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At least 73 records · Page 4

Composition and Dynamical Processes of Ions in Giant Magnetospheres: The Importance of In Situ Measurements for Advancing the Current Knowledge [Slides]

In this white paper, we emphasize the importance of in situ ion composition measurements provided by plasma mass spectrometers in planetary magnetospheres (Uranus and Neptune) aimed for future planetary missions. We present our current understanding on magnetospheres of Uranus and Neptune that are largely based on Plasma Science Investigation (PLS, faraday cups) and Low Energy Charged Particle (LECP) instrument on Voyager 2 and what measurements need to be made to improve it. We emphasize that the future missions equipped with plasma mass spectrometers must visit these magnetospheres again to advance our current knowledge. Finally, this white paper summarizes key science questions that needs to be addressed which all of them requires a direct ion composition measurements from a plasma spectrometer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

IPN Absorption Coefficients

The dataset contains aerosol light absorption and scattering coefficients measured by three single-wavelength Integrated Photoacoustic Nephelometers (IPN). The absorption coefficients were measured at 405, 721, and 1047 nm, while the scattering coefficients were measured at 405 and 721 nm. The single scattering albedo (SSA) at 405 and 721 nm were also calculated from the IPN measurements. The three IPNs shared a common inlet without impactor/cyclone in July; in August, a PM2.5 cyclone inlet was installed to reduce measurement noise and improve data quality. The 721-nm IPN experienced laser shutdown issues, causing missing of a large fraction of the 721-nm measurements, especially in July. As described before, the 721-nm laser issue was less frequent in August after the cyclone installation, improving the data completeness and quality. The IPN raw data were noisy, making identifying patterns and trends difficult; therefore, the hourly average data are recommended over the raw data. The hourly average data were cross-checked with the filter-based TAP and PSAP measurements, which showed that their patterns, trends, and peaks matched. However, due to the differences in working mechanisms and principles of the filter-based and photoacoustic particle-phase instruments, the IPN measurements are lower than the filter-based measurements despite that they have consistent patterns, trends, and peaks.

54 ENVIRONMENTAL SCIENCES↗

EPCAPE-PT-LANL Measurements: Aerodynamic Part Sizer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: Aerodynamic particle sizer (TSI) Files data_10min_APS.csv Header: - List [0.54 to 19.81] middle of the size bin in microns: Data reports the concentration particles in this size bin per cubic centimeter, dN/dLog(dp). - CVI_Flag[bool]: A boolean flag indicating whether the Counterflow Virtual Impactor (CVI) was active (true) or inactive (false) during the measurement.

54 ENVIRONMENTAL SCIENCES↗

Fluorescent bioaerosol particle concentrations measured by the DU WIBS during the AGINSGP field experiment

Real-time, immersion mode ambient fluorescent bioaerosol concentrations were measured at ARM’s Southern Great Plains (SGP) site during the AGINSGP field experiment using a Wideband Integrated Bioaerosol Sensor (DMT Inc.; WIBS-4A). The WIBS-4A is an optical particle counter that also measures single particle fluorescence in three channels, along with particle asymmetry. Particles are grouped into different types depending on which channels they fluoresce in. The instrument was located in the guest instrument facility (GIF) and measured fluorescent particle concentrations from April 7th to April 29th. Data presented here are the concentrations for each particle type, binned in 5 minute increments. Air was drawn into the GIF through custom aluminum stack inlets (6” inner diameter) attached vertically to the outer GIF wall and the GIF outside platform. A blower pulled air through the stacks at a velocity of 1 m/s. Aerosol instruments subsampled via wall ports, through either 3/8” or 1/4" copper lines, depending on sample flow of the instrument. Particles were dried using a silica diffusion dryer prior to analysis.

54 ENVIRONMENTAL SCIENCES↗

Testing of a 40-kWth Counterflow Particle-Supercritical Carbon Dioxide Narrow-Channel, Fluidized Bed Heat Exchanger

