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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

A High-Efficient Solution for Electro-Hydraulic Actuators with Energy Regeneration Capability

This paper proposes a cost-effective, robustly practical solution for a high-efficient electro-hydraulic actuator (EHA) for linear drives. The solution addresses the challenges of high costs and limited efficiency that limit the application of EHA for the electrification of many off-road vehicles. Based on a variable-speed electric motor and a low-cost technology for a fixed-displacement pump, the proposed solution is suitable for a compact implementation and it is capable of energy regeneration under overrunning load conditions. Two different architectures—an open circuit and a closed circuit one—are considered to determine the most practical and efficient configuration as well as the control features. Both architectures minimize throttling losses associated with the conventional regulation of hydraulic actuators. Actuator velocities below the minimum and beyond the maximum allowable pump flow rate are achieved in both architectures using a proportional valve that bypasses the pump flow. The paper describes the design methodology as well as the simulation and experimental activities performed to verify the control strategies as well as energy efficiency. Considering an EHA system of about 20 kW, a complete efficiency map of the system is determined for all the possible four quadrants of operation thus including both resistive and overrunning loads, where energy recuperation is implemented. Simulation and experimental results show that the energy efficiency of the hydraulic systems can reach 84.7% in resistive phases. In assistive phases, the hydraulic system can recover up to 81.8% of the actuator energy. Here, the comparison between open-circuit and closed-circuit structures shows the advantages of the former in terms of energy efficiency. The proposed solution is suitable for electrified hydraulic actuation systems, in both industrial and mobile applications. With the advantages of the low cost of the hydraulic unit and high energy efficiency, it is particularly suitable for mobile applications such as construction machines, that are recently experiencing a significant electrification trend.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2025

CalTestBed - Delphire - Testing and Evaluation of Delphire Sentinel System (CRADA Final Report)

The Delphire Sentinel is a modular fire detection and communications system operating as a mobile field unit, with low voltage DC power supplied by onboard photovoltaics (PV) and batteries. The Sentinel addresses several aspects of fire detection, communications and data analysis. The Sentinel's mobility enables it to be rapidly deployed and operate independently of existing power and communications networks. The duration of independent operation depends critically on the energy consumption of the systems and performance of the onboard PV and battery. The purpose of this testing is to ascertain the power draw and energy consumption of the Delphire Sentinel prototype system under several operational states, including various data transfer packet sizes, transmission time and frequencies, and communication pathways (Wi-Fi, cellular, satellite) expected to be encountered in field deployments. It will also include procedures to test the ability of the Sentinel to operate for extended periods without loss of functionality. Based on results from energy and power measurements, and anticipated duty cycles in field deployments, we will model annual system autonomy (e.g. loss of load probability) for off-grid operation in representative locations.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Fire reduces riverine DOC concentration draining a watershed and alters post-fire DOC recovery patterns

Abstract The loading of dissolved organic carbon (DOC) from soils to inland waters and ultimate transport to the ocean is a critical flux pathway in the terrestrial biosphere carbon cycle. Fires can significantly affect this flux through biogeochemical processes related to oxidation and mobilization of DOC in the soil. Therefore, in order to accurately estimate and model terrestrial carbon storage and export to the marine environment, we need to better understand the effects of fire on DOC flux. In this analysis, we compiled available observational data sets from seven watersheds across the conterminous United States generally spanning the years 1999–2019. We used these data sets to examine the effects of fire on riverine DOC concentration draining a watershed to study both the immediate impacts and the post-fire recovery patterns. Our results suggest that these fires result in an immediate decrease in riverine DOC concentration draining the watershed by 26 ± 15%, and the time required for DOC concentrations to recover to pre-fire levels was estimated to be, on average, approximately 9 months. During recovery, DOC concentration was 24 ± 11% lower than the long-term average for the watershed. In addition, the larger the proportion of the watershed that burned, the greater the concentration decrease and the longer the time period for post-fire recovery.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Automated Work Package: Initial Wireless Communication Platform Design, Development, and Evaluation

