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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Study of electron-induced chemical transformations in polymers

In extreme ultraviolet (EUV) photoresist exposure, the primary and secondary electrons drive chemistry rather than the EUV photons themselves. These electrons have a wide range of energies below approximately 80 eV, which are capable of complex network of reactions during exposure. To better understand the ability of electrons of different energies within the EUV primary and secondary electron range, we want to characterize and compare the chemistry induced in pure polymer films by direct exposure to electrons. Thin films of poly(tert-butyl methacrylate), poly(methyl methacrylate), and poly(4-hydroxystyrene) were exposed to a 20 to 80 eV electron beam. Outgassing during exposure was characterized in-situ using a quadrupole residual gas analyzer. The thickness changes were measured using ellipsometry and chemical bond structure data were collected using Fourier-transform infrared spectroscopy (FTIR) after exposure to compare different exposure conditions. Poly(4-hydroxystyrene) demonstrated stability during electron exposures. Exposures of the other two materials led to outgassing of protecting groups, the intensity of which decayed in time. Outgassing, FTIR, and thickness loss data exhibited approximately linear relationships to each other.

Mueller, Maximillian↗
NASA NTRS1974

A spherical gas bearing for airborne application

A spherical gas bearing is analyzed and tested for an airborne application. The externally pressurized bearing supports an inertially stabilized 36-in aperture, infrared telescope. The bearing provides the isolation of rotary motion from the aircraft and also serves as a seal between the aircraft cabin and cavity condition at 50,000 ft altitude. The accompanying temperature gradient of 135 F across the 16-in.-diam bearing created special design and manufacturing considerations. Test data on the static load under temperature and vacuum environment are presented in support of the analysis.

Bouvier, A.↗
NASA NTRS1996

High Resolution Spectroscopy of Vega-like Stars: Abundances and Circumstellar Gas

Vega-like stars are main-sequence stars exhibiting excess infrared emission. In an effort to improve the information available on this class of star, 13 stars have been analyzed which have been classed as Vega-like, or have an infra-red excess attributable to dust in their circumstellar environment. In a separate paper stellar properties such as effective temperature and log g have been derived and in this poster we highlight the results of the photospheric abundance analysis also carried out during this work. King recently drew attention to the possible link between Vega-like stars and the photospheric metal-depleted class of A-stars, the Lambda Bootis stars. Since Vega-like stars are thought to have disks of dust, it might be expected that accretion of depleted gas onto the surface of these stars may cause this same phenomenon. In the 6 stars studied for depletions, none showed the extreme underabundance patterns observed in Lambda Bootis stars. However, depletions of silicon and magnesium were found in two of the sample, suggesting that these elements are in silicate dust grains in the circumstellar environment of these stars. Absorption lines attributed to circumstellar gas have been positively identified in three stars in our sample. Individual cases show evidence either of high-velocity outflowing gas, variability in the circumstellar lines observed, or evidence of circumstellar gas in excited lines of Fe II. No previous identification of circumstellar material has been made for two of the stars in question.

Dunkin, S. K.↗
DOE OSTI2020

A new approach for measuring the carbon and oxygen content of atmospherically relevant compounds and mixtures

Abstract. Due to its complexity, gas- and particle-phase organic carbon in the atmosphere is often classified by its bulk physicochemical properties. However, there is a dearth of robust, moderate-cost approaches to measure the bulk chemical composition of organic carbon in the atmosphere. This is particularly true for the degree of oxygenation, which critically affects the properties and impacts of organic carbon but for which routine measurement approaches are lacking. This gap has limited the understanding of a wide range of atmospheric components, including particulate matter, the mass of which is monitored worldwide due to its health and environmental effects but the chemical characterization of which requires relatively high capital costs and complex operation by highly trained technical personnel. In this work, we demonstrate a new approach to estimate the mass of carbon and oxygen in analytes and mixtures that relies only on robust, moderate-cost detectors designed for use with gas chromatography. Organic compounds entering a flame ionization detector were found to be converted with approximately complete efficiency to CO2, which was analyzed downstream using an infrared detector to measure the mass of carbon analyzed. The ratio of the flame ionization detector (FID) signal generated to CO2 formed (FID∕CO2) was shown to be strongly correlated (R2=0.89) to the oxygen-to-carbon ratio (O∕C) of the analyte. Furthermore, simple mixtures of analytes behaved as the weighted average of their components, indicating that this correlation extends to mixtures. These properties were also observed to correlate well with the sensitivity of the FID estimated by structure activity relationships (quantified as the relative effective carbon number). The relationships between measured FID∕CO2, analyte O∕C, and FID sensitivity allow the estimation of one property from another with <15 % error for mixtures and <20 % error for most individual analytes. The approach opens the possibility of field-deployable, autonomous measurement of the carbon and oxygen content of particulate matter using time-tested, low-maintenance detectors, though such an application would require some additional testing on complex mixtures. With some instrumental modifications, similar measurements on gas-phase species may be feasible. Moreover, the potential expansion to additional gas chromatography detectors may provide concurrent measurement of other elements (e.g., sulfur, nitrogen).

