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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

In-process monitoring and prediction of droplet quality in droplet-on-demand liquid metal jetting additive manufacturing using machine learning

Abstract In droplet-on-demand liquid metal jetting (DoD-LMJ) additive manufacturing, complex physical interactions govern the droplet characteristics, such as size, velocity, and shape. These droplet characteristics, in turn, determine the functional quality of the printed parts. Hence, to ensure repeatable and reliable part quality it is necessary to monitor and control the droplet characteristics. Existing approaches for in-situ monitoring of droplet behavior in DoD-LMJ rely on high-speed imaging sensors. The resulting high volume of droplet images acquired is computationally demanding to analyze and hinders real-time control of the process. To overcome this challenge, the objective of this work is to use time series data acquired from an in-process millimeter-wave sensor for predicting the size, velocity, and shape characteristics of droplets in DoD-LMJ process. As opposed to high-speed imaging, this sensor produces data-efficient time series signatures that allows rapid, real-time process monitoring. We devise machine learning models that use the millimeter-wave sensor data to predict the droplet characteristics. Specifically, we developed multilayer perceptron-based non-linear autoregressive models to predict the size and velocity of droplets. Likewise, a supervised machine learning model was trained to classify the droplet shape using the frequency spectrum information contained in the millimeter-wave sensor signatures. High-speed imaging data served as ground truth for model training and validation. These models captured the droplet characteristics with a statistical fidelity exceeding 90%, and vastly outperformed conventional statistical modeling approaches. Thus, this work achieves a practically viable sensing approach for real-time quality monitoring of the DoD-LMJ process, in lieu of the existing data-intensive image-based techniques.

Gaikwad, Aniruddha (ORCID:0000000285642621)↗

The C 2 H 4 O isomers in the oxidation of ethylene

A combined rotational spectroscopy, thermochemistry, and kinetic modeling study explores the mechanism of acetaldehyde (ethanal), vinyl alcohol (ethenol), and ethylene oxide (oxirane) formation in the oxidation of ethylene (ethene). Multiplexed quantitative detection of oxidation intermediates and products exiting a SiO 2 / SiC microreactor at 1700 K is demonstrated with the BrightSpec W-band chirped-pulse Fourier transform millimeter-wave spectrometer. The broadband rotational spectrum contains transitions of formaldehyde (CH 2 O), methoxy (CH 3 O), methanol (CH 3 OH), ketene (CH 2 CO), acetaldehyde (CH 3 CHO), syn-vinyl alcohol (syn- CH 2 CHOH), anti-vinyl alcohol (anti-CH 2 CHOH), oxirane (c-CH 2 OCH 2 ), propyne (CH 3 CCH), and syn-propanal (syn-CH 3 CH 2 CHO). We focus on the three C 2 H 4 O species and deduce their concentration ratio [CH 3 CHO]:[CH 2 CHOH]:[c-CH 2 OCH 2 ] = 1:0.7(2):0.06(2) by comparing the observed line intensities to those simulated with the PGOPHER software. Detailed thermochemistry of the C 2 H 4 O isomers and conformers is provided by Active Thermochemical Tables. The observed excess concentrations of vinyl alcohol and oxirane relative to the more stable acetaldehyde compared to the equilibrium ratio at 1700 K (1:0.087:0.000024), point to direct chemical pathways to these higher energy isomers. The mechanism for the formation of the three C 2 H 4 O isomers is analyzed using a 0-D homogenous reactor kinetics simulation for ethylene oxidation. The ratios of the C 2 H 4 O isomers concentrations predicted by the kinetic model are compared to the experimental values.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Real-time steerable frequency-stepped Doppler backscattering (DBS) system for local helicon wave electric field measurements on the DIII-D tokamak

