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At least 73 records · Page 4

Microwave-enhanced methane cracking for clean hydrogen production in shale rocks

Here, steam methane reforming (SMR) generates about 95% of hydrogen (H 2 ) in the U.S. using natural gas as a main feedstock. However, this technology also generates a large amount of carbon dioxide (CO 2 ), a major greenhouse gas causing global warming. Carbon capture and storage (CCS) technique is required, but the cost and safety of storing CO 2 underground are a concern. Here we propose a new approach using microwave/electromagnetic irradiation to produce clean hydrogen from unrecovered hydrocarbons within petroleum reservoirs. Solid carbon or CO 2 produced during this process will be simultaneously sequestrated underground without involving CCS. In this paper, we perform a series of experiments to investigate the in-situ hydrogen production from shale gas (methane) conversion by passing a methane stream through a packed shale rock sample heated by microwave. We found that methane conversion was significantly enhanced in the presence of Fe and Fe 3 O 4 particles as catalysts, with a conversion of 40.5% and 100% at reaction temperature of 500 °C and 600 °C, respectively. Methane conversion is promoted at a lower reaction temperature by the catalytic effect of minerals in shale. Additionally, the influences of catalysts, shale rock, and methane flow rate are characterized.

08 HYDROGEN↗

Comparative Life Cycle Evaluation of the Global Warming Potential (GWP) Impacts of Renewable Natural Gas Production Pathways

Renewable Natural Gas (RNG) sources are being considered in future energy strategy discussions as potential replacements for fossil natural gas (FNG). While today’s supply of RNG resources is insufficient to meet U.S. demands, there is significant interest in its viability to supplement and decarbonize the natural gas supply. However, the resources that compare the life cycle global warming potential (GWP) of various RNG production pathways are lacking and focus mostly on a singular pathway. This effort is an attempt to close this gap and provide a comparison between the life cycle GWP of three major RNG pathways and the FNG pathway. The three RNG pathways evaluated are Anaerobic Digestion (AD), Thermal Gasification (TG), and Power-to-Gas (P2G) using various feedstocks. The functional unit is 1MJ of compressed RNG ready for injection into the natural gas transmission network. The results show that RNG production is not always carbon neutral or negative. Depending on the pathway the GWP impact of RNG production can range from -229 to 27 g CO 2 e/MJ compressed RNG, with AD of animal manure and AD of municipal solid waste being the least and the most impactful pathways, respectively, compared to the 10.1 g CO 2 e/MJ impact for compressed FNG.

54 ENVIRONMENTAL SCIENCES↗

Temperature Trends in the Northwestern Tibetan Plateau Constrained by Ice Core Water Isotopes Over the Past 7,000 Years

Abstract The reasons for the Holocene temperature conundrum, known as the inconsistency between the reconstructed cooling and the inferred warming simulations during the Holocene, remain unclear. Temperature reconstructions from the Tibetan Plateau (TP) provide important insights for understanding the Holocene temperature conundrum due to enhanced sensitivity to climate at high altitudes. Given the significant positive correlation between air temperature and δ 18 O in precipitation over the northern TP, the stable isotopic records of ice cores recovered from this area are widely used for paleotemperature reconstruction. Here we present a new high‐resolution δ 18 O record from the Chongce ice cores to bedrock, dated back to 7 ka BP by the accelerator mass spectrometry (AMS) 14 C dating technique. Our reconstructed temperature record shows a long‐term warming trend until ~2 ka BP, followed by an abrupt change to a relatively cool period until the start of the industrial‐era warming. This record challenges the widely recognized Holocene reconstruction from the neighboring Guliya ice core. It is also different from many previous temperature reconstructions, most of which have summer biases and show a long‐term cooling trend over the past two millennia. In addition, our record shows that temperatures during the recent decades are almost the highest during the past 7 ka BP, highlighting the unusual warming forced by anthropogenic greenhouse gases.

Pang, Hongxi↗

Is turning down the sun a good proxy for stratospheric sulfate geoengineering?

