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Finely powdered titanium oxide was added to silicone azide as the sintering agent to produce a nonflammable material. Mixing proportions, physical properties, and chemical composition of the fireproofing material are included.
A description is presented of an analysis of a total of 26 samples from three core segments (70009, 70008, 70007) of the Apollo 17 deep drill string. The deep drill string was taken about 700 m east of the Camelot Crater in the Taurus-Littrow region of the moon. Three core segments have been chemically characterized from the mainly coarse-grained upper portion of the deep drill string. The chemical data suggest that the entire 70007-70009 portion of the deep drill string examined was not deposited as a single unit, but was formed by several events sampling slightly different source materials which may have occurred over a relatively short period of time. According to the data from drill stem 70007, there were at least two phases of deposition. Core segment 70009 is probably derived from somewhat different source material than 70008. It seems to be a very well mixed material.
The global characteristics of the Martian surface layer are discussed on the basis of thermal, albedo, color, and radar data for the region between approximately 60 deg S and 60 deg N. Thermal data reveal the presence of large low- and high-inertia regions of the northern hemisphere, with much of the south covered by material of moderate inertia. There is a strong anticorrelation between inertia and albedo, a correlation between inertia and rock abundance, and, over much of the planet, a correlation of radar-derived density with inertia. Viking Orbiter color data indicate the presence of three major surface materials: low-inertia, bright-red material that is presumably dust; high-inertia, dark-grey material interpreted to be lithic material mixed with palagonitelike dust; and moderate-inertia, dark-red material that is rough at subpixel scales and interpreted to be indurated. Observations from the Viking landing sites show rocks, fines of varying cohesion and crusts. These sites have indications of aeolian erosion and deposition in the recent past.
In this work, we present a gradient-informed design optimization of nuclear reactor core components based on neutronics objectives with both continuous and discrete materials. The main argument in favor of using gradient-informed design optimization is that it scales well with increasing dimensionality of the design space. First, a challenge problem with 121 free parameters is solved with a gradient-informed method and then with a genetic algorithm. Then, a challenge problem to optimize the flux profile of a simplified assembly with eight axial zones is solved. Both challenge problems are solved using directly calculated derivatives from Tools for Sensitivity and Uncertainty Analysis Methodology Implementation (TSUNAMI) in the SCALE package. Furthermore, we demonstrate how a discrete optimization problem—selection of materials for 121 voxels—can be lifted into a continuous problem with mixed materials. In the continuous space, adjoint-based gradients are well-defined, and gradient descent is applicable. Then, a forcing function is introduced that with the selection of an appropriately sized hyperparameter can be used to guide the optimized continuous solution back into a discrete solution. This paper presents an account of the challenges that were faced when applying a gradient-informed optimization algorithm using a Monte Carlo calculation to estimate the gradient information and compares a gradient descent optimization method to a genetic algorithm optimization of the same geometry. Overall, this work demonstrates the potential use of adjoint-based gradient calculations in design optimization of nuclear systems.
Global and regional dust storms on Mars have been observed from Earth-based telescopes, Mars orbiters, and surface rovers and landers. Dust storms can be global and regional. Dust is material that is suspended into the atmosphere by winds and has a particle size of 1-3 micrometer. Planetary scientist refer to loose unconsolidated materials at the surface as "soil." The term ''soil'' is used here to denote any loose, unconsolidated material that can be distinguished from rocks, bedrock, or strongly cohesive sediments. No implication for the presence or absence of organic materials or living matter is intended. Soil contains local and regional materials mixed with the globally distributed dust by aeolian processes. Loose, unconsolidated surface materials (dust and soil) may pose challenges for human exploration on Mars. Dust will no doubt adhere to spacesuits, vehicles, habitats, and other surface systems. What will be the impacts on human activity? The objective of this paper is to review the chemical, mineralogical, and physical properties of the martian dust and soil.
The Fukushima Daiichi accident generated degraded nuclear fuel material, mixed with other reactor components, known as molten core-concrete interaction (MCCI) material. Simulant MCCI material was synthesised, excluding highly radioactive fission products, containing depleted U, and incorporating Ce as a surrogate for Pu. Multi-modal µ-focus X-ray analysis revealed the presence of the expected suite of U-Zr-O containing minerals, in addition to crystalline silicate phases CaSiO 3 , SiO 2 -cristobalite and Ce-bearing percleveite, (Ce,Nd) 2 Si 2 O 7 . The formation of perclevite resulted from reaction between the U-Zr-O-depleted Ce-Nd-O melt and the silicate (SiO 2 ) melt. It was determined that the majority of U was present as U 4 , whereas Ce was observed to be present as Ce 3+ , consistent with the highly reducing synthesis conditions. A range of Fe-containing phases characterised by different average oxidation states were identified, and it is hypothesised that their formation induced heterogeneity in the local oxygen potential, influencing the oxidation state of Ce.