The Department of Energy’s Light Water Reactor Sustainability Program is developing the scientific basis to ensure long-term reliability, productivity, safety, and security of the nuclear power industry in the United States. The Instrumentation, Information, and Control (II&C) pathway of the program aims to increase the role of advanced II&C technologies to achieve this objective. One of the pathway efforts at Idaho National Laboratory (INL) is to improve the work packages execution process by replacing the expensive, inefficient, bulky, complex, and error-prone paper-based work orders with automated work packages (AWPs). An AWP is an automated and dynamic presentation of the work package designed to guide the user through the work process. It is loaded on a mobile device, such as a tablet, and is capable of communicating with plant equipment and systems to acquire plant and procedure states. The AWP replaces those functions where a computer is more efficient and reliable than a human. To enable the automatic acquisition of plant data, it is necessary to design and develop a prototype platform for data exchange between the field instruments and the AWP mobile devices. The development of the platform aims to reveal issues and solutions generalizable to large-scale implementation of a similar system. Topics such as bandwidth, robustness, response time, interference, and security are usually associated with wireless communication. These concerns, along with other requirements, are listed in an earlier INL report. Specifically, the targeted issues and performance aspects in this work are relevant to the communication infrastructure from the perspective of promptness, robustness, expandability, and interoperability with different technologies.

Automated Work Packages↗
NASA NTRS1992

Fuel cell technology for lunar surface operations

Hydrogen-oxygen fuel cells have been shown, in several NASA and contractor studies, to be an enabling technology for providing electrical power for lunar bases, outposts, and vehicles. The fuel cell, in conjunction with similar electrolysis cells, comprises a closed regenerative energy storage system, commonly referred to as a regenerative fuel cell (RFC). For stationary applications, energy densities of 1,000 watt-hours per kilograms an order of magnitude over the best rechargeable batteries, have been projected. In this RFC, the coupled fuel cell and electrolyzer act as an ultra-light battery. Electrical energy from solar arrays 'charges' the system by electrolyzing water into hydrogen and oxygen. When an electrical load is applied, the fuel cell reacts the hydrogen and oxygen to 'discharge' usable power. Several concepts for utilizing RFC's, with varying degrees of integration, have been proposed, including both primary and backup roles. For mobile power needs, such as rovers, an effective configuration may be to have only the fuel cell located on the vehicle, and to use a central electrolysis 'gas station'. Two fuel cell technologies are prime candidates for lunar power system concepts: alkaline electrolyte and proton exchange membrane. Alkaline fuel cells have been developed to a mature production power unit in NASA's Space Shuttle Orbiter. Recent advances in materials offer to significantly improve durability to the level needed for extended lunar operations. Proton exchange membrane fuel cells are receiving considerable support for hydrospace and terrestrial transportation applications. This technology promises durability, simplicity, and flexibility.

Deronck, Henry J.↗
DOE OSTI2016

Automated Work Package: Initial Wireless Communication Platform Design, Development, and Evaluation

The Department of Energy's Light Water Reactor Sustainability Program is developing the scientific basis to ensure long-term reliability, productivity, safety, and security of the nuclear power industry in the United States. The Instrumentation, Information, and Control (II and C) pathway of the program aims to increase the role of advanced II and C technologies to achieve this objective. One of the pathway efforts at Idaho National Laboratory (INL) is to improve the work packages execution process by replacing the expensive, inefficient, bulky, complex, and error-prone paper-based work orders with automated work packages (AWPs). An AWP is an automated and dynamic presentation of the work package designed to guide the user through the work process. It is loaded on a mobile device, such as a tablet, and is capable of communicating with plant equipment and systems to acquire plant and procedure states. The AWP replaces those functions where a computer is more efficient and reliable than a human. To enable the automatic acquisition of plant data, it is necessary to design and develop a prototype platform for data exchange between the field instruments and the AWP mobile devices. The development of the platform aims to reveal issues and solutions generalizable to large-scale implementation of a similar system. Topics such as bandwidth, robustness, response time, interference, and security are usually associated with wireless communication. These concerns, along with other requirements, are listed in an earlier INL report. Specifically, the targeted issues and performance aspects in this work are relevant to the communication infrastructure from the perspective of promptness, robustness, expandability, and interoperability with different technologies. The development of a prompt system entailed significant performance optimization, including the use of parallel processing, parallel communication, modularity, noise filtering, and frequency tuning. A robust system was achieved by enforcing a persistent continuous data exchange that automatically detects and conveys a failure of any link or component in any part of the system, and that automatically restores the communication once the link or component is restored. An expandable topology was enabled by modularity and load sharing. The number of servers, mobile devices, and field instruments is not limited from a system structure point of view. The system interoperability was achieved by enforcing the independence of the field communication application from the mobile device application. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS2012

