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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Linear gyrokinetic stability of a high β non-inductive spherical tokamak

Spherical tokamaks (STs) have been shown to possess properties desirable for a fusion power plant such as achieving high plasma β and having increased vertical stability. To understand the confinement properties that might be expected in the conceptual design for a high β ST fusion reactor, a 1 GW ST plasma equilibrium was analyzed using local linear gyrokinetics to determine the type of micro-instabilities that arise. Kinetic ballooning modes and micro-tearing modes are found to be the dominant instabilities. The parametric dependence of these linear modes was determined and, from the insights gained, the equilibrium was tuned to find a regime marginally stable to all micro-instabilities at θ 0 = 0.0. This work identifies the most important micro-instabilities expected to generate turbulent transport in high β STs. The impact of such modes must be faithfully captured in first-principles-based reduced models of anomalous transport that are needed for predictive simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Validation of gyrokinetic simulations in NSTX and projections for high-k turbulence measurements in NSTX-U

An extensive validation effort performed for a modest-beta NSTX NBI-heated H-mode discharge predicts that electron thermal transport can be entirely explained by electron-scale turbulence fluctuations driven by the electron temperature gradient mode (ETG), both in conditions of strong and weak ETG turbulence drive. Thermal power-balance estimates computed by TRANSP as well as the shape of the high-k density fluctuation wavenumber spectrum and the fluctuation level ratio between strongly driven and weakly driven ETG-turbulence conditions can be matched by nonlinear gyrokinetic simulations and a synthetic diagnostic for high-k scattering. Linear gyrokinetic simulations suggest that the ion-scale instability in the weak ETG condition is close to the critical threshold for the kinetic ballooning mode instability, and nonlinear ion-scale gyrokinetic simulations show that turbulence might be in a state reminiscent of a Dimits' shift regime, opening speculation on the role that ion-scale turbulence might play for the weak ETG condition. A simulation that matched all experimental constraints is chosen to project high-k turbulence spectra in NSTX-U, revealing that the new high-k system [R. Barchfeld et al., Rev. Sci. Instrum. 89, 10C114 (2018)] should be sensitive to density fluctuations from radially elongated streamer structures. In this study, two schemes are designed to characterize the radial and poloidal wavenumber dependence of the density fluctuation wavenumber power spectrum around the streamer peak, suggesting future high-k fluctuation measurements could be sensitive to an asymmetry in the k r spectrum introduced due to the presence of strong background flow shear.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Fully Kinetic Simulations of Proton-beam-driven Instabilities from Parker Solar Probe Observations

The expanding solar wind plasma ubiquitously exhibits anisotropic nonthermal particle velocity distributions. Typically, proton velocity distribution functions (VDFs) show the presence of a core and a field-aligned beam. Novel observations made by the Parker Solar Probe (PSP) in the innermost heliosphere have revealed new complex features in the proton VDFs, namely anisotropic beams that sometimes experience perpendicular diffusion. In this study, we use a 2.5D fully kinetic simulation to investigate the stability of proton VDFs with anisotropic beams observed by PSP. Our setup consists of a core and an anisotropic beam population that drift with respect to each other. This configuration triggers a proton beam instability from which nearly parallel fast magnetosonic modes develop. Our results demonstrate that before this instability reaches saturation, the waves resonantly interact with the beam protons, causing perpendicular heating at the expense of the parallel temperature.

79 ASTRONOMY AND ASTROPHYSICS↗

Synchrotron-driven Instabilities in Relativistic Plasmas of Arbitrary Opacity

Recent work has shown that synchrotron emission from relativistic plasmas leads the electron distribution to form an anisotropic ring in momentum space, which can be unstable to both kinetic and hydrodynamic instabilities. Fundamental to these works was the assumption that the plasma was optically thin, allowing all emitted radiation to escape. Here, we examine the behavior of these instabilities as the plasma becomes more optically thick. To do this, we extend a recently developed Fokker–Planck operator for synchrotron emission and absorption in mildly relativistic plasmas to ultrarelativistic plasmas. For a given set of plasma parameters, photons emitted by higher-energy electrons tend to be higher frequency, and thus more easily escape the plasma. As a result, the ratio of the photon emission rate (radiative drag) to absorption rate (radiative diffusion) for a given electron is extremely energy dependent. Given this behavior, we determine the critical parameters that control the opacity, and show how the plasma gradually transitions to become more isotropic and stable at higher opacity.

