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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1976

Examples of synoptic changes in ozone and circulation in the stratosphere

The Backscatter Ultraviolet (BUV) experiment on board the Nimbus 4 polar orbiting satellite has been measuring the total ozone content and high-level atmospheric ozone profiles since early 1970. Synoptic type analyses of these data are now being accomplished and compared with appropriate constant-pressure analyses of stratospheric circulation. Ozone changes during a stratospheric warming of early 1971 are investigated by comparison with circulation changes in the layer between 30 mb (24 km) and 2 mb (42 km). A general increase in ozone concentrations, more pronounced in the higher latitudes, is noted during the warming period. Plans for future investigation are discussed, including analysis of ozone observations beginning from 1970 on every two-day basis for comparison with constant-pressure height, temperature, and wind charts analyzed with the aid of radiosonde, rocketsonde, and satellite data.

Finger, F. G.↗
NASA NTRS2004

NASA's Earth Observing System (EOS): Observing the Atmosphere, Land, Oceans, and Ice from Space

The Earth Observing System (EOS) is a space-based observing system comprised of a series of satellite sensors by which scientists can monitor the Earth, a Data and Information System (EOSDIS) enabling researchers worldwide to access the satellite data, and an interdisciplinary science research program to interpret the satellite data. During this year, the last of the first series of EOS missions, Aura, was launched. Aura is designed exclusively to conduct research on the composition, chemistry, and dynamics of the Earth's upper and lower atmosphere, employing multiple instruments on a single spacecraft. Aura is the third in a series of major Earth observing satellites to study the environment and climate change and is part of NASA's Earth Science Enterprise. The first and second missions, Terra and Aqua, are designed to study the land, oceans, atmospheric constituents (aerosols, clouds, temperature, and water vapor), and the Earth's radiation budget. The other seven EOS spacecraft include satellites to study (i) land cover & land use change, (ii) solar irradiance and solar spectral variation, (iii) ice volume, (iv) ocean processes (vector wind and sea surface topography), and (v) vertical variations of clouds, water vapor, and aerosols up to and including the stratosphere. Aura's chemistry measurements will also follow up on measurements that began with NASA's Upper Atmosphere Research Satellite and continue the record of satellite ozone data collected from the TOMS missions. In this presentation I will describe how scientists are using EOS data to examine the health of the earth's atmosphere, including atmospheric chemistry, aerosol properties, and cloud properties, with a special but not exclusive look at the latest earth observing mission, Aura.

King, Michael D.↗
NASA NTRS2005

NASA's Earth Observing System (EOS): Observing the Atmosphere, Land, Oceans, and Ice from Space

The Earth Observing System (EOS) is a space-based observing system comprised of a series of satellite sensors by whch scientists can monitor the Earth, a Data and Information System (EOSDIS) enabling researchers worldwide to access the satellite data, and an interdisciplinary science research program to interpret the satellite data. During this year, the last of the first series of EOS missions, Aura, was launched. Aura is designed exclusively to conduct research on the composition, chemistry, and dynamics of the Earth's upper and lower atmosphere, employing multiple instruments on a single spacecraft. Aura is the third in a series of major Earth observing satellites to study the environment and climate change and is part of NASA's Earth Science Enterprise. The first and second missions, Terra and Aqua, are designed to study the land, oceans, atmospheric constituents (aerosols, clouds, temperature, and water vapor), and the Earth's radiation budget. The other seven EOS spacecraft include satellites to study (i) land cover & land use change, (ii) solar irradiance and solar spectral variation, (iii) ice volume, (iv) ocean processes (vector wind and sea surface topography), and (v) vertical variations of clouds, water vapor, and aerosols up to and including the stratosphere. Aura's chemistry measurements will also follow up on measurements that began with NASA's Upper Atmosphere Research Satellite and continue the record of satellite ozone data collected from the TOMS missions. In this presentation I will describe how scientists are using EOS data to examine the health of the earth's atmosphere, including atmospheric chemistry, aerosol properties, and cloud properties, with a special look at the latest earth observing mission, Aura.