Experimental Investigation of Transient Sublimator Performance

Sublimators have been used as heat rejection devices for a variety of space applications including the Apollo Lunar Module and the Extravehicular Mobility Unit (EMU). Sublimators typically operate with steady-state feedwater utilization at or near 100%. However, sublimators are currently being considered for operations in a cyclical topping mode, which represents a new mode of operation for sublimators. Sublimators can be used as a supplemental heat rejection device during mission phases where the environmental temperature or heat rejection requirement changes rapidly. This scenario may occur during low lunar orbit, low earth orbit, or other planetary orbits. In these mission phases, the need for supplemental heat rejection will vary between zero and some fraction of the overall heat load. In particular, supplemental heat rejection is required for the portion of the orbit where the radiative sink temperature exceeds the system setpoint temperature. This paper will describe the effects of these transient starts and stops on the feedwater utilization during various feedwater timing scenarios. Experimental data from various scenarios is analyzed to investigate feedwater consumption efficiency under the cyclical conditions. Start up utilization tests were conducted to better understand the transient performance. This paper also provides recommendations for future sublimator design and transient operation.

Sheth, Rubik B.↗
DOE OSTI2018

Accelerator-Driven Subcritical System for Disposing of the U.S. Spent Nuclear Fuel Inventory

The current United States inventory of the spent nuclear fuel (SNF) is ~80,000 metric tons of heavy metal (MTHM), including ~131 tons of minor actinides (MAs) and ~669 tons of plutonium. This study describes a conceptual design of an accelerator-driven subcritical (ADS) system for disposing of this SNF inventory by utilizing the 131 tons of MAs inventory and a fraction of the plutonium inventory for energy production, and transmuting some long-lived fission products. An ADS system with a homogeneous subcritical fission blanket was first examined. A spallation neutron source is used to drive the blanket and it is produced from the interaction of a 1-GeV proton beam with a lead-bismuth eutectic (LBE) target. The blanket has a liquid mobile fuel using LBE as the fuel carrier. The fuel materials are dissolved, mixed, or suspended in the liquid fuel carrier. Monte Carlo analyses were performed to determine the overall parameters of the concept. Steady-state Monte Carlo simulations were performed for three similar fission blankets. Except for, the loaded amount of actinide materials in the LBE is either 5, 7, or 10% of the total volume of the blanket, respectively. The neutron multiplication factors of the three blankets are ~0.98 and the initial MAs blanket inventories are ~10 tons. In addition, Monte Carlo burnup simulations using the MCB5 code were performed to analyze the performance of the three conceptual ADS systems. During operation, fresh fuel was fed into the fission blanket to adjust its reactivity and to control the system power. The burnup analysis shows that the three ADS concepts consume about 1.2 tons of actinides per full power year and produce 3 GW thermal power, with a proton beam power of 25 MW. For the blankets with 5, 7, or 10% actinide fuel particles loaded in the LBE, assuming that the ADS systems can be operated for 35 full-power years, the total MA materials consumed in the three ADS systems are about 30.6, 35.3, and 37.2 tons, respectively. Thus, the corresponding numbers of ADS systems to utilize the 131 tons of MA materials of the SNF inventory are 4.3, 3.7, or 3.5, respectively. ADS concepts with tube bundles inserted in the fission blanket were analyzed to overcome the disadvantages of the homogeneous blanket concept. The liquid lead is used as the target material, the mobile fuel carrier, and the primary coolant to avoid the polonium production from bismuth. Reactor physics and thermal-hydraulic analyses were coupled to determine the parameters of the heterogeneous fission blanket. The engineering requirements for a satisfactory operation performance of the HT-9 ferritic steel structure material have been realized. Two heterogeneous concepts of the subcritical fission blanket with the liquid lead mobile fuel inside or outside the tube bundles were considered. The heterogeneous configuration with the mobile fuel inside the tubes showed better performance than the configuration with mobile fuel outside the bundle tubes. The Monte Carlo burnup codes, MCB5 and SERPENT were both used to simulate the fuel burnup in the ADS concepts with the mobile fuels inside the tubes. The burnup analyses were carried out for 35 full power years. The results show that 5 ADS systems can dispose of the total United States inventory of the spent nuclear fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

