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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Modelling of TGS growth in space

Attention is called to the necessity of programming the temperature downward in order to maintain a constant growth rate in the absence of convection. Trial and error numerical computations are performed to find the first approximation for the required isothermal dissolution period, linear ramp, and polynomial temperature variation period. The linear ramp rate is limited by the specified maximum temperature gradient. The isothermal dissolution turns out to be unnecessary. The linear ramp must be stopped before the polynomial period is begun in order to avoid overshooting the specified maximum growth rate. After a few hours, the temperature profile approaches steady-state behavior.

Liu, L. C.↗

Cosmic rays in a random magnetic field: Breakdown of the quasilinear derivation of the kinetic equation

The problem of deriving a kinetic equation for the cosmic ray distribution function in a random magnetic field is considered. A model is adopted which is mathematically simple but which contains the essential physics. The perturbation expansion upon which the quasi-linear treatment is based is investigated. The existence of resonant particles causes the breakdown of the adiabatic approximation frequently used in this theory. Resonant particles cause a general secular growth of higher order terms in the expansion which invalidates the entire perturbative approach.

Kaiser, T. B.↗

Web-dendritic ribbon growth

A web furnace was constructed for pulling dendritic-web samples. The effect of changes in the furnace thermal geometry on the growth of dendritic-web was studied. Several attempts were made to grow primitive dendrites for use as the dendritic seed crystals for web growth and to determine the optimum twin spacing in the dendritic seed crystal for web growth. Mathematical models and computer programs were used to determine the thermal geometries in the susceptor, crucible melt, meniscus, and web. Several geometries were determined for particular furnace geometries and growth conditions. The information obtained was used in conjunction with results from the experimental growth investigations in order to achieve proper conditions for sustained pulling of two dendrite web ribbons. In addition, the facilities for obtaining the following data were constructed: twin spacing, dislocation density, web geometry, resistivity, majority charge carrier type, and minority carrier lifetime.

Hilborn, R. B., Jr.↗

The role of thermophysics in the design, optimization and understanding of semiconductor crystal growth in space

The compound semiconductor material PbSnTe has been investigated by NASA Langley Research Center as part of the Material Processing in Space (MPS) experiment in the framework of the Space Shuttle program. The long-range goal of the research is the improving of the performance of infrared detectors for use in remote sensing experiments. Three distinct techniques will be used in the low-g environment of space: two techniques involving bulk growth from melt and a vapor growth technique. In order to establish realistic estimates of the required time for experiments and to determine the thermal gradients that will be required to avoid constitutional supercooling, the diffusion coefficients must be accurately measured, however more data especially in the vapor-solid phase relations are needed.

Crouch, R. K.↗

Improving crop classification through attention to the timing of airborne radar acquisitions

Radar remote sensors may provide valuable input to crop classification procedures because of (1) their independence of weather conditions and solar illumination, and (2) their ability to respond to differences in crop type. Manual classification of multidate synthetic aperture radar (SAR) imagery resulted in an overall accuracy of 83 percent for corn, forest, grain, and 'other' cover types. Forests and corn fields were identified with accuracies approaching or exceeding 90 percent. Grain fields and 'other' fields were often confused with each other, resulting in classification accuracies of 51 and 66 percent, respectively. The 83 percent correct classification represents a 10 percent improvement when compared to similar SAR data for the same area collected at alternate time periods in 1978. These results demonstrate that improvements in crop classification accuracy can be achieved with SAR data by synchronizing data collection times with crop growth stages in order to maximize differences in the geometric and dielectric properties of the cover types of interest.

Brisco, B.↗

Dendritic solidification under microgravity conditions

The Isothermal Dendritic Growth Experiment is undergoing development in cooperation with NASA-Lewis in order to test dendritic growth theory at small supercoolings in low earth orbit. The apparatus encompasses four major subsystems: a temperature-controlled thermostatic bath capable of millikelvin stability, a photographic data collection system, a crystal-growth chamber, and a start-detection system which initiates data collection. Comparisons are made with ground-based study methods for dendritic growth.