King, Michael D.↗
NASA NTRS2024

Advanced Libya-4 radiometric and atmospheric characterization utilizing MODIS and VIIRS full-scan reflective solar band measurements

The NASA Clouds and the Earth's Radiant Energy System (CERES) project provides observed flux and cloud products to the climate science community. The CERES instruments, along with the MODIS and VIIRS imagers, are onboard the Terra, Aqua, NPP, and NOAA20 satellites. In order to produce seamless multi-platform integrated products, long-term sensor stability and inter-calibration are required. Inter-calibration between sensors within the same sun-synchronous orbit relies on Earth invariant targets because simultaneous nadir overpasses are not possible. To facilitate inter-calibration efforts, the CERES Imager and Geostationary Calibration Group (IGCG) has improved the Libya-4 target characterization. Improvements include full scan angle characterization to enable daily observations, clear-sky identification using individual scan angle dynamic spatial homogeneity thresholds, and atmospheric corrections. The water vapor correction was found to be effective across the full scan, whereas the ozone and aerosol corrections were less effective. The atmospheric-corrected normalized radiance temporal fluctuations are similar across scan angles, spectral bands, and between the MODIS and VIIRS imagers, suggesting that the fluctuations are a result of the natural variability of the Libya-4 surface reflectance. The Libya-4 surface variability is more than likely caused by changes in the prevailing winds that alter sand dune orientation and resulting shadows. The full-scan-imager atmosphere and angle corrected reflected solar band radiance trend standard errors are between 0.6% and 1.0%, and for near-nadir observations, are between 0.5% and 0.8%. The advanced characterization suggests that the Libya-4 short-term surface reflectance anomalies may need to be considered for imager stability monitoring and inter-calibration efforts.

Libya-4 Pseudo-invariant Calibration Site↗
NASA NTRSDate not supplied

Overview of the SPARC Reanalysis Intercomparison Project (S-RIP) during 2013-2020

The Stratosphere-troposphere Processes And their Role in Climate (SPARC) project is one of the four core projects of the World Climate Research Programme (WCRP). Researchers interested in SPARC use global atmospheric reanalysis products to understand a wide range of processes and variability in the atmosphere, to validate chemistry climate models, and to investigate and identify climate change. The SPARC Reanalysis Intercomparison Project (S-RIP) was initiated in 2011 and officially started in 2013 to conduct a coordinated intercomparison of all major global atmospheric reanalysis data sets. The S-RIP has been aiming at writing up an assessment report in the SPARC report series (to be published by the end of 2020) (1) on overall quality of temperature, winds, ozone, and water vapor data, (2) on more process- and region-oriented evaluation of the Brewer–Dobson circulation, extratropical stratosphere-troposphere coupling, extratropical upper troposphere and lower stratosphere, the tropical tropopause layer, the quasi-biennial oscillation, polar processes, and the upper stratosphere and lower mesosphere, and (3) with a coordinated description of the reanalysis systems. We also have an inter-journal special issue on "The SPARC Reanalysis Intercomparison Project (S-RIP)" in Atmospheric Chemistry and Physics (ACP) and Earth System Science Data (ESSD). In the presentation, we will discuss key findings and recommendations as well as the evaluation of this rst phase of the S-RIP activity.

Masatomo Fujiwara↗
NASA NTRS2014

The QBO in Two GISS Global Climate Models: 1. Generation of the QBO

The adjustment of parameterized gravity waves associated with model convection and finer vertical resolution has made possible the generation of the quasi-biennial oscillation (QBO) in two Goddard Institute for Space Studies (GISS) models, GISS Middle Atmosphere Global Climate Model III and a climate/middle atmosphere version of Model E2. Both extend from the surface to 0.002 hPa, with 2deg × 2.5deg resolution and 102 layers. Many realistic features of the QBO are simulated, including magnitude and variability of its period and amplitude. The period itself is affected by the magnitude of parameterized convective gravity wave momentum fluxes and interactive ozone (which also affects the QBO amplitude and variability), among other forcings. Although varying sea surface temperatures affect the parameterized momentum fluxes, neither aspect is responsible for the modeled variation in QBO period. Both the parameterized and resolved waves act to produce the respective easterly and westerly wind descent, although their effect is offset in altitude at each level. The modeled and observed QBO influences on tracers in the stratosphere, such as ozone, methane, and water vapor are also discussed. Due to the link between the gravity wave parameterization and the models' convection, and the dependence on the ozone field, the models may also be used to investigate how the QBO may vary with climate change.

