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At least 73 records · Page 4

AmeriFlux FLUXNET-1F US-xLE NEON Lenoir Landing (LENO)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xLE NEON Lenoir Landing (LENO). This is the FLUXNET version of the carbon flux data for the site US-xLE NEON Lenoir Landing (LENO) produced by applying the standard ONEFlux (1F) software. Site Description - This terrestrial field site is located in a hardwood bottomland with seasonal flooding each spring located in southwest Alabama. The meteorological/flux tower and tower sampling plots are located at Lenoir Landing and the distributed plots are located approximately 5 km south of the tower at Choctaw National Wildlife Refuge. The ecosystem at LENO is dominated by closed-canopy pine-oak mixed forest with a developed understory, and also includes a small fraction of meadows, wetlands, and smaller water bodies. Dominant plant species include American sweetgum (Liquidambar styraciflua), American hornbeam (Carpinus caroliniana), and loblolly pine (Pinus taeda). Choctaw National Wildlife Refuge also provides a protected wintering area for waterfowl and wood duck brood habitat. This site is colocated with the Lower Tombigbee river aquatic site.

Network), NEON (National Ecological Observatory [N↗

The Effect of Rapid Development on Soil CO2 Efflux in a Cellulosic Biofuel Stand

As awareness of climate change increases, the need for carbon neutral fuel sources is growing. Lignocellulosic biofuel derived from pine trees has been suggested as one potential energy source; however, it requires more research before its efficacy for climate change mitigation can be determined. Due to the large share of forest carbon held in soils and the extensive area of pine plantations in the southeast U.S., a better understanding of plantation soil carbon dynamics is critical for biofuel carbon accounting. This study evaluated the effects of canopy development and productivity on soil CO2 efflux, a proxy for soil respiration (Rs), in an intensively managed loblolly pine (Pinus taeda) stand over a period from May 2015 to December 2019. We found that leaf area index (LAI) and gross ecosystem production (GEP), as well as meteorological variables, had significant effects on Rs, but that both overall Rs and soil carbon pools did not increase over the course of the study. We thus hypothesize that GEP and LAI had intra-annual effects on Rs, and that the lack of change in Rs is the result of an increase in autotrophic respiration (Ra) that offset a decrease in decomposition of the previous stand’s organic matter.

09 BIOMASS FUELS↗

Analysis of xylem formation in pine by cDNA sequencing

Secondary xylem (wood) formation is likely to involve some genes expressed rarely or not at all in herbaceous plants. Moreover, environmental and developmental stimuli influence secondary xylem differentiation, producing morphological and chemical changes in wood. To increase our understanding of xylem formation, and to provide material for comparative analysis of gymnosperm and angiosperm sequences, ESTs were obtained from immature xylem of loblolly pine (Pinus taeda L.). A total of 1,097 single-pass sequences were obtained from 5' ends of cDNAs made from gravistimulated tissue from bent trees. Cluster analysis detected 107 groups of similar sequences, ranging in size from 2 to 20 sequences. A total of 361 sequences fell into these groups, whereas 736 sequences were unique. About 55% of the pine EST sequences show similarity to previously described sequences in public databases. About 10% of the recognized genes encode factors involved in cell wall formation. Sequences similar to cell wall proteins, most known lignin biosynthetic enzymes, and several enzymes of carbohydrate metabolism were found. A number of putative regulatory proteins also are represented. Expression patterns of several of these genes were studied in various tissues and organs of pine. Sequencing novel genes expressed during xylem formation will provide a powerful means of identifying mechanisms controlling this important differentiation pathway.

Non-NASA Center↗

AmeriFlux FLUXNET-1F US-NC1 NC_Clearcut

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-NC1 NC_Clearcut. This is the FLUXNET version of the carbon flux data for the site US-NC1 NC_Clearcut produced by applying the standard ONEFlux (1F) software. Site Description - The North Carolina Clearcut site is located in a pine plantation amongst the mixed forests of the North Carolina lower coastal plain. Owned by the Weyerhaeuser Company, the plantation is managed for the purpose of commercial logging. In 2004, 70 ha of 75 year old native hardwoods was harvested. Following the clearcut, the stand was bedded and planted with loblolly pine seedlings. The only significant natural disturbances during the measurement period was a severe drought that lasted from summer of 2007 through 2008. Consequently, the 2007 total amount of precipitation was 486 mm below the 30-year norm.

