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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Systematic Studies in Dynamic Material Response—Early-Career Postdoctoral Research LAO-065-16, Year 2 of 2

Our method (developed under Brandon La Lone’s strategic SDRD) for making low-pressure shock Hugoniot measurements has been improved. It holds great promise for making better low pressure Hugoniot measurements and contributing to the shock physics community. We have refined our method for obtaining information on strength properties of materials, including copper, aluminum, and iron, to a potentially workable technique. Looking at materials other than aluminum with greater strength would likely produce relevant data. Our work with pure iron has yielded interesting results that complement other work on various steel alloys.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Picosecond laser ablation of poly-L-lactide: Effect of crystallinity on the material response

The picosecond laser ablation of poly-L-lactide (PLLA) as a function of laser fluence and degree of crystallinity was examined. The ablation parameters and the surface modifications were analyzed under various irradiation conditions using laser wavelengths ranging from the ultraviolet through the visible. When processing the amorphous PLLA, both energy threshold and topography varied considerably depending on laser wavelength. Laser irradiation showed a reduction in the energy ablation threshold as the degree of crystallinity increased, probably related to photomechanical effects involved in laser ablation with ultra-short pulses and the lower stress accommodation behavior of semicrystalline polymers. In particular, cooperative chain motions are impeded by the higher degree of crystallinity, showing fragile mechanical behavior and lower energy dissipation. The experimental results on ablation rate versus laser energy showed that UV laser ablation on semicrystalline PLLA was more efficient than the visible ablation, i.e., it exhibits higher etch rates over a wide range of pulse energy conditions. These results were interpreted in terms of photo-thermal and photo-chemical response of polymers as a function of material micro-structure and incident laser wavelength. High quality micro-grooves were produced in amorphous PLLA, reveling the potential of ultra-fast laser processing technique in the field of micro-structuring biocompatible and biodegradable polymers for biomedical applications.

36 MATERIALS SCIENCE↗

Theoretical prediction of a highly responsive material: Spin fluctuations and superconductivity in FeNiB 2 system

By analyzing the Fe-Ni-B compositional diagram, we predict an energetically and dynamically stable FeNiB 2 compound. This system belongs to the class of highly responsive state of materials, as it is very sensitive to the external perturbations. This state is also characterized by a high level of spin fluctuations, which strongly influence possible magnetic long- and short-range orders. Furthermore, we demonstrate that these antiferromagnetically dominating fluctuations could lead to the appearance of spin mediated superconductivity. The obtained results suggest a promising avenue for the search of strong spin fluctuation systems and related superconductors. Spin fluctuations (SFs) in itinerant electron magnets play an important role in many metallic systems including weak itinerant magnets, heavy fermion compounds, actinides, Invar alloys, and many magnetoresistive materials. SFs also have been identified in high-temperature superconductors and recently discovered Fe-based superconductors with a clear suggestion about their crucial influence on the mechanisms of unconventional superconductivity. In the majority of cases, superconductivity appears near the magnetic quantum critical point, where magnetism has a pure itinerant character with no local moments involved. This is exactly a case when quantum SFs (including spin zero-point motion) are strong and provide a dominating contribution to many observable physical properties. However, as a typical example, in a case of superconductivity, the direct calculations and prediction of critical temperature from first principles are still not possible. In this situation, one can focus on searching for materials with a strong level of SF, leading to the possible development of promising physical properties. In this paper, we will introduce qualitatively the concept of a highly responsive state (HRS) (see Fig. 1). This term is used here to indicate that a physical system is in a state characterized by an order parameter, which is very sensitive to the external perturbations (pressure, magnetic fields, etc.). The HRS is naturally related to closeness to the instability and, as usual in such situations, one can expect that fluctuations are very important.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Material Response of One-Dimensional, Steady-State Transpiration Cooling in Radiative and Convective Environments

A simplified analytical solution for thermal response of a transpiration-cooled porous heat-shield material in an intense radiative-convective heating environment is presented. Essential features of this approach are "two-flux method" for radiative transfer process and "two-temperature" assumption for solid and gas temperatures. Incident radiative-convective heatings are specified as boundary conditions. Sample results are shown using porous silica with CO2 transpiration and some parameters quantitatively show the effect on this transpiration cooling system. Summarized maps for mass injection rate, porosity and blowing correction factor for radiation are obtained in order to realize such a cooling system.

Kubota, Hirotoshi↗

Analytical ultrasonics for evaluation of composite materials response. Part 1: Physical interpretation

The phenomena associated with the propagation of elastic waves in anisotropic materials are discussed. Wave modes propagating in general directions relative to the material coordinate system are not purely longitudinal nor transverse. Hence the generation of ultrasonic waves by common piezoelectric transducers will generate multiple modes to some extent. The received signals will likely be a combination of different modes. When using two transducers to send and receive ultrasonic waves, deviation of the energy flux vector may reduce the apparent value of the received signal unless the proper orientation of the two transducers with respect to one another is taken into account. And application of reflection from plane boundaries for the purposes of making certain measurements may lead to misinterpretation of results unless one is aware of the differences in multiple mode generation and critical angle phenomena between isotropic and anisotropic materials. When studies or characterizations of composite materials by ultrasonics are to be performed, these phenomena must be taken into consideration so that proper and correct application and interpretation of the measurements can be made. Finally, attention must be drawn again to the fact that composite materials are heterogeneous by definition. The results discussed here have been determined for homogeneous materials only. While the assumption of homogeneity appears to be valid for certain wavelength ranges in composites, future work must continue to study the phenomena of wave propagation in anisotropic, nonhomogeneous materials.