middle atmosphere dynamics↗
NASA NTRS1987

Instrument systems for the Upper Atmosphere Research Satellite

The NASA Upper Atmosphere Research Satellite program for improving both methods needed to maintain the physical and chemical integrity of the upper atmosphere and techniques for the early detection of harmful changes in the ozone layer is discussed. Through satellite measurements, theoretical studies, and model analyses, the program will provide integrated global measurements of the chemistry, dynamics, and energetics of the stratosphere, mesosphere, and lower thermosphere. The 10 state-of-the-art instrument systems employed in the program are described, including the solar UV spectral irradiance monitor, the particle environment monitor, the cryogenic limb array etalon spectrometer, the wind imaging interferometer, and the active cavity radiometer irradiance monitor.

Arnold, Ray J.↗
NASA NTRS1986

Predicting earth's dynamic changes

Given a suitable strategy for conducting measurements, satellite-based remote sensing of the earth can furnish valuable information on the dynamic changes of such planetary characteristics as ocean surface temperatures and atmospheric CO2. Observations must be global and synoptic, quantitatively validated, and consistent over the long term. A program spanning 20 years will study such critical variables as solar flux, stratospheric temperature, aerosols and ozone, cloud cover, tropospheric gases and aerosols, radiation balance, surface temperature, albedo, precipitation, vegetation cover, moisture, snow and ice, as well as oceanic color, topography, and wind stress.

Rasool, S. I.↗
NASA NTRSDate not supplied

TROPOMI Geometry-dependent Lambertian-Equivalent surface Reflectivity (GLER) Product for Improved Trace-Gas Retrieval

Accurate information about the reflectivity of the Earth's surface is required for most satellite retrievals of atmospheric composition, and this information is generally taken from monthly surface reflectivity climatology that neglects angular dependence. Previously we introduced Geometry-dependent Lambertian-equivalent surface reflectivity (GLER) which captures solar and satellite viewing angle dependence as well as daily and seasonal changes. GLER is calculated from simulations of Rayleigh-only top-of-atmosphere (TOA) radiances over non-Lambertian surfaces. We use NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) product over land and the wind-dependent Cox–Munk wave-facet slope distribution including water-leaving radiance over water to accounts for surface BRDF. We have developed global GLER product, previously for the Ozone Monitoring Instrument (OMI) and recently for Sentinel-5 Precursor (S5P) TROPOspheric Monitoring Instrument (TROPOMI) with several new improvements and updates. We have implemented the near real time daily V006 MODIS MCD43C1 BRDF data and gap-filled with a daily BRDF coefficient climatology created from 2002-2017 V006 MCD43GF data. The NASA’s Global Modelling Initiative hourly 0.25 x 0.25 deg Replay simulations are used for more accurate determination of pixel specific terrain pressure. To improve detection of seasonal snow/ice scenes, we use the 4-km snow cover product from the Interactive Multi-sensor Snow and Ice Mapping System (IMS). Finally, we use an improved version of the vector linearized discrete ordinate radiative transfer (VLIDORT) for update of the top-of-atmosphere (TOA) radiance look-up-tables (LUTs). We demonstrate how the use of GLER is beneficial to TROPOMI’s high spatial resolution (up to 3.5 km x 3.5 km) measurements to monitor atmospheric trace gas pollutants down to the sub-city scale.