Glicksman, M. E.↗

Efficiently modeling neural networks on massively parallel computers

Neural networks are a very useful tool for analyzing and modeling complex real world systems. Applying neural network simulations to real world problems generally involves large amounts of data and massive amounts of computation. To efficiently handle the computational requirements of large problems, we have implemented at Los Alamos a highly efficient neural network compiler for serial computers, vector computers, vector parallel computers, and fine grain SIMD computers such as the CM-2 connection machine. This paper describes the mapping used by the compiler to implement feed-forward backpropagation neural networks for a SIMD (Single Instruction Multiple Data) architecture parallel computer. Thinking Machines Corporation has benchmarked our code at 1.3 billion interconnects per second (approximately 3 gigaflops) on a 64,000 processor CM-2 connection machine (Singer 1990). This mapping is applicable to other SIMD computers and can be implemented on MIMD computers such as the CM-5 connection machine. Our mapping has virtually no communications overhead with the exception of the communications required for a global summation across the processors (which has a sub-linear runtime growth on the order of O(log(number of processors)). We can efficiently model very large neural networks which have many neurons and interconnects and our mapping can extend to arbitrarily large networks (within memory limitations) by merging the memory space of separate processors with fast adjacent processor interprocessor communications. This paper will consider the simulation of only feed forward neural network although this method is extendable to recurrent networks.

Farber, Robert M.↗

Nucleation and Convection Effects in Protein Crystal Growth

Our work under this grant has significantly contributed to the goals of the NASA supported protein crystallization program. We have achieved the main objectives of the proposed work, as outlined in the original proposal: (1) We have provided important insight into protein nucleation and crystal growth mechanisms to facilitate a rational approach to protein crystallization; (2) We have delineated the factors that currently limit the x-ray diffraction resolution of protein crystals, and their correlation to crystallization conditions; (3) We have developed novel technologies to study and monitor protein crystal nucleation and growth processes, in order to increase the reproducibility and yield of protein crystallization. We have published 17 papers in peer-reviewed scientific journals and books and made more than 15 invited and 9 contributed presentations of our results at international and national scientific meetings.

Vekilow, Peter G.↗

Space Infrared Astronomy in the 21st Century

New technology and design approaches have enabled revolutionary improvements in astronomical observations from space. Worldwide plans and dreams include orders of magnitude growth in sensitivity and resolution for all wavelength ranges, and would give the ability to learn our history, from the Big Bang to the conditions for life on Earth. The Next Generation Space Telescope, for example, will be able to see the most distant galaxies as they were being assembled from tiny fragments. It will be 1/4 as massive as the Hubble, with a mirror 3 times as large, cooled to about 30 Kelvin to image infrared radiation. I will discuss plans for NGST and hopes for future large space telescopes, ranging from the Space UV Optical (SUVO) telescope to the Filled Aperture Infrared (FAIR) Telescope, the Space Infrared Interferometric Telescope (SPIRIT), and the Submillimeter Probe of the Evolution of Cosmic Structure (SPECS).

Mather, John C.↗

Carbon Nanostructure: Its Evolution During its Impact Upon Soot Growth and Oxidation

The proposed work is a ground-based study to define and quantify soot nanostructural changes in response to growth conditions, thermal and oxidative treatments and to quantify their impact upon further oxidation and growth of highly ordered carbon materials. Experimental data relating soot oxidation rates to multiple oxidizing species concentrations will directly test for additive or synergistic soot oxidation rates. Such validation is central for assessing the applicability of individual soot oxidation rates and designing oxidative strategies for controlling soot loadings in and emissions from turbulent combustion processes. Through these experiments, new insights into soot nanostructure evolution during and its impact upon oxidation by O2 and OH will be realized. It is expected that the results of this effort will spawn new research directions in future microgravity and 1g environments. Issues raised by positive or even negative demonstration of the hypotheses of this proposal have direct bearing on modelling and controlling soot formation and its destruction in nearly every combustion process producing soot.