Noormets, Asko↗

Corrosion Studies of Pine-Derived Bio-Oil and Heavy Fuel Oil Blends

To reduce the amount of greenhouse gas produced from the combustion of petroleum fuels, renewable liquid fuels are needed. Pyrolysis of biomass provides a means to produce liquid fuels to displace current petroleum products. However, common ferrous alloys are susceptible to high corrosion rates when exposed to bio-oil. This study analyzes the effects of blending bio-oil derived from loblolly pine with heavy fuel oil added to reduce corrosion of common structural alloys. Laboratory corrosion studies of six different blends of bio-oil/heavy fuel oil were performed for 1,000 hours at 50°C. Chemical characterization was also performed to determine the total acid content of each blend. Post-exposure characterizations such as changes in weight, X-ray diffraction, dye penetrant testing, and metallography were performed to provide more insight into the corrosion mechanism of bio-oil/heavy fuel oil blends. We hypothesized that the corrosion rates of ferrous alloys would increase with an increase in bio-oil concentration. The results of these characterization and corrosion studies confirmed this hypothesis and will be reported.

09 BIOMASS FUELS↗

Relating P-band AIRSAR backscatter to forest stand parameters

As part of research on forest ecosystems, the Jet Propulsion Laboratory (JPL) and collaborating research teams have conducted multi-season airborne synthetic aperture radar (AIRSAR) experiments in three forest ecosystems including temperate pine forest (Duke, Forest, North Carolina), boreal forest (Bonanza Creek Experimental Forest, Alaska), and northern mixed hardwood-conifer forest (Michigan Biological Station, Michigan). The major research goals were to improve understanding of the relationships between radar backscatter and phenological variables (e.g. stand density, tree size, etc.), to improve radar backscatter models of tree canopy properties, and to develop a radar-based scheme for monitoring forest phenological changes. In September 1989, AIRSAR backscatter data were acquired over the Duke Forest. As the aboveground biomass of the loblolly pine forest stands at Duke Forest increased, the SAR backscatter at C-, L-, and P-bands increased and saturated at different biomass levels for the C-band, L-band, and P-band data. We only use the P-band backscatter data and ground measurements here to study the relationships between the backscatter and stand density, the backscatter and mean trunk dbh (diameter at breast height) of trees in the stands, and the backscatter and stand basal area.

Wang, Yong↗

Failure Modes and Effects Analysis of Biorefinery Pathways

This talk provides an overview of failure modes and effects analysis (FMEA) development and implementation as a systematic criticality and risk assessment tool for biorefinery pathways within the FCIC. This supports a quality by design (QbD) approach, and this talk provides a high-level overview of the results for the FMEA evaluation focused on the generation of pine residue materials for high-temperature pyrolysis conversion. the FMEA interviews included two approaches. The first approach was based around the entire system of unit operations giving a wholistic system level view. The second approach used detailed interviews from individual unit operation within the system allowing for specific failures for individual system components. These two approaches provide different resolutions of information about the reliability and risk. The FMEA results focused on failures associated with meeting critical quality attributes (CQAs) identified for the high temperature conversion of loblolly pine residues and were supplemented with experimental data supporting process upsets and reliability also collected within the consortium. Estimations of risk scores for meeting each given CQA specification, identification of the impacts for not meeting a CQA specification, capturing causes associated with material attributes and process parameters for each failure, identification of current detection methods, and speculation of potential mitigation strategies for decreasing a failure’s risk score were gathered through the FMEA interviews, and were combined to understand the overall process risk metrics and where technology, process, and knowledge improvements are needed in order to de-risk emerging biorefineries.

