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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Improved Wide Operating Temperature Range of LiNiCoAiO2-based Li-ion Cells with Methyl Propionate-based Electrolytes

Demonstration of wide operating temperature range Li-ion electrolytes Methyl propionate-based wide operating temperature range electrolytes were demonstrated to provide dramatic improvement of the low temperature capability of Quallion prototype Li-ion cells (MCMB-LiNiCoAlO2). Some formulations were observed to deliver over 60% of the room temperature capacity using a 5C rate at - 40oC !! Represents over a 4-fold improvement over the baseline electrolyte system. Demonstrated operational capability of a number of systems over a wide temperature range (-40 to +70 C) Demonstrated reasonably good long term cycle life performance at high temperature (i.e., at +40deg and +50 C) A number of formulations containing electrolytes additives (i.e., FEC, VC, LiBOB, and lithium oxalate) have been shown to have enhanced lithium kinetics at low temperature and promising high temperature resilience. Demonstrated good performance in larger capacity (12 Ah) Quallion Li-ion cells with methyl propionate-based electrolytes. Current efforts focused upon performing life studies and the impact upon low temperature capability.

Li-ion electrolytes↗

Providing Affordable Access to the Lunar and Martian Gravity Environments for Conducting Scientific Research and Enabling Technology Development

NASA’s Artemis campaign aims to explore the Moon for scientific discovery, technology advancement, and to learn how to live and work on another world as we prepare for human missions to Mars. Like the Moon, Mars is a rich destination for scientific discovery and a driver of technologies that will enable humans to travel and explore far from Earth. Conducting space research and validating gravity-dependent technologies in low-Earth orbit or on the surface of the Moon or Mars is expensive and typically requires long project life cycles. To achieve NASA’s Moon to Mars objectives, it will be necessary to have affordable, ground-based test platforms for carrying out this research and technology development in the relevant gravity environment. A proposed upgrade to NASA Glenn Research Center’s Zero Gravity Research Facility is presented that will provide more than 10 seconds of any prescribed gravity level between microgravity and Earth gravity, allowing users to rapidly conduct dozens of tests per day in a microgravity, Lunar, and Martian gravity environment. The design concept is described along with expected performance characteristics, and technologies and research areas that will benefit. The proposed ground-based variable gravity test capability will enable scientific breakthroughs and Moon to Mars technology and subsystem development while also providing a tool for educating and inspiring future scientists and engineers.

Variable Gravity↗

The Open Data Repository - an Open Science Platform for Long-Tail Research Data

Introduction: ‘Long-tail’ research is performed by individual PIs and small research teams, producing what are often highly diverse, but relatively small da-tasets that span a variety of traditional scientific disci-plines. ‘Long-tail’ research is a fundamental part of realizing NASA’s goals in planetary sciences and a key input feeding into mission life cycles. The ‘long-tail’ has traditionally lacked the resources (available to larg-er groups and missions) to overcome barriers inhibit-ing the adoption of open science practices, including lack of acknowledgment, time, money, guidance, ex-pertise, and trust in available platforms1. Here we show how the Open Data Repository’s (ODR) data publish-ing platform could help lower some of these barriers and accelerate the adoption of open-science practices in planetary science.