Initial Testing of Off-Gas Recycle Condensate Liquid from the WTP Low Activity Waste Vitrification Process - 16432

The Waste Treatment and Immobilization Plant (WTP) under construction at the Hanford site is designed to treat and immobilize the inventory of High-Level Waste stored in the 177 underground storage tanks. The WTP process flow was designed to pre-treat this waste, separating it into High Level Waste (HLW) and Low Activity Waste (LAW) fractions for vitrification. Vitrification of the waste generates a condensate stream from the off-gas processes originating from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP). The baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed through the LAW melter again. If the Pretreatment facility is unavailable, this baseline disposition pathway is not viable. Additionally, chloride, fluoride, and sulfate are partially volatile in the melter, accumulating to high concentrations while recycling and impacting the glass waste loading and facility throughput. The primary radionuclide that volatizes and accumulates is {sup 99}Tc. The long half-life and environmental mobility of {sup 99}Tc complicates disposal options for this secondary aqueous waste stream. This task is investigating {sup 99}Tc removal to examine the potential for diverting this stream to an alternate disposition path and avoiding impacting the glass waste loading. Separation methods for {sup 99}Tc have focused on using inorganic precipitation agents that can remove it by reducing it from soluble pertechnetate ion, with a +7 oxidation state, to insoluble technetium dioxide in the +4 oxidation state. Stannous chloride (SnCl{sub 2}) has been found highly effective at causing the reduction and precipitating {sup 99}Tc for removal, but it also precipitates other components. The primary competitor that precipitates is chromium, which consumes the redox activity of the Sn(II), causing addition of more of the SnCl{sub 2}. Research has examined the optimum quantity of SnCl{sub 2}, mixing time, and the impact of other redox-active species. It is also important to know the stability of the precipitated {sup 99}Tc in process conditions, since it is expected it will eventually be re-oxidized by oxygen and dissolve. This work is expected to determine if a {sup 99}Tc removal step could be used to decontaminate the bulk of this stream, and make it suitable for other disposal paths so that the chloride, fluoride, and sulfate can be diverted away from the glass melter. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRSDate not supplied

ISS EVA80 EMU Water in the Helmet Failure and Associated Analytical Response

On March 23rd, 2022, during Extra-Vehicular Activity (EVA) 80 aboard the International Space Station (ISS) crew identified an 8-10-inch diameter thin film of water in the pressure bubble of the suit during repress. This launched an investigation to determine the cause of the water in the helmet as well as short- and long-term mitigation efforts to enable return to EVA as quickly as possible. The investigation analysis efforts in combination with hardware inspection and testing determined the most likely cause of the water in the helmet to be sublimator carryover as a result of high latent loading put on the system. In parallel with this investigation, efforts were being made to mitigate any future water in the helmet events. The short-term mitigation strategy developed is to install absorbent material in the pressure bubble to capture water as it enters the helmet before it can impact the astronauts. This hardware is referred to as the Helmet Absorption Band (HAB) and Helmet Absorption Pad – Extender (HAP-E). Longer-term mitigation strategies include a device to capture small water events before entering the helmet by installing a water capture system in the vent loop of the Extravehicular Mobility Unit (EMU). This effort is coined the T2 Water Capture System. Additionally, developing an on-orbit sublimator challenge test which will be able to verify sublimator performance before and after EVAs. The sublimator is the hardware which condenses water vapor and removes it from the vent loop, and this hardware is referred to as the EMU Moisture Injection Test System (EMITS). Based on the investigation and short-term water capture solutions the ISS Program decided to return to nominal EVAs on October 7, 2022. With the addition of the long-term mitigation strategies, the team hopes to be able to prevent any future water in the helmet events.