Deliberately blocking out a small portion of the incoming solar radiation would cool the climate. One such approach would be injecting SO2 into the stratosphere, which would produce sulfate aerosols that would remain in the atmosphere for 1–3 years, reflecting part of the incoming shortwave radiation. The cooling produced by the aerosols can offset the warming produced by increased greenhouse gas (GHG) concentrations, but it would also affect the climate differently, leading to residual differences compared to a climate not affected by either. Many climate model simulations of geoengineering have used a uniform reduction of the incoming solar radiation as a proxy for stratospheric aerosols, both because many models are not designed to adequately capture relevant stratospheric aerosol processes, and because a solar reduction has often been assumed to capture the most important differences between how stratospheric aerosols and GHG would affect the climate. Here we show that dimming the sun does not produce the same surface climate effects as simulating aerosols in the stratosphere. By more closely matching the spatial pattern of solar reduction to that of the aerosols, some improvements in this idealized representation are possible, with further improvements if the stratospheric heating produced by the aerosols is included. This is relevant both for our understanding of the physical mechanisms driving the changes observed in stratospheric-sulfate geoengineering simulations, and in terms of the relevance of impact assessments that use a uniform solar dimming.

Visioni, Daniele↗

Organosulfur Aerosols Likely Carried Sulfur MIF Signatures in the Early Earth’s Atmosphere

Signatures of mass-independent fractionation (MIF) of sulfur in Archean sulfide and sulfate minerals are widely thought to record an anoxic early Earth’s atmosphere. While experiments of ultraviolet irradiation of SO 2 produce significant sulfur mass-independent fractionation (S-MIF) in reaction products (elemental sulfur and residual sulfur dioxide), they have not been able to reproduce the isotope patterns, in particular Δ 36 S/Δ 33 S ratios, observed in the geologic rock record. Studies that focused on organic sulfur gases and hazes in Archean did not report organosulfur aerosol photoproducts as major contributors to Archean S-MIF chemistry. Here we show, for the first time, that photochemical reactions of SO 2 in the presence of gaseous hydrocarbons (CH 4 , C 2 H 2 , and C 2 H 4 ) produce haze-like organosulfur aerosols bearing S-MIF with variable Δ 36 S/Δ 33 S ratios. The isotope trends for the organosulfur photoproducts produced in our experiments suggest that in addition to elemental sulfur, organosulfur compounds—in particular methanesulfonic acid—are a key component of S-MIF signals from the atmosphere to the ocean and sediments with possible links to Archean atmosphere warmed by a methane greenhouse.

54 ENVIRONMENTAL SCIENCES↗

Earth's Energy Imbalance More Than Doubled in Recent Decades

Abstract Global warming results from anthropogenic greenhouse gas emissions which upset the delicate balance between the incoming sunlight, and the reflected and emitted radiation from Earth. The imbalance leads to energy accumulation in the atmosphere, oceans and land, and melting of the cryosphere, resulting in increasing temperatures, rising sea levels, and more extreme weather around the globe. Despite the fundamental role of the energy imbalance in regulating the climate system, as known to humanity for more than two centuries, our capacity to observe it is rapidly deteriorating as satellites are being decommissioned.

Mauritsen, Thorsten [Department of Meteorology and↗

Projecting Future Energy Production from Operating Wind Farms in North America. Part II: Statistical Downscaling