TROPOMI↗
NASA NTRS1998

Tropospheric- Stratospheric Measurement Studies Summary

The two high altitude aircraft, ER-2 NASA #706 and 709 and the DC-8 NASA #717 are in active use in several programs of upper atmospheric research to study polar ozone changes, stratospheric-tropospheric exchange processes and atmospheric effects of aviation aircraft. The ER-2 has participated in seven major missions which mainly concentrated on vortex dynamics and the large losses of Ozone in the Polar regions (Ozone hole) observed in the spring. One mission verified the complex dynamical chemical and physical processes that occur during sunrise and sunset. Stratospheric Tracers of Atmospheric Transport (STRAT) obtained background measurements using the full ER-2 suite of instruments. Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) in 1997 assisted in understanding the mid-latitude and Arctic Ozone losses during the Northern Summer. The DC-8 with the Meteorological Measurement System (MMS) has participated in the Subsonic Aircraft: Cloud and Contrail Effects Special Study (SUCCESS), in 1996 and the Subsonic assessment Ozone and Nitrogen oxide experiment (SONEX) in 1997 missions. The MMS with its sophisticated software accurately measures ground speed and attitude, in-situ static and dynamic pressure total temperature, which are used to calculate the three dimensional wind fields, static pressure, temperature and turbulence values to meteorological accuracy. The meteorological data is not only of interest for its own sake in atmospheric dynamical processes such as mountain waves and flux measurements; but is also required by other ER-2 experiments that simultaneously measure water vapor, O3, aerosols, NO, HCl, CH4, N2O, ClO, BrO, CO2, NOy, HOx and temperature gradients. MMS products are extensively used to assist in the interpretation of their results in understanding the importance of convective effects relative to in-situ chemical changes, as may be noted by examining the list of references attached. The MMS consists of three subsystems: (a) aircraft instrumentation, inertial navigation system (INS), static and dynamic pressure taps, (b) additional dedicated instrumentation measuring angle of attack, yaw, total temperature, and a GPS which on the DC-8 measures position, velocity and attitude (c) an on board data, storage and computing acquisition system. This instrumentation and the associated software requires both an on-going laboratory ground calibration procedure for the total air temperature, static and total pressure inputs, verification of the INS dynamic response and also extensive air measurements and intercomparisons which ultimately verify and calibrate the complete system and its software. More than the usual accuracy is required because of the near cancellation occurring in the difference between the ground speed and true airspeed vectors used to give the wind vector. In the past year we have redesigned, recalibrated and used the MMS system on the NASA DC-8 that was previously used in the SUCCESS mission for the SONEX mission. Two papers were co-authored based on SUCCESS flights. Several reports and handouts were written for SONEX. Calibrations of the DC-8 pressure transducer temperature measuring thermistors was completed and an extensive analysis spanning several years of data files of the DC-8 Rosemount pressure transducer calibrations was done.

Browen, Stuart W.↗
NASA NTRS2005

Trends from the Long-term Data Record and Models: What Do They Tell Us About our Ability to Predict Ozone Recovery?

Our industrial society has performed an experiment on the stratospheric ozone layer over the last several decades. The initial part of this experiment was the rapidly increasing release of halogen-containing compounds that carry chlorine and bromine to the stratosphere where they can cause a loss of ozone. The present part of this experiment is the implementation of the Montreal Protocol, which has led to a leveling off of these halogen compounds and the beginning of their slow removal from the atmosphere. The observation and attribution of ozone response to the halogens has been a particularly important and difficult task because of the impact of solar cycle uv variation, two major volcanic eruptions (El Chichon and Pinatubo), and interannual dynamic variability of the stratosphere. We have run 3 different simulations of the chemistry and transport of ozone and the minor constituents that affect ozone to help evaluate our understanding of the causes of ozone change and to assess our ability to predict ozone recovery with the removal of halogens from the stratosphere. One simulation, using the Goddard chemical transport model (CTM), had interannual variability in the dynamics for the entire 50 years of simulation, which included the past 3 decades (1974-2004) and the next 2 decades to 2022. The other two simulations used the Global Modeling Initiative (GMI) CTM with no dynamical variability: one used a the winds and temperatures from a repeating warm Arctic winter and the other used a repeating cold Arctic winter. All simulations included the effects of aerosol surfaces from volcanic eruptions on chemical reactions as well as the variation in UV over the 11-year solar cycle.