42 ENGINEERING↗
NASA NTRS2008

Middle UV to Near-IR Spectrum of Electron-Excited SO2

We investigated the electron impact-induced fluorescence spectrum of SO2 to provide excitation cross sections for modeling Io's mission spectrum and analyzing Cassini Imaging Science Subsystem observations. The electron-excited middle-ultraviolet visible optical near-infrared (VOIR) emission spectrum of SO2 gas was generated in the laboratory and studied from 2000 to 11,000 A at a resolution of (Delta)(lamda) approximately 2.5 A full width at half maximum (FWHM). The VOIR laboratory spectrum longward of 6000 A consists entirely of S I, II and O I, II multiplets for electron impact energies above approximately 15 eV. Between 2000 and 6000 A, we find previously identified molecular bands from both SO and SO2. This work represents a significant improvement in spectral resolution over our earlier work done at 18 A FWHM. From a measurement of the medium-resolution spectrum, we provide detailed 25- and 100-eV emission cross sections for spectral features from 2000 to 11,000 A . On the basis of these data, we suggest future ground-based and satellite telescopic observations in the VOIR that are of promise for understanding Io's atmosphere.

sulpher dioxide↗
NASA NTRS1971

A Fluorescent Source NDIR Carbon Monoxide Analyzer

This paper describes a new technique for measuring trace quantities of carbon monoxide by the nondispersive infrared (NDIR) methods. The technique uses the property of infrared fluorescence in a gas to generate a specific source of radiation which is an exact match of the absorption spectrum of the fundamental band of carbon monoxide. This results in an instrument with high sensitivity and specificity for CO. A novel method of referencing using an isotopic species of CO confers great stability on the instrument.

Link, W. T.↗
NASA NTRS1999

The Contribution of Ionizing Starts to the Far-Infrared and Radio Emission in the Milky Way: Evidence for a Swept-up Shell and Diffuse Ionized Halo Around the W4 Chimney/Supershell

Normandeau have proposed that W4 is a galactic chimney, the only chimney to-date identified in our Galaxy. Using the recent approx. 1 min resolution IGA (Infrared Galaxy Atlas) and DRAO (Dominion Royal Astrophysical Observatory) CGPS (Canadian Galactic Plane Survey) galactic plane surveys we analyze the far-infrared and radio structure of the W 4 chimney/supershell. We show W4 has a swept-up partially ionized shell of gas and dust which is powered by the OCl 352 star cluster. Analysis of the dust column density establishes there is dense interstellar material below the shell, directly showing the dense material which caused the lower shell expansion to stall. Due to much lower densities above the Galactic plane, the upper W4 shell achieved 'breakout' to form a Galactic chimney. Although the shell appears ionization bounded, it is very inhomogenous and an ionized halo provides evidence of significant Lyman continuum leakage. A large fraction of the OCl 352 cluster photons escape to large distances and are available to ionize the WIM (warm ionized medium) component of the interstellar medium.

