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NASA NTRS2018

Aubrite and Enstatite Chondrite Impact Melt Meteorites: Analogs to Mercury?

New data obtained during the MESSENGER mission has allowed us to better contrain the composition and mineralogy of the mercurian surface. One unique feature of Mercury is its extremely low oxygen fugacity (ƒO2) (Iron Wustite (IW) -7.3 to IW-2.6). At such extreme conditions, elements that exhibit lithophile behavior on Earth can exhibit chalcophile or siderophile behavior, leading to the formation of exotic sulfides and metals. As no samples have been returned from Mercury, it is critical to study meteorite analogs to better under-stand the formation conditions of the minerals present at the mercurian surface, as well as mercurian magmatic processes. Given the low fO2 on Mercury, we have selected to investigate potential meteoritic analogs for Mercury among the most reduced meteorite types, including the aubrites and enstatite chondrite impact melts. The aubrites are differentiated meteorites that show varying degrees of brecciation, have a similar ƒO2 to the mercurian surface and interior, and contain exotic sulfides that have been inferred to be present on the mercurian surface. The enstatite chondrite impact melts are from undifferentiated parent bodies, have a similar ƒO2 to the mercurian surface and interior, and contain exotic sulfides that have been inferred to be present on the mercurian surface. In this study, we present a comprehensive analysis of a representative suite of aubrites and enstatite chondrite impact melts and assess their relevance to under-standing magmatic processes on Mercury.

Wilbur, Z. E.↗

NASA NTRS1972

Shock metamorphic effects in the Luna 16 soil sample from Mare Fecunditatis.

Diverse lunar soil fragments returned from the Luna 16 mission were examined for evidence in shock metamorphism in order to evaluate the role of meteorite impact in forming the lunar regolith at a new site relatively distant from the Apollo landing sites. It was found that shock metamorphic effects, characteristic of meteorite impact and virtually identical to those observed in Apollo samples, are common in the Luna 16 fragments. Two types of shock effects are present - i.e., a deformation and partial melting features in rock and mineral fragments, and heterogeneous glasses and glassy breccias produced by shock melting. It is concluded that these shock metamorphic effects indicate that regolith formation by meteorite impact has occurred in Mare Fecunditatis and is a general process over the entire moon.

French, B. M.↗

NASA NTRS1986

Impact on rock, water, and air

It is argued that the meteorite-impact accretion is a process vital to the formation of the earth and terrestrial planets and that the evolution of the surfaces with time is affected by impacts. The paper reviews the previous calculations of Ahrens and O'Keefe of the effect of meteorite impacts on the rock surface of the earth, on the ocean, and the atmosphere, and presents some new work on the mechanism of impact-induced atmospheric escape. Using the similarity solution, the mass of atmosphere lost due to the impacts of 1 to 5 kg radius projectiles is calculated. It is shown that no atmosphere is lost for surface sources with energies less than 10 to the 27th erg. Impact of objects in the energy range 10 to the 27th to 10 to the 30th ergs causes gas losses of 10 to the 11th to 10 to the 14th kg (i.e., 10 to the -8th to 10 to the -5th of the total present atmospheric budget). Impact energies of greater than 10 to the 30th ergs cause little increase in atmospheric loss.

Ahrens, Thomas J.↗

NASA NTRS1974

Glass production differences for equal-diameter impact craters

A thermodynamic model of meteorite impact is used to investigate the possibility that the creation of two impact craters of the same apparent diameter may have been accompanied by dissimilar shock heating regimes. For small craters, the idea may be concisely represented by the question of which event produces more glass, a large slow meteorite or a small fast one, if the resulting craters are of the same diameter. So that the results may be most apparent, the only parameters varied in this study are meteorite size and impact velocity. Identical basaltic material is assumed for meteorite and target. For impact velocities between 10 and 70 km/sec, an available model determines the radius of a spherical meteorite which would produce a crater diameter of 20 cm.