Abstract Capacity factors (CFs) derived from daily expected power at 22 operating wind farms in different regions of North America are used as predictands to train statistical downscaling algorithms using output from ERA5. The statistical downscaling models are then used to make CF projections for a suite of CMIP6 Earth System Models (ESMs). Downscaling is performed using a hybrid statistical approach that employs synoptic types derived using k -means clustering applied to sea level pressure fields with variance corrections applied as a function of the pressure gradient intensity. ESMs exhibit marked variability in terms of the skill with which the frequency of synoptic types and pressure gradients are reproduced relative to ERA5, and that differential skill is used to infer differential credibility in the associated CF projections. Projections of median annual mean CF [P50(CF)] in each 20-yr period from 1980 to 2099 show evidence of declines at most wind farms except in parts of the southern Great Plains, although the magnitude of the changes is strongly dependent on the ESM. For example, P50(CF) in 2080–99 deviate from those in 1980–99 by from −3.1 to +0.2 percentage points in the Northeast. The largest-magnitude declines in P50(CF) ranging from −3.9 to −2 percentage points are projected for the southern West Coast. CF trends exhibit marked seasonality and are strongly linked to changes in the relative intensity of future synoptic patterns, with much less impact from shifts in the occurrence of synoptic types over time. Internal climate modes continue to play a significant role in inducing interannual variability in wind power production, even under high radiative forcing scenarios. Significance Statement We describe how future climate changes may affect wind resources and wind power generation. Near-term changes in projected wind power electricity generation potential at operating wind farms over North America are small, but by the end of the current century electricity production is projected to decrease in many areas but may increase in parts of the southern Great Plains. The amount of change in projected wind power production is a strong function of the Earth system model that is downscaled and also depends on the continued presence of internally forced climate variability. An additional dependence on the amount of greenhouse gas–induced global warming indicates the transition of the energy sector to low-carbon sources may assist in maintaining the abundant U.S. wind resource.

Meteorology & Atmospheric Sciences↗

Sensitivity of surface temperature to oceanic forcing via q-Flux Green’s function experiments. Part III: asymmetric response to warming and cooling

Climate response is often assumed to be linear in climate sensitivity studies. However, by examining the surface temperature (TS) response to pairs of oceanic forcings of equal amplitude but opposite sign in a large set of local q-flux perturbation experiments with CAM5 coupled to a slab, we find strong asymmetry in TS responses to the heating and cooling forcings, indicating a strong nonlinearity intrinsic to the climate system examined. Regardless of where the symmetric forcing is placed, the cooling response to the negative forcing always exceeds the warming to the positive forcing, implying an intrinsic inclination towards cooling of our current climate. Thus, the ongoing global warming induced by increasing greenhouse gases may have already been alleviated by the asymmetric component of the response. The common asymmetry in TS response peaks in high latitudes, especially along sea ice edges, with notable seasonal dependence. Decomposition into different radiative feedbacks through a radiative kernel indicates that the asymmetry in the TS response is realized largely through lapse rate and albedo feedbacks. Further process interference experiments disabling the seasonal cycle and/or sea ice reveal that the asymmetry originates ultimately from the presence of the sea ice component and is further amplified by the seasonal cycle. The fact that a pair of opposite tropical q-flux forcings can excite very similar asymmetric response as a pair placed at 55°S strongly suggests the asymmetric response is a manifestation of an internal mode of the climate model system.

Liu, Fukai↗

Poleward Migration of the Latitude of Maximum Tropical Cyclone Intensity—Forced or Natural?

Abstract Past studies have shown a significant observed poleward trend in the latitude at which tropical cyclones reach their lifetime maximum intensity (LMI), especially in the northwest Pacific basin. Given the brevity of the historical record, it remains difficult to separate the forced trend from internal variability of the climate system. A recently developed tropical cyclone downscaling model is used to downscale the Community Earth System Model, version 2 (CESM2), preindustrial control simulation. It is found that the observed trend in the latitude at which tropical cyclones reach their LMI in the northwest Pacific is very unlikely to be caused by internal variability. The same downscaling model is then used to downscale CESM2 simulations under historical forcing. The resulting trend distribution shows a significant poleward migration of tropical cyclone LMI even after regressing out both natural variability and the part of the forced warming pattern that projects onto natural variability. The results indicate that the observed poleward migration of the latitude at which tropical cyclones reach their LMI in the northwest Pacific basin is likely to be, at least in part, forced. However, the magnitude of the projected poleward trend in climate models can be significantly modulated by the simulated spatial pattern of ocean warming. This highlights how discrepancies between models and observations, with regard to projected changes to the equatorial zonal sea surface temperature gradient under anthropogenic forcing, can lead to large uncertainties in projected changes to the LMI latitude of tropical cyclones. Significance Statement Observations in the northwest Pacific basin show that the latitude at which tropical cyclones are at their most intense has been trending northward in the recent half century. These changes are important since tropical cyclones could bring hazardous weather to coastal areas that are poorly equipped to handle them. Here, we show that natural variations in Earth’s climate are very unlikely to explain the observed poleward trend in the latitude that tropical cyclone reach their maximum intensity. We find that it is much more likely that the observed trend is forced by human-related emissions, though the spatial pattern of warming in response to greenhouse emissions can have significant impacts on the magnitude of the trend.

