is important as thaw-driven changes in the fluxes of IC and ALK could produce feedbacks in the global carbon cycle. Enhanced production of sulfuric acid through sulfide oxidation is particularly poorly quantified despite its potential to remove ALK from the ocean-atmosphere system and increase pCO 2 , producing a positive feedback leading to more warming and permafrost degradation. In this work, we quantified weathering in the Koyukuk River, a major tributary of the Yukon River draining discontinuous permafrost in central Alaska, based on water and sediment samples collected near the village of Huslia in summer 2018. Using measurements of major ion abundances and sulfate (SO 4 2- ) sulfur ( 34 S/ 32 S) and oxygen ( 18 O/ 16 O) isotope ratios, we employed the MEANDIR inversion model to quantify the relative importance of a suite of weathering processes and their net impact on pCO 2 . Calculations found that approximately 80% of SO 4 2- in mainstem samples derived from sulfide oxidation with the remainder from evaporite dissolution. Moreover, 34 S/ 32 S ratios, 13 C/ 12 C ratios of dissolved IC, and sulfur X-ray absorption spectra of mainstem, secondary channel, and floodplain pore fluid and sediment samples revealed modest degrees of microbial sulfate reduction within the floodplain. Weathering fluxes of ALK and IC result in lower values of pCO 2 over timescales shorter than carbonate compensation (~10 4 yr) and, for mainstem samples, higher values of pCO 2 over timescales longer than carbonate compensation but shorter than the residence time of marine (~10 7 yr). Furthermore, the absolute concentrations of and Mg 2+ in the Koyukuk River, as well as the ratios of SO 4 2- and Mg 2+ to other dissolved weathering products, have increased over the past 50 years. Through analogy to similar trends in the Yukon River, we interpret these changes as reflecting enhanced sulfide oxidation due to ongoing exposure of previously frozen sediment and changes in the contributions of shallow and deep flow paths to the active channel. Overall, these findings confirm that sulfide oxidation is a substantial outcome of permafrost degradation and that the sulfur cycle responds to permafrost thaw with a timescale-dependent feedback on warming.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2006

Flora: A Proposed Hyperspectral Mission

In early 2004, one of the authors (Stephen Ungar, NASA GSFC) presented a mission concept called "Spectrasat" at the AVIRIS Workshop in Pasadena, CA. This mission concept grew out of the lessons learned from the Earth Observing-One (EO-1) Hyperion Imaging Spectrometer and was structured to more effectively accomplish the types of studies conducted with Hyperion. The Spectrasat concept represented an evolution of the technologies and operation strategies employed on EO-I. The Spectrasat concept had been preceded by two community-based missions proposed by Susan Ustin, UC Davis and Robert Green, NASA JPL. As a result of community participation, starting at this AVIRIS Workshop, the Spectrasat proposal evolved into the Flora concept which now represents the combined visions of Gregory Asner (Carnegie Institute), Stephen Ungar, Robert Green and Robert Knox, NASA GSFC. Flora is a proposed imaging spectrometer mission, designed to address global carbon cycle science issues. This mission centers on measuring ecological disturbance for purposes of ascertaining changes in global carbon stocks and draws heavily on experience gained through AVIRIS airborne flights and Hyperion space born flights. The observing strategy exploits the improved ability of imaging spectrometers, as compared with multi-spectral observing systems, to identify vegetation functional groups, detect ecosystem response to disturbance and assess the related discovery. Flora will be placed in a sun synchronous orbit, with a 45 meter pixel size, a 90 km swath width and a 31 day repeat cycle. It covers the spectral range from 0.4 to 2.5 micrometers with a spectral sampling interval of 10 nm. These specifications meet the needs of the Flora science team under the leadership of Gregory Asner. Robert Green, has introduced a spectrometer design for Flora which is expected to have a SNR of 600: 1 in the VNIR and 450: 1 in the SWIR. The mission team at NASA GSFC is designing an Intelligent Payload Module (IPM) designed to effectively reduce the volume of data required to be transmitted down to the ground. This paper discusses mission science objectives, describes the mission concept and presents the current status of possible funding opportunities leading to realization of the mission.