Particle-based primary heat exchangers (HXs) must deliver sCO2 fluid temperatures above 700°C to couple particle-based concentrating solar receivers and thermal energy storage (TES) sub-systems with efficient sCO2 power cycles. Particle-sCO2 HX designs have struggled to meet DOE cost targets (≤ $150/kWth) due to the amount of expensive nickel alloys necessary for manufacturing full-scale, particle-sCO2 HXs. Our team has demonstrated that mild bubbling fluidization of falling particles in a counterflow narrow-channel fluidized bed can reduce required HX surface area and thus, costs by increasing particle-wall heat transfer coefficients hT,w > 800 W m-2 K-1. This paper reports on the fabrication and testing of a stainless steel, particle-sCO2 HX with 12 fluidized-bed channels approximately 10.5 mm deep spaced between diffusion-bonded, micro-channel sCO2 plates. The HX with a core length of ≈0.56 m is fed with CARBOBEAD HSP particles through a short, fluidized freeboard zone just above the core. Testing to date in the National Solar Thermal Test Facility (NSTTF) at Sandia National Laboratories has shown that parallel bed fluidization maintains uniform particle inventory across the instrumented channels. Heat transfer thermal duty between the particle and sCO2 flows exceeds 30 kWth with sCO2 inlet temperatures of 200ºC and particle inlet temperatures up to 440ºC and mass flow rates of 0.2 kg s-1 fluidized by counterflowing gas flow rates of 0.005 kg s-1. Tests at higher particle and sCO2 inlet temperatures (600ºC and 400ºC respectively) are targeted to achieve > 40 kWth with model-predicted overall heat transfer coefficients U > 400 W m-2 K-1.

14 SOLAR ENERGY↗

A Novel Optical Instrument for On-Line Measurement of Particle Size Distribution—Application to Clean Coal Technologies

A flow cell is a critical measurement interface for many optical instruments. However, the flows are often sampled under harsh conditions, such as under high pressure and/or high temperature, in the presence of particles, moisture, vapors with high dew points or corrosive gases. Therefore, obtaining a high-optical-quality flow cell that does not perturb the measurement is a significant challenge. To address this challenge, we proposed a new flow cell that employs a unique laminar coaxial flow field (for the purge and sample flows). A test system was built to conduct particle size distribution (PSD) measurements with no sampling bias using a state-of-the-art analyzer (Malvern Panalytical Insitec). The results revealed that the measurement zone is well defined solely by the sample flow, and the optical windows are well protected by the purge flow, with minimal risk of any depositions from the sample flow. Using this flow cell, the Insitec can successfully measure PSD under high pressure and temperature under moist, corrosive conditions without generating any sampling bias. Importantly, we successfully applied this flow cell for on-line PSD measurement for the flue gas of a 100 kWth pressurized oxy-coal combustor operating at 15 bara.

Cheng, Mao (ORCID:0000000213273900)↗

Virtual Slit Cycloidal Mass Spectrometry for Isotopic Measurements of Actinide Particles

The Virtual Slit Cycloidal Mass Spectrometer is a unique instrument for analysis of particles with mass spectrometry. It combines the unique properties of the cycloidal mass analyzer with capacitive transimpedance amplifier array detectors to make a portable instrument potentially capable of high sensitivity measurements on single particles, including high precision isotope ratios.

47 OTHER INSTRUMENTATION↗

Portable Optical Particle Spectrometer aboard an Airborne Platform (POPS_AIR) Instrument Handbook

The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility portable optical particle spectrometer (POPS) is a lightweight particle spectrometer designed for aerosol particle size distribution measurement. Several POPS of different versions have been procured to serve as routine instruments for the ARM Aerial Facility (AAF) unmanned aerial systems (UAS) and tethered balloon system (TBS) deployment since 2018. POPS measures the aerosol particle size distribution approximately between 0.13 and 3 μm.

54 ENVIRONMENTAL SCIENCES↗

Field intercomparison of ice nucleation measurements: the Fifth International Workshop on Ice Nucleation Phase 3 (FIN-03)