A new technique called friction stir interlocking (FSI) was applied for lap-joining of AZ31 magnesium sheet and thermoset carbon fiber reinforced polymer (TS-CFRP) sheet. Instead of directly joining AZ31 and TS-CFRP, a series of magnesium interlocks were used to friction stir weld with AZ31 sheet to enable joining with TS-CFRP. Microstructural characterization of joint cross sections showed that a tool rotation rate of 800 rpm produced incomplete mixing of magnesium interlocks and the top AZ31 sheet, while 1200 rpm achieved sufficient material mixing to avoid unwelded regions. Mechanical property characterization showed that AZ31/TS-CFRP dissimilar joints failed through the magnesium interlock shanks during lap shear tensile testing, with a maximum normalized joint strength reaching ~100 MPa.
Silicon carbide (SiC) represents a promising but largely untested plasma-facing material (PFM) for next-step fusion devices. In this work, an analytic mixed-material erosion model is developed by calculating the physical (via SDTrimSP) and chemical (via empirical scalings) sputtering yield from SiC, Si, and C. The Si content in the near-surface SiC layer is predicted to increase during D plasma bombardment due to more efficient physical and chemical sputtering of C relative to Si. Silicon erosion from SiC thereby occurs primarily from sputtering of the enriched Si layer, rather than directly from the SiC itself. SiC coatings on ATJ graphite, manufactured via chemical vapor deposition, were exposed to repeated H-mode plasma discharges in the DIII-D tokamak to test this model. The qualitative trends from analytic modeling are reproduced by the experimental measurements, obtained via spectroscopic inference using the S/XB method. Quantitatively the model slightly under-predicts measured erosion rates, which is attributed to uncertainties in the ion impact angle distribution, as well as the effect of edge-localized modes. After exposure, minimal changes to the macroscopic or microscopic surface morphology of the SiC coatings were observed. Compositional analysis reveals Si enrichment of about 10%, in line with expectations from the erosion model. Extrapolating to a DEMO-type device, an order-of-magnitude decrease in impurity sourcing, and up to a factor of 2 decrease in impurity radiation, is expected with SiC walls, relative to graphite, if low C plasma impurity content can be achieved. Furthermore, these favorable erosion properties motivate further investigations of SiC as a low-Z, non-metallic PFM.
Multiple streams of fluids combined to produce various structures. Spherical or nearly spherical micro-shells containing two or more discrete inclusions produced by proposed technique. Pairs of coaxial nozzles combined in arrays of two or more. Each pair of nozzles generate inner jet surrounded by sheath of fluid. Multiple jets combined to form droplets composed of shells and cores. Spheres designed so cores combine to mix or react only after leaving shell generator. Similarly, two or more shell-wall materials mix or react after leaving generator.
Experiments on the National Ignition Facility (NIF) have provided clear evidence of ablator material mixing into the Hot-Spot, leading to degraded performance. However, inferring the amount of mix and Hot-Spot conditions from typical experimental observations (e.g. x-ray spectra and images) is highly challenging. Here, we have developed an analysis method that utilizes machine learning assisted Bayesian inference to find the probability distributions of the Hot-Spot and mix conditions. This approach uses a neural network, trained on an idealized 2-dimensional representation of the Hot-Spot and mix distribution, and Bayesian inference to find the statistical distributions of Hot-Spot conditions that provide a match with observations. We have tested this method with synthetic data from simulations.
Foil or thin wire at weld root is used to verify weld penetration. When weld is adequate, material mixes with weld and traces of it diffuse to weld crown. Spectroscopic analysis of samples identifies foreign material and verifies root has fused. Weld roots are usually inaccessible to visual inspection, and X-ray and ultrasonic inspection techniques are not always reliable. Good results are obtained with use of gold/nickel alloy.
