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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Manipulating ultrafast even-order nonlinear chiral responses of L-tryptophan by polarization pulse shaping

Molecular chirality has long been monitored in the frequency domain in the ultraviolet, visible, and infrared regimes. Recently developed time-domain approaches can detect time-dependent chiral dynamics by enhancing intrinsically weak chiral signals. Even-order nonlinear signals in chiral molecules have gained attention thanks to their existence in the electric dipole approximation, without relying on the weaker higher-order multipole interactions. We illustrate the optimization of temporal polarization pulse-shaping in various frequency ranges (infrared/optical and optical/X ray) to enhance chiral nonlinear signals. These signals can be recast as an overlap integral of matter and field pseudoscalars which contain the relevant chiral information. Simulations are carried out for second- and fourth-order nonlinear spectroscopies in L-tryptophan.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Titan's Winter Polar Vortex

Titan's atmosphere has provided an interesting study in contrasts and similarities with Earth's. While both have N$_2$ as the dominant constituent and comparable surface pressures $\sim1$ bar, Titan's next most abundant molecule is CH$_4$, not O$_2$, and the dissociative breakup of CH$_4$ and N$_2$ by sunlight and electron impact leads to a suite of hydrocarbons and nitriles, and ultimately the photochemical smog that enshrouds the moon. In addition, with a 15.95-day period, Titan is a slow rotator compared to Earth. While the mean zonal terrestrial winds are geostrophic, Titan's are mostly cyclostrophic, whipping around the moon in as little as 1 day. Despite the different dynamical regime, Titan's winter stratosphere exhibits several characteristics that should be familiar to terrestrial meteorologists. The cold winter pole near the 1 -mbar level is circumscribed by strong winds (up to 190 m/s) that act as a barrier to mixing with airmasses at lower latitudes. There is evidence of enhancement of several organic species over the winter pole, indicating subsidence. The adiabatic heating associated with this subsidence gives rise to a warm anomaly at the 0.01-mbar level, raising the stratopause two scale heights above its location at equatorial latitudes. Condensate ices have been detected in Titan's lower stratosphere within the winter polar vortex from infrared spectra. Although not always unambiguously identified, their spatial distribution exhibits a sharp gradient, decreasing precipitously across the vortex away from the winter pole. The interesting question of whether there is important heterogeneous chemistry occurring within the polar vortex, analogous to that occurring in the terrestrial polar stratospheric clouds in the ozone holes, has not been addressed. The breakup of Titan's winter polar vortex has not yet been observed. On Earth, the polar vortex is nonlinearly disrupted by interaction with large-amplitude planetary waves. Large-scale waves have not been identified in Titan's atmosphere, so the decay of its polar vortex may be more gradual than on Earth. Observations from an extended Cassini mission into late northern spring should provide critical data indicating whether the vortex goes away with a bang or just fades away.

Flasar, F.M.↗

Enhanced second-harmonic generation from WS 2 /ReSe 2 heterostructure

Van der Waals stacking presents new opportunities for nonlinear optics with its remarkable tunability and scalability. However, the fundamental role of interlayer interactions in modifying the overall nonlinear optical susceptibilities remains elusive. In this work, we report anisotropic enhancement of second-harmonic generation (SHG) from a WS 2 /ReSe 2 heterobilayer, where the individual composite layers possess distinctive crystal phases. We investigate polarization-resolved response and twist-angle dependence in SHG and reveal that band alignment alone is insufficient to explain the observed anisotropy in the modified SHG response. Spectral shifts in excitonic features highlight band renormalization, supporting the role of hybridization between the two layers. Furthermore, SHG enhancement is highly anisotropic and can even be suppressed in some orientations, suggesting possible intensity-borrowing mechanisms within the heterostructure. Our work demonstrates the ability to tune both the intensity and polarization dependence of nonlinear optical responses with van der Waals stacking of distinctive crystal phases.