Rehfuss, D. E.↗

NASA NTRS2010

Stability of Basalt plus Anhydrite plus Calcite at HP-HT: Implications for Venus, the Earth and Mars

"Canali" observed at Venus surface by Magellan are evidence for very long melt flows, but their composition and origin remain uncertain. The hypothesis of water-rich flow is not reasonable regarding the temperature at Venus surface. The length of these channels could not be explained by a silicate melt composition but more likely, by a carbonate-sulfate melt which has a much lower viscosity (Kargel et al 1994). One hypothesis is that calcite CaCO3 and anhydrite CaSO4 which are alteration products of basalts melted during meteorite impacts. A famous example recorded on the Earth (Chicxulub) produced melt and gas rich in carbon and sulfur. Calcite and sulfate evaporites are also present on Mars surface, associated with basalts. An impact on these materials might release C- and S-rich melt or fluid. Another type of planetary phenomenon (affecting only the Earth) might provoke a high pressure destabilization of basalt+anhydrite+calcite. Very high contents of C and S are measured in some Earth s magmas, either dissolved or in the form of crystals (Luhr 2008). As shown by the high H content and high fO2 of primary igneous anhydrite-bearing lavas, the high S content in their source may be explained by subduction of an anhydrite-bearing oceanic crust, either directly (by melting followed by eruption) or indirectly (by release of S-rich melt or fluid that metasomatize the mantle) . Calcite is a major product of oceanic sedimentation and alteration of the crust. Therefore, sulfate- and calcite-rich material may be subducted to high pressures and high temperatures (HP-HT) and release S- and C-rich melts or fluids which could influence the composition of subduction zone lavas or gases. Both phenomena - meteorite impact and subduction - imply HP-HT conditions - although the P-T-time paths are different. Some HP experimental/theoretical studies have been performed on basalt/eclogite, calcite and anhydrite separately or on a combination of two. In this study we performed piston-cylinder experiments at 1 GPa between 950 and 1700 C using a mixture of 70wt% tholeiitic basalt + 15wt% anhydrite + 15wt% calcite. Up to ~1440 C, an ultracalcic (CaO>13.5 wt%; CaO/Al2O3>1 wt%) picrobasaltic (SiO2~40-45 wt%; Na2O+K2O<2 wt%) melt containing up to 5 wt% SO3 and up to 5.3 wt% CO2+H2O (calculated by difference) is present in equilibrium with clinopyroxene, anhydrite, spinel-chromite, a CAS-phase and a gas composed mainly of CO and an aliphatic thiol (CH2)4SH. Hydrogen was incorporated either by contact between the starting material and air or by diffusion through the capsule during the experiments. The S content in the gas increases with temperature and run duration, implying that gases with various C/S ratios might be released during an impact or at subduction zones, depending on the P-T-t path and on the H content. Above approx.1440 C, a Ca-rich carbonate-sulfate melt forms (in equilibrium with the picrobasaltic melt) which contains a few percents of Na and K. Such melt is not expected to form at Earth s subduction temperatures. If it forms by meteorite impact, it might crystallize too fast to explain long flows like Venus canali. A different basalt/anhydrite/calcite ratio might, however, decrease its formation temperature.

Martin, A. M.↗

NASA NTRS1973

Studies related to the evolution of the lunar soil materials

Studies of the chemistry and morphology of the lunar samples are reported. The presence of fragments of plagoclase in the centers of the impact craters indicate that the glass spheres were derived by meteoritic impact from high velocity particles, while the glass was at high temperatures. From the study of the Apollo 16 samples, it is suggested that this material was formed in a hot impact ejecta blanket, or in an igneous environment, and later exposed to meteoritic impact. It is suggested that particles from Apollo 17 were formed in a cloud of siliceous vapors.

Carter, J. L.↗

NASA NTRS1973

The nature of lunar soil

Characteristics of lunar soil are examined. The paper includes topics such as lunar soil genesis, particle types, grain size distribution, grain shape distribution, specific gravity, minimum and maximum density, and relative density. Lunar soil, consisting of complex mixtures of mineral fragments, miscellaneous glasses, agglutinates, and lithic fragments, is produced primarily by meteorite impacts. The grain size distributions for soils exposed to meteorite reworking for 100 million yr or more are classified as well-graded silty sands and sandy silts. The specific gravity of submillimeter lunar soil samples varies from 2.9 to 3.24 and individual particles range from 1.0 to greater than 3.32. Differences in specific gravity, intragranular porosity, particle shape, surface texture, and grain arrangements result in wide ranges in minimum and maximum densities. Meteorite impacts cause in situ lunar soil to have a low relative density at the surface which increases rapidly to a very high relative density at depths greater than 10 cm to 20 cm.