A new frequency-stepped Doppler backscattering (DBS) system has been integrated into a real-time steerable electron cyclotron heating launcher system to simultaneously probe local background turbulence (f < 10 MHz) and high-frequency (20–550 MHz) density fluctuations in the DIII-D tokamak. The launcher allows for 2D steering (horizontally and vertically) over wide angular ranges to optimize probe location and wavenumber response. The vertical steering can be optimized during a discharge in real time. The new DBS system employs a programmable frequency synthesizer with adjustable dwell time as a source to launch either O or X-mode polarized millimeter waves. This system can step in real-time over the entire E-band frequency range (60–90 GHz). This combination of capabilities allows for the diagnosis of the complex internal spatial structure of high power (>200 kW) helicon waves (476 MHz) injected from an external antenna during helicon current drive experiments in DIII-D. Broadband density fluctuations around the helicon frequency are observed during real-time scans of measurement location and wavenumber during these experiments. Analysis indicates that these broadband high-frequency fluctuations are a result of backscattering of the DBS millimeter-wave probe beam from plasma turbulence modulated by the helicon wave. It is observed that background turbulence is effectively locally “tagged” with the helicon wave electric field, forming images of the turbulent spectrum in the overall density fluctuation spectrum that appear as high-frequency sidebands of the turbulence. These observations of background turbulence and high-frequency fluctuations open up the possibility of monitoring local helicon wave amplitude by comparing the high-frequency signal amplitude to the simultaneously measured background turbulence. In combination with the real-time measurement location and wavenumber scanning capabilities (offered by real-time frequency-stepping and steering), this allows rapid determination of the spatial distribution of the helicon wave power during steady-state plasma operation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Molecular structure determination: Equilibrium structure of pyrimidine (m-C 4 H 4 N 2 ) from rotational spectroscopy (reSE) and high-level ab initio calculation (re) agree within the uncertainty of experimental measurement

The pure rotational spectrum of pyrimidine (m-C 4 H 4 N 2 ), the meta-substituted dinitrogen analog of benzene, has been studied in the millimeter-wave region from 235 GHz to 360 GHz. The rotational spectrum of the ground vibrational state has been assigned and fit to yield accurate rotational and distortion constants. Over 1700 distinct transitions were identified for the normal isotopologue in its ground vibrational state and least-squares fit to a partial sextic S-reduced Hamiltonian. Transitions for all four singly substituted 13 C and 15 N isotopologues were observed at natural abundance and were likewise fit. Deuterium-enriched samples of pyrimidine were synthesized, giving access to all eleven possible deuterium-substituted isotopologues, ten of which were previously unreported. Experimental values of rotational constants and computed values of vibration–rotation interaction constants and electron-mass corrections were used to determine semi-experimental equilibrium structures (r e SE ) of pyrimidine. The r e SE structure obtained using coupled-cluster with single, double, and perturbative triple excitations [CCSD(T)] corrections shows exceptional agreement with the re structure computed at the CCSD(T)/cc-pCV5Z level (≤0.0002 Å in bond distance and ≤0.03° in bond angle). Of the various computational methods examined, CCSD(T)/cc-pCV5Z is the only method for which the computed value of each geometric parameter lies within the statistical experimental uncertainty (2σ) of the corresponding semi-experimental coordinate. The exceptionally high accuracy and precision of the structure determination is a consequence of the large number of isotopologues measured, the precision and extent of the experimental frequency measurements, and the sophisticated theoretical treatment of the effects of vibration–rotation coupling and electron mass. Taken together, these demanding experimental and computational studies establish the capabilities of modern structural analysis for a prototypical monocyclic aromatic compound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spectroscopy of Chlorosyl Fluoride, FClO