79 ASTRONOMY AND ASTROPHYSICS↗

Controlling the Phase Transition in CsPbI 3 Nanowires

Cesium lead iodide (CsPbI 3 ) is a promising semiconductor with a suitable band gap for optoelectronic devices. CsPbI 3 has a metastable perovskite phase that undergoes a phase transition into an unfavorable nonperovskite phase in an ambient environment. This phase transition changes the optoelectronic properties of CsPbI 3 and hinders its potential for device applications. Therefore, it is of central importance to understand the kinetics of such instability and develop strategies to control and stabilize the perovskite phase. Here, we use ultralong CsPbI 3 nanowires as a model platform to investigate the phase transition kinetics. Our results depict the role of environmental stressors (moisture and temperature) in controlling the phase transition dynamics of CsPbI 3 , which can serve as guiding principles for future phase transition studies and the design of related photovoltaics. Furthermore, we demonstrate the controllability of phase propagation on individual nanowires by varying the moisture level and temperature.

36 MATERIALS SCIENCE↗

Nonlinear mode coupling and energetics of driven magnetized shear-flow turbulence

To comprehensively understand the saturation of two-dimensional (2D) magnetized Kelvin–Helmholtz-instability-driven turbulence, energy transfer analysis is extended from the traditional interaction between scales to include eigenmode interactions, by using the nonlinear couplings of linear eigenmodes of the ideal instability. While both kinetic and magnetic energies cascade to small scales, a significant fraction of turbulent energy deposited by unstable modes in the fluctuation spectrum is shown to be re-routed to the conjugate-stable modes at the instability scale. They remove energy from the forward cascade at its inception. The remaining cascading energy flux is shown to attenuate exponentially at a small scale, dictated by the large-scale stable modes. Guided by a widely used instability-saturation assumption, a general quasi-linear model of instability is tested by retaining all nonlinear interactions except those that couple to the large-scale stable modes. These complex interactions are analytically removed from the magnetohydrodynamic equations using a novel technique. Observations are an explosive large-scale vortex separation instead of the well-known merger of 2D, a dramatic enhancement in turbulence level and spectral energy fluxes, and a reduced small-scale dissipation length scale. These show the critical role of the stable modes in instability saturation. Possible reduced-order turbulence models are proposed for fusion and astrophysical plasmas, based on eigenmode-expanded energy transfer analyses.

Physics↗

Magnetogenesis in a Collisionless Plasma: From Weibel Instability to Turbulent Dynamo

We report on a first-principles numerical and theoretical study of plasma dynamo in a fully kinetic framework. By applying an external mechanical force to an initially unmagnetized plasma, we develop a self-consistent treatment of the generation of “seed” magnetic fields, the formation of turbulence, and the inductive amplification of fields by the fluctuation dynamo. Driven large-scale motions in an unmagnetized, weakly collisional plasma are subject to strong phase mixing, which leads to the development of thermal pressure anisotropy. This anisotropy triggers the Weibel instability, which produces filamentary “seed” magnetic fields on plasma-kinetic scales. The plasma is thereby magnetized, enabling efficient stretching and folding of the fields by the plasma motions and the development of Larmor-scale kinetic instabilities such as the firehose and mirror. The scattering of particles off the associated microscale magnetic fluctuations provides an effective viscosity, regulating the field morphology and turbulence. During this process, the seed field is further amplified by the fluctuation dynamo until energy equipartition with the turbulent flow is reached. By demonstrating that equipartition magnetic fields can be generated from an initially unmagnetized plasma through large-scale turbulent flows, this work has important implications for the origin and amplification of magnetic fields in the intracluster and intergalactic mediums.