Carrier, W., III↗

NASA NTRS1991

The role of impacts in the history of the early earth

The significant conclusions of a conference called 'Meteorite Impact and the Early Earth' are reported including data which support the notion that extraterrestrial impacts greatly influenced the development of the earth. The cratering of other planetary surfaces is discussed, and the energy added by meteorite impacts is characterized. The primary effects of large impacts are set forth in terms of atmospheric, oceanic, and biological considerations which suggest that the ramifications would have been significant. Contentious issues include the variation of impact rate with time in the early universe, the interpretation of the record of intense bombardment in the lunar highlands, and the effects related to alternative scenarios. Directions of future study are mentioned including the identification of terrestrial impact structures, conducting searches in the Archean, and assessing ancient impact rates.

French, Bevan M.↗

NASA NTRSDate not supplied

Understanding the Response of Common Spacecraft Shields to Hypervelocity Impacts of Meteorite and Other Terrestrial Analog Materials

Micrometeoroid and orbital debris (MMOD) populations can vary significantly in composition, density, and homogeneity. Hypervelocity testing campaigns intended to design and optimize MMOD shields for spacecraft are recognizing the need to investigate shield response from different types of impactors that span the range of densities observed in the MMOD population, such as nylon, Al, Al 2 O 3 , steel, and Cu. These tests, however, still pre-dominantly employ spherical and homogenous projectiles. Adding any compositional or mineralogical complexity to the impactor, such as what would be expected from a polymineralic micrometeoroid, for ex-ample, will be concomitant with a more complex shockwave structure in the projectile after it impacts the outer surface of any type of MMOD shield. The magnitude of these complexities will depend on how varied the mineralogy of the projectile is, but in the case of a metal-bearing chondrite, the disparate shock impendence between adjacent metal and silicate grains will potentially create localized areas of shock focusing (local increase in nominal shock pressure), or shock shadowing (local decrease in nominal shock pressure). The response of a MMOD shield is generally predicted using a ballistic limit equation – a semiempirical curve, derived from hypervelocity testing data, that denotes a particle diameter (for a given set of impact conditions such as projectile density and impact angle) when a shield will fail as a function of impact speed. These curves exhibit inflection points as a function of impact speed that represent when the projectile experiences sufficient pressure to fragment, melt, or vaporize. The introduction of shock focusing and shadowing in a heterogenous projectile will add uncertainty to the predicted pressures needed to go through each transition, leading to increased uncertainty in the expected performance of the MMOD shield. Therefore, it is necessary to explore the performance of MMOD shields in hypervelocity tests against more complex, natural projectile materials. To this end we have conducted a comparative test series to begin investigating the impact damage caused by meteoritic and terrestrial-analog projectiles, to that of spherical Al projectiles of similar mass.

Impact testing↗

NASA NTRS2008

A Review of Lunar Meteorite Impact-Melt Clast Compositions and Ages

One of the important outstanding goals of lunar science is understanding the bombardment history of the Moon and calibrating the impact flux curve for extrapolation to the Earth and other terrestrial planets. Obtaining a sample from a carefully-characterized interior melt sheet or ring massif is a reliable way to tell a single crater's age. A different but complementary approach is to use extensive laboratory characterization (microscopic, geochemical, isotopic) of float samples to understand the integrated impact history of a region. Both approaches have their merits and limitations. In essence, the latter is the approach we have used to understand the impact history of the Feldspathic Highland Terrain (FHT) as told by lunar feldspathic meteorites.

