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At least 73 records · Page 4

Processing of Lunar Soil Simulant for Space Exploration Applications

NASA's long-term vision for space exploration includes developing human habitats and conducting scientific investigations on planetary bodies, especially on Moon and Mars. Processing and utilization of planetary in-situ resources is recognized as an important element of this vision since it can minimize the level of up-mass that will have to be transported from earth to the planetary bodies. Within this scope and context, we have undertaken a general effort aimed primarily at extracting and refining metals, developing glass, glass-ceramic, or traditional ceramic type materials using lunar soil simulants. In this paper we will present preliminary results on our effort on simultaneous carbothermal reduction of oxides for elemental extraction and zone refining for obtaining high purity metals. In additions we will demonstrate the possibility of developing glass fibers as reinforcement agents for planetary habitat construction, glasses for fixing nuclear waste from potential nuclear power generators, and glasses for magnetic applications. The paper will also include initial thermal characterization of the glasses produced from lunar simulant. Compositional analysis of processed samples will be presented.

Sen, Subhayu↗

Magmatic Processes That Produced Lunar Fire Fountains

Reanalysis of the Apollo 15 A, B, and C green glass beads from slide 15426,72, led to the discovery of patchy, highly vesicular glass rims adhering to beads. These rims are high in S and Ni and low in MgO, but otherwise compositionally similar to the green glasses. We find that these rims represent a unique melt composition that places constraints on lunar magmatic processes. Combining the compositional data for the vesicular glass rims with new minor element data for the green glass beads leads us to hypothesize that the vesicular rim fluid originated near the green glass source, at about 2.2 GPa. These findings support the theory of a heterogeneous lunar mantle, and suggest that sulfur did not drive the eruption from depth, but that degassing volatiles into the vacuum did drive the final fire fountain eruption.

Elkins-Tanton, Linda T.↗

Innovative techniques for the production of energetic radicals for lunar materials processing including photogeneration via concentrated solar energy

The Department of Materials Science and Engineering (MSE) is investigating the use of monatomic chlorine produced in a cold plasma to recover oxygen and metallurgically significant metals from lunar materials. Development of techniques for the production of the chlorine radical (and other energetic radicals for these processes) using local planetary resources is a key step for a successful approach. It was demonstrated terrestrially that the use of UV light to energize the photogeneration of OH radicals from ozone or hydrogen peroxide in aqueous solutions can lead to rapid reaction rates for the breakdown of toxic organic compounds in water. A key question is how to use the expanded solar resource at the lunar surface to generate process-useful radicals. This project is aimed at investigating that question.

Osborn, D. E.↗

Adventures in Lunar Core Processing: Timeline of and Preparation for Opening of Core Sample 73002 for the ANGSA Program

The Apollo mission returned 382 kg of rocks, soil and core samples, which have helped to advance our knowledge of lunar science. Studies of these lunar samples are crucial for our understanding of the Moon’s geological evolution. Here, we present the meticulous process that involves preparing for, and ultimately opening, the unopened Apollo 17 drive tube: 73002,0, so that the next generation of lunar scientists can further our insight into the Moon’s history.

Krysher, C. H.↗

Combined Gamma Ray/neutron Spectroscopy for Mapping Lunar Resources

Some elements in the Moon can be resources, such as hydrogen and oxygen. Other elements, like Ti or the minerals in which they occur, such as ilmenite, could be used in processing lunar materials. Certain elements can also be used as tracers for other elements or lunar processes, such as hydrogen for mature regoliths with other solar-wind-implanted elements like helium, carbon, and nitrogen. A complete knowledge of the elemental composition of a lunar region is desirable both in identifying lunar resources and in lunar geochemical studies, which also helps in identifying and using lunar resources. The use of gamma ray and neutron spectroscopy together to determine abundances of many elements in the top few tens of centimeters of the lunar surface is discussed. To date, very few discussions of elemental mapping of planetary surfaces considered measurements of both gamma rays and the full range of neutron energies. The theories for gamma ray and neutron spectroscopy of the Moon and calculations of leakage fluxes are presented here with emphasis on why combined gamma ray/neutron spectroscopy is much more powerful than measuring either radiation alone.