09 BIOMASS FUELS↗

The Co-Firing of Pine Biomass and Waste Coal in 100 and 600 MW Power Plants: A Sustainable Approach to Reduce GHG Emissions

Climate change is a global issue that has gained much attention recently. Co-firing biomass with coal/waste coal reduces the electricity sector’s GHG emissions sustainably. This study uses commercial software to model waste coal and biomass co-firing in 100 MW and 600 MW power plants. The objective is to assess the effects of fluid types (subcritical and supercritical), plant capacities (100 MW and 600 MW), boiler types (pulverized coal and circulating fluidized bed boilers), biomass and waste coal co-firing ratios (0:100, 20:80, 40:60, 60:40, 80:20, and 100:0), and carbon capture and storage efficiencies (0%, 90%, 95%, and 97%) on performance parameters such as net plant efficiency, heat rate, net plant CO2 and SO2, and particulate matter emissions. The feedstocks selected for this investigation include anthracite waste coal and loblolly pine biomass. As the biomass fraction increases from 0% to 100%, co-fired power plants net efficiency increases by 3–8%. Supercritical plants had a 6% higher net plant efficiency than the subcritical plants. The study found that the biomass’s high heating value decreased the fuel flow rate and reduced plant CO2 emissions by 10–16%. With 100% biomass power plant feed and 90% carbon capture and storage efficiency, CO2 emissions drop by 83% and SO2 and PM emissions drop to zero.

Bhoi, Prakashbhai R. (ORCID:0000000333104888)↗

Beyond carbon flux partitioning: Carbon allocation and nonstructural carbon dynamics inferred from continuous fluxes

Carbon (C) allocation and nonstructural carbon (NSC) dynamics play essential roles in plant growth and survival under stress and disturbance. However, quantitative understanding of these processes remains limited. Here, in this work, we propose a framework where we connect commonly measured carbon cycle components (eddy covariance fluxes of canopy CO 2 exchange, soil CO 2 efflux, and allometry-based biomass and net primary production) by a simple mass balance model to derive ecosystem-level NSC dynamics (NSC i ), C translocation (dC i ), and the biomass production efficiency (BPE i ) in above- and belowground plant (i = agp and bgp) compartments. We applied this framework to two long-term monitored loblolly pine (Pinus taeda) plantations of different ages in North Carolina and characterized the variations of NSC and allocation in years under normal and drought conditions. The results indicated that the young stand did not have net NSC flux at the annual scale, whereas the mature stand stored a near-constant proportion of new assimilates as NSC every year under normal conditions, which was comparable in magnitude to new structural growth. Roots consumed NSC in drought and stored a significant amount of NSC post drought. The above- and belowground dC i and BPE i varied more from year to year in the young stand and approached a relatively stable pattern in the mature stand. The belowground BPE bgp differed the most between the young and mature stands and was most responsive to drought. With the internal C dynamics quantified, this framework may also improve biomass production estimation, which reveals the variations resulting from droughts. Overall, these quantified ecosystem-scale dynamics were consistent with existing evidence from tree-based manipulative experiments and measurements and demonstrated that combining the continuous fluxes as proposed here can provide additional information about plant internal C dynamics. Given that it is based on broadly available flux data, the proposed framework is promising to improve the allocation algorithms in ecosystem C cycle models and offers new insights into observed variability in soil–plant–climate interactions.

54 ENVIRONMENTAL SCIENCES↗

Water use in a young Pinus taeda bioenergy plantation: Effect of intensive management on stand evapotranspiration

Abstract The increasing demand for plant‐derived bioenergy is projected to expand tree plantations with intensive silviculture and improved tree genetics. These silvicultural practices result in faster stand development and canopy closure, which may also influence the systems' water dynamics. Here, we studied the evapotranspiration (ET) of a young (5 years old) intensively managed loblolly pine ( Pinus taeda ) stand and investigated the components of ET to determine its contribution to overall water use. We also compared ET with plantations that received less intensive management to determine whether our stand used more water. We used the eddy covariance method to estimate ecosystem‐level total ET (ET EC ), while plot‐level estimates of ET (ET P ) were obtained via soil lysimeters, sap flow sensors, and throughfall collectors, enabling measurement of the components of ET. Soil evaporation (Es) was the largest component of ET P (36%) over the course of the study, while transpiration and canopy interception accounted for 27% and 22%, respectively. Es decreased with stand development, while transpiration and canopy interception increased. Leaf area index (LAI) and precipitation were the most significant factors controlling ET and its components. Compared to previous studies in different sites that have similar age but lower LAI, our stand had higher water use. This high water use in the early stages of stand development was primarily due to high Es before the canopy was fully developed. While there are potential sources of uncertainty when comparing ET EC and the component fluxes in ET P , results from the two methods were not significantly different. This study had the advantage of using multiple methods to understand and verify the component processes that contribute to ET. Therefore, we recommend that multiple measurement techniques be used in the long‐term observation of ET, and in particular for the evaluation of the impact that intensively managed forests have on water resources in the southeastern United States.