‘Long-tail’ research↗

Ni-MH storage test and cycle life test

Gates Aerospace Batteries is conducting two long term test programs to fully characterize the NiMH cell technology for aerospace applications. The first program analyzes the effects of long term storage upon cell performance. The second program analyzes cycle life testing and preliminary production lot testing. This paper summarizes these approaches to testing the NiMH couple and culminates with initial storage and testing recommendations. Long term storage presents challenges to deter the adverse condition of capacity fade in NiMH cells. Elevated but stabilized pressures and elevated but stabilized end-of-charge voltages also appear to be a characteristic phenomenon of long term storage modes. However, the performance degradation is dependent upon specific characteristics of the metal-hydride alloy. To date, there is no objective evidence with which to recommend the proper method for storage and handling of NiMH cells upon shipment. This is particularly critical due to limited data points that indicate open circuit storage at room temperature for 60 to 90 days will result in irrecoverable capacity loss. Accordingly a test plan was developed to determine what method of mid-term to long-term storage will prevent irrecoverable capacity loss. The explicit assumption is that trickle charging at some rate above the self-discharge rate will prevent the irreversible chemical changes to the negative electrode that result in the irrecoverable capacity loss. Another premise is that lower storage temperatures, typically 0 C for aerospace customers, will impede any negative chemical reactions. Three different trickle charge rates are expected to yield a fairly flat response with respect to recoverable capacity versus baseline cells in two different modes of open circuit. Specific attributes monitored include: end-of-charge voltage, end-of-charge pressure, mid-point discharge voltage, capacity, and end-of-discharge pressure. Cycle life testing and preliminary production lot testing continue to dominate the overall technology development effort at GAB. The cell life test program reflects continuing improvements in baseline cell designs. Performance improvements include lower and more stable charge voltages and pressures. The continuing review of production lot testing assures conformance to the design criteria and expectations. This is especially critical during this period of transferring technology from research and development status to production.

Dell, R. Dan↗

NASA PS304 Lubricant Tested in World's First Commercial Oil-Free Gas Turbine

In a marriage of research and commercial technology, a 30-kW Oil-Free Capstone microturbine electrical generator unit has been installed and is serving as a test bed for long-term life-cycle testing of NASA-developed PS304 shaft coatings. The coatings are used to reduce friction and wear of the turbine engine s foil air bearings during startup and shut down when sliding occurs, prior to the formation of a lubricating air film. This testing supports NASA Glenn Research Center s effort to develop Oil-Free gas turbine aircraft propulsion systems, which will employ advanced foil air bearings and NASA s PS304 high temperature solid lubricant to replace the ball bearings and lubricating oil found in conventional engines. Glenn s Oil-Free Turbomachinery team s current project is the demonstration of an Oil-Free business jet engine. In anticipation of future flight certification of Oil-Free aircraft engines, long-term endurance and durability tests are being conducted in a relevant gas turbine environment using the Capstone microturbine engine. By operating the engine now, valuable performance data for PS304 shaft coatings and for industry s foil air bearings are being accumulated.

Weaver, Harold F.↗

NASA Lunar Mining and Construction Activities and Plans

The Space Exploration Policy enacted by the US Congress in 2005 calls for the US National Aeronautics and Space Administration (NASA) to implement a sustained and affordable human and robotic program to explore the solar system and beyond; Extend human presence across the solar system, starting with a human return to the Moon by the year 2020, in preparation for human exploration of Mars and other destinations; Develop the innovative technologies, knowledge, and infrastructures both to explore and to support decisions about the destinations for human exploration; and Promote international and commercial participation in exploration to further U.S. scientific, security, and economic interests. In 2006, NASA released the Lunar Architecture Study, which proposed establishing a lunar Outpost on the Moon with international participation to extend human presence beyond Earth's orbit, pursue scientific activities, use the Moon to prepare for future human missions to Mars, and expand Earth s economic sphere. The establishment of sustained human presence on the Moon for science and exploration combines the design, integration, and operation challenges experienced from both the short Apollo lunar missions and the build-up and sustained crew operations of the International Space Station (ISS). Apollo experience reminds developers and mission planners that hardware must operate under extremely harsh environmental and abrasive conditions and every kilogram of mass and payload must be critical to achieve the mission s objectives due to the difficulty and cost of reaching the lunar surface. Experience from the ISS reminds developers and mission planners that integration of all hardware must be designed and planned from the start of the program, operations and evolution of capabilities on a continuous basis are important, and long-term life-cycle costs and logistical needs are equally or more important than minimizing early development and test costs. Overarching all of this is the need to implement efforts that are sustainable and affordable. One area NASA is developing that can significantly change how systems required for sustained human presence are designed and integrated, as well as potentially break our reliance on Earth supplied logistics, is In-Situ Resource Utilization (ISRU). ISRU, also known living off the land, involves the extraction and processing of local resources into useful products. In particular, the ability to make propellants, life support consumables, fuel cell reagents, and radiation shielding can significantly reduce the cost, mass, and risk of sustained human activities beyond Earth. Also, the ability to modify the lunar landscape for safer landing, transfer of payloads from the lander an outpost, dust generation mitigation, and infrastructure placement and buildup are also extremely important for long-term lunar operations. While extra-terrestrial excavation, material handling and processing, and site preparation and construction may be new to NASA and other space agencies, there is extensive terrestrial hardware and commercial experience that can be leveraged. This paper will provide an overview of current NASA activities in lunar ISRU mining and construction and how terrestrial experience in these areas are important to achieving the goal of affordable and sustainable human exploration.