79 ASTRONOMY AND ASTROPHYSICS↗

Experimental considerations and applications for time-resolved impedance on silicon-anode battery systems

Dynamic electrochemical impedance spectroscopy (dEIS) utilizes a superimposed multi-sinusoidal waveform and enables temporally resolved investigations on various electrochemical processes; however, the signal-to-noise ratio must be maximized while retaining linearity and stationarity within the system. In the present work, we probe the impact of the waveform’s total amplitude as well as the waveform and phase profiles. The equal amplitude multi-sinusoidal waveform with 35 mV total amplitude (<1 mV per frequency) and random phase profile exhibits the lowest impedance noise. This input signal is sufficient in avoiding the high frequency signal attenuation from the potentiostat’s low-pass filter. Additionally, we demonstrate the optimized dEIS waveform’s utility in investigating surface passivation within thin-film and composite silicon (Si) anodes. Within a two-electrode Si-lithium metal coin cell, the charge transfer resistance (RCT) associated with alloying kinetics dominates the overall impedance. RCT increases with state of charge indicating a kinetic bottleneck at higher lithiation states. To explore this further, we utilize a three-electrode Si-LiNi0.8Mn0.1Co0.1O2 pouch cell to deconvolute the Si impedance contributions. The evolution of the solid electrolyte interphase (SEI) and charge transfer resistances correlate to specific Li–Si alloy phases. We attribute this to the influence of Si particle volume expansion on SEI instabilities and a kinetic bottleneck at higher lithiation states.

Lam, Steven [ORNL]↗

Inter-ELM pedestal evolution and the role of edge fluctuations in the C-Mod and DIII-D tokamaks

Edge localized modes (ELMs) lead to a cyclical behaviour of the H-mode pedestal density, temperature and pressure. Substantial evidence exists associating the ELM crash with violation of ideal MHD stability, via current driven kink/peeling modes and/or pressure gradient driven ballooning modes. Recovery from ELM crashes and buildup to the next ELM crash is an active and critical area of edge physics research for ITER projections. In one set of theories, the pedestal pressure profile in H-mode discharges is predicted to be limited by micro-instabilities. One such micro-instability is the kinetic ballooning mode (KBM), which is hypothesized to provide a ‘soft’ limit that regulates the edge transport, thereby restricting the local pressure gradient. In this picture, e.g. in the EPED model, the pedestal width expands slowly until the ideal MHD stability limit is reached. Experiments were recently performed on the C-Mod and DIII-D devices to search for instabilities correlated with the pedestal evolution between ELMs. The results show correlations between the onset of quasi-coherent fluctuations between type I ELMs and a critical temperature gradient. Linear gyrokinetic calculations have shown that these fluctuations have characteristics similar to those expected for KBMs. These results provide additional data toward validation of the EPED model, increasing confidence in ITER projections.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Microphysically modified magnetosonic modes in collisionless, high-β plasmas

With the support of hybrid-kinetic simulations and analytic theory, we describe the nonlinear behaviour of long-wavelength non-propagating (NP) modes and fast magnetosonic waves in high-β collisionless plasmas, with particular attention to their excitation of and reaction to kinetic micro-instabilities. The perpendicularly pressure balanced polarization of NP modes produces an excess of perpendicular pressure over parallel pressure in regions where the plasma β is increased. For mode amplitudes |δB/B 0 |≳0.3, this excess excites the mirror instability. Particle scattering off these micro-scale mirrors frustrates the nonlinear saturation of transit-time damping, ensuring that large-amplitude NP modes continue their decay to small amplitudes. At asymptotically large wavelengths, we predict that the mirror-induced scattering will be large enough to interrupt transit-time damping entirely, isotropizing the pressure perturbations and morphing the collisionless NP mode into the magnetohydrodynamic (MHD) entropy mode. In fast waves, a fluctuating pressure anisotropy drives both mirror and firehose instabilities when the wave amplitude satisfies |δB/B 0 |≳2β -1 . The induced particle scattering leads to delayed shock formation and MHD-like wave dynamics. Taken alongside prior work on self-interrupting Alfvén waves and self-sustaining ion-acoustic waves, our results establish a foundation for new theories of electromagnetic turbulence in low-collisionality, high-β plasmas such as the intracluster medium, radiatively inefficient accretion flows and the near-Earth solar wind.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Atomically dispersed metal–nitrogen–carbon catalysts for fuel cells: advances in catalyst design, electrode performance, and durability improvement