2D materials↗

Theory of nonlinear terahertz susceptibility in ferroelectrics

An analytical theory is developed for predicting the nonlinear susceptibility of ionic polarization to continuous electromagnetic waves in both bulk and strained thin film ferroelectrics. Using a perturbation method for solving the nonlinear equation of motion for ionic polarization within the framework of Landau-Ginzburg-Devonshire theory, the full second-order nonlinear susceptibility tensor is derived as a function of frequency, temperature, and strain. Here, the theory predicts the coexistence of a significantly enhanced second-order dielectric susceptibility and a relatively low dielectric loss in BaTiO 3 films with a strain-stabilized monoclinic ferroelectric phase and in a strained SrTiO 3 film near its temperature-driven second-order ferroelectric-to-paraelectric phase transition. In this paper, we establish a theoretical framework for predicting and exploiting nonlinear interactions between terahertz waves and ferroelectric materials and, more generally, suggest exciting opportunities to strain-engineer nonlinear dynamical properties of ferroelectrics beyond the static and quasistatic limits.

36 MATERIALS SCIENCE↗

Stabilization of the Polar Structure and Giant Second-Order Nonlinear Response of Single Crystal γ-NaAs 0.95 Sb 0.05 Se 2

The dearth of suitable materials significantly restricts the practical development of infrared (IR) laser systems with highly efficient and broadband tuning. Recently, γ-NaAsSe 2 is reported, and it exhibits a large nonlinear second-harmonic generation (SHG) coefficient of 590 pm V —1 at 2 µm. However, the crystal growth of γ-NaAsSe 2 is challenging because it undergoes a phase transition to centrosymmetric δ-NaAsSe 2 . Herein, the stabilization of non-centrosymmetric γ-NaAsSe 2 by doping the As site with Sb, which results in γ-NaAs 0.95 Sb 0.05 Se 2 is reported. The congruent melting behavior is confirmed by differential thermal analysis with a melting temperature of 450 °C and crystallization temperature of 415 °C. Single crystals with dimensions of 3 mm × 2 mm are successfully obtained via zone refining and the Bridgman method. The purification of the material plays a significant role in crystal growth and results in a bandgap of 1.78 eV and thermal conductivity of 0.79 Wm —1 K —1 . The single-crystal SHG coefficient of γ-NaAs 0.95 Sb 0.05 Se 2 exhibits an enormous value of |d 11 | = 648 ± 74 pm V —1 , which is comparable to that of γ-NaAsSe 2 and ≈20× larger than that of AgGaSe 2 . Importantly, the bandgap of γ-NaAs 0.95 Sb 0.05 Se 2 (1.78 eV) is similar to that of AgGaSe 2 , thus rendering it highly attractive as a high-performing nonlinear optical material.

36 MATERIALS SCIENCE↗

Nonlinear evolution of a large-amplitude circularly polarized Alfven wave: Low beta

The nature of turbulent cascades arising from the parametric instabilities of a monochromatic field-aligned large-amplitude circularly polarized Alfven wave is investigated via direct numerical simulation for the case of low plasma Beta and no wave dispersion. The magnetohydrodynamic code permits nonlinear couplings in the parallel direction to the ambient magnetic field and one perpendicular direction. Compressibility is included in the form of a polytropic equation of state. Anisotropic turbulent cascades, similar to those found in early incompressible two-dimensional simulations, occur after nonlinear saturation of the parallel propagating decay instability. The turbulent spectrum can be divided into three regimes: the lowest wave numbers are dominated by lower sideband remnants of the parametric process, intermediate wave numbers display nearly incompressible dynamics, and the highest wave numbers are dominated by acoustic turbulence.