FClO has been proposed as an intermediate in reactions involving ClF, Cl2O, and ClF3O, and it has been suggested as a molecule of atmospheric interest. It has been prepared in situ by the hydrolysis of ClF3. The pure rotational spectrum of FClO has been studied by conventional millimeter wave techniques and by microwave Fourier transform spectroscopy. Selected transitions were searched for using predictions based on an analysis of the nu(sub 1) band. FClO is an asymmetric prolate top, kappa = -0.8950 for F(35)ClO, with a rather small dipole component of 0.093 (4) D along the a-axis and a larger one of 1.93 (5) D along the b-axis. Transitions with 0 <= J <= 54 and 0 <= K(sub a) <= 18 were observed. Cl hyperfine splitting was generally observable throughout the spectrum with F-19 spin-rotation splitting observable as well in the microwave region. Structural parameters, harmonic force constants, and nuclear magnetic shielding parameters were derived and will be compared with data of related molecules, such as ClF3, ClF, FClO2, and FClO3. High resolution infrared spectra were taken in the regions of the FCl stretching mode and bending mode around 600 and 310/cm, respectively. A preliminary analysis indicates that the FCl stretch, near 596.86/cm for F(35)ClO, is in resonance with the dark overtone of delta near 617/cm. A brief progress report will be given.

Mueller, Holger S. P.↗

Millimeter wave satellite concepts, volume 1

The identification of technologies necessary for development of millimeter spectrum communication satellites was examined from a system point of view. Development of methodology based on the technical requirements of potential services that might be assigned to millimeter wave bands for identifying the viable and appropriate technologies for future NASA millimeter research and development programs, and testing of this methodology with selected user applications and services were the goals of the program. The entire communications network, both ground and space subsystems was studied. Cost, weight, and performance models for the subsystems, conceptual design for point-to-point and broadcast communications satellites, and analytic relationships between subsystem parameters and an overall link performance are discussed along with baseline conceptual systems, sensitivity studies, model adjustment analyses, identification of critical technologies and their risks, and brief research and development program scenarios for the technologies judged to be moderate or extensive risks. Identification of technologies for millimeter satellite communication systems, and assessment of the relative risks of these technologies, was accomplished through subsystem modeling and link optimization for both point-to-point and broadcast applications.

Hilsen, N. B.↗

Radio, millimeter-submillimeter, and infrared spectra of flat-spectrum extragalactic radio sources

We present radio to submillimeter-wave continuum spectra of 44 bright, compact extragalactic radio sources with flat spectra at centimeter wavelengths ('blazars'). Infrared J, H, and K flux densities are added to the spectra of six of these objects. These spectra are useful in comparisons of x-ray and gamma-ray measurements with the multiwaveband properties of blazars. A number of the objects have been detected as strong, hard gamma-ray sources by the Compton Gamma Ray Observatory (CGRO). The millimeter-wave spectra of the gamma-ray bright blazars we observe are flatter on average than for the sample as a whole.

Bloom, Steven D.↗

Development of Leaky Wave Antennas for Layered Ridge Dielectric Waveguide

The millimeter wave, especially above 100 GHz, and the submillimeter wave frequency spectrum offers the possibility for narrow-beam, high-resolution antennas which are critical for high definition radars required for space debris tracking, airport ground avoidance radars, and missile tracking. In addition, the frequency which most atmospheric constituents may be detected lie in this part of the frequency spectrum. Therefore, the development of electronic components for millimeter/submillimeter wave passive sensors is required for environmental monitoring of the Earth's atmosphere. Typical microwave transmission lines such as microstrip and coplanar waveguide rely on two or more electrical conductors to concentrate and guide the electromagnetic energy. Unfortunately, the surface resistance of the conductors increases as the square root of frequency. In addition, the circuit dimensions must be decreased with increasing frequency to maintain a single mode transmission line which further increases the conductor loss. An alternative family of transmission lines are formed from two or more insulating materials and rely on the differences in the permittivities between the two materials to guide the wave. No metal conductors are required although some dielectric waveguides do utilize a metallic ground plane to facilitate the interconnections of active electrical elements or to reduce the transmission line size. Examples of such transmission lines are image guides, insulated image guides, trapped image guides, ridge guide, and layered ridge dielectric waveguide (LRDW). Although most dielectric waveguides have dimensions on the order of lambda to provide sufficient field confinement, the LRDW has been shown to provide good field confinement for electrically small lines. This offers an advantage in circuit integration. It has been shown that a periodic array of metallic strips placed either along or on top of a dielectric waveguide forms an effective radiator. This antenna is easy to fabricate and there is good background of microstrip type antenna design information in the literature. This paper reports the development of the first frequency scanning antenna fed by a LRDW.