Reedy, R. C.↗

Processing of Lunar Soil Simulant for Space Exploration Applications

NASA's long-term vision for space exploration includes developing human habitats and conducting scientific investigations on planetary bodies, especially on Moon and Mars. To reduce the level of up-mass processing and utilization of planetary in-situ resources is recognized as an important element of this vision. Within this scope and context, we have undertaken a general effort aimed primarily at extracting and refining metals, developing glass, glass-ceramic, or traditional ceramic type materials using lunar soil simulants. In this paper we will present preliminary results on our effort on carbothermal reduction of oxides for elemental extraction and zone refining for obtaining high purity metals. In additions we will demonstrate the possibility of developing glasses from lunar soil simulant for fixing nuclear waste from potential nuclear power generators on planetary bodies. Compositional analysis, x-ray diffraction patterns and differential thermal analysis of processed samples will be presented.

Sen, Subhayu↗

Lunar differentiation processes.

Igneous rock differentiation as applied to Moon, noting pressure-depth and pressure-temperature phase relationships

LUNAR SURFACE↗

Effect of Space Radiation Processing on Lunar Soil Surface Chemistry: X-Ray Photoelectron Spectroscopy Studies

Current understanding of the chemistry and microstructure of the surfaces of lunar soil grains is dominated by a reference frame derived mainly from electron microscopy observations [e.g. 1,2]. These studies have shown that the outermost 10-100 nm of grain surfaces in mature lunar soil finest fractions have been modified by the combined effects of solar wind exposure, surface deposition of vapors and accretion of impact melt products [1,2]. These processes produce surface-correlated nanophase Feo, host grain amorphization, formation of surface patinas and other complex changes [1,2]. What is less well understood is how these changes are reflected directly at the surface, defined as the outermost 1-5 atomic monolayers, a region not easily chemically characterized by TEM. We are currently employing X-ray Photoelectron Spectroscopy (XPS) to study the surface chemistry of lunar soil samples that have been previously studied by TEM. This work includes modification of the grain surfaces by in situ irradiation with ions at solar wind energies to better understand how irradiated surfaces in lunar grains change their chemistry once exposed to ambient conditions on earth.

Dukes, C.↗

Space environment and lunar surface processes

The development of a general rock/soil model capable of simulating in a self consistent manner the mechanical and exposure history of an assemblage of solid and loose material from submicron to planetary size scales, applicable to lunar and other space exposed planetary surfaces is discussed. The model was incorporated into a computer code called MESS.2 (model for the evolution of space exposed surfaces). MESS.2, which represents a considerable increase in sophistication and scope over previous soil and rock surface models, is described. The capabilities of previous models for near surface soil and rock surfaces are compared with the rock/soil model, MESS.2.

Comstock, G. M.↗

How we processed Apollo lunar seismic data

The Apollo lunar seismic station network gathered data continuously at a rate of 3 x 10 to the 8th bits per day for nearly eight years until termination in September, 1977. The data were processed and analyzed using a PDP-15 minicomputer. On average, 1500 long-period seismic events were detected yearly. Automatic event detection and identification schemes proved unsuccessful because of occasional high noise levels and, above all, the risk of overlooking unusual natural events. The processing procedures which were finally chosen consist of plotting all the data on a compressed time scale, visually picking events from the plots, transferring event data to separate sets of tapes and performing detailed analyses using the latter. Many problems remain, especially in the automatic processing of extraterrestrial seismic signals.

Nakamura, Y.↗

Alsep data processing: How we processed Apollo Lunar Seismic Data

The Apollo lunar seismic station network gathered data continuously at a rate of 3 x 10 to the 8th power bits per day for nearly eight years until the termination in September, 1977. The data were processed and analyzed using a PDP-15 minicomputer. On the average, 1500 long-period seismic events were detected yearly. Automatic event detection and identification schemes proved unsuccessful because of occasional high noise levels and, above all, the risk of overlooking unusual natural events. The processing procedures finally settled on consist of first plotting all the data on a compressed time scale, visually picking events from the plots, transferring event data to separate sets of tapes and performing detailed analyses using the latter. Many problems remain especially for automatically processing extraterrestrial seismic signals.

Latham, G. V.↗

Experimental Investigation of Space Radiation Processing in Lunar Soil Ilmenite: Combining Perspectives from Surface Science and Transmission Electron Microscopy