Terebey, Susan↗
NASA NTRS2005

Infrared Extinction and the Initial Conditions for Star and Planet Formation

This grant funded a research program to use infrared extinction measurements to probe the detailed structure of dark molecular clouds and investigate the physical conditions which give rise to star and planet formation. The goals of the this program were to: 1) acquire deep infrared and molecular-line observations of a carefully selected sample of nearby dark clouds, 2) reduce and analyze the data obtained in order to produce detailed extinction maps of the clouds, 3) use the results to measure and quantitatively describe the physical conditions of the dense gas and dust that produce stars and their accompanying planetary systems in molecular clouds. The goals of this project were met and exceeded as described below. 1) The infrared data for the project were obtained in a number of observing runs using the 3.5-meter NTT and 8-meter VLT telescopes of the European Southern Observatory in Chile and the 1.2-meter telescope of the Smithsonian Astrophysical Observatory in Arizona, the 1 0-meter Keck telescope in Hawaii, the 6.5-meter MMT of the Smithsonian Astrophysical Observatory in Arizona, and the NASA Hubble Space Telescope. The molecular-line data was obtained in three runs using the IRAM 30-meter telescope in Spain and one run with the ESO-15 meter millimeter-wave telescope in Chile. Millimeter-wave continuum measurements were obtained with the 15-meter JCMT in Hawaii. 2) Considerable effort was expended to reduce the infrared imaging observations including the development of custom software to produce high quality photometry and source astrometry. All the millimeter-line data was reduced using standard reduction routines. The highlights of the infrared analysis were the production of detailed extinction maps and the construction of profiles of the density structure of the B68, Coalsack, B335 and Lupus clouds. 3) The principal scientific accomplishments of this research program include the following: We were able to use our infrared observations to determine the density structure of the B68 cloud to an unprecedented level of precision. This lead to a major breakthrough in the study of molecular cloud structure. For the first time we have been able to characterize the structure of a dark cloud in a detail only exceeded by that known for a star. We determined that the cloud's structure is exquisitely well described by the equations of a Bonner-Ebert sphere (a pressure confined isothermal sphere). We were able to show that the cloud is very nearly in equilibrium with the internal thermal pressure of the cloud balancing gravity and the external pressure of the surrounding interstellar medium. We were able to determine for the first time the gas-to-dust ratio in a dense cloud core. We also demonstrated a new method to determine extremely precise distances to such clouds by combining knowledge of the properties of Bonner-Ebert Spheres with our infrared and millimeter-wave observations.

Lada, Charles J.↗
NASA NTRS1985

Determining bonding, thickness, and density via thermal wave impedance NDE

Bonding, density, and thickness of coatings have a vital effect on their performance in many applications. Pioneering development work on thermal wave nondestructive evaluation (NDE) methods during the past 25 years has resulted in an array of useful techniques for performing bonding, density, and thickness measurements in a practical shop environment. The most useful thermal wave methods for this purpose are based on thermal wave surface impedance measurement or scanning. A pulse of heat from either a thermal transducer or a hot gas pulse is projected onto the surface, and the resulting temperature response is analyzed to unfold the bonding, density, and thickness of the coating. An advanced emissivity independent infrared method was applied to detect the temperature response. These methods were recently completely computerized and can automatically provide information on coating quality in near real-time using the proper equipment. Complex shapes such as turbine blades can be scanned. Microscopic inhomogeneities such as microstructural differences and small, normal, isolated voids do not cause problems but are seen as slight differences in the bulk thermal properties. Test objects with rough surfaces can be effectively nondestructively evaluated using proper thermal surface impedance methods. Some of the basic principles involved, as well as metallographic results illustrating the ability of the thermal wave surface impedance method to detect natural nonbonds under a two-layer thermally sprayed coating, will be presented.

Green, D. R.↗
NASA NTRS1977

Thermochemical characterization of polymers for improved fire safety

Apparatus has been constructed for studying the thermal decomposition of polymers as a function of temperature. Such data is needed to evaluate the toxic threat presented by polymeric materials under fire conditions such as the smoldering fire of the type that occurs in closed areas such as coat closets in which anaerobic decomposition of polymers occurs. The apparatus allows the products of thermal decomposition to be collected and analyzed by infrared spectrometry and mass spectrometry. Data obtained from dog hair, an aromatic polyamide, polyphenylene sulfide, and polybenzimidazole are presented. It was found that significant amounts of toxic gas were evolved from dog hair at temperatures as low as 250 C, while temperatures in excess of 500 C were necessary in order for the evolution of toxic gas from the aromatic polymers to become significant.

Lerner, N. R.↗
NASA NTRS1985

Concentration of methane in the troposphere deduced from 1951 infrared solar spectra

The 1-2 percent increase in tropospheric methane determined from gas chromatographic measurements since 1977 has important implications for atmospheric photochemistry and climate. To extend the measurement baseline, solar absorption spectra have been analyzed and mean troposphere CH4 mixing ratios for the years 1951 and 1981, and an average rate of CH4 increase of 1.1 + or - 0.2 percent per year is found for this period.

Rinsland, C. P.↗
NASA NTRS1997

Infrared Response of H2 to X-Rays in Dense Clouds

The excitation by X-rays and cosmic rays of molecular hydrogen in interstellar clouds is analyzed. We carried out detailed calculations of entry efficiencies in rovibrational levels of H2 following impact with fast electrons produced by X-ray ionization of the gas. The competing effect of collisional excitation, and quenching by the ambient gas is examined in detail. Up to date values for H-H2 collisional rate coefficients are adopted, and some derivations of H2-H2 rovibrational rate coefficients from existing literature data are proposed. Several models as a function of temperature, density, and ionization rate are presented. We found that H2 infrared emission in X-ray dominated regions (XDR) is potentially observable for temperatures and ionization rates lower than certain critical values (typically T < 1000 K and zeta/n(sub H) < 10(exp -15) cc/s where zeta is the ionization rate). At higher temperatures, collisional excitation by the ambient gas dominates the population of low vibrational levels, and at higher values of zeta/n(sub H) the abundance of H2 is negligible. If such conditions are satisfied, the resulting infrared emission spectrum can be used as a diagnostic of nearby X-ray sources such as in cooling flows in galaxy clusters, quasars, Seyfert galaxies and supernova remnants. The intensity ratio of the 2-1S(1) and 1-0S(1) lines measured for the Seyfert galaxy NGC 1275 is consistent with X-ray pumping.