Abstract. The third phase of the Fifth International Ice Nucleation Workshop (FIN-03) was conducted at the Storm Peak Laboratory in Steamboat Springs, Colorado, in September 2015 to facilitate the intercomparison of instruments measuring ice-nucleating particles (INPs) in the field. Instruments included two online and four offline measurement systems for INPs, which are a subset of those utilized in the laboratory study that comprised the second phase of FIN (FIN-02). The composition of the total aerosols was characterized using the Particle Analysis by Laser Mass Spectrometry (PALMS) and Wideband Integrated Bioaerosol Sensor (WIBS) instruments, and aerosol size distributions were measured by a laser aerosol spectrometer (LAS). The dominant total particle compositions present during FIN-03 were composed of sulfates, organic compounds, and nitrates, as well as particles derived from biomass burning. Mineral-dust-containing particles were ubiquitous throughout and represented 67 % of supermicron particles. Total WIBS fluorescing particle concentrations for particles with diameters of > 0.5 µm were 0.04 ± 0.02 cm−3 (0.1 cm−3 highest; 0.02 cm−3 lowest), typical of the warm season in this region and representing ≈ 9 % of all particles in this size range as a campaign average. The primary focus of FIN-03 was the measurement of INP concentrations via immersion freezing at temperatures > −33 °C. Additionally, some measurements were made in the deposition nucleation regime at these same temperatures, representing one of the first efforts to include both mechanisms within a field campaign. INP concentrations via immersion freezing agreed within factors ranging from nearly 1 to 5 times on average between matched (time and temperature) measurements, and disagreements only rarely exceeded 1 order of magnitude for sampling times coordinated to within 3 h. Comparisons were restricted to temperatures lower than −15 °C due to the limits of detection related to sample volumes and very low INP concentrations. Outliers of up to 2 orders of magnitude occurred between −25 and −18 °C; a better agreement was seen at higher and lower temperatures. Although the 5–10 factor agreement of INP measurements found in FIN-03 aligned with the results of the FIN-02 laboratory comparison phase, giving confidence in progress of this measurement field, this level of agreement still equates to temperature uncertainties of 3.5 to 5 °C that may not be sufficient for numerical cloud modeling applications that utilize INP information. INP activity in the immersion-freezing mode was generally found to be an order of magnitude or more, making it more efficient than in the deposition regime at 95 %–99 % water relative humidity, although this limited data set should be augmented in future efforts. To contextualize the study results, an assessment was made of the composition of INPs during the late-summer to early-fall period of this study inferred through comparison to existing ice nucleation parameterizations and through measurement of the influence of thermal and organic carbon digestion treatments on immersion-freezing ice nucleation activity. Consistent with other studies in continental regions, biological INPs dominated at temperatures of > −20 °C and sometimes colder, while arable dust-like or other organic-influenced INPs were inferred to dominate below −20 °C.

54 ENVIRONMENTAL SCIENCES↗

FY23 Update: Aerosol Sampling for the Canister Deposition Field Demonstration

This report describes the results of preliminary testing of aerosol monitoring equipment that will be used to continuously monitor the aerosol source term for the multi-year Canister Deposition Field Demonstration (CDFD). These data are required inputs for the development and validation of models for the deposition of dust and potentially corrosive salts on the surface of spent nuclear fuel (SNF) dry storage canisters. Surface salt loads correlate with the extent of corrosion damage on a metal surface, and potentially to the likelihood and timing of initiation of stress corrosion cracks. Aerosols will be monitored at the CDFD site using three instruments. A Dekati ® ELPI+ cascade impactor will be used for real-time monitoring of aerosol particle sizes. It will also collect dust in 14 size bins on impactor targets that can be chemically analyzed to determine the soluble salts present as a function of particle size. However, this instrument can only measure dried aerosols, with a diameter of <10 µm. The second instrument is a Topas laser particle size spectrometer, which provides real-time monitoring of aerosol particle sizes up to ~40 µm in size. It monitors both the ambient (potentially deliquesced) aerosol particle size distributions required for the dust deposition models and the distributions of the equivalent dried particles, allowing correlation with the Dekati ® data. However, it does not discriminate between inert dust particles and salt aerosols, and it does not retain samples of the different particle sizes for later analysis. The third instrument that will monitor aerosols at the CDFD site is a Clean Air Status and Trends Network (CASTNET) tower, which uses a multiple canister system to collect weekly samples for analysis to total suspended aerosol particle compositions and atmospheric gas concentrations. This status report describes work in FY23 to develop the capabilities for using these tools. In two training exercises, the cascade impactor and laser particle sizer were deployed in two different testing environments, one indoor and one outdoor. For the cascade impactor, the tests provided opportunities for the operators to familiarize themselves with impactor substrate preparation, and post-test sample removal and analysis. For the laser particle sizer, the tests were used to evaluate different instrument parameters, to determine the most appropriate settings for capturing transient events. Data and samples were collected for weeks to months for each test, and the results are presented here. In addition to the preliminary testing, contracts were developed with WSP Analytical Labs for sample preparation and analysis of the cascade impactor samples. The impactor tower from outdoor test was delivered to WSP and used to train the staff there in disassembly, sample extraction, sample analysis, and tower reassembly with new target substrates. These are tasks that WSP will be performing routinely for the CDFD project. The CASTNET system cannot be purchased or tested until an actual site has been selected for the CDFD test. Work for this FY has been restricted to preparation of contracts for purchasing the CASTNET tower, and for sample analysis, once the tower is in operation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

mergedsmpsaps

Merged aerosol particle size distributions for the Aerodynamic Particle Sizer (APS) and Scanning Mobility Particle Sizer (SMPS) instruments