54 ENVIRONMENTAL SCIENCES↗

Little vertical and circumferential variations in stem xylem water Δ 2 H and Δ 18 O in three tree species

Vertical and circumferential patterns of xylem water isotope signatures in large trees are rarely characterized but may influence interpretation of water source investigations and soil/xylem water isotope offsets. Furthermore, to examine vertical and circumferential variation in xylem water δ 2 H and δ 18 O, we collected xylem tissue at 5 heights (0, 1, 4, 7 and 10 m) from three replicate trees of three species with contrasting xylem anatomy, two angiosperms (Liquidambar styraciflua and Quercus nigra) and one gymnosperm (Pinus taeda). Concurrently, we also determined δ 2 H and δ 18 O of groundwater, soil water, and recent precipitation. On a different day, we collected circumferential samples at 1 m from the same trees to test for sectorality effects. Water from stem and soil samples were cryogenically extracted and analyzed for δ 2 H and δ 18 O. Mean xylem water δ 2 H and δ 18 O were significantly different between species, both vertically and circumferentially. We did not find significant (p = 0.05) systematic variation in δ 2 H or δ 18 O with height. We found no significant evidence for sectorality effects on δ 2 H, δ 18 O. Variances of vertical synoptic xylem water δ 2 H or δ 18 O were similar between species, 7.2–10.4‰ for δ 2 H and 0.58–0.81‰ for δ 18 O. Circumferential variances were also similar between species, 4.0–6.0 for δ 2 H and 0.37–0.44 for δ 18 O. A mixing model showed that sweetgum, water oak and loblolly pine, were drawing most of their water from deep soil from 45 to 190 cm (84.7, 68.4 and 53.2%, respectively) however, soil water-excess values indicate δ 2 H fractionation effects on these estimates. Dual isotope mixing model evaluation with single and multiple sample configurations showed that source water estimates were not affected by within tree variability of xylem water signatures. Xylem water δ 2 H and δ 18 O variability with height or circumference, was 3.2 and 2.7 times less than between tree variation because of transient temporal and spatial processes and is, therefore, not likely to affect interpretations of water sourcing in these three species.

59 BASIC BIOLOGICAL SCIENCES↗

Impact of storage and blending of algae and forest product residue on fuel blendstock production

Seasonal impacts on the production of algae biomass require blending with other feedstocks such as wood to maintain consistent annual conversion capacity. Idaho National Laboratory (INL) has developed a long-term storage strategy for algae biomass using ensiling, or anaerobic wet storage, that was tested for blends of algae and wood to stabilize the feedstock supply for processing to fuels. Additionally, blending biomass (algae and wood) leverages existing biomass storage approaches commonly used by the feed and forage industry. Earlier research also has demonstrated positive results that indicate ensiling is more effective and economical in normalizing biomass feedstock supply prior to conversions such as HTL (hydrothermal liquefaction) than preserving biomass by drying. By assessing impacts beginning with upstream logistic operations and proceeding through each conversion step, this work focuses on conversion of ensiled and blended biomass to fungible liquid transportation fuel blendstocks. This is accomplished by conversion of the blended biomass (62% Chlorella sp. blended with 38% loblolly pine forest product residues [FPR]) to bio-crude through HTL and subsequent upgrading through HT (hydrotreating) with a commercial refinery catalyst analogous to a refinery process to produce hydrocarbon fuel. In this work, results indicate that carbon retention and quality are preserved in both the bio-crude and upgraded fuel from the ensiled blend, indicating the potential of this approach for managing seasonal variations in algae biomass productivity.