Results are presented of a program to determine the impact resistance of composite fan blades subjected to foreign object damage (FOD) while operating under conditions simulating a short take-off and landing (STOL) engine at takeoff. The full-scale TF39 first-stage fan blade was chosen as the base design for the demonstration component since its configuration and operating tip speeds are similar to a typical STOL fan blade several composite configurations had already been designed and evaluated under previous programs. The first portion of the program was devoted toward fabricating and testing high impact resistant, aerodynamically acceptable composite blades which utilized only a single material system in any given blade. In order to increase the blade impact capability beyond this point, several mixed material (hybrid) designs were investigated using S-glass and Kevlar as well as boron and graphite fibers. These hybrid composite blades showed a marked improvement in resistance to bird impact over those blades made of a single composite material. The work conducted under this program has demonstrated substantial improvement in composite fan blades with respect to FOD resistance and has indicated that the hybrid design concept, which utilizes different types of fibers in various portions of a fan blade design depending on the particular requirements of the different areas and the characteristics of the different fibers involved, shows a significant improvement over those designs utilizing only one material system.
Diffraction experiments are reported which indicate that the new Bi-Ca-Sr-Cu-O layer-structure superconductor possesses a primitive orthorhombic unit cell with probable space group Pnnn. The material exhibits severe structural disorder which is primarily related to stacking within the layers. The apparent orthorhombic structure is an average resulting from orthorhombic material mixed with monoclinic domains in two twinned orientations. Two distinct types of structural disorder that are common in materials synthesized to date are also described. This disorder complicates the crystallographic analysis and suggests that X-ray and neutron diffraction methods may yield only an average structure.
ABSTRACT Here we present a study of radial chemical mixing in non-rotating massive main-sequence stars driven by internal gravity waves (IGWs), based on multidimensional hydrodynamical simulations with the fully compressible code MUSIC. We examine two proposed mechanisms of material mixing in stars by IGWs that are commonly quoted, relating to thermal diffusion and sub-wavelength shearing. Thermal diffusion provides a non-restorative effect to the waves, leaving material displaced from its previous equilibrium, while shearing arising within the waves drives weak localized flows, mixing the fluid there. Using IGW spectra from the simulations, we evaluate theoretical predictions of mixing rates due to these mechanisms. We show, for $20\, \mathrm{M}_\odot$ main-sequence stars, that neither of these mechanisms are likely to create mixing sufficient to correct inaccuracies in current stellar evolution models. Furthermore, we compare these predictions to results obtained from Lagrangian tracer particles, following a method recently used for global simulations of stellar interiors to measure mixing by IGWs in their radiative zones. We demonstrate that tracer particle methods face significant numerical challenges in measuring the small diffusion coefficients predicted by the aforementioned theories, for which they are prone to yielding artificially enhanced coefficients. Diffusion coefficients based on such methods are currently used with stellar evolution codes for asteroseismic studies, but should be viewed with caution. Finally, in a case where tracer particles do not suffer from numerical artefacts, we suggest that a diffusion model is not suitable for time-scales typically considered by 2D numerical simulations.
We modeled plasma edge localized mode (ELM) sputter erosion for a Small Angle Slot divertor with a tungsten coated region (SAS-VW), designed for experiments in the DIII-D tokamak, and proposed for use in future advanced tokamaks. The simulations use a free-streaming, 1000 eV, C +6 and D +1 ELM impingement model, with SOLPS-ITER, ITMC-DYN, and REDEP/WBC code packages for background plasma, material response, and erosion/redeposition respectively. The results show ELM'ing plasma gross and net tungsten erosion fluxes of the mixed-material C/W surface peaking at the slot entrance region, and an order of magnitude higher than for non-ELMs. The per-pulse erosion, however, remains low, of order 0.5 nm, due to expected moderate ELM frequencies and duration in DIII-D. Here, the ELMs result in a ~25x higher peak sputtered W current leaving the divertor slot region, towards the core plasma, compared to the ELM-free plasma case. The time-integrated escape current, however, may not significantly affect core plasma high-Z contamination concerns, for a 1% ELM duty factor, but may be an issue for higher frequency ELMs. In general, the modeling results appear favorable for effective testing of the SAS-VW divertor in DIII-D, and extrapolation to innovative divertor designs in future ITER-like and DEMO fusion devices.