Cohen, Barbara A.↗

DOE OSTI2024

Numerical modelling of impact seismic sources using the stress glut theory

SUMMARY Meteorite impacts have proved to be a significant source of seismic signal on the Moon, and have now been recorded on Mars by InSight seismometers. Understanding how impacts produce seismic signal is key to the interpretation of this unique data, and to improve their identification in continuous seismic records. Here, we use the seismic Representation Theorem, and particularly the stress glut theory, to model the seismic motion resulting from impact cratering. The source is described by equivalent forces, some resulting from the impactor momentum transfer, and others from the stress glut, which represents the mechanical effect of plasticity and non linear processes in the source region. We condense these equivalent forces into a point-source with a time-varying single force and nine-component moment tensor. This analytical representation bridges the gap between the complex dynamics of crater formation, and the linear point-source representation classically used in seismology. Using the multiphysics modelling software HOSS, we develop a method to compute the stress glut of an impact, and the associated point-source from hypervelocity impact simulations. For a vertical and an oblique impact at 1000 m s−1, we show that the moment tensor presents a significant deviatoric component. Hence, the source is not an ideal isotropic explosion contrary to previous assumptions, and draws closer to a double couple for the oblique impact. The contribution of the point force to the seismic signal appears negligible. We verify this model by comparing two signals: (1) HOSS is coupled to SPECFEM3D to propagate the near-source signal elastically to remote seismic stations; (2) the point-source model derived from the stress-glut theory is used to generate displacements at the same distance. The comparison shows that the point-source model is accurately simulating the low-frequency impact seismic waveform, and its seismic moment is in trend with Lunar and Martian impact data. High-frequencies discrepancies exist, which are partly related to finite-source effects, but might be further explained by the difference in mathematical framework between classical seismology and HOSS’ numerical modelling.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1988

The role of extraterrestrial phenomena in extinction

In the several years since the Alvarez report of anomalously high iridium concentrations at the Cretaceous-Tertiary boundary, evidence for the involvement of meteorite impacts in biological extinction has increased dramatically. Much more research will be needed, however, before meteorite impact is established as a general causal factor in extinction. Of ever greater long-term interest is the possibility that other extraterrestrial forces have had important influences on the evolution of life. To recognize the effects of such forces, it will be necessary to coordinate the research of astronomy and paleontology so that testable predictions can be formulated. It is possible that known, systematic changes in the Solar System or Galaxy have had effects on global biology and that these effects have been preserved in the paleontological record.

Non-NASA Center↗

NASA NTRS1988

Soil mechanics on the Moon, Mars, and Mulberry

From a soil mechanics point of view, the Moon is a relatively simple place. Without any water, organics, or clay minerals, the geotechnical properties of the lunar soil are confined to a fairly limited range. Furthermore, the major soil-forming agent is meteorite impact, which breaks the big particles into little particles; and simultaneously, cements the little particles back together again with molten glass. After about a hundred million years of exposure to meteorite impact, the distribution of particle sizes in the soil achieves a sort of steady state. The majority of the returned lunar soil samples have been found to be well-graded silty-sand to sandy-silt (SM in the Unified Soil Classification System). Each of the particle size distributions plots within a relatively narrow band, which appears to be uniform over the entire lunar surface. This further restricts the range of physical properties of the lunar surface. In contrast, Martian soils should exhibit an extremely wide range of properties. We already know that there is a small amount of water in the soil, greater than in the Martian atmosphere. Furthermore, the soil is suspected to be smectitic clay. That makes two out of the three factors that greatly affect the properties of terrestrial soils.

Carrier, W. D., III↗

NASA NTRS2018

Potential Mercurian Analogues: Aubrite and Enstatite Chondrite Impact Melt Meteorites