The urgent need to address the high-cost issue of proton-exchange membrane fuel cell (PEMFC) technologies, particularly for transportation applications, drives the development of simultaneously highly active and durable platinum group metal-free (PGM-free) catalysts and electrodes. The past decade has witnessed remarkable progress in exploring PGM-free cathode catalysts for the oxygen reduction reaction (ORR) to overcome sluggish kinetics and catalyst instability in acids. Among others, scientists have identified the newly emerging atomically dispersed transition metal (M: Fe, Co, or/and Mn) and nitrogen co-doped carbon (M–N–C) catalysts as the most promising alternative to PGM catalysts. Here, we provide a comprehensive review of significant breakthroughs, remaining challenges, and perspectives regarding the M–N–C catalysts in terms of catalyst activity, stability, and membrane electrode assembly (MEA) performance. A variety of novel synthetic strategies demonstrated effectiveness in improving intrinsic activity, increasing active site density, and attaining optimal porous structures of catalysts. Rationally designing and engineering the coordination environment of single metal MN x sites and their local structures are crucial for enhancing intrinsic activity. Increasing the site density relies on the innovative strategies of restricting the migration and agglomeration of single metal sites into metallic clusters. Relevant understandings provide the correlations among the nature of active sites, nanostructures, and catalytic activity of M–N–C catalysts at the atomic scale through a combination of experimentation and theory. Current knowledge of the transferring catalytic properties of M–N–C catalysts to MEA performance is limited. Rationally designing morphologic features of M–N–C catalysts play a vital role in boosting electrode performance through exposing more accessible active sites, realizing uniform ionomer distribution, and facilitating mass/proton transports. We outline future research directions concerning the comprehensive evaluation of M–N–C catalysts in MEAs. The most considerable challenge of current M–N–C catalysts is the unsatisfied stability and rapid performance degradation in MEAs. Therefore, we further discuss practical methods and strategies to mitigate catalyst and electrode degradation, which is fundamentally essential to make M–N–C catalysts viable in PEMFC technologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Scale and Activity of Symmetric Instability Estimated from a Global Submesoscale-Permitting Ocean Model

Abstract Symmetric instability (SI) extracts kinetic energy from fronts in the surface mixed layer (SML), potentially affecting the SML structure and dynamics. Here, a global submesoscale-permitting ocean model named MITgcm LLC4320 simulation is used to examine the Stone linear prediction of the maximum SI scale to estimate grid spacings needed to begin resolving SI. Furthermore, potential effects of SI on the usable wind work are estimated roughly: this estimate of SI “activity” is useful for assessing if these modes should be resolved or parameterized. The maximum SI scale varies by latitude with median values from 568 to 23 m. Strong seasonality is observed in the SI scale and activity. The median scale in winter is 188 m globally, 2.5 times of that of summer (75 m). SI is more active in winter: 15% of the time compared with 6% in summer. The strongest SI activity is found in the western Pacific, western Atlantic, and Southern Oceans. The required grid spacings for a global model to begin resolving SI eddies in the SML are 24 m (50% of regions resolved) and 7.9 m (90%) in winter, decreasing to 9.4 m (50%) and 3.6 m (90%) in summer. It is also estimated that SI may reduce usable wind work by an upper bound of 0.83 mW m −2 globally, or 5% of the global magnitude. The sensitivity of these estimates to empirical thresholds is provided in the text.

Dong, Jihai↗

Krash-ESL-Final report

During the period of the current Grant, the effort of the UCSD researchers was focused on: i) The application of the gyrokinetic code COGENT code to study the kinetic drift wave instability and its impact on blob dynamics, and ii) The modeling of edge plasma transport in collisional and semi-collisional regimes, and iii) Impurity transport in edge plasma and the incorporation of plasma-impurity collision operator (hereafter unlike particle collision operator) into COGENT. Over the years four UCSD graduate students (J. Angus, W. Lee, Y. Zhang, and A. Knyazev), funded under this Grant, contributed to the COGENT development/utilization and defended their PhD theses, which are based, partly, on their research related to the COGENT. Three of them (J. Angus, W. Lee, and Y. Zhang) have received “The Best MAE Graduate Student of the Year” awards. Whereas W. Lee after defending his PhD thesis returned back to his home country (South Korea), J. Angus, and Y. Zhang are continuing their research in plasma physics in the LLNL and LANL, whereas A. Knyazev currently is a postdoctoral fellow at Columbia University working on the theoretical aspects of advanced stellarators. The results obtained in our studies were disseminated in many papers published in first-class refereed scientific journals and presented on prestigious scientific meetings including the Annual APS DPP Meeting, Sherwood Fusion Theory Conference, IAEA Fusion Energy Conferences, International Conferences on Plasma-Surface Interactions in Controlled Fusion Devices, International Workshops on Edge Plasma Theory in Fusion Devices, etc. In what follows we highlight the major accomplishments of the UCSD Team in the main areas of our research.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Long-Term Science Goals with In Situ Observations at the Sun-Earth Lagrange Point L4