Lin, Jonathan↗

Investigation of the effects of turbulence modeling on the prediction of compression-ignition combustion unsteadiness

Adverse effects of global warming due to the greenhouse gas emissions is changing the actual paradigm for the use energy resources. In the absence of a mid-term solution for reducing these emissions in transportation, internal combustion (IC) engines are going to coexist in the social spheres in the foreseeable future. Therefore, the study of other IC engine-related problems remains relevant to ensuring the health of the society. In this investigation, a numerical methodology for comprehensive understanding of Noise, Vibration and Harshness in internal combustion engines is proposed. Due to its inherent complexity and lack of awareness, the main objective is to evaluate the impact of the turbulence modeling framework on the in-cylinder acoustic field recreation. Modal decomposition methods have been applied to isolate the coherent flow structures and to analyze how they change with the turbulence approach. Results demonstrate that the choice of the turbulence model is a critical aspect for noise modeling. Unsteady Reynolds-Averaged Navier-Stokes schemes predict a raw estimation of the internal acoustic field with the added value of being computationally less expensive. However, the use of more complex turbulence approaches such us large eddy simulation offers an accurate prediction of the acoustic structures and their cyclic dispersion.

Broatch, A.↗

ELECTRIFICATION OF A HEAVY-DUTY OFF-ROAD MATERIAL HANDLER: ENERGY SAVINGS AND EMISSION REDUCTIONS

Federal regulations are driving the adoption of electrification technologies to reduce carbon dioxide equivalent (CO2e) emissions, a metric that quantifies the global warming potential of various greenhouse gases in terms of carbon dioxide (CO2). Although no specific CO2 regulations exist for heavy-duty off-road machines, future reductions are likely, given stricter emissions standards for on-road vehicles. The heavy-duty off-road sector offers significant fuel-saving potential, as its focus has traditionally been on reliability and performance rather than fuel efficiency. This dissertation examines fuel and CO2e savings opportunities on a heavy-duty off-road material handler, the Pettibone Cary-Lift 204i, from stock configuration to simple modifications to a complete teardown and reconfiguration of the machine with a plug-in series hybrid architecture using electrified hydraulics. The study begins by modeling the baseline machine’s fuel and energy consumption, calibrating with experimental data from custom operating cycles. An energy analysis identifies key areas for fuel savings. Two simple powertrain modifications result in a combined 16.2% fuel savings. Next, a Pugh-style analysis narrows a list of electrified architectures, leading to high-fidelity models that evaluate total lifetime CO2e and costs. Higher electrification levels reduce CO2e emissions but increase costs, and electricity grid emissions significantly impact CO2e for plug-in architectures. A plug-in series hybrid is chosen for the project. In its base control form, 49% fuel and 29% CO2e savings are expected from the plug-in series hybrid compared to the baseline machine. Further savings are pursued through regenerative braking (6.3%) and load-following hydraulic control (17.8%), totaling 24.1% fuel savings, and leading to a total of 61% fuel and 41% CO2e savings compared to the baseline. Battery chemistries and charging strategies are also analyzed for cost and CO2e impacts, finding LFP batteries as superior due to longevity, and overnight level 2 charging usually at a lower cost but resulting in higher emissions than opportunity DC fast-charging (DCFC). DCFC emissions are highly dependent on grid emissions, and DCFC cost is highly dependent on grid demand charges. Finally, artificial intelligence is applied to operating cycle recognition. Neural network accuracy ranges from 81% to 99%, with applications to worksite efficiency and safety improvements.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Microbial dormancy and its impacts on northern temperate and boreal terrestrial ecosystem carbon budget