The MESSENGER (MErcury Surface Space ENvironment GEochemistry and Ranging Spacecraft) mission provided new data that have helped us better constrain the surficial mineralogy and composition of Mercury. Mercury has an extremely low oxygen fugacity (f O2) (Iron Wustite (IW) -7.3 to IW -2.6), and at these unique conditions, elements, which usually exhibit lithophile behavior on Earth, can exhibit chalcophile or siderophile behavior on Mercury. No samples have been returned from Mercury; therefore, we must study candidate meteorite analogs to better understand the formation conditions of minerals inferred to be present at the Mercurian surface and Mercurian magmatic processes. In this study, we present a comprehensive analysis of a representative suite of eight aubrites and four enstatite chondrite impact melts (ECIM), which both have a similar f O2 to Mercury, and contain exotic sulfides that have been inferred to be present at the Mercurian surface. These characteristics allow us to assess their relevance for understanding the mineralogy and magmatic processes of Mercury. The ECIM were previously classified as aubrites, but we show that they are actually ECIM with a potential EH (high enstatite) parent body origin due to the presence of niningerite, Si-enriched kamacite, and uniform Ni in schreibersite. We propose that, with respect to the aubrites, the ECIM represent an ideal candidate for Mercurian studies due to their mineralogy and modal mineralogy. Compared to the aubrites, the ECIM samples do not contain forsterite or diopside, show a poorer sulfide diversity, contain graphite, and have a higher volume percentage of metal phases. Although the Mercurian surface contains forsterite and diopside, graphite and a similar amount of metal and sulfides as seen in the ECIM are inferred to be present on Mercury. According to the calculated normative Mercurian mineralogy, both candidate meteorites are most analogous to the Caloris Basin and Northern Plains Lower Mg regions.

Wilbur, Zoe E.↗

NASA NTRS1992

Al Umchaimin depression, Western Iraq: An impact structure?

Al Umchaimin, in Arabic 'hiding place' or 'place of ambush', is located at latitude 32 degrees 35.5 N and longitude 39 degrees 25 E. The nearly circular depression averages 2.75 km in diameter and is 33-42 m deep. It is floored with fine-grained, clay-rich deposits, estimated to be 36 m thick, the surface of which shows well-developed desiccation fissures or mudcracks when dry. Because of its nearly circular planimetric shape and its apparent isolation from other surface and subsurface features, it has been considered by some to be a possible meteorite impact structure and by others to be a surface collapse feature that originated following removal of magma from the subsurface as the magma extruded elsewhere. Al Umchaimin was listed in the U.S. Geological Survey tabulation of 110 structures worldwide for which a meteorite impact origin had been suggested. It was placed in Category 6 Structures for which more data are required for classification. It is concluded that, on the basis of the studies that have been made of Al Umchaimin and on the basis of the brief site visit made, Al Umchaimin probably is not an impact structure but most likely resulted from the enlargement and coalescence of sink holes and eventual collapse of the roof material into the resulting cavity.

Underwood, James R., Jr.↗

NASA NTRS1974

Mixing of the lunar regolith

A probabilistic model for mixing and turnover rates for the lunar regolith due to meteoritic impact is presented and evaluated using results from laboratory impact experiments and estimated meteoritic fluxes. The upper millimeter of the lunar surface is shown to be the primary mixing zone in the regolith and an important source for impact melts and vapors. Below this 'mixing layer' the rate of mixing and turnover decreases very rapidly with increasing depth, consistent with well-preserved stratigraphy and resident times deduced from deep drill core tube samples.