Veronica Lee Pizor↗
DOE OSTI2019

Federal Emergency Management Agency Mobile Housing Unit Running Gear Testing (Final Report)

The Federal Emergency Management Agency (FEMA) stages manufactured housing units (MHUs) at key locations to be used during disasters when other housing accommodations cannot be arranged for individuals or families. Due to the unpredictability of natural disasters and the limitations of the manufactured housing industry to produce large numbers of MHUs in very short periods of time, it is necessary for FEMA to store a large number of units for many months or years. With these long storage periods come degradation issues with frames, tires, bearing, and braking systems. These types of issues are also of interest to the U.S. Department of Transportation (DOT) Federal Motor Carrier Safety Administration (FMCSA) because regulated carriers normally transport these units and 49 CFR 393.75 Tires specifies tire loading restrictions for manufactured homes. To compare the running gear (tires, brakes, drums, bearings, axles, springs, and spring mounting hardware) currently specified in the 2014 Rugged Based Performance Requirements (RBPR) and the newly recommended running gear specified in the upcoming revision to the RBPR, the Oak Ridge National Laboratory (ORNL) outlined a Longevity Test Plan, which focused on the assessment of component longevity (failure rates by component type). The Test Plan also studied the forces imparted to the MHU from the running gear from interaction with the roadway for both the running gear in the 2014 RBPR and the running gear specified in the upcoming RBPR revision. Since the assessment of component longevity and failures are also issues of concern for FMCSA, both agencies collaborated to support the research presented in this report. The tests and data collection were conducted at the Navistar Proving Grounds (NPG) in New Carlisle (near South Bend), Indiana, during the May-November 2018 period. Four alternatives for the suspension system of a typical three-bedroom MHU were considered in this test. Alternative 0 was the MHU that was selected from the FEMA staging area in Selma, Alabama. Empirical data had shown that, on average, this alternative experiences one tire failure every 150 miles (or 0.0067 tire failures per mile traveled). Before testing, Alternative 0 was equipped with similar running gear hardware, although in new condition and installed following the manufacturer’s specifications. This became the Baseline Unit, or Alternative 1. Another unit, also selected from the FEMA staging area in Selma, Alabama, was equipped with better axles (i.e., axles that were rated for 7,000lbs as opposed to 6,000lbs for the Baseline Unit) and better tires. This became the Upgrade Unit, or Alternative 2. At the end of the Longevity Test, the Upgrade Unit was mounted with radial tires. This became Alternative 3.Alternative 1 (Baseline Unit) had, on average, one tire failure every 251 miles (or 0.0040 tire failures per mile traveled). So, by simply following the correct manufacturer’s specifications for the assembly of the transportation system, a reduction of 41% in the per mile tire failure was achieved. In the same test, Alternative 2 (Upgrade Unit) showed, on average, one tire failure every 728 miles traveled (or 0.0014 tire failure s per mile traveled). When the Upgrade Unit was mounted with radial tires in the last part of the test, no tire failures were observed for the 2,400 miles tested. That is, in the case of the radial tires (Alternative 3) the tire failure was less than one per 2,400 miles traveled (or less than 0.0004 tire failures per mile traveled). The data collected for the Longevity Test showed that the maximum accelerations were registered in all cases at the center of the MHU in the vertical direction. The overall maximum was registered by the Baseline Unit, Alternative 1. If that value is normalized to 100%, then the Upgrade Unit (Alternative 2) showed, on average, 81% at the same location, and Alternative 3 (radial-tire test) 59%. That is, the upgraded transportation system showed a reduction of 19% and 41% in the vertical accelerations transmitted to MHU at its center when regular and radial tires, respectively, were used. As part of the Test Protocol, NPG conducted a visual inspection of the MHUs and transportation system at the end of each test day. ORNL reviewed all the inspection reports in an attempt to determine if there was any difference in the damage that the Baseline and Upgrade MHUs showed during the test. The Upgrade Unit always showed lower accelerations transmitted to the MHU than the Baseline Unit. In most cases, these differences were statistically significant. The FEMA inspection report, conducted by a FEMA certified inspector at the end of the tests, included a shorter list of damaged items for the Baseline Unit than for the Upgrade Unit, although similar type of damages was described for both units. This may be an indication that, although lower than those of the Baseline Unit, the accelerations transmitted by the Upgrade Unit were above the threshold at which MHU elements start to fail.