Strahan, Susan↗
NASA NTRSDate not supplied

Faster Tropical Upper Stratospheric Upwelling is Driving Changes in Ozone Chemistry

Trends in N2O and the chlorofluorocarbons (CFCs) cause trends in O3 through changes in their reactive product gases, NOx and ClOx, but transport plays an important role because it controls the distribution of the long‐lived source gases that produce ozone‐destroying radicals. In this study we show that increased tropical upwelling 10‐5 hPa from 2013‐2021 has changed upper stratospheric (UpS) composition and shifted the balance of O3 loss processes. We use N2O, HNO3, NOx, temperature and O3 data from the Aura Microwave Limb Sounder (MLS) and the SCI‐Sat Atmospheric Chemistry Experiment Fourier Transport Spectrometer (ACE‐FTS) over a 16‐year period to show how changes in reactive nitrogen species affected gas phase ozone chemistry above 30 hPa between June 2013‐May 2021 compared to the previous 8 years, June 2005‐May 2013. We use 2 simulations of the Global Modeling Initiative (GMI) chemistry transport model (CTM), with and without time varying MERRA2 meteorology, to understand how dynamical changes during this 16‐yr period affected O3 through changes in loss via the NOx and ClOx cycles. We also identify the role that the quasi‐biennial oscillation (QBO) in tropical zonal winds plays in the UpS composition changes. We find large increases in tropical upwelling and poleward transport in the northern branch of the UpS transport circulation since 2013 that dramatically increased the abundance of the N2O and its odd nitrogen product gases, NOx and HNO3. O3 loss by NOx in the Arctic UpS increased due to dynamically driven composition change, explaining the observed weak O3 recovery in that region since 2005. The increased upwelling also drove decreases in tropical NOx, leading to increased tropical O3 from 12‐6 hPa.

middle atmosphere chemistry and composition↗
NASA NTRS2011

El Nino-Southern Oscillation Correlated Aerosol Angstrom Exponent Anomaly Over the Tropical Pacific Discovered in Satellite Measurements

El Nino.Southern Oscillation (ENSO) is the dominant mode of interannual variability in the tropical atmosphere. ENSO could potentially impact local and global aerosol properties through atmospheric circulation anomalies and teleconnections. By analyzing aerosol properties, including aerosol optical depth (AOD) and Angstrom exponent (AE; often used as a qualitative indicator of aerosol particle size) from the Moderate Resolution Imaging Spectrometer, the Multiangle Imaging Spectroradiometer and the Sea ]viewing Wide Field ]of ]view Sensor for the period 2000.2011, we find a strong correlation between the AE data and the multivariate ENSO index (MEI) over the tropical Pacific. Over the western tropical Pacific (WTP), AE increases during El Nino events and decreases during La Nina events, while the opposite is true over the eastern tropical Pacific (ETP). The difference between AE anomalies in the WTP and ETP has a higher correlation coefficient (>0.7) with the MEI than the individual time series and could be considered another type of ENSO index. As no significant ENSO correlation is found in AOD over the same region, the change in AE (and hence aerosol size) is likely to be associated with aerosol composition changes due to anomalous meteorological conditions induced by the ENSO. Several physical parameters or mechanisms that might be responsible for the correlation are discussed. Preliminary analysis indicates surface wind anomaly might be the major contributor, as it reduces sea ]salt production and aerosol transport during El Nino events. Precipitation and cloud fraction are also found to be correlated with tropical Pacific AE. Possible mechanisms, including wet removal and cloud shielding effects, are considered. Variations in relative humidity, tropospheric ozone concentration, and ocean color during El Nino have been ruled out. Further investigation is needed to fully understand this AE ]ENSO covariability and the underlying physical processes responsible for it.

Li, Jing↗
NASA NTRS2000

Performance of the GEOS-3/Terra Data Assimilation System in the Northern Stratospheric Winter 1999/2000