Source record↗

Magnetic Control of Solutal Buoyancy Driven Convection

Volumetric forces resulting from local density variations and gravitational acceleration cause buoyancy induced convective motion in melts and solutions. Solutal buoyancy is a result of concentration differences in an otherwise isothermal fluid. If the fluid also exhibits variations in magnetic susceptibility with concentration then convection control by external magnetic fields can be hypothesized. Magnetic control of thermal buoyancy induced convection in ferrofluids (dispersions of ferromagnetic particles in a carrier fluid) and paramagnetic fluids have been demonstrated. Here we show the nature of magnetic control of solutal buoyancy driven convection of a paramagnetic fluid, an aqueous solution of Manganese Chloride hydrate. We predict the critical magnetic field required for balancing gravitational solutal buoyancy driven convection and validate it through a simple experiment. We demonstrate that gravity driven flow can be completely reversed by a magnetic field but the exact cancellation of the flow is not possible. This is because the phenomenon is unstable. The technique can be applied to crystal growth processes in order to reduce convection and to heat exchanger devices for enhancing convection. The method can also be applied to impose a desired g-level in reduced gravity applications.

Ramachandran, N.↗

Analysis of Effluent Gases During the CCVD Growth of Multi Wall Carbon Nanotubes from Acetylene

Catalytic chemical vapor deposition was used to grow multi-walled carbon nanotubes on a Fe:Co:CaCO3 catalyst from acetylene. The influent and effluent gases were analyzed by gas chromatography and mass spectrometry at different time intervals during the nanotubes growth process in order to better understand and optimize the overall reaction. A large number of byproducts were identified and it was found that the number and the level for some of the carbon byproducts significantly increased over time. The CaCO3 catalytic support thermally decomposed into CaO and CO2 resulting in a mixture of two catalysts for growing the nanotubes, which were found to have outer diameters belonging to two main groups 8 to 35 nm and 40 to 60 nm, respectively.

Schmitt, T. C.↗

Markov Modeling of Component Fault Growth over a Derived Domain of Feasible Output Control Effort Modifications

This paper introduces a novel Markov process formulation of stochastic fault growth modeling, in order to facilitate the development and analysis of prognostics-based control adaptation. A metric representing the relative deviation between the nominal output of a system and the net output that is actually enacted by an implemented prognostics-based control routine, will be used to define the action space of the formulated Markov process. The state space of the Markov process will be defined in terms of an abstracted metric representing the relative health remaining in each of the system s components. The proposed formulation of component fault dynamics will conveniently relate feasible system output performance modifications to predictions of future component health deterioration.

Bole, Brian↗

Mixing the Solar Wind Proton and Electron Scales: Effects of Electron Temperature Anisotropy on the Oblique Proton Firehose Instability

The double adiabatic expansion of the nearly collisionless solar wind plasma creates conditions for the firehose instability to develop and efficiently prevent the further increase of the plasma temperature in the direction parallel to the interplanetary magnetic field. The conditions imposed by the firehose instability have been extensively studied using idealized approaches that ignore the mutual effects of electrons and protons. Recently, more realistic approaches have been proposed that take into account the interplay between electrons and protons, unveiling new regimes of the parallel oscillatory modes. However, for oblique wave propagation the instability develops distinct branches that grow much faster and may therefore be more efficient than the parallel firehose instability in constraining the temperature anisotropy of the plasma particles. This paper reports for the first time on the effects of electron plasma properties on the oblique proton firehose (PFH) instability and provides a comprehensive vision of the entire unstable wave-vector spectrum, unifying the proton and the smaller electron scales. The plasma β and temperature anisotropy regimes considered here are specific for the solar wind and magnetospheric conditions, and enable the electrons and protons to interact via the excited electromagnetic fluctuations. For the selected parameters, simultaneous electron and PFH instabilities can be observed with a dispersion spectrum of the electron firehose (EFH) extending toward the proton scales. Growth rates of the PFH instability are markedly boosted by the anisotropic electrons, especially in the oblique direction where the EFH growth rates are orders of magnitude higher.

plasmas↗

Shape Parameter for a Non-Axisymmetric Isothermal Dendrite

In previous work, we found approximate solutions for paraboloids having perturbations with four-fold axial symmetry in order to model dendritic growth in cubic materials. These solutions provide self-consistent corrections through second order in a shape parameter e to the Peclet number-supercooling relation of the Ivantsov solution. The parameter e is proportional to the amplitude of the four-fold correction to the dendrite shape, as measured from the Ivantsov paraboloid of revolution. We calculate e by comparing the dendrite tip shape to the portion of the equilibrium shape near the growth direction, (001), for anisotropic surface free energy, where the ni are components of the unit normal of the crystal surface. This comparison results in epsilon = -2(epsilon 4), independent of the Peclet number. From the experimental value of epsilon 4, we find epsilon approximately 0.011, in good agreement with the measured value epsilon approximately 0.008 of LaCombe et al.