Ungar, Stephen↗
DOE OSTI2020

Metabolic Constraints of Organic Matter Mineralization and Metal Cycling

Floodplains are poorly understood and dynamic components of the global carbon cycle that not are well represented in Earth system models. Further, they have a dominant influence on the cycling of important metals within critical transport conduits between surface waters and groundwater. The physical characteristics of floodplains make the hydrology and associated coupled biology and geochemistry particularly responsive to ongoing and impending changes in climate, river management, and land development

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2012

Characterizing 3D Vegetation Structure from Space: Mission Requirements

Human and natural forces are rapidly modifying the global distribution and structure of terrestrial ecosystems on which all of life depends, altering the global carbon cycle, affecting our climate now and for the foreseeable future, causing steep reductions in species diversity, and endangering Earth s sustainability. To understand changes and trends in terrestrial ecosystems and their functioning as carbon sources and sinks, and to characterize the impact of their changes on climate, habitat and biodiversity, new space assets are urgently needed to produce high spatial resolution global maps of the three-dimensional (3D) structure of vegetation, its biomass above ground, the carbon stored within and the implications for atmospheric green house gas concentrations and climate. These needs were articulated in a 2007 National Research Council (NRC) report (NRC, 2007) recommending a new satellite mission, DESDynI, carrying an L-band Polarized Synthetic Aperture Radar (Pol-SAR) and a multi-beam lidar (Light RAnging And Detection) operating at 1064 nm. The objectives of this paper are to articulate the importance of these new, multi-year, 3D vegetation structure and biomass measurements, to briefly review the feasibility of radar and lidar remote sensing technology to meet these requirements, to define the data products and measurement requirements, and to consider implications of mission durations. The paper addresses these objectives by synthesizing research results and other input from a broad community of terrestrial ecology, carbon cycle, and remote sensing scientists and working groups. We conclude that: (1) current global biomass and 3-D vegetation structure information is unsuitable for both science and management and policy. The only existing global datasets of biomass are approximations based on combining land cover type and representative carbon values, instead of measurements of actual biomass. Current measurement attempts based on radar and multispectral data have low explanatory power outside low biomass areas. There is no current capability for repeatable disturbance and regrowth estimates. (2) The science and policy needs for information on vegetation 3D structure can be successfully addressed by a mission capable of producing (i) a first global inventory of forest biomass with a spatial resolution 1km or finer and unprecedented accuracy (ii) annual global disturbance maps at a spatial resolution of 1 ha with subsequent biomass accumulation rates at resolutions of 1km or finer, and (iii) transects of vertical and horizontal forest structure with 30 m along-transect measurements globally at 25 m spatial resolution, essential for habitat characterization. We also show from the literature that lidar profile samples together with wall-to53 wall L-band quad-pol-SAR imagery and ecosystem dynamics models can work together to satisfy these vegetation 3D structure and biomass measurement requirements. Finally we argue that the technology readiness levels of combined pol-SAR and lidar instruments are adequate for space flight. Remaining to be worked out, are the particulars of a lidar/pol-SAR mission design that is feasible and at a minimum satisfies the information and measurement requirement articulated herein.

Hall, Forrest G.↗
DOE OSTI2026

Accelerated Carbon and Water Cycles in the Amazon and Congo Basins Revealed From TRENDY Models and Remote Sensing Products

Tropical forests play a vital role in the global carbon cycle and land–atmosphere interactions. Estimating tropical forest carbon–water dynamics is challenging due to observational and modeling uncertainties. This study leverages the “Trends and drivers of the regional scale terrestrial sources and sinks of carbon dioxide” (TRENDY) project models and satellite observations to assess changes (2003–2021) in vegetation carbon, gross primary production (GPP), evapotranspiration (ET), and net biosphere production (NBP) in the Amazon and Congo. Atmospheric CO 2 , climate variability, and land use and land cover changes constrain these variables between 1700 and 2021 with the overall increasing trends of carbon stock and fluxes. The models overestimate vegetation carbon and GPP, while ET and NBP are consistent with observations. Fire-activated models predict lower values for vegetation carbon and GPP, ET, and NBP, aligning more closely with observations. The higher ET from fire-activated models may result from enhanced soil evaporation due to increased canopy openings. Fire-inactivated models could well estimate the magnitudes of NBP. The high vegetation carbon in nitrogen-enabled models points to simulation uncertainties and imbalance in model numbers regarding the nitrogen cycle. Although the nitrogen cycle enhances water use efficiency in both the Amazon and Congo, the models show a higher sensitivity to the nitrogen cycle in the Congo. This study highlights the challenges in accurately representing tropical biogeochemical cycles and the values of satellite products in model evaluations, underscoring the need for standard modeling protocols that address biogeochemical components (e.g., nutrient cycles) to better resolve process-based representations.