A large amount of soil carbon in northern temperate and boreal regions could be emitted as greenhouse gases in a warming future. However, lacking detailed microbial processes such as microbial dormancy in current biogeochemistry models might have biased the quantification of the regional carbon dynamics. Here the effect of microbial dormancy was incorporated into a biogeochemistry model to improve the quantification for the last century and this century. Compared with the previous model without considering the microbial dormancy, the new model estimated the regional soils stored 75.9 Pg more C in the terrestrial ecosystems during the last century and will store 50.4 and 125.2 Pg more C under the RCP8.5 and RCP2.6 scenarios, respectively, in this century. This study highlights the importance of the representation of microbial dormancy in earth system models to adequately quantify the carbon dynamics in the northern temperate and boreal natural terrestrial ecosystems.

54 ENVIRONMENTAL SCIENCES↗

Humate's Role in Terrestrial Greenhouse Gas and Water Reduction

Carbon dioxide (CO 2 ) is considered the sole culprit for global warming; however, nitrous oxide (N 2 O), a greenhouse gas (GHG) with approximately 300 times more global warming potential than CO 2 , accounts for 6% of the GHG emissions in the United States. Seventy five percent of N 2 O emissions come from synthetic nitrogen (N) fertilizer usage in the agriculture sector primarily due to excess fertilization. Numerous studies have shown that changes in soil management practices, specifically optimizing N fertilizer use and amending soil with organic and humate materials can reverse soil damage and improve a farmer's or land reclamation company's balance sheet. Soil restoration is internationally recognized as one of the lowest cost GHG abatement opportunities available. Profitability improves in two ways: (1) lower operating costs resulting from lower input costs (water and fertilizer); and (2) increased revenue by participation in emerging GHG offsets markets, and water quality trading markets.

54 ENVIRONMENTAL SCIENCES↗

Porewater constituents inhibit microbially mediated greenhouse gas production (GHG) and regulate the response of soil organic matter decomposition to warming in anoxic peat from a Sphagnum -dominated bog

Abstract Northern peatlands store approximately one-third of terrestrial soil carbon. Climate warming is expected to stimulate the microbially mediated degradation of peat soil organic matter (SOM), leading to increasing greenhouse gas (GHG; carbon dioxide, CO2; methane, CH4) production and emission. Porewater dissolved organic matter (DOM) plays a key role in SOM decomposition; however, the mechanisms controlling SOM decomposition and its response to warming remain unclear. The temperature dependence of GHG production and microbial community dynamics were investigated in anoxic peat from a Sphagnum-dominated peatland. In this study, peat decomposition, which was quantified by GHG production and carbon substrate utilization is limited by terminal electron acceptors (TEA) and DOM, and these controls of microbially mediated SOM degradation are temperature-dependent. Elevated temperature led to a slight decrease in microbial diversity, and stimulated the growth of specific methanotrophic and syntrophic taxa. These results confirm that DOM is a major driver of decomposition in peatland soils contains inhibitory compounds, but the inhibitory effect is alleviated by warming.

Song, Tianze (ORCID:0000000282060247)↗

Emergence of decadal linkage between Western Australian coast and Western–central tropical Pacific

Abstract The impact of interbasin linkage on the weather/climate and ecosystems is significantly broader and profounder than that of only appearing in an individual basin. Here, we reveal that a decadal linkage of sea surface temperature (SST) has emerged between western Australian coast and western–central tropical Pacific since 1985, associated with continuous intensification of decadal variabilities (8–16 years). The rapid SST changes in both tropical Indian Ocean and Indo-Pacific warm pool in association to greenhouse gases and volcanoes are emerging factors resulting in enhanced decadal co-variabilities between these two regions since 1985. These SST changes induce enhanced convection variability over the Maritime Continent, leading to stronger easterlies in the western–central tropical Pacific during the warm phase off western Australian coast. The above changes bring about cooling in the western–central tropical Pacific and strengthened Leeuwin Current and anomalous cyclonic wind off western Australian coast, and ultimately resulting in enhanced coupling between these two regions. Our results suggest that enhanced decadal interbasin connections can offer further understanding of decadal changes under future warmer conditions.