Ghosh, S.↗

Effect of triangularity on ion-temperature-gradient-driven turbulence

The linear and nonlinear properties of ion-temperature-gradient-driven turbulence with adiabatic electrons are modeled for axisymmetric configurations for a broad range of triangularities δ, both negative and positive. Peak linear growth rates decrease with negative δ but increase and shift toward a finite radial wavenumber kx with positive δ. The growth-rate spectrum broadens as a function of kx with negative δ and significantly narrows with positive δ. Here, the effect of triangularity on linear instability properties can be explained through its impact on magnetic polarization and curvature. Nonlinear heat flux is weakly dependent on triangularity for |δ|≤0.5, decreasing significantly with extreme δ, regardless of sign. Zonal modes play an important role in nonlinear saturation in the configurations studied, and artificially suppressing zonal modes increased nonlinear heat flux by a factor of about four for negative δ, increasing with positive δ by almost a factor of 20. Proxies for zonal-flow damping and drive suggest that zonal flows are enhanced with increasing positive δ.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Spatiotemporal control of laser intensity using differentiable programming

Optical techniques for spatiotemporal control can produce laser pulses with custom amplitude, phase, or polarization structure. In nonlinear optics and plasma physics, the use of structured pulses typically follows a forward design approach, in which the efficacy of a known structure is analyzed for a particular application. Inverse approaches, in contrast, enable the discovery of new structures with the potential for superior performance. Here, an implementation of the unidirectional pulse propagation equation that supports automatic differentiation is combined with gradient-based optimization to design structured pulses with features that are advantageous for a range of nonlinear optical and plasma-based applications: (1) a longitudinally uniform intensity over an extended region, (2) a superluminal intensity peak that travels many Rayleigh ranges with constant duration, spot size, and amplitude, and (3) a laser pulse that ionizes a gas to form a uniform column of plasma. In the final case, optimizing the full spatiotemporal structure improves the performance by a factor of 15 compared to optimizing only spatial or only temporal structure, highlighting the advantage of spatiotemporal control.

automatic differentiation↗

Effect of Faraday rotation on the circular polarization of the Crab Nebula

The effect of Faraday rotation on the circular polarization of an electromagnetic wave propagating through a magnetized plasma is calculated for various limits of the plasma and wave parameters appropriate to a 30-Hz wave in the Crab Nebula. It is shown that a static magnetic field of the proper geometry and only a few times stronger than the wave field can reduce the circular polarization of the nonlinear inverse Compton radiation to a value below the observed upper limit.-

Gerver, M. J.↗

Precision bridge circuit using a temperature sensor

A precision bridge measurement circuit connected to a current source providing a linear output voltage versus resistance change of a variable resistance (resistance temperature transducer) including a voltage follower in one branch of the bridge so that the zero setting of the transducer resistance does not depend upon the current source or upon an excitation voltage. The zero setting depends only on the precision and stability of the three resistances. By connecting the output of an instrumentation amplifier to a feedback resistor and then to the output of the voltage follower, minor nonlinearities in the resistance-vs-temperature output of a resistance-temperature transducer, such as a platinum temperature sensor, may be corrected. Sensors which have nonlinearity opposite in polarity to platinum, such as nickel-iron sensors, may be linearized by inserting an inverting amplifier into the feedback loop.

Mount, Bruce E.↗

Absolute Intercalibration of Spaceborne Microwave Radiometers

Absolute calibration of spaceborne microwave radiometer observations consists of accurate determination of antenna cold space spillover, cross-polarization contamination, and nonlinearity coefficients of the receivers. We deem the GMI sensor to be the most accurate calibrated spaceborne microwave radiometer due to its unique calibration design features and its carefully planned orbit maneuvers. We demonstrate how to transfer the GMI calibration to other spaceborne radiometers, whose operations have sufficient time overlap with GMI. Specifically, we show results for WindSat and AMSR2. The sensor intercalibration is based on brightness temperature matchups between GMI and the other instruments over both open ocean and rainforest scenes. To assess the calibration accuracy, we compare the intercalibrated brightness temperatures with radiative transfer model calculations. In addition, we provide in situ validation results for wind speed and water vapor retrievals from the intercalibrated sensors. The intercalibration methodology allows for the creation of a multidecadal climate data record from passive microwave satellite observations. Significance Statement Creating a long-term climate data record of satellite observations of ocean winds, water vapor, and other variables requires careful and accurate calibration of the various sensors that are used. In particular, it is important to achieve the best possible consistency between the measurements from all the different instruments. This is a challenging task as the configuration and accuracy of these instruments can differ widely. The purpose of our paper is to demonstrate and validate the basic methodology for performing this intercalibration. The backbone of our method is data observed by a well-calibrated sensor that measures the passive microwave emission from Earth’s surface and atmosphere. We show how to transfer its calibration standard to other sensors.