54 ENVIRONMENTAL SCIENCES↗

Proposal to search for long-lived neutral particles in CERN service shafts

Long-lived particles are predicted by many extensions of the Standard Model and have been gaining interest in recent years. In this paper the original proposal is presented for AN Underground Belayed In-Shaft (ANUBIS) detector that substantially extends the sensitivity to particle lifetimes by instrumenting the existing service shafts above the ATLAS or CMS experiments with tracking stations. For scenarios with electrically neutral long-lived particles with 𝑚 ≳ 1~GeV produced at the electroweak scale and above, the lifetime reach is increased by 2-3 orders of magnitude compared to currently operating and approved future experiments at the LHC. Here, the original ANUBIS detector design proposal is outlined along with the projected costs.

ANUBIS↗

Project ICEBall: Cryo-SEM images of Captured Cirrus Ice Particles. ARM SGP, October 21-November 1, 2021

This dataset includes a unique set of cryo-SEM images of captured cirrus ice particle from ARM Project ICEBall, which was conducted at and around the Southern Great Plains site from October 21- November 1, 2021. The instrument used for particle collection, Ice Crystal Encapsulation by Ball (ICE-Ball), is described in Magee et al. 2021, 'Captured cirrus ice particles in high definition", Atmos. Chem. Phys. The ice particles were captured on balloon flights directly from cirrus cloud formations between 7-12 km on seven ICEBall flights on these dates: October 21, 23, 24, 25, 26, 31, and Nov. 1.

54 ENVIRONMENTAL SCIENCES↗

Accessing the deuteron source with pion-deuteron femtoscopy in Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV

Femtoscopy of nonidentical particle pairs has been instrumental for precision measurements of both two-particle sources and the final-state interactions in high-energy elementary and heavy-ion collisions. The majority of measurements assessing the source properties are based on identical particle pairs, providing direct access to the characteristics of the single-particle source. The work in this paper demonstrates, via femtoscopy measurements of charged pion-deuteron pairs in Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV, the feasibility of accessing the characteristics of the single-particle femtoscopic source by using particle pairs with large mass differences such as pions and deuterons. The first experimental results of the measurement of deuteron source sizes in ultrarelativistic heavy-ion collisions are presented. The results show good agreement with the trend derived from other charged hadrons such as pions, kaons, and protons as a function of transverse mass, indicating similar source properties.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

mergedsmpsapsml

Merged aerosol particle size distributions for the Aerodynamic Particle Sizer (APS) and Scanning Mobility Particle Sizer (SMPS) instruments with Machine Learning Quality Checks Applied

54 ENVIRONMENTAL SCIENCES↗

ARM Aerial Facility (AAF) Water-based Condensation Particle Counter

The condensation particle counter (CPC) measures sub-micron aerosol particle number concentration by condensing fluid onto particles and causing them to grow to sizes that are easily detectable by optical scattering. The condensing liquid is typically an alcohol (e.g., butanol) or water. Depending on the CPC type, typical CPC instruments can count particles with sizes that range from 3 to 3000 nanometers (ultrafine CPC) or from 10 to 3000 nanometers (fine CPC).

54 ENVIRONMENTAL SCIENCES↗

EPCAPE-PT-LANL Measurements: Scanning Mobility Particle Sizer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: Scanning Mobility Particle Sizer (TSI), DMA Classifier Model 3082 + CPC Detector Model 3752. Data Notes: The SMPS dataset is limited due to necessary instrument maintenance and subsequent extensive downtime. Data is only available from October 21 to November 8, 2023. Post November 22, 2023, the NanoScan instrument provided coverage for the latter half of the campaign. To ensure consistency, the data was resampled into uniform size bins ranging from 15 nm to 667 nm. This adjustment was required due to changes in size bins and the maximum diameter that occurred after maintenance and repairs. Multiple Charge Correction applied, Nanoparticle Agglomerate Mobility Analysis not applied, and Diffusion Correction applied. Header: - List [15 nm to 667 nm] middle of the size bin in nanometers: Data reports the concentration particles in this size bin per cubic centimeter, dN/dLog(dp). - CVI_Flag[bool]: A boolean flag indicating whether the Counterflow Virtual Impactor (CVI) was active (true) or inactive (false) during the measurement.

54 ENVIRONMENTAL SCIENCES↗