Science & Technology - Other Topics↗

Atmospheric methane removal: a research agenda

Atmospheric methane removal (e.g. in situ methane oxidation to carbon dioxide) may be needed to offset continued methane release and limit the global warming contribution of this potent greenhouse gas. Because mitigating most anthropogenic emissions of methane is uncertain this century, and sudden methane releases from the Arctic or elsewhere cannot be excluded, technologies for methane removal or oxidation may be required. Carbon dioxide removal has an increasingly well-established research agenda and technological foundation. No similar framework exists for methane removal. We believe that a research agenda for negative methane emissions—‘removal' or atmospheric methane oxidation—is needed. We outline some considerations for such an agenda here, including a proposed Methane Removal Model Intercomparison Project (MR-MIP). This article is part of a discussion meeting issue 'Rising methane: is warming feeding warming? (part 1)'.

54 ENVIRONMENTAL SCIENCES↗

Harnessing Carbon: A Review of Current Technologies for Transform-ing Methane into Value-added Products

The concern over greenhouse gases, methane (CH 4 ) and carbon dioxide (CO 2 ), is increasing rapidly. There have been strides to find solutions to this global issue but there is not a clear path to a successful end goal. The concentration of CH 4 and CO 2 in the atmosphere has increased significantly over the last 60 years, methane is a great source of concern due to its ability to trap a high amount of heat in the atmosphere. These greenhouse gases contribute to global warming which has caused changes in the environment, including the melting of ice caps, and altered weather patterns. This review investigates biotechnology that has promising potential to aid in the mitigation of the negative effects methane has on the environment by exploring microorganisms, specifically methanotrophs, for their ability to convert methane into secondary value-added products that can be used for a wide range of applications. Methane as a feedstock could provide financial benefits due to the vast amount of methane available from sources like landfills, wastewater treatment plants, and agricultural sites. Furthermore, this review will look at the prospects of bioreactor technology and the potential for more environmentally friendly plastics, such as polyhydroxyalkanoate (PHA), to shy away from traditional petroleum-based plastics. The continuous advancement of bioreactor technology is crucial to mitigating greenhouse gas emissions.

36 MATERIALS SCIENCE↗

Investigating Future Arctic Sea Ice Loss and Near–Surface Wind Speed Changes Related to Surface Roughness Using the Community Earth System Model

The Arctic is undergoing a pronounced and rapid transformation in response to changing greenhouse gasses, including reduction in sea ice extent and thickness. There are also projected increases in near-surface Arctic wind. This study addresses how the winds trends may be driven by changing surface roughness and/or stability in different Arctic regions and seasons, something that has not yet been thoroughly investigated. We analyze 50 experiments from the Community Earth System Model Version 2 (CESM2) Large Ensemble and five experiments using CESM2 with an artificially decreased sea ice roughness to match that of the open ocean. We find that with a smoother surface there are higher mean wind speeds and slower mean ice speeds in the autumn, winter, and spring. The artificially reduced surface roughness also strongly impacts the wind speed trends in autumn and winter, and we find that atmospheric stability changes are also important contributors to driving wind trends in both experiments. In contrast to the clear impacts on winds, the sea ice mean state and trends are statistically indistinguishable, suggesting that near-surface winds are not major drivers of Arctic sea ice loss. Two major results of this work are: (a) the near-surface wind trends are driven by changes in both surface roughness and near-surface atmospheric stability that are themselves changing from sea ice loss, and (b) the sea ice mean state and trends are driven by the overall warming trend due to increasing greenhouse gas emissions and not significantly impacted by coupled feedbacks with the surface winds.

54 ENVIRONMENTAL SCIENCES↗