The Korean heliospheric community, led by the Korea Astronomy and Space Science Institute (KASI), is currently assessing the viability of deploying a spacecraft at the Sun-Earth Lagrange Point L4 in collaboration with National Aeronautics and Space Administration (NASA). The aim of this mission is to utilize a combination of remote sensing and in situ instruments for comprehensive observations, complementing the capabilities of the L1 and L5 observatories. The paper outlines long-term scientific objectives, underscoring the significance of multi-point in-situ observations to better understand critical heliospheric phenomena. These include coronal mass ejections, magnetic flux ropes, heliospheric current sheets, kinetic waves and instabilities, suprathermal electrons and solar energetic particle events, as well as remote detection of solar radiation phenomena. Furthermore, the mission’s significance in advancing space weather prediction and space radiation exposure assessment models through the integration of L4 observations is discussed. This article is concluded with an emphasis on the potential of L4 observations to propel advancements in heliospheric science.

79 ASTRONOMY AND ASTROPHYSICS↗

Interplay of Three-Dimensional Instabilities and Magnetic Reconnection in the Explosive Onset of Magnetospheric Substorms

Magnetospheric substorms are preceded by a slow growth phase of magnetic flux loading and current sheet thinning in the tail. Extensive data sets have provided evidence of the triggering of instabilities at substorm onset, including magnetic reconnection and ballooning instabilities. Using an exact kinetic magnetotail equilibrium we present particle-in-cell simulations which capture the explosive nature of substorms through a disruption of the dipolarization front by the ballooning instability. We use self-consistent particle tracking to determine the nonthermal particle acceleration mechanisms.

79 ASTRONOMY AND ASTROPHYSICS↗

Validation of magnetized gas-jet experiments to investigate the effects of an external magnetic field on laser-plasma instabilities

Laser-plasma instabilities (LPI) play a detrimental role in energy coupling to the target in inertial confinement fusion (ICF). The recent development of applied strong magnetic fields for use in ICF and laboratory astrophysics experiments has opened opportunities to investigate the role of external magnetic fields on LPIs. Recent numerical studies have shown that stimulated Raman scattering (SRS) can be mitigated by external magnetic fields in the kinetic regime of the instability and warrant systematic experimental studies to validate modelling. To this end, we design experiments at the OMEGA-EP laser facility to investigate the effect of an external perpendicular B-field of 5–30 T on the backscattered light spectrum from a gas-jet target. We present measurements from a proof-of-principle experiment, where the backward-SRS (BSRS) is in the kinetic regime, for which the magnetization is expected to produce the greatest effects on instability growth. New simulations motivated by this experiment are used to inform the proposal of an upgraded experimental design. Our simulation predictions show that the new design is suited to experimentally demonstrating BSRS mitigation by an external magnetic field, despite the magnetization effects on the hydrodynamics, as well as the inherent temporal and spatial variations in plasma conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Omnigenous stellarators with improved ideal and kinetic ballooning stability

Omnigenity is a property of a magnetic field which ensures confinement of trapped particles. It is a necessary requirement for any high-performance stellarator. After creating an omnigenous equilibrium, one must also ensure reduced transport resulting from kinetic and magnetohydrodynamic (MHD) instabilities. To this end, we leverage the GPU-accelerated DESC optimization suite, which is used to design stable, finite-β omnigenous equilibria with poloidal, toroidal, and helical symmetry, achieving Mercier, ideal ballooning, and as a consequence, improved kinetic ballooning stability. We discover stellarators with second stability, a regime of large pressure gradient where an equilibrium becomes ideal ballooning stable, and demonstrate and explore both using theory and gyrokinetic simulations the connection between ideal and kinetic ballooning stability.

optimization↗