42 ENGINEERING↗
DOE OSTI2019

Monte Carlo fuel burnup analyses of the Accelerator-Driven Subcritical systems

Here, we discuss the Monte Carlo fuel burnup analysis performed for the Argonne National Laboratory (ANL) Accelerator-Driven Subcritical (ADS) conceptual design. The ANL ADS conceptual design was determined to dispose of the 131 tons of Minor Actinides (MA) fuel of the current United States Spent Nuclear Fuel (SNF) inventory. It uses a neutron source from 1 GeV 25MW proton beam with the liquid lead target to drive the subcritical fission assembly. It utilizes the liquid metal slurry fuel concept to load the MAs fuel. The subcritical fission assembly has a neutron multiplication factor of 0.98. The total fission power generated in the system is about 2.67 GW. The system is designed to operate for 35 full power years. Monte Carlo fuel burnup analyses were performed to calculate the amount of MAs consumed by the ANL ADS conceptual design. The MCNP6 computer program was used to simulate the high energy physics of the protons striking the liquid lead target for generating the neutron source. The MCB5 and SERPENT Monte Carlo burnup computer programs were used to simulate the fuel burnup during the ADS operation. In the ANL ADS conceptual configuration, the reactivity loss during the fuel burnup is compensated by adding fresh fuel into the subcritical assembly. In this paper, both batch and continuous fueling modes are examined. The fresh fuel particles are loaded into the slurry fuel carrier at the beginning of each burnup step of the batch-fueling mode and loaded continuously into the slurry fuel carrier during the operation in the continuous fueling mode. Monte Carlo fuel burnup analyses show that one ANL ADS conceptual design can consume about 25.7 tons of MAs fuel during the 35 full power years with the continuous fueling mode. About five units is required to dispose of the 131 tons of MAs

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2015

Managing work flow and logistic at waste processing facilities using the waste compliance and tracking system - 15392

Work flow and logistics at a busy radioactive waste processing complex or permitted treatment, storage, and disposal facility (TSDF) can pose a monumental challenge. An efficient operation requires good communication between engineering, logistics, and waste operators. The Los Alamos National Laboratory (LANL) has implemented an application that facilitates seamless communication of work flow requirements, between engineering, logistics, and waste operations personnel in the field. The Waste Compliance and Tracking System (WCATS), a comprehensive waste management system designed at LANL, provides four key elements to support logistics: (a) the container work path, (b) directed unit operation requests, (c) notification of pending operations, and (d) real-time status tools for office and field workers. The combination of these elements allows everyone to function as a team, with a shared knowledge of what is needed to accomplish facility objectives. The first element is like a road map indicating which unit operations are needed and in what sequence they should be performed; this is referred to as a 'work path'. It automatically routes a waste item or container from operation to operation. For example, a given work path might indicate that waste items require radiological survey, radioassay, and a technical review, in that order. When the work path is assigned to a container, the system enforces the correct order of operations. Directed unit operation 'requests', the second element, fills a gap between pre-planned, formal 'work path' activities and the need for flexibility to direct preparatory operations or deal with unexpected issues, like staging or mining containers in preparation for a shipment or transferring containers from one storage unit to another to clear a path for building maintenance. Logistics engineers prepare these 'requests', and the system monitors the status and completion of the work. The third element, notifications, allows team members to subscribe to and receive notice that an operation is pending, initiated, or complete. This functionality supports a range of communication options, including e-mail, cell phone, pager, or application in-box messaging. Notifications allow waste operations personnel to multi-task, and remain in the loop on the status of facility-wide activities. Finally, the fourth element provides tools that communicate work path pending operations and directed requests to field workers on their mobile computer, allowing them to mine or pick containers from storage units, and leverage the capabilities of a bar-code scanner to avoid selection mistakes. Oversight and summary tools are provided, allowing logistics personnel to monitor work path and request task status, identify work-flow bottlenecks, and maximize the efficiency of waste operations. The Waste Compliance and Tracking System (WCATS) provides an innovative, comprehensive set of tools that allow large-scale radioactive waste processing facilities to manage logistics, maximize efficient use of the workforce, and create a team environment, where everyone from management to the waste handlers have an understanding of the work load and what needs to be accomplished. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2013

Bimetallic Nanocatalysts in Mesoporous Silica for Hydrogen Production from Coal-Derived Fuels