Gault, D. E.↗

NASA NTRS2009

Understanding the Reactivity of Lunar Dust for Future Lunar Missions

During the Apollo missions, dust was found to cause numerous problems for various instruments and systems. Additionally, the dust may have caused momentary health issues for some of the astronauts. Therefore, the plan to resume robotic and manned missions to the Moon in the next decade has led to a renewed interest in the properties of lunar dust, ranging from geological to chemical to toxicological. An important property to understand is the reactivity of the dust particles. Due to the lack of an atmosphere on the Moon, there is nothing to protect the lunar soil from ultraviolet radiation, solar wind, and meteorite impacts. These processes could all serve to activate the soil, or produce reactive surface species. On the Moon, these species can be maintained for millennia without oxygen or water vapor present to satisfy the broken bonds. Unfortunately, the Apollo dust samples that were returned to Earth were inadvertently exposed to the atmosphere, causing them to lose their reactive characteristics. In order to aid in the preparation of mitigation techniques prior to returning to the Moon, we measured the ability of lunar dust, lunar dust simulant, and quartz samples to produce hydroxyl radicals in solution[1]. As a first approximation of meteorite impacts on the lunar surface, we ground samples using a mortar and pestle. Our initial studies showed that all three test materials (lunar dust (62241), lunar dust simulant (JSC-1Avf), and quartz) produced hydroxyl radicals after grinding and mixing with water. However, the radical production of the ground lunar dust was approximately 10-fold and 3-fold greater than quartz and JSC-1 Avf, respectively. These reactivity differences between the different samples did not correlate with differences in specific surface area. The increased reactivity produced for the quartz by grinding was attributed to the presence of silicon- or oxygen-based radicals on the surface, as had been seen previously[2]. These radicals may also play a part in the reactivity of the lunar dust and lunar simulant. However, other factors would seem to be required to account for the greatly increased reactivity of the lunar soil. It was proposed that nanometer-size Fe 0 (zero valent) particles in the lunar soil might play a role, as they are not present in quartz or lunar dust simulant. The present work has been performed with the aim of understanding the origin of the considerable reactivity of lunar dust[3]. We have ground 8 lunar soils of varying maturity and source (highland or mare) and measured the hydroxyl-radical production and decay of the reactivity. It was determined that there is a direct correlation between the reactivity and the amount of nanophase metallic iron particles (as a function of soil maturity, I s/FeO, in which Is is the amount of iron present as nanophase iron particles present and FeO is the total iron content) in the samples; thus, the highland soils, with their lesser total FeO content, are less reactive than ground mare soils. Additionally, grinding of nanophase iron simulant [4] showed reactivity in line with the lunar soils and much greater than lunar dust simulant or quartz. Studies aimed at determining the time required to deactivate the reactive soils in a habitable environment showed that the average time to reach 50% of the initial reactivity was approximately 3.5 hours. However, even after one week, none of the soils had returned completely to its unground level of reactivity. In contrast to the reactivity results, there was no obvious correlation between the maturity of the soil and its deactivation time. These results provide the first chemical reactivity and persistence values as an important property of lunar soils, data that is paramount as mankind prepares to return to the Moon.

Wallace, William↗

NASA NTRS2007

The Formation and Chronology of the PAT 91501 Impact-Melt L-Chondrite with Vesicle-Metal-Sulfide Assemblages

The L chondrite Patuxent Range (PAT) 41 91501 is an 8.5-kg unshocked, homogeneous, igneous-textured impact melt that cooled slowly compared to other meteoritic impact melts in a crater floor melt sheet or sub-crater dike. We conducted mineralogical and tomographic studies of previously unstudied mm- to cm-sized metal-sulfide-vesicle assemblages and chronologic studies of the silicate host. Metal-sulfide clasts constitute about 1 vol.%, comprise zoned taenite, troilite and pentlandite, and exhibit a consistent orientation between metal and sulfide and of metal-sulfide contacts. Vesicles make up approximately 2 vol.% and exhibit a similar orientation of long axes. Ar-39-Ar-40 measurements date the time of impact at 4.461 +/- 0.008 Gyr B.P. Cosmogenic noble gases and Be-10 and Al-2l activities suggest a pre-atmospheric radius of 40-60 cm and a cosmic ray exposure age of 25-29 Myr, similar to ages of a cluster of L chondrites. PAT 91501 dates the oldest known impact on the L chondrite parent body. The dominant vesicle-forming gas was S2 (approximately 15-20 ppm), which formed in equilibrium with impact-melted sulfides. The meteorite formed in an impact melt dike beneath a crater, as did other impact melted L chondrites, such as Chico. Cooling and solidification occurred over approximately 2 hours. During this time, approximately 90% of metal and sulfide segregated from the local melt. Remaining metal and sulfide grains oriented themselves in the local gravitational field, a feature nearly unique among meteorites. Many of these metal sulfide grains adhered to vesicles to form aggregates that may have been close to neutrally buoyant. These aggregates would have been carried upward with the residual melt, inhibiting further buoyancy-driven segregation. Although similar processes operated individually in other chondritic impact melts, their interaction produced the unique assemblage observed in PAT 91501.

Benedix, G. K.↗