Ponchak, George E.↗

Collaborative research in tunneling and field emission pumped surface wave local oscillators and amplifiers for infrared and submillimeter wavelengths under director's discretionary fund

Progress is reported in work towards the development of surface wave sources for the infrared and sub-millimeter portion of the spectrum to be based upon electron pumping by tunneling electrons in metal-barrier-metal or metal-barrier-semiconductor devices. Tunneling phenomena and the coupling of radiation to tunnel junctions were studied. The propagation characteristics of surface electro-magnetic modes in metal-insulator-p(++) semiconductor structures as a function of frequency were calculated. A model for the gain process based upon Tucker's formalism was developed and used to estimate what low frequency gain might be expected from such structures. The question of gain was addressed from a more fundamental viewpoint using the method of Lasher and Stern.

Gustafson, T. K.↗

Atlas 2 Animation

The Atmospheric Laboratory for Applications and Science-2 (ATLAS-2), was designed to collect data on the relationship between the sun's energy output and Earth's middle atmosphere and how these factors affect the ozone layer. The ATLAS-2 flew on the Space Shuttle Discovery's mission SST-56, launched on April 8, 1993. The videotape consists of an animated tour of the instruments that were included as part of the mission. The first half of the tape shows the various instruments, pointing to each in turn and identifying each by the associated initialisms. The instruments identified were: the Atmospheric Trace Molecule Spectroscopy (ATMOS), Millimeter Wave Atmospheric Sounder (MAS), Shuttle Solar Backscatter Ultraviolet/A (SSBUV/A) spectrometer, Solar Spectrum Measurement (SOLSPEC) instrument, Solar Ultraviolet Irradiance Monitor (SUSIM), Active Cavity Radiometer (ACR) and Solar Constant (SOLCON).) The second half of the animation shows the same tour without the pointing or the identification of the instruments.

Source record↗

The microwave spectrum of the AlO radical

The rotational spectrum of the aluminum monoxide radical in the ground electronic state X 2Sigma(+) was observed in the millimeter- and submillimeter-wave region. Aluminum monoxide radicals were generated directly in a flow reactor absorption cell by the reaction of N2O with aluminum vaporized from a high-temperature crucible. The observed spectrum was analyzed to yield molecular constants including the rotational constant, centrifugal distortion constant, spin-rotation interaction constant, magnetic hyperfine interaction constants, and nuclear quadrupole coupling constant.

Yamada, Chikashi↗

Millimeter-wave spectra and variability of bright, compact radio sources

Observations at 2.7 mm and at 1.5 cm were used to study the millimeter spectra and variability of 176 bright, compact radio sources. More than 20 percent of the flat-spectrum sources, but none of the steep-spectrum sources, were seen to vary at 1.5 cm by at least 30 percent over ten months. This is consistent with the hypothesis that flat-spectrum sources are compact and possibly beamed, while steep-spectrum sources are not. These data can also be used to choose sources for VLBI observations and for calibration of millimeter-wave observations.