In steam reforming reactions (SRRs) of alkanes and alcohols to produce H 2 , noble metals such as platinum (Pt) and palladium (Pd) are extensively used as catalyst. These metals are expensive; so, to reduce noble-metal loading, bi-metallic nanocatalysts containing non-noble metals in MCM-41 (Mobil Composition of Material No. 41, a mesoporous material) as a support material with high-surface area were synthesized using one-pot hydrothermal procedure with a surfactant such as cetyltrimethylammonium bromide (CTAB) as a template. Bi-metallic nanocatalysts of Pd-Ni and Pd-Co with varying metal loadings in MCM-41 were characterized by x-ray diffraction (XRD), N 2 adsorption, and Transmission electron microscopy (TEM) techniques. The BET surface area of MCM-41 (~1000 m 2 /g) containing metal nanoparticles decreases with the increase in metal loading. The FTIR studies confirm strong interaction between Si-O-M (M = Pd, Ni, Co) units and successful inclusion of metal into the mesoporous silica matrix. The catalyst activities were examined in steam reforming of methanol (SRM) reactions to produce hydrogen. Reference tests using catalysts containing individual metals (Pd, Ni and Co) were also performed to investigate the effect of the bimetallic system on the catalytic behavior in the SRM reactions. The bimetallic system remarkably improves the hydrogen selectivity, methanol conversion and stability of the catalyst. The results are consistent with a synergistic behavior for the Pd-Ni-bimetallic system. The performance, durability and thermal stability of the Pd-Ni/MCM-41 and Pd-Co/MCM-41 suggest that these materials may be promising catalysts for hydrogen production from biofuels. A part of this work for synthesis and characterization of Pd-Ni-MCM-41 and its activity for SRM reactions has been published (“Development of Mesoporous Silica Encapsulated Pd-Ni Nanocatalyst for Hydrogen Production” in “Production and Purification of Ultraclean Transportation Fuels”; Hu, Y., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2011.)

08 HYDROGEN↗
DOE OSTI2025

Epoxy-based vitrimeric semi-interpenetrating network/MXene nanocomposites for hydrogen gas barrier applications

Herein, we report MXene-filled epoxy-based vitrimeric nanocomposites featuring a semi-interpenetrating network (S-IPN) to develop a hydrogen gas (H 2 ) barrier coating with self-healing characteristics for compressed H 2 storage applications. The reversible epoxy network was formed by synthesizing linear epoxy chains with pendent bis-hydroxyl groups using amino diol, which were then crosslinked with 1,4-benzenediboronic acid to generate dynamic boronic ester linkages. To achieve the S-IPN-type molecular arrangement, the epoxy chains were in situ crosslinked in the presence of poly(ethylene-co-vinyl alcohol) (EVOH), giving rise to a self-healing network (EEP) with a healing efficiency of 87%. Into the S-IPN vitrimer (EEP), a 2D platelet-type nanofiller MXene was incorporated to introduce a tortuous path for H 2 gas diffusion along with improved mechanical properties. The nanocomposite coating was applied to nylon 6 liner material, which is conventionally used in all-composite H 2 storage vessels. Further, the application of a 2 wt% MXene/EEP nanocomposite coating showed a permeability coefficient of 0.062 cm 3 mm m -2 d -1 atm -1 exhibiting ~96% reduction in gas permeability compared to uncoated nylon 6. The same nanocomposite exhibited a healing efficiency of 79%. Increasing the MXene loading to 10 wt% further reduced the permeability coefficient to 0.002 cm 3 mm m -2 d -1 atm -1 ; however, the healing efficiency decreased due to restricted chain mobility. In essence, the current work highlights the potential of vitrimeric S-IPN nanocomposite coatings for H 2 gas-barrier applications, enhancing safety and performance.