Henneke, E. G., II↗

Designing for time-dependent material response in spacecraft structures

To study the influence on overall deformations of the time-dependent constitutive properties of fiber-reinforced polymeric matrix composite materials being considered for use in orbiting precision segmented reflectors, simple sandwich beam models are developed. The beam models include layers representing the face sheets, the core, and the adhesive bonding of the face sheets to the core. A three-layer model lumps the adhesive layers with the face sheets or core, while a five-layer model considers the adhesive layers explicitly. The deformation response of the three-layer and five-layer sandwich beam models to a midspan point load is studied. This elementary loading leads to a simple analysis, and it is easy to create this loading in the laboratory. Using the correspondence principle of viscoelasticity, the models representing the elastic behavior of the two beams are transformed into time-dependent models. Representative cases of time-dependent material behavior for the facesheet material, the core material, and the adhesive are used to evaluate the influence of these constituents being time-dependent on the deformations of the beam. As an example of the results presented, if it assumed that, as a worst case, the polymer-dominated shear properties of the core behave as a Maxwell fluid such that under constant shear stress the shear strain increases by a factor of 10 in 20 years, then it is shown that the beam deflection increases by a factor of 1.4 during that time. In addition to quantitative conclusions, several assumptions are discussed which simplify the analyses for use with more complicated material models. Finally, it is shown that the simpler three-layer model suffices in many situations.

Hyer, M. W.↗

Assessment of a One-Dimensional Finite Element Charring Ablation Material Response Model for Phenolic-Impregnated Carbon Ablator

In this study, mathematical formulations to model charring ablation problems were numerically implemented using finite element analysis (FEA) with ABAQUS, which account for the material decomposition and progressive surface removal in the heat conduction and the surface energy balance equations. FEA was performed for a one-dimensional model to predict the temperature and ablation histories of a phenolic-impregnated carbon ablator sample (i.e., a common heat shield material for hypersonic vehicles and spacecraft) subjected to oxy-acetylene torch flame (i.e., 0.8 SLPM acetylene gas to 2.7 SLPM oxygen gas). The recovery enthalpy and convective heat transfer coefficient for the ablation model were calculated based on gas compositions and two assumed surface conditions (i.e., equilibrium and frozen). Simulations using the calculated recovery enthalpy and convective heat transfer coefficient resulted in a recession rate of 6.38 times (equilibrium) and 14.08 times (frozen) higher than the experimental data, despite fair agreement of the surface temperature. In addition, the effect of the heat transfer coefficient was investigated through a steady-state ablation analysis. The results of the analysis indicate that there is not one single value for the heat transfer coefficient that would allow the prediction to match both measured recession rate and surface temperature. Possible reasons for such an inconsistency are provided and discussed.

Thermal Protection System↗

High speed synchrotron x-ray phase contrast imaging of dynamic material response to split Hopkinson bar loading

The successful process of amalgamating both the time-resolved imaging capabilities present at the Advanced Photon Source beamline 32ID-B and the proficiency of high-rate loading offered by the split Hopkinson or Kolsky compression/tension bar apparatus is discussed and verification of system effectiveness is expressed via dynamic experiments on various material systems. Single particle sand interaction along with glass cracking during dynamic compression, and fiber-epoxy interfacial failure, ligament-bone debonding, and single-crystal silicon fragmentation due to dynamic tension, were imaged with 0.5 {mu}s temporal resolution and {mu}m-level spatial resolution. Synchrotron x-ray phase contrast imaging of said material systems being loaded with the Kolsky bar apparatus demonstratively depicts the effectiveness of the novel union between these two powerful techniques, thereby allowing for in situ analysis of the interior of the material system during high-rate loading for a variety of applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Constitutive modeling of inelastic anisotropic material response

A constitutive equation was developed to predict the inelastic thermomechanical response of single crystal turbine blades. These equations are essential for developing accurate finite element models of hot section components and contribute significantly to the understanding and prediction of crack initiation and propagation. The method used was limited to unified state variable constitutive equations. Two approaches to developing an anisotropic constitutive equation were reviewed. One approach was to apply the Stouffer-Bodner representation for deformation induced anisotropy to materials with an initial anisotropy such as single crystals. The second approach was to determine the global inelastic strain rate from the contribution of the slip in each of the possible crystallographic slip systems. A three dimensional finite element is being developed with a variable constitutive equation link that can be used for constitutive equation development and to predict the response of an experiment using the actual specimen geometry and loading conditions.

Stouffer, D. C.↗