09 BIOMASS FUELS↗

Whole-tree dormant season nitrogen pools for different species receiving combinations of fertilization and irrigation after one short rotation

Our understanding of the accretion and distribution of tree tissue nitrogen (N) pools across a variety of species and genotypes suitable for short-rotation woody crop (SRWC) production in response to water and N availability remains limited. We measured dormant-season, rotation-length, whole-tree N pools for five tree genotypes from four species (two eastern cottonwood, Populus deltoides Bartr., genotypes; American sycamore, Platanus occidentalis L.; American sweetgum, Liquidambar styraciflua L.; and loblolly pine, Pinus taeda L.) receiving irrigation (I), fertilization (F), their combination (IF), or no resources manipulation (C). Our results demonstrate that foliar nitrogen concentration [N] responded to fertilization but was constrained within genotype-specific ranges and varied temporally. Tree genotypes differed in their composite and component tissue N content (N C ), and these differences mostly reflected tissue mass (i.e., larger components and trees resulted in higher N C ). Resource amendments (I, F, IF) resulted in up to 3.8-fold increases in N C compared with C, which were most pronounced for sycamore and sweetgum with F and IF treatments, respectively. By the end of the rotation, forest stands accumulated 73 to 452 kg N ha –1 in tree tissues with 40 – 78 % distributed aboveground and 22 – 60 % distributed belowground. A critical difference between genotypes was that all hardwoods exhibited larger belowground N distributions than the evergreen conifer. Our results stress the importance of belowground N pools and highlight differences among genotypes. Furthermore, our study underscores valuable information about N pools across genotypes suitable for SRWC production, which can be leveraged to inform fertilization plans and devise sustainable nutrient management as production expands across marginal lands.

54 ENVIRONMENTAL SCIENCES↗

National forest timber bids and export price interlinkages in the USA: The bounds testing approach

We examine the interrelationships of national forest timber bid and log export prices for Douglas-fir (Region 6) in 2003–2021 and loblolly pine (Region 8) using time-series stationarity and bounds-testing approaches. The analysis shows the difference in time series properties across different geographies and time scales. Bid prices for these dominant species of timber in each of two Forest Service regions are found to be stationary, while log export prices for those same species appear to be non-stationary. Bounds testing conducted with autoregressive distributed lag modeling methods provides strong evidence for a cointegrating relationship between timber bid prices and log export prices in Forest Service Region 6. In Region 8, evidence for a cointegrating relationship was weak. Here, the share of salvage wood in national forest timber sales is a statistically significant control variable in all models estimated.

54 ENVIRONMENTAL SCIENCES↗

X-ray fluorescence and XANES spectroscopy revealed diverse potassium chemistries and colocalization with phosphorus in the ectomycorrhizal fungus Paxillus ammoniavirescens

Ectomycorrhizal (ECM) fungi play a major role in forest ecosystems and managed tree plantations. Particularly, they facilitate mineral weathering and nutrient transfer towards colonized roots. Among nutrients provided by these fungi, potassium (K) has been understudied compared to phosphorus (P) or nitrogen (N). The ECM fungus Paxillus ammoniavirescens is a generalist species that interacts with the root of many trees and can directly transfer K to them, including loblolly pine. However, the forms of K that ECM fungi can store is still unknown. Here, we used synchrotron potassium X-ray fluorescence (XRF) and K-edge X-ray Absorption Near Edge Structure (XANES) spectroscopy on P. ammoniavirescens growing in axenic conditions to investigate the K chemistries accumulating in the center and the edge of the mycelium. We observed that various K forms accumulated in different part of the mycelium, including K-nitrate (KNO 3 ), K-C-O compounds (such as K-tartrate K 2 (C 4 H 4 O 6 ) and K-oxalate (K 2 C 2 O 4 )), K-S and K-P compounds. Saprotrophic fungi have been shown to excrete carboxylic acids, which in turn play a role in soil mineral weathering. Our finding of several K counter-ions to carboxylic acids may suggest that, besides their direct transfer to colonized roots, K ions can also be involved in the production of compounds necessary for sourcing nutrients from their surrounding environment by ECM fungi. Additionally, this work reveals that XANES spectroscopy can be used to identify the various forms of K accumulating in biological systems.