As part of NASA's support for the Terra satellite, which became operational in January 2000, the Data Assimilation Office introduced a new version of the GEOS data assimilation system (DAS) in November 1999. This system, GEOS-3/Terra, differs from its predecessor in several ways, notably through an increase in horizontal resolution (from 2-by-2.5 degrees to 1-by-1 degree), a slightly lower upper boundary (0.1 instead of 0.01hPa) with fewer levels (48 as opposed to 70), and substantial changes to the tropospheric physics package. This paper will address the performance of the GEOS-3/Terra DAS in the stratosphere. it focusses on the analyses (produced four times daily) and the five-day forecasts (produced twice daily). These were important for the meteorological support of the SAGE-3 Ozone Loss and Validation Experiment, based in Kiruna, Northern Sweden, in the winter of 1999/2000. It is shown that the analyses of basic meteorological fields (temperature, geopotential height, and horizontal wind) are in good agreement with those from other centers. The analyses captured the cold polar vortex which persisted through most of the winter. It is shown that forecasts (up to five days) tend to have a warm bias, which is important for the prediction of polar stratospheric clouds, which are triggered by temperatures of 195K (or lower). The importance of accurate upper tropospheric forecasts in predicting the stratospheric flow is highlighted in the context of the evolution of the shape of the stratospheric polar vortex. A prominent blocking high in the Atlantic region in January was an important factor determining the shape of the distorted lower stratospheric vortex; the predictive skill of these features was strongly coupled in the GEOS-3/Terra system.

Pawson, S.↗
DOE OSTI2020

Role of the Terrestrial Biosphere in Atmospheric Chemistry and Climate

The terrestrial biosphere–atmosphere interface provides a key chemical, biological, and physical lower boundary for the atmosphere. The presence of vegetation itself modifies the physical boundary, or the biogeophysical aspects of the system, by controlling important climate drivers such as soil moisture, light environment, and temperature. The leaf surface area of the terrestrial biosphere provides additional surface area for emissions, and it can be up to 55% of the total Earth’s surface area during the boreal summer. Vegetation also influences the biogeochemical aspects of the system by emitting a broad suite of reactive trace gases such as biogenic volatile organic compound (BVOC) emissions and climate-relevant primary biological aerosol particles (PBAP). Many of these emissions are a function of meteorological and climatological conditions at the surface, including temperature, light environment, soil moisture, and winds. Once emitted, they can be processed in the troposphere through a suite of chemical reactions. BVOC can contribute to the formation of ozone and secondary organic aerosols (SOA), and PBAP can rupture to form smaller particles with climatic relevance. These emissions and subsequent aerosol products can influence atmospheric processes that affect the surface climate, such as the attenuation of radiation, the formation of greenhouse gases such as ozone that can feedback to surface air temperature, and the alteration of clouds and subsequent precipitation. These atmospheric changes can then feedback to the land surface and emissions themselves, creating positive or negative feedback loops that can dampen or amplify the emission response. For the dominant BVOC isoprene, the feedback response to temperature can be positive or negative depending on ambient temperatures that drive isoprene emissions. The feedback response to soil moisture and precipitation can be positive, negative, or uncoupled depending on the moisture content of the soil and the total atmospheric aerosol loading. For light, the isoprene response can be positive or negative depending on the role of diffuse light. Overall, these feedbacks highlight the dynamical response of the biosphere to changing atmospheric conditions across a range of time scales, from minutes for trace gases and aerosols, to months for phenological changes, to years for land cover and land use change. Here, the dynamic aspect of this system requires us to understand, simulate, and predict the complex feedbacks between the biosphere and atmosphere and understand their role in the simulation and understanding of climate and global change. From the observational perspective, these feedbacks are challenging to identify in observations, and predictive modeling tools provide a crucial link for understanding how these feedbacks will change under warming climate scenarios.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1998

Analysis of record-breaking low ozone values during the 1997 winter over NDSC Station Lauder, New Zealand

During early August 1997, the ozone column density measured over Lauder was unusually low, with a minimum value of 222 Dobson Units (DU) at August 10. These observations are striking since in August, during the Austral winter, the ozone column density should be heading towards its yearly maximum; The August mean ozone column density measured over Lauder between 1987 and 1996 was 348(+/-28) DU, the lowest monthly average in these ten years was 255 DU. Regular altitude profile measurements of ozone, performed at Network for the Detection of Stratospheric Change (NDSC) station Lauder, make it possible to do a detailed, altitude-resolved, study of the low ozone observations. The measurements show ozone poor air in two altitude regions of the stratosphere: A 'high region', extending from the 600 K to the 1050 K isentrope (25 to 34 km), and a 'low region', below about 550 K (22 km). High resolution reverse trajectory maps of potential vorticity (PV) and ozone mixing ratio, based on the assumption of passive advection by the large-scale three-dimensional winds, show that in the 'high region' the ozone poor air was part of the polar vortex, which was centered off the pole and extended over Lauder for several days, while in the 'low region' the ozone poor air was mixed in from low latitudes. A rapid recovery of the ozone column density, by more than 110 DU within 24 hours, was observed when in the low region an ozone rich filament of the polar vortex moved over Lauder, while in the high region the (ozone poor) high part of the vortex moved away.