The design allows for the low-stress mounting of fragile objects, like thin walled glass, by using particular ways of compensating, isolating, or releasing the coefficient of thermal expansion (CTE) differences between the mounted object and the mount itself. This mount profile is lower than true full kinematic mounting. Also, this approach enables accurate positioning of the component for electrical and optical interfaces. It avoids the higher and unpredictable stress issues that often result from potting the object. The mount has been built and tested to space-flight specifications, and has been used for fiber-optic, optical, and electrical interfaces for a spaceflight mission. This mount design is often metal and is slightly larger than the object to be mounted. The objects are optical or optical/electrical, and optical and/or electrical interfaces are required from the top and bottom. This requires the mount to be open at both ends, and for the object s position to be controlled. Thin inside inserts at the top and bottom contact the housing at defined lips, or edges, and hold the fragile object in the mount. The inserts can be customized to mimic the outer surface of the object, which further reduces stress. The inserts have the opposite CTE of the housing material, partially compensating for the CTE difference that causes thermal stress. A spring washer is inserted at one end to compensate for more CTE difference and to hold the object against the location edge of the mount for any optical position requirements. The spring also ensures that any fiber-optic or optic interface, which often requires some pressure to ensure a good interface, does not overstress the fragile object. The insert thickness, material, and spring washer size can be traded against each other to optimize the mount and stresses for various thermal and vibration load ranges and other mounting requirements. The alternate design uses two separate, unique features to reduce stress and hold the object. A release agent is applied to the inside surface of the mount just before the binding potting material is injected in the mount. This prevents the potting material from bonding to the mount, and thus prevents stress from being applied, at very low temperatures, to the fragile object being mounted. The potting material mixing and curing is temperature- and humidity-controlled. The mount has radial grooves cut in it that the potting material fills, thus controlling the vertical position of the mounted object. The design can easily be used for long and thin objects, short and wide objects, and any shape in between. The design s advantages are amplified for long and thin fragile objects. The general testing range was 45 to +45 C, but multiple mounts were successfully tested down to 60 and up to 50 C and the design can be adjusted for larger ranges.
Ordinary chondritic meteorites are an abundant type of stony meteorite characterized by the presence of chondrules. Chondrules are small spheres consisting of silicate, metal, and sulfide minerals that experienced melting in the nebula before incorporation into chondritic meteorite parent bodies. Therefore, chondrules record a variety of processes that occurred in the early solar nebula. Two common types of unequilibrated chondrules with porphyritic textures include FeO-poor (type I) and FeO-rich (type II) each subdivided into an A (SiO2-poor) and B (SiO2-rich) series. Type IA chondrules include those with high proportions of olivine phenocrysts (>80% olivine) and type IB chondrules include those with high proportions of pyroxene phenocrysts (<20% olivine). An intermediate composition, type IAB chondrules include those chondrules in which the proportion of olivine phenocrysts is between 20-80%. We conducted high-temperature laboratory experiments (melting at 1550 C) to produce type I chondrules from average unequilibrated ordinary chondrite (UOC) material mixed with small amounts of additional olivine. The experiments were conducted by adding forsteritic rich olivine (San Carlos olivine, Fo 91) to UOC material (GRO 95544) in a 30/70 ratio, respectively. Results of these high temperature experiments suggest that we have replicated type IA chondrule textures and compositions with dynamic crystallization experiments in which a heterogeneous mixture of UOC (GRO 95544) and olivine (San Carlos olivine) were melted at 1550 C for 1 hr. and cooled at 5-1000 C/hr using graphite crucibles in evacuated silica tubes to provide a reducing environment.
Rayleigh–Taylor (RT) instabilities are important fluid instabilities that arise in inertial confinement fusion (ICF) capsule implosions, and many other contexts. Multi-mode coupling is observed in experiments and plays a substantial role in material mix from RT instabilities. In this work, we study the evolution of highly multimodal perturbations (power law distribution) that approximate those found at manufactured material interfaces. We use simulations of over 2000 different perturbations in the LANL code xRAGE to identify distinct phases in the processes of bubble growth and bubble merger which can be visualized in a 2D phase portrait with clear regimes of mode growth and decay. Our results show that the dynamic evolution of the instability strongly depends on the mode of the perturbations and mode interactions. The merger process accelerates bubble growth. A non-Markovian region and a transition of the instability from: (1) initial exponential growth to (2) linear growth and to (3) quadratic growth and asymptotic behavior, are clearly captured in the phase space. We have developed a quantitative model of bubble growth that reproduces the dynamic behavior of ensembles of perturbations. Implications for ICF capsules designed for robustness against instabilities are discussed.