Energetic ions mostly from the solar wind play a major role in lunar space weathering because they contribute structural and chemical changes to the space-exposed surfaces of lunar regolith grains. In mature mare soils, ilmenite (FeTiO3) grains in the finest size fraction have been shown in transmission electron microscope (TEM) studies to exhibit key differences in their response to space radiation processing relative to silicates [1,2,3]. In ilmenite, solar ion radiation alters host grain outer margins to produce 10-100 nm thick layers that are microstructurally complex, but dominantly crystalline compared to the amorphous radiation-processed rims on silicates [1,2,3]. Spatially well-resolved analytical TEM measurements also show nm-scale compositional and chemical state changes in these layers [1,3]. These include shifts in Fe/Ti ratio from strong surface Fe-enrichment (Fe/Ti >> 1), to Fe depletion (Fe/Ti < 1) at 40-50 nm below the grain surface [1,3]. These compositional changes are not observed in the radiation-processed rims on silicates [4]. Several mechanism(s) to explain the overall relations in the ilmenite grain rims by radiation processing and/or additional space weathering processes were proposed by [1], and remain under current consideration [3]. A key issue has concerned the ability of ion radiation processing alone to produce some of the deeper- penetrating compositional changes. In order to provide some experimental constraints on these questions, we have performed a combined X-ray photoelectron spectroscopy (XPS) and field-emission scanning transmission electron (FE-STEM) study of experimentally ion-irradiated ilmenite. A key feature of this work is the combination of analytical techniques sensitive to changes in the irradiated samples at depth scales going from the immediate surface (approx.5 nm; XPS), to deeper in the grain interior (5-100 nm; FE-STEM).

Christoffersen, R.↗

Space environment and lunar surface processes, 2

The top few millimeters of a surface exposed to space represents a physically and chemically active zone with properties different from those of a surface in the environment of a planetary atmosphere. To meet the need or a quantitative synthesis of the various processes contributing to the evolution of surfaces of the Moon, Mercury, the asteroids, and similar bodies, (exposure to solar wind, solar flare particles, galactic cosmic rays, heating from solar radiation, and meteoroid bombardment), the MESS 2 computer program was developed. This program differs from earlier work in that the surface processes are broken down as a function of size scale and treated in three dimensions with good resolution on each scale. The results obtained apply to the development of soil near the surface and is based on lunar conditions. Parameters can be adjusted to describe asteroid regoliths and other space-related bodies.

Comstock, G. M.↗

Extracting Oxygen from Lunar Simulant Using a Transparent Furnace Pulsed Fluidized Bed

In the event that humans return to the moon, utilizing the local materials will be beneficial for extended stays. Rather than transporting resources, such as oxygen, from Earth, NASA is investigating methods of extracting it from lunar regolith. One promising process is hydrogen reduction. In the hydrogen reduction process, lunar regolith is heated to 1000 C in the presence of hydrogen. The iron oxide (Fe-O) bonds, found in lunar material, are broken and the hydrogen attracts the oxygen to produce water vapor [Allen et al., 1996]. FeO + H2 (right arrow) Fe +H2O. The water vapor is then captured, cleaned, and electrolyzed. The hydrogen is recycled back to the reduction process and the oxygen is stored until consumed by an end user (propulsion, life support, etc.). To obtain a good oxygen yield, the majority of lunar regolith must be exposed to the hydrogen gas and have a high rate of heat transfer from heat source to particle. This is achieved with good solids mixing via fluidization or mechanical agitation. In Generation II of the ROxygen program, the ROxygen Team at Johnson Space Center (JSC) investigated the feasibility of gas only pulsed fluidization as the only means to mix synthetic lunar regolith (simulant) at high temperatures. Fluidized beds have been used in industry to effectively process powders for decades. They consist of gas flowing upward through a bed of particles. The stirring action continuously moves the grains around to achieve uniform mixing of gas, solids, and heat [Geldart, 1986]. A transparent furnace unit was developed by Thoughventions Unlimited LLC (TvU) to aid in the qualitative observation of the fluidization behavior at high temperatures. Multipoint thermocouples and pressure sensors provided quantitative information regarding the quality of mixing. The water produced was measured using humidity sensors and captured using a NASA designed and built condenser. Once the simulant was processed, pneumatically transporting the 'hot' simulant out of the furnace was investigated.

Oryshchyn, L.↗

Irradiation history and accretionary processes in lunar and meteoritic breccias

Particle track studies reveal an abundant record of fossil solar flare tracks in breccia components. Metamorphic events govern the degree to which this record is preserved, and studies of phases with different track retentivities allow limits to be placed on temperatures reached during a rock's history. The least affected breccias have never experienced temperatures as great as 300 C. Two breccias which contain xenon from spontaneous fission of Pu-244 (14301 and 14318) and Xe-129 (14301 only) have never been heated above about 700 C. This and evidence for a surface irradiation of some of the breccia components support a surface implantation model for the origin of the xenon in these breccias. Green glass spheres in 15086 have not been heated above about 300 C during or after breccia formation yet have retained fission tracks for less than 0.7 G.y. Argon ages of about 3.5 G.y. for similar green glass are at least five times as great and may indicate that the glass was not completely outgassed at is formation.

Macdougall, D.↗