Sanders, Gerald B.↗

Brayton heat exchange unit development program

A Brayton Heat Exchanger Unit (BHXU), consisting of a recuperator, a heat sink heat exchanger and a gas ducting system, was designed, fabricated, and tested. The design was formulated to provide a high performance unit suitable for use in a long-life Brayton-cycle powerplant. A parametric analysis and design study was performed to establish the optimum component configurations to achieve low weight and size and high reliability, while meeting the requirements of high effectiveness and low pressure drop. Layout studies and detailed mechanical and structural design were performed to obtain a flight-type packaging arrangement. Evaluation testing was conducted from which it is estimated that near-design performance can be expected with the use of He-Xe as the working fluid.

Morse, C. J.↗

Brayton heat exchanger unit development program (alternate design)

A Brayton Heat Exchanger Unit Alternate Design (BHXU-Alternate) consisting of a recuperator, a heat sink heat exchanger, and a gas ducting system, was designed and fabricated. The design was formulated to provide a high performance unit suitable for use in a long-life Brayton-cycle powerplant. Emphasis was on double containment against external leakage and leakage of the organic coolant into the gas stream. A parametric analysis and design study was performed to establish the optimum component configurations to achieve low weight and size and high reliability, while meeting the requirements of high effectiveness and low pressure drop. Layout studies and detailed mechanical and structural design were performed to obtain a flight-type packaging arrangement, including the close-coupled integration of the BHXU-Alternate with the Brayton Rotating Unit (BRU).

Duncan, J. D.↗

The 1981 Goddard Space Flight Center Battery Workshop

Results of testing, analysis, and development of lithium, nickel-cadmium, and nickel-hydrogen batteries are reported. Focus is on the improvement of power systems in the areas of high capacity, high energy density, and long cycle and storage life. Applications of these batteries as spacecraft power supplies are discussed. Those spacecraft include deepspace probes, spacecraft in geostationary orbit, and large space systems in low-Earth orbit.

Halpert, G.↗

Pretreatment of CO oxidation catalysts

CO oxidation catalysts with high activity in the range of 25 C to 100 C are important for long-life, closed-cycle operation of pulsed carbon dioxide 2 lasers. A reductive pretreatment with either CO or H sub 2 was shown to significantly enhance the activity of a commerically-available platinum on tin (IV) oxide (Pt/SnO2) catalyst relative to an oxidative or inert pretreatment or no pretreatment. Pretreatment at temperatures of 175 C and above caused an initial dip in observed CO or O sub 2 loss or CO sub 2 formation in a test gas mixture of 1 percent CO and 0.5 percent O sub 2 in a He gas matrix before a steady-state yield was obtained. This dip was found to be caused by dehydration of the surface of the catalyst and was readily eliminated by humidifying the catalyst or the test gas mixture. It was also found that too much moisture resulted in a lower overall yield of CO sub 2. Under similar conditions, it is hypothesized that the effect of the humidification is to increase the concentration of OH groups on the surface of the catalyst. The effect of having high concentration of CO sub 2 in the test gas mixture upon the loss of CO and O sub 2 as well as the effect of periods of relaxation of the catalyst under non-test gas conditions was studied. The purpose of these studies was to gain an insight into the mechanism of CO oxidation on this type of catalyst.