Shi, Mingjie [Pacific Northwest National Laborator↗
DOE OSTI2020

Scaling carbon fluxes from eddy covariance sites to globe: synthesis and evaluation of the FLUXCOM approach

FLUXNET comprises globally distributed eddy-covariance-based estimates of carbon fluxes between the biosphere and the atmosphere. Since eddy covariance flux towers have a relatively small footprint and are distributed unevenly across the world, upscaling the observations is necessary to obtain global-scale estimates of biosphere–atmosphere exchange. Based on cross-consistency checks with atmospheric inversions, sun-induced fluorescence (SIF) and dynamic global vegetation models (DGVMs), here we provide a systematic assessment of the latest upscaling efforts for gross primary production (GPP) and net ecosystem exchange (NEE) of the FLUXCOM initiative, where different machine learning methods, forcing data sets and sets of predictor variables were employed. Spatial patterns of mean GPP are consistent across FLUXCOM and DGVM ensembles (R 2 >0.94 at 1° spatial resolution) while the majority of DGVMs show, for 70 % of the land surface, values outside the FLUXCOM range. Global mean GPP magnitudes for 2008–2010 from FLUXCOM members vary within 106 and 130 PgC yr -1 with the largest uncertainty in the tropics. Seasonal variations in independent SIF estimates agree better with FLUXCOM GPP (mean global pixel-wise R 2 ~0.75) than with GPP from DGVMs (mean global pixel-wise R 2 ~0.6). Seasonal variations in FLUXCOM NEE show good consistency with atmospheric inversion-based net land carbon fluxes, particularly for temperate and boreal regions (R 2 >0.92). Interannual variability of global NEE in FLUXCOM is underestimated compared to inversions and DGVMs. The FLUXCOM version which also uses meteorological inputs shows a strong co-variation in interannual patterns with inversions (R 2 =0.87 for 2001–2010). Mean regional NEE from FLUXCOM shows larger uptake than inversion and DGVM-based estimates, particularly in the tropics with discrepancies of up to several hundred grammes of carbon per square metre per year. These discrepancies can only partly be reconciled by carbon loss pathways that are implicit in inversions but not captured by the flux tower measurements such as carbon emissions from fires and water bodies. We hypothesize that a combination of systematic biases in the underlying eddy covariance data, in particular in tall tropical forests, and a lack of site history effects on NEE in FLUXCOM are likely responsible for the too strong tropical carbon sink estimated by FLUXCOM. Furthermore, as FLUXCOM does not account for CO 2 fertilization effects, carbon flux trends are not realistic. Overall, current FLUXCOM estimates of mean annual and seasonal cycles of GPP as well as seasonal NEE variations provide useful constraints of global carbon cycling, while interannual variability patterns from FLUXCOM are valuable but require cautious interpretation. Exploring the diversity of Earth observation data and of machine learning concepts along with improved quality and quantity of flux tower measurements will facilitate further improvements of the FLUXCOM approach overall.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

A framework for testing soil carbon dynamics post land-use transition in a multisector dynamics model

Soil carbon plays a crucial role in the global carbon cycle. Changes in land use can determine whether carbon is stored or is emitted into the atmosphere as carbon dioxide, which has broad implications for the human and Earth systems. These feedbacks to the carbon cycle and their socio-economic drivers are modelled by many global multisector dynamics models to project future possibilities for the human-Earth system. One notable model of this class is the Global Change Analysis Model (GCAM), which uses a simplified process to model soil organic carbon (SOC) content after land-use transition across 384 land units. While the current GCAM soil carbon framework is based on scientific principles, it has not been tested against experimental data. This work examines rates of SOC change from GCAM input data. Specifically, first order rate constants derived from model inputs were compared to values from two syntheses to assess GCAM’s accuracy. Welch’s t-tests and linear models were used to determine if rate constants were consistent across all tested geographical areas and land-use transition types. While we found that there was general agreement on the direction and magnitude (i.e., rate) of SOC change, the rate constant derived from GCAM and empirical values differed strongly in a subset of specific instances. These results indicate that GCAM’s current SOC dynamics during land use transition successfully capture broad patterns of change in this critical carbon pool, but should be interpreted with caution at finer spatial scales. One potential cause of these discrepancies is our highly aggregated variable, soil timescale, which could be made more granular to improve accuracy. When using economically rooted multisector dynamics models, such as GCAM, it is critical to understand such model limitations for representing specific Earth system processes.