Edelson, R. A.↗

W/V-Band RF Propagation Experiment Design

The utilization of frequency spectrum for space-to-ground communications applications has generally progressed from the lowest available bands capable of supporting transmission through the atmosphere to the higher bands, which have required research and technological advancement to implement. As communications needs increase and the available spectrum in the microwave frequency bands (3 30 GHz) becomes congested globally, future systems will move into the millimeter wave (mm-wave) range (30 300 GHz). While current systems are operating in the Ka-band (20 30 GHz), systems planned for the coming decades will initiate operations in the Q-Band (33 50 GHz), V-Band (50 75 GHz) and W Band (75 110 GHz) of the spectrum. These bands offer extremely broadband capabilities (contiguous allocations of 500 MHz to 1GHz or more) and an uncluttered spectrum for a wide range of applications. NASA, DoD and commercial missions that can benefit from moving into the mm-wave bands include data relay and near-Earth data communications, unmanned aircraft communications, NASA science missions, and commercial broadcast/internet services, all able to be implemented via very small terminals. NASA Glenn Research Center has a long history of performing the inherently governmental function of opening new frequency spectrum by characterizing atmospheric effects on electromagnetic propagation and collaborating with the satellite communication industry to develop specific communications technologies for use by NASA and the nation. Along these lines, there are critical issues related to W/V-band propagation that need to be thoroughly understood before design of any operational system can commence. These issues arise primarily due to the limitations imposed on W/V-band signal propagation by the Earth s atmosphere, and to the fundamental lack of understanding of these effects with regards to proper system design and fade mitigation. In this paper, The GRC RF propagation team recommends measurements that are required to assure that the risk associated with the use of mm-wave is minimized. We develop first order beacon and transponder system payload requirements and beacon terminal requirements. We will suggest and discuss a possible hardware implementation for the space segment, as well for the ground segment. A discussion on a propagation measurement campaign for taking relevant statistical data is also included.

Acosta, Roberto J.↗

Solar millimeter bursts

Solar burst observations in the region above 10 GHz (wavelengths less than 3 cm.) are discussed. Observations have shown that many major solar events have large millimeter wave components. The total burst radio energy is frequently concentrated in this part of the spectrum. Graphs are presented showing the peak flux density spectrum for bursts on specific dates. Microwave burst mean duration is plotted as a function of the particle energy.

Croom, D. L.↗

Remote sensing technologies for Space Missions in the second half of the nineties' decade

The remote sensing research and technology to be used in the development of future NASA missions are discussed, with consideration given to earth sciences, planetary sciences, solar physics, and astrophysics. The remote sensing missions planned in the four application areas, their payload packages, and the particular instruments that will make up these packages are described. The advanced technologies to be used include systems and devices that address the detection of radiation in the radio, microwave, millimeter wave, submillimeter wave, IR, visible, UV, X-ray, and gamma-ray parts of the spectrum, including supporting technologies, such as optics, liquid cryogen transfer systems, and 'smart' sensors.

Sokoloski, M. M.↗

A Non-Cooperative Game-Based Distributed Beam Scheduling Framework for 5G Millimeter-Wave Cellular Networks

Here, this paper studies the problem of distributed beam scheduling for 5G millimeter-Wave (mm-Wave) cellular networks where base stations (BSs) belonging to different operators share the same spectrum without centralized coordination among them. Our goal is to design efficient distributed scheduling algorithms to maximize the network utility, which is a function of the achieved throughput by the user equipment (UEs), subject to the average and instantaneous power consumption constraints of the BSs. We propose a Media Access Control (MAC) and a power allocation/adaptation mechanism utilizing the Lyapunov stochastic optimization framework and non-cooperative games. In particular, we first decompose the original utility maximization problem into two sub-optimization problems for each time frame, which are a convex optimization problem and a non-convex optimization problem, respectively. By formulating the distributed scheduling problem as a non-cooperative game where each BS is a player attempting to optimize its own utility, we provide a distributed solution to the non-convex sub-optimization problem via finding the Nash Equilibrium (NE) of the game whose weights are determined optimally by the Lyapunov optimization framework. Finally, we conduct simulation under various network settings to show the effectiveness of the proposed game-based beam scheduling algorithm in comparison to that of several reference schemes.

42 ENGINEERING↗