Brinksma, E. J.↗
NASA NTRS2009

The Structure and Dynamics of Titan's Middle Atmosphere and Troposphere

Titan, after Venus, is the second example in the solar system of an atmosphere with a global cyclostrophic circulation. The origin and maintenance of these superrotating atmospheres is not well understood, but Titan has a strong seasonal modulation in the middle atmosphere, and the seasonal changes in the winds may offer clues. The pole in winter and early spring is characterized by temperatures 20-30 K cooler at 140-170 km than those at low latitudes, and strong circumpolar winds as high as 190 m/s at 200- 250 km. At these levels the polar region is characterized by enhanced concentrations of several organic gases, and also detectable condensates. All this suggests that the polar vortex provides a mixing barrier between winter polar and lower-latitude air masses, analogous to the polar ozone holes on Earth. Because the concentrations of organic gases increase with altitude in the middle atmosphere, the observed enhancements suggest subsidence over the winter pole. Consistent with this are the observed temperatures approximately 200 K at the winter-polar stratopause (280 km), making it the warmest part of the atmosphere. The warm stratopause likely results from adiabatic heating associated with the subsidence. Recent observations in late northern winter and early spring indicate that the warm anomaly at the winter-polar stratopause is weakening;. In contrast to the middle atmosphere, latitude contrasts in tropospheric temperatures are muted. During the northern winter season, they were approximately 5 K at the tropopause and 3 K or less near the surface, being coldest at high northern latitudes. This is understandable in terms of the long radiative relaxation times in the troposphere, compared to times that are much shorter than a season in the upper stratosphere and higher. Curiously, the transition between the small meridional contrast (and presumably seasonal variations) in temperatures observed in the troposphere and the large variations observed at higher altitudes occurs abruptly above 80 km. Here the temperatures in the lower stratosphere, generally increasing with altitude, exhibit a sudden drop with increasing altitude at high northern latitudes, producing the contrast between low and high northern winter latitudes in the upper stratosphere described above. While the radiative relaxation time associated with infrared gaseous coolants decreases with altitude in the stratosphere, the abrupt transition suggests the presence of an optically thick condensate at thermal-infrared wavelengths. Near the surface, temperature lapse rates are adiabatic over the lowest 2 km, with the suggestion of a nocturnal stable inversion over the lowest 200 m in radio-occultation soundings near the morning terminator. At mid and high latitudes in both winter and summer hemispheres, the profiles are more statically stable (i.e., subadiabatic). This is most pronounced in the winter hemisphere.

Flasar, F.M.↗
NASA NTRS1993

HALOE Antarctic observations in the spring of 1991

HALOE observations of O3, CH4, HF, H2O, NO, NO2, and HCl collected during the October 1991 Antarctic spring period are reported. The data show a constant CH4 mixing ratio of about 0.25 ppmv for the altitude range from 65 km down to about 25 km at the position of minimum wind speed in the vortex: i.e., the vortex center, and depressions in pressure versus longitude contours of NO, NO2, HF, and HCl in this same region. Water vapor, HF, and HCl enhancement are also observed in the vortex center region above about 25 km. Between 10 and 20 km, the expected mixing ratio signatures exist within the vortex, i.e., low ozone and dehydration. The water vapor increased by 50 percent, and the ozone level doubled inside the vortex between October 11 and 24 in the 15-20 km layer. These changes imply a time constant for recovery from ozone hole conditions of 19 and 30 days for O3 and H2O, respectively. The data further show the presence of air inside the vortex between 3 and 30 mb which has mixing ratios characteristic of midlatitudes.

Russell, James M., III↗