carbon↗
DOE OSTI2021

Reducing Model Uncertainty of Climate Change Impacts on High Latitude Carbon Assimilation

The Arctic Boreal Region (ABR) has a large impact on global vegetation-atmosphere interactions and is experiencing markedly greater warming than the rest of the planet, a trend that is projected to continue with anticipated future emissions of CO 2 . The ABR is a significant source of uncertainty in estimates of carbon uptake in terrestrial biosphere models (TBMs) such that reducing this uncertainty is critical for more accurately estimating global carbon cycling and understanding the response of the region to global change. Process representation and parameterization associated with gross primary productivity (GPP) drives a large amount of this model uncertainty, particularly within the next 50 years, where the response of existing vegetation to climate change will dominate estimates of GPP for the region. Furthermore, we review our current understanding and model representation of GPP in northern latitudes, focusing on vegetation composition, phenology and physiology, and consider how climate change alters these three components. We highlight challenges in the ABR for predicting GPP, but also focus on the unique opportunities for advancing knowledge and model representation, particularly through the combination of remote sensing and traditional boots-on-the-ground science.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1992

Ocean-atmospheric linkages

This chapter focuses on the role of the ocean in the global carbon cycle on the time scale of decades to centuries. The input rate of CO2 to the atmosphere due to fossil fuel burning and deforestation has continued to increase over the last century. To balance the global carbon budget, a sink is required whose magnitude is changing on similar time scales. We have sought to identify aspects of the ocean system that are capable of responding on decadal time scales, to examine our present ability to model such changes, and to pinpoint ways in which this ability could be improved. Many other important aspects of the ocean's role in global change are not addressed, including the importance of oceanic heat transport and thermal inertia to the climate system, biogeochemical cycling of elements other than carbon, and the importance of the ocean as a source or sink of trace gases.

Rintoul, Stephen R.↗
DOE OSTI2024

Virus ecology and 7‐year temporal dynamics across a permafrost thaw gradient

Abstract Soil microorganisms are pivotal in the global carbon cycle, but the viruses that affect them and their impact on ecosystems are less understood. In this study, we explored the diversity, dynamics, and ecology of soil viruses through 379 metagenomes collected annually from 2010 to 2017. These samples spanned the seasonally thawed active layer of a permafrost thaw gradient, which included palsa, bog, and fen habitats. We identified 5051 virus operational taxonomic units (vOTUs), doubling the known viruses for this site. These vOTUs were largely ephemeral within habitats, suggesting a turnover at the vOTU level from year to year. While the diversity varied by thaw stage and depth‐related patterns were specific to each habitat, the virus communities did not significantly change over time. The abundance ratios of virus to host at the phylum level did not show consistent trends across the thaw gradient, depth, or time. To assess potential ecosystem impacts, we predicted hosts in silico and found viruses linked to microbial lineages involved in the carbon cycle, such as methanotrophy and methanogenesis. This included the identification of viruses of Candidatus Methanoflorens, a significant global methane contributor. We also detected a variety of potential auxiliary metabolic genes, including 24 carbon‐degrading glycoside hydrolases, six of which are uniquely terrestrial. In conclusion, these long‐term observations enhance our understanding of soil viruses in the context of climate‐relevant processes and provide opportunities to explore their role in terrestrial carbon cycling.