Ectomycorrhizal symbiosis↗

Using a coupled dispersion model to estimate depletion of a tritium oxide plume by a forest

Tritium processing facilities may release tritium oxide (HTO) to the atmosphere which poses potential health risks to exposed co-located workers and to offsite individuals. Most radiological consequence analyses determine HTO dose by applying Gaussian plume models to simulate the transport of HTO. Within these models, deposition velocity is used to assess the sum of all deposition processes acting on the plume. While this may account for vegetative and soil uptake or respiration processes, it may currently lack inclusion of the complex interactions within heterogeneous forested environments. In this complex morphology, dispersion patterns are significantly altered by changing flow regimes above and below the forest canopy and by the transfer of plume material across the canopy boundary. To determine the effects of a heterogeneous forest canopy on an airborne HTO plume, a Gaussian plume model coupled with an advection-diffusion plume model was applied to estimate transport in the free atmosphere above the forest and within the forest canopy and understory. During 2012, wind speed and wind direction measurements taken at 5 heights, ranging from 2-m to 28-m, on an instrumented meteorological tower located in a loblolly pine forest at the Department of Energy (DOE) Savannah River Site (SRS), near Aiken, SC. From these measurements, model predictions were made over a full spectrum of meteorological conditions. Deposition and resuspension velocities were calculated based on the model-predicted flux of plume material across the top of the forest canopy. Additionally, net deposition velocity of the plume material was calculated as the difference between the deposition and resuspension velocities. The 1st and 5th percentile net deposition velocities were estimated to be 0.7 cm s-1 and 1.2 cm s-1, respectively.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Shear rate dependency on flowing granular biomass material

The commercialization of bioenergy has been significantly limited by various material handling issues due to the poor flowability of granular biomass materials. A good understanding of flow physics and robust constitutive models to predict flow behavior across multiple regimes are essential to address these issues. In this study, we investigated the multi-regime flow behavior of loblolly pine chips, a widely used bioenergy feedstock, through comprehensive inclined plane flow experiments and simulations. A quasi-static hypoplastic model and a cross-regime Drucker-Prager-µ(I) model were calibrated and validated against the physical experiments to investigate the quasi-static and dense flow behavior. The results show that for granular biomass, 1) plane flow (iso-thickness along the plane) exists within a smaller range of inclination while heap flow (varying thickness along the plane) exists within a broader range of inclination, as compared with conventional granular materials (e.g., glass beads); 2) the scaling law of granular biomass flowing on an inclined plane (Froude Number versus dimensionless thickness) forms a bi-linear trend with the turning point governed by the quasi-static and dense flow regimes; 3) the multi-regime DP-µ(I) model can capture the flow behavior in both regimes well at the cost of extra calibration. In conclusion, these findings advance the scientific understanding of the multi-regime flow behavior of granular biomass materials and shed light on formulating novel constitutive models to assist granular biomass handling in the bioenergy industry.

09 BIOMASS FUELS↗

Direct Conversion of Biomass Carbohydrates to Platform Chemicals: 5-Hydroxymethylfurfural (HMF) and Furfural

5-hydroxymethylfurfural (HMF) and furfural are promising platform molecules which can be converted to fuel intermediates and hydrocarbon fuels. Herein, one-step, direct conversion of the carbohydrates in never treated biomass to HMF and furfural in a microwave reactor was investigated. The influence of reaction temperature, time, feedstock, addition of Lewis and Bronsted acids, solvent and solvent to aqueous ratio were studied to find the optimum process conditions to maximize the yields of furfurals. The reaction conditions of 200 degrees C for 5 min with 33 mM HCl and 8 mM AlCl 3 using a dioxane/water (4:1) miscible solvent system were found to be the most conducive for direct dehydration of the glucan and hemicelluloses present in untreated poplar wood to furfural and HMF in yields of 91 and 69%, respectively. Furfural could be easily produced in yields greater than 80%, and once formed, it was found to be stable under the various process conditions explored. In contrast, HMF yields varied with both reaction time and temperature, as it readily underwent rehydration to levulinic acid in yields approaching 25-30% at increased reaction severity. The additions of both Bronsted (HCl) and Lewis (AlCl 3 ) acids in catalytic amounts, i.e., 33 and 8 mM, respectively, were required to maximize the yield of furfurals. Reactions were also performed on other feedstocks (corn stover, switchgrass, loblolly pine, and pure cellulose) to investigate the effect of feedstock type on furfurals yields. Results showed that HMF and furfural yields were primarily dependent on hexosan and pentosan loading regardless of the type of feedstock. In addition, biomass physical features, such as crystallinity or the presence of other biomass constituents, such as lignin, had little influence on furfurals yields.

09 BIOMASS FUELS↗