Vannorman, John D.↗

The effect of H2O and pretreatment on the activity of a Pt/SnO2 catalyst

CO oxidation catalysts with high activity at 25 C to 100 C are important for long-life, closed-cycle operation of pulsed CO2 lasers. A reductive pretreatment with either CO or H2 has been shown to significantly enhance the activity of a commercially available platinum on tin (IV) oxide (Pt/SnO2) catalyst relative to an oxidative or inert pretreatment or no pretreatment. Pretreatment at temperatures of 175 C and above causes an initial dip in the observed CO2 yield before the steady-state yield is attained. This dip has been found to be caused by dehydration of the catalyst during pretreatment and is readily eliminated by humidifying the catalyst or the reaction gas mixture. It is hypothesized that the effect of humidification is to increase the concentration of OH groups on the catalyst surface which play a role in the reaction mechanism.

Vannorman, John D.↗

Lithium-Ion Small Cell Battery Shorting Study

Positive Temperature Coefficient (PTC) provides adequate sustained hard short protection for AEA batteries with up to 8 cells in series. PTC cannot protect against sustained hard short in AEA batteries with 10 cells or more in series. Protective fused connector is a proven way to protect larger batteries from hard short damage: a) Hard short not credible in unmanned missions; b) However, recommended during ground handling; c) Inexpensive item. Preliminary diode protection scheme has passed manned space safety requirements for high voltage batteries. SCM confirmed fused connector did not affect battery health, however, this affect of hard short on the its long calendar and cycle life performance needs to be verified.

Pearson, Chris↗

Design of a flight qualified long-life cryocooler

A second generation Stirling cycle cryogenic refrigerator with a linear drive, magnetic bearings, and clearance seals; designed to produce 5 watts of cooling at 65 Kelvin and to meet Space Shuttle mission requirements is described. The first generation refrigerator met all performance specifications, and operated with no failure for over 12,030 hours. Meeting launch requirements necessitated improvements in the electromagnetic bearings, the radial position sensors, and in the structural design of the moving elements. Organic contamination was eliminated by the use of all metal and ceramic construction. Reductions in system input power are attained by an integral magnetic spring/motor for the displacer and by more efficient linear motors and drive electronics.

Knox, L.↗

Space-Hardware Design for Long Life With High Reliability

In 1991, the Cassini Project, NASA's planetary project to place a spacecraft in orbit about Saturn, funded a study at the Jet Propulsion Laboratory (JPL) to identify rules for design and test of hardware required to function reliably in space for very long lifetimes. Twenty-nine subjects were considered comprising 130 specific rules related to long-life issues such as accelerated life testing, cycling of mechanical devices, selection and application of parts, semiconductor junction temperatures, and worst-case analysis for long life. The study was subsequently published as a JPL document. One major conclusion of the workshop was that unattended space missions extending out to 25 years or more are feasible.

design↗

Space shuttle prototype check valve development

Contaminant-resistant seal designs and a dynamically stable prototype check valve for the orbital maneuvering and reaction control helium pressurization systems of the space shuttle were developed. Polymer and carbide seal models were designed and tested. Perfluoroelastomers compatible with N2O4 and N2H4 types were evaluated and compared with Teflon in flat and captive seal models. Low load sealing and contamination resistance tests demonstrated cutter seal superiority over polymer seals. Ceramic and carbide materials were evaluated for N2O4 service using exposure to RFNA as a worst case screen; chemically vapor deposited tungsten carbide was shown to be impervious to the acid after 6 months immersion. A unique carbide shell poppet/cutter seat check valve was designed and tested to demonstrate low cracking pressure ( 2.0 psid), dynamic stability under all test bench flow conditions, contamination resistance (0.001 inch CRES wires cut with 1.5 pound seat load) and long life of 100,000 cycles (leakage 1.0 scc/hr helium from 0.1 to 400 psig).

Tellier, G. F.↗