Microbiology↗
DOE OSTI2023

Investigating permafrost carbon dynamics in Alaska with artificial intelligence

Abstract Positive feedbacks between permafrost degradation and the release of soil carbon into the atmosphere impact land–atmosphere interactions, disrupt the global carbon cycle, and accelerate climate change. The widespread distribution of thawing permafrost is causing a cascade of geophysical and biochemical disturbances with global impacts. Currently, few earth system models account for permafrost carbon feedback (PCF) mechanisms. This research study integrates artificial intelligence (AI) tools and information derived from field-scale surveys across the tundra and boreal landscapes in Alaska. We identify and interpret the permafrost carbon cycling links and feedback sensitivities with GeoCryoAI, a hybridized multimodal deep learning (DL) architecture of stacked convolutionally layered, memory-encoded recurrent neural networks (NN). This framework integratesin-situmeasurements and flux tower observations for teacher forcing and model training. Preliminary experiments to quantify, validate, and forecast permafrost degradation and carbon efflux across Alaska demonstrate the fidelity of this data-driven architecture. More specifically, GeoCryoAI logs the ecological memory and effectively learns covariate dynamics while demonstrating an aptitude to simulate and forecast PCF dynamics—active layer thickness (ALT), carbon dioxide flux (CO 2 ), and methane flux (CH 4 )—with high precision and minimal loss (i.e. ALT RMSE : 1.327 cm [1969–2022]; CO 2 RMSE : 0.697µmolCO 2 m −2 s −1 [2003–2021]; CH 4 RMSE : 0.715 nmolCH 4 m −2 s −1 [2011–2022]). ALT variability is a sensitive harbinger of change, a unique signal characterizing the PCF, and our model is the first characterization of these dynamics across space and time.

Environmental Sciences & Ecology↗
DOE OSTI2021

Development of energetic and enzymatic limitations on microbial carbon cycling in soils

Soil organic carbon (SOC) constitutes an important reservoir in the global carbon cycle that is vulnerable to transformation and loss from land use and climate change. Anoxic conditions protect SOC from microbial degradation through limiting the energetics of respiration and inhibiting extracellular oxidative enzymes. Given growing evidence of prevalent anaerobic microsites in upland soils, we designed an experiment testing the development of dissolved organic carbon (DOC) signatures of energetic and enzymatic limitations on microbial carbon utilization across simulated soil aggregates or peds. Reactors comprised a soil column “aggregate” underlying an advective “macropore” channel. Soils received downward diffusive inputs of aerated porewater media with added nitrate, sulfate, or no amendment—where native ferrihydrite served as dominant anaerobic terminal electron acceptor (TEA). After 40 days, added nitrate resulted in highest bulk respiration and DOC production while sulfate did not differ from the control. Nominal oxidation state of carbon (NOSC) was higher (more favorable) with added TEAs at soil surfaces and decreased with depth, while NOSC in the non-amended soil remained lower and constant with depth. DOC generally increased with depth, which along with decreasing NOSC values indicates joint electron-donor and acceptor control over respiration energetics. Of all organic compound classes, only the relative abundance of phenolics increased between 0 and 0.5 cm depth, which aligns with the oxic-anoxic transition and suggests oxidative enzyme inhibition. Furthermore, our results suggest that oxygen limitation within upland soil aggregates may preserve SOC via both energetic and enzymatic C protection mechanisms, which are vulnerable upon exposure to oxygen.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2003

Strangelove Ocean and Deposition of Unusual Shallow-Water Carbonates After the End-Permian Mass Extinction

The severe mass extinction of marine and terrestrial organisms at the end of the Permian Period (approx. 251 Ma) was accompanied by a rapid negative excursion of approx. 3 to 4 per mil in the carbon-isotope ratio of the global surface oceans and atmosphere that persisted for some 500,000 into the Early Triassic. Simulations with an ocean-atmosphere/carbon-cycle model suggest that the isotope excursion can be explained by collapse of ocean primary productivity (a Strangelove Ocean) and changes in the delivery and cycling of carbon in the ocean and on land. Model results also suggest that perturbations of the global carbon cycle resulting from the extinctions led to short-term fluctuations in atmospheric pCO2 and ocean carbonate deposition, and to a long-term (>1 Ma) decrease in sedimentary burial of organic carbon in the Triassic. Deposition of calcium carbonate is a major sink of river-derived ocean alkalinity and for CO2 from the ocean/atmosphere system. The end of the Permian was marked by extinction of most calcium carbonate secreting organisms. Therefore, the reduction of carbonate accumulation made the oceans vulnerable to a build-up of alkalinity and related fluctuations in atmospheric CO2. Our model results suggest that an increase in ocean carbonate-ion concentration should cause increased carbonate accumulation rates in shallow-water settings. After the end-Permian extinctions, early Triassic shallow-water sediments show an abundance of abiogenic and microbial carbonates that removed CaCO3 from the ocean and may have prevented a full 'ocean-alkalinity crisis' from developing.