Katherine Wentz↗

Self-precession and frequency shift for electromagnetic waves in homogeneous plasmas

The nonlinear propagation of an arbitrarily polarized electromagnetic wave in a uniform plasma is studied. It is shown that nonlinear effects cause precession of the polarization ellipse as the wave propagates. The ellipticity remains constant, but the orientation of the principal axes is rotated relative to its initial value. A relativistic Vlasov model is used to study nonlinear frequency shifts as well as self-precession, in a plasma of arbitrary temperature. Even when the electron temperature is much greater than the product of the electron mass times the square of the velocity of light, the qualitative nature of these two processes remains unchanged, although their dependence on the plasma density is altered in significant ways. Implications of these effects for plasma instabilities driven by strong electromagnetic waves are briefly discussed.

Arons, J.↗

Simulation of amplitude-modulated circularly polarized Alfven waves for beta less than one

The nonlinear properties of the amplitude-modulated circularly polarized Alfven wave are studied for beta less than one. The temporal behavior of the wave packet of the electromagnetic hybrid simulation is compared with a numerical solution of the derivative nonlinear Schroedinger (DNLS) equation. It is shown that the left-hand-polarized mode evolves into a shocklike structure due to the modulational instability. However, both cyclotron damping and a snowplow effect near the steepened wave packet suppress its further steepening, contrary to the predictions of the DNLS equation. For the right-hand mode, formation of the shock does not take place, and the initial time development is well described by the DNLS equation. The daughter Alfven wave and ion acoustic waves are excited due to the decay instability at a later time. Heating or acceleration of the particles takes place for both left- and right-hand waves. Energy transfer from the wave to the particles occurs effectively when substantial modulation in the wave amplitude is present.

Machida, S.↗

Nonlinear optical response of metal-barrier-metal junctions

The optical response of metal-barrier-metal (MBM) junctions is discussed, with emphasis on the nonlinearity of response associated with reversal of polarity as optical intensity is increased. This nonlinear behavior can be used to measure correlation functions of optical pulses or to generate ultrashort electrical pulses. Expressions for the current flowing through the insulating barrier (junction), and for the rectification current, are given. Pulse signal and polarity of the electrical pulse evolves as the junction bias is varied about the null-signal bias. The apparatus used to obtain rectification pulse signals is described; the calculated evolution of the rectified pulse shape is found to correspond to that of pulse signals obtained experimentally. The generation of pulses six orders of magnitude smaller than a previously-obtained instrument-limited 1.6 nanosecond pulse has been observed.

Fan, B.↗

Numerical simulation of polar lows and comma clouds using simple dry models

Linear and nonlinear numerical channel models are used to simulate polar low/comma cloud evolution. The basic state of the model is idealized and can be specified analytically. It has strong horizontal as well as vertical wind shear and implicitly includes the effect of sensible heat fluxes from the lower boundary. This is done by having a layer of reduced stability present in the lower troposphere. The results of the linear model study are presented and used to provide input for the nonlinear model integration. It is shown that, given sufficient horizontal resolution, many features of polar low/comma clouds can be simulated by the nonlinear primitive equations model and the idealized basic state, in particular a rapidly growing disturbance with a wavelength on the order of 1000 km.

Mudrick, Stephen E.↗