McFadden, G. B.↗

Instability of ring current protons beyond the plasmapause during injection events.

The stability of ring current protons with an injection spectrum modeled by a loss cone distribution function is examined for typical ring current parameters. It is found that a quasi-electrostatic ion loss cone mode can be excited with frequencies just below and growth rates of the order of 0.01 times the ion plasma frequency. The instability is strongest in the moderate beta about equal to 1, low-density region just outside the plasmapause; for the beta much greater than 1 auroral regions and the high-density plasmasphere the mode is nearly stable. For the same ring current parameters the electromagnetic ion cyclotron wave is almost nonconvectively unstable, with growth rates of the order of 0.1 times the ion cyclotron frequency. The combination of the two unstable modes results in a large quasi-linear diffusion coefficient throughout most of the proton velocity space. Unless it is maintained by rapid inward convection, the ring current injection anisotropy will be reduced by diffusion toward the loss cone on time scales short in comparison to the minimum precipitation lifetime.

Coroniti, F. V.↗

The effects of temperature and NaCl concentration on tetragonal lysozyme face growth rates

Measurements were made of the (110) and (101) face growth rates of the tetragonal form of hen egg white lysozyme at 0.1M sodium acetate buffer, pH 4.0, from 4 to 22 C and with 3.0%, 5.0%, and 7.0% NaCl used as the precipitating salt. The data were collected at supersaturation ratios ranging from approximately 4 to approximately 63. Both decreasing temperature and increasing salt concentrations shifted plots of the growth rate versus C/C(sat) to the right, i.e. higher supersaturations were required for comparable growth rates. The observed trends in the growth data are counter to those expected from the solubility data. If tetragonal lysozyme crystal growth is by addition of ordered aggregates from the solution, then the observed growth data could be explained as a result of the effects of lowered temperature and increased salt concentration on the kinetics and equilibrium processes governing protein-protein interactions in solution. The data indicate that temperature would be a more tractable means of controlling the growth rate for tetragonal lysozyme crystals contrary to the usual practice in, e.g., vapor diffusion protein crystal growth, where both the precipitant and protein concentrations are simultaneously increased. However, the available range for control is dependent upon the protein concentration, with the greatest growth rate control being at the lower concentration.

Forsythe, Elizabeth↗

Center for the development of commercial crystal growth in space

The second year of operation of the Center for Commercial Crystal Growth in Space is described. This center is a consortium of businesses, universities and national laboratories. The primary goal of the Center's research is the development of commercial crystal growth in space. A secondary goal is to develop scientific understanding and technology which will improve commercial crystal growth on earth. In order to achieve these goals the Center's research is organized into teams by growth technique; melt growth, solution growth, and vapor growth. The melt growth team is working on solidification and characterization of bulk crystals of gallium arsenide and cadmium telluride. They used high resolution X-ray topography performed at the National Synchrotron Light Source at Brookhaven National Laboratory. Streak-like features were found in the diffraction images of semi-insulating undoped LEC GaAs. These were shown to be (110) antiphase boundaries, which have not been reported before but appear to be pervasive and responsible for features seen via less-sensitive characterization methods. The results on CdTe were not as definitive, but indicate that antiphase boundaries may also be responsible for the double peaks often seen in X-ray rocking curves of this material. A liquid encapsulated melt zone system for GaAs has been assembled and techniques for casting feed rods developed. It was found that scratching the inside of the quartz ampoules with silicon carbide abrasive minimized sticking of the GaAs to the quartz. Twelve floating zone experiments were done.

Wilcox, William R.↗