Rampino, Michael R.↗
NASA NTRS2001

Towards the Development of a Global Precipitation Measurement (GPM) Mission Concept

The scientific success of the Tropical Rainfall Measuring Mission (TRMM) and additional satellite-focused precipitation retrieval projects have paved the way for a more advanced global precipitation mission. A comprehensive global measuring strategy is currently under study - Global Precipitation Measurement (GPM). The GPM study could ultimately lead to the development of the Global Precipitation Mission. The intent of GPM is to address looming scientific questions arising in the context of global climate-water cycle interactions, hydrometeorology, weather prediction and prediction of freshwater resources, the global carbon cycle, and biogeochemical cycles. This talk overviews the status and scientific agenda of this proposed mission currently planned for launch in the 2007-2008 time frame. GPM is planning to expand the scope of precipitation measurement through the use of a constellation of 6-10 satellites, one of which will be an advanced TRMM-like "core" satellite carry dual-frequency Ku-Ka band radar and a microwave radiometer (e.g. TMI-like). The other constellation members will likely include new lightweight satellites and co-existing operational/research satellites carrying passive microwave radiometers. The goal behind the constellation is to achieve no worse than 3-hour sampling at any spot on the globe. The constellation's orbit architecture will consist of a mix of sun-synchronous and non-su n -synchronous satellites with the "core" satellite providing measurement of cloud-precipitation microphysical processes plus "training calibrating" information to be used with the retrieval algorithms for the constellation satellite measurements. The GPM is organized internationally, currently involving a partnership between NASA in the US, NASDA in Japan, and ESA in Europe (representing the European community). The program is expected to involve additional international partners, other federal agencies, and a diverse collection of scientists from academia, government, and the private sector.

Shepherd, Marshall↗
NASA NTRS1988

Coastal Zone Color Scanner

The Coastal Zone Color Scanner (CZCS) spacecraft ocean color instrument is capable of measuring and mapping global ocean surface chlorophyll concentration. It is a scanning radiometer with multiband capability. With new electronics and some mechanical, and optical re-work, it probably can be made flight worthy. Some additional components of a second flight model are also available. An engineering study and further tests are necessary to determine exactly what effort is required to properly prepare the instrument for spaceflight and the nature of interfaces to prospective spacecraft. The CZCS provides operational instrument capability for monitoring of ocean productivity and currents. It could be a simple, low cost alternative to developing new instruments for ocean color imaging. Researchers have determined that with global ocean color data they can: specify quantitatively the role of oceans in the global carbon cycle and other major biogeochemical cycles; determine the magnitude and variability of annual primary production by marine phytoplankton on a global scale; understand the fate of fluvial nutrients and their possible affect on carbon budgets; elucidate the coupling mechanism between upwelling and large scale patterns in ocean basins; answer questions concerning the large scale distribution and timing of spring blooms in the global ocean; acquire a better understanding of the processes associated with mixing along the edge of eddies, coastal currents, western boundary currents, etc., and acquire global data on marine optical properties.

Johnson, B.↗
DOE OSTI2023

Long-Term Changes in Concentration and Yield of Riverine Dissolved Silicon From the Poles to the Tropics

Riverine exports of silicon (Si) influence global carbon cycling through the growth of marine diatoms, which account for ~25% of global primary production. Climate change will likely alter river Si exports in biome-specific ways due to interacting shifts in chemical weathering rates, hydrologic connectivity, and metabolic processes in aquatic and terrestrial systems. Nonetheless, factors driving long-term changes in Si exports remain unexplored at local, regional, and global scales. We evaluated how concentrations and yields of dissolved Si (DSi) changed over the last several decades of rapid climate warming using long-term data sets from 60 rivers and streams spanning the globe (e.g., Antarctic, tropical, temperate, boreal, alpine, Arctic systems). We show that widespread changes in river DSi concentration and yield have occurred, with the most substantial shifts occurring in alpine and polar regions. The magnitude and direction of trends varied within and among biomes, were most strongly associated with differences in land cover, and were often independent of changes in river discharge. These findings indicate that there are likely diverse mechanisms driving change in river Si biogeochemistry that span the land-water interface, which may include glacial melt, changes in terrestrial vegetation, and river productivity. Finally, trends were often stronger in months outside of the growing season, particularly in temperate and boreal systems, demonstrating a potentially important role of shifting seasonality for the flux of Si from rivers. Our results have implications for the timing and magnitude of silica processing in rivers and its delivery to global oceans.

54 ENVIRONMENTAL SCIENCES↗