Tine, S.↗
DOE OSTI2025

In Situ Atmospheric Plume Thermometry via Carbon Monoxide Spectral Profile: Laboratory and Field Validation

For small molecules with large rotational constants, knowing the relative intensities of the ro-vibrational transitions can be used to determine the temperature within a gas plume. We demonstrate the use of carbon monoxide (CO) as an in situ spectroscopic probe of gas plume temperature by application of both laboratory and standoff Fourier transform infrared spectroscopy to monitor the CO spectral response at different temperatures. Here, the measured CO rotational contours were analyzed using a simple Boltzmann model to deduce the population distribution of the J-levels, from which the in-plume temperature is deduced. The method was vetted by comparing deduced temperatures in both static laboratory measurements of known temperatures, as well as field measurements using a simulated smokestack release. For the smokestack experiments, spectroscopically deduced temperatures were compared to readings from a series of thermocouples placed at strategically sampled distances along the plume trajectory. Both the spectroscopically-derived and thermocouple-measured temperatures revealed an expansion-induced (mixing) rapid cooling of the plume, with the infrared thermometry values displaying greater temperature values which are believed to better represent the actual plume temperatures.

Analysis of rotational structure↗
NASA NTRS1986

First results from Spacelab 2

Preliminary results of physical experiments carried out during the Spacelab 2 Shuttle mission are summarized. Attention is given to experiments in the fields of plasma dynamics; solar physics; high-energy astrophysics; and astronomy. Plasma experiments included an ejectable plasma diagnosics package and measurements of the passive charging of the Shuttle vehicle in the surrounding space plasma. The solar physics instrument package consisted of a solar spectral irradiance monitor; a solar optical universal polarimeter (SOUP); and a solar helium abundance high-resolution telescope and spectrograph (HRTS). Astronomical observations were performed using a scanning infrared telescope (IRT) which consisted of a highly baffled herschelian telescope and 10 detectors covering wavelengths from 2 to 120 microns. Cosmic-ray nuclei were detected and analyzed using gas Cerenkov counters and a transition radiation detector. Addition experiments included a thin film fluid dynamics payload and analysis of blood samples taken from the mission specialists. Complete data records from the experiments have now been distributed for an analysis period which will take at least a year. A table listing the Spacelab 2 experiments and their principal investigators is provided.

Urban, E. W.↗
NASA NTRS1991

Molecular gas in luminous infrared galaxies

Radio observations of 60 bright IRAS galaxies with redshifts of 1500-25,000 km/sec are reported. Data obtained in the 1-0 line of CO using the 12-m NRAO radio telescope during 1985-1988 are presented in extensive tables, graphs, and line profiles and analyzed along with similar data on 29 less distant IRAS bright galaxies (Tinney et al., 1990). The galaxies are found to have H2 masses of (1-60) x 10 to the 9th solar mass and a mean ratio of H2 to warm dust of 540 + or - 290, corresponding to a total gas/dust ratio of 900-1100. The discrepancy between this value and that for the Galaxy (about 150) is tentatively attributed to the presence of undetected cold dust or errors in interpreting the IR data. The mechanisms which might be responsible for the high ratios of IR luminosity to H2 mass (2-220 solar luminosity per solar mass) are discussed.

Sanders, D. B.↗
NASA NTRS1987

On the nitrogen-induced far-infrared absorption spectra

The rototranslational absorption spectrum of gaseous N2 is analyzed, considering quadrupolar and hexadecapolar induction mechanisms. The available experimental data are accounted for by using a line-shape analysis in which empirical profiles describe the single-line translational profiles. Thus, a simple procedure is derived that allows the prediction of the N2 spectrum at any temperature. On the basis of the results obtained for the pure gas, a procedure to compute the far-infrared spectrum of the N2-Ar gaseous mixture is also proposed. The good agreement between computed and experimental N2-Ar data indicates that it is possible to predict the far-infrared absorption induced by N2 on the isotropic polarizability of any interacting partner.

Dore, P.↗