42 ENGINEERING↗
DOE OSTI2017

Second Validation Testing of Canberra-Obayashi Mobile type TruckScan Pre-production Unit - 17214

Canberra Industries, Inc., (Now, Mirion Technologies (Canberra), Inc.), has developed and validated a new truck monitoring system 'Mobile TruckScan (MTSCAN)' for use with the Interim Storage Facilities (ISF) in Japan. MTSCAN consists of eight shielded LED-stabilized 3x3' NaI detectors. Each detector has a lead shield with a collimated view of the truck. Four detectors are placed on each side of the truck, thus 8 in total, each at about 1.1 meter from the side of the truck. These NaI detectors and collimators were calibrated by the Canberra In-Situ Object Counting System (ISOCS) mathematical efficiency calculation tool. Around the Fukushima Daiichi NPS area, the decontaminated waste was put into flexible containers called Super Sacks (SS), for transportation to the ISF, typically in 10 metric ton dump trucks. The MTSCAN pre-production unit was used to measure multiple SSs loaded into 10 ton trucks, and was able to accurately report the activity of each individual SS, with around 10-20 second acquisition time. The system can also accommodate smaller 2 ton and larger 20 ton trucks. The system is relatively compact, and therefore easy to move and setup at a different location. MTSCAN is expected to measure the SSs after loading onto trucks at the Temporary Storage Area (TSA), and at the entrance of the ISF. The MTSCAN assay results showed good accuracy in this demonstration which simulated the actual operation. From these tests, the combined standard deviation for each SS is about 20%, when compared to the reference activity from multiple Ge measurements of each sack. (authors)

07 ISOTOPE AND RADIATION SOURCES↗
NASA NTRS1990

Computation of maximum gust loads in nonlinear aircraft using a new method based on the matched filter approach and numerical optimization

Time-correlated gust loads are time histories of two or more load quantities due to the same disturbance time history. Time correlation provides knowledge of the value (magnitude and sign) of one load when another is maximum. At least two analysis methods have been identified that are capable of computing maximized time-correlated gust loads for linear aircraft. Both methods solve for the unit-energy gust profile (gust velocity as a function of time) that produces the maximum load at a given location on a linear airplane. Time-correlated gust loads are obtained by re-applying this gust profile to the airplane and computing multiple simultaneous load responses. Such time histories are physically realizable and may be applied to aircraft structures. Within the past several years there has been much interest in obtaining a practical analysis method which is capable of solving the analogous problem for nonlinear aircraft. Such an analysis method has been the focus of an international committee of gust loads specialists formed by the U.S. Federal Aviation Administration and was the topic of a panel discussion at the Gust and Buffet Loads session at the 1989 SDM Conference in Mobile, Alabama. The kinds of nonlinearities common on modern transport aircraft are indicated. The Statical Discrete Gust method is capable of being, but so far has not been, applied to nonlinear aircraft. To make the method practical for nonlinear applications, a search procedure is essential. Another method is based on Matched Filter Theory and, in its current form, is applicable to linear systems only. The purpose here is to present the status of an attempt to extend the matched filter approach to nonlinear systems. The extension uses Matched Filter Theory as a starting point and then employs a constrained optimization algorithm to attack the nonlinear problem.

Pototzky, Anthony S.↗
DOE OSTI2016

Use of a Ca-Citrate-Phosphate Solution to Form Hydroxyapatite for Uranium Stabilization of Old Rifle Sediments: Laboratory Proof of Principle Studies

The Old Rifle Site is a former vanadium and uranium ore-processing facility located adjacent to the Colorado River and approximately 0.3 miles east of the city of Rifle, CO. The former processing facilities have been removed and the site uranium mill tailings are interned at a disposal cell north of the city of Rifle. However, some low level remnant uranium contamination still exists at the Old Rifle site. In 2002, the United States Nuclear Regulatory Commission (US NRC) concurred with United States Department of Energy (US DOE) on a groundwater compliance strategy of natural flushing with institutional controls to decrease contaminant concentrations in the aquifer. In addition to active monitoring of contaminant concentrations, the site is also used for DOE Legacy Management (LM) and other DOE-funded small scale field tests of remediation technologies. The purpose of this laboratory scale study was to evaluate the effectiveness of a hydroxyapatite (Ca 10 (PO 4 ) 6 (OH) 2 ) permeable reactive barrier and source area treatment in Old Rifle sediments. Phosphate treatment impact was evaluated by comparing uranium leaching and surface phase changes in untreated to PO4-treated sediments. The impact of the amount of phosphate precipitation in the sediment on uranium mobility was evaluated with three different phosphate loadings. A range of flow velocity and uranium concentration conditions (i.e., uranium flux through the phosphate-treated sediment) was also evaluated to quantify the uranium uptake mass and rate by the phosphate precipitate.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