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At least 73 records · Page 4

Three-dimensional mantle dynamics with an endothermic phase transition

3D convection for the spinel to perovskite phase change has been simulated numerically. Results for Rayleigh (Ra) numbers of 0(10 exp 6) show intermittent layering with a strong robust plume rising through the phase boundary. Many descending instabilities are deflected but merging cold sheets come together at a junction. A pool of cold material accumulates underneath in the phase-transition zone. A strong gravitational instability results, which precipitates a rapid and massive discharge of upper-mantle material.

Honda, S.↗

Evolution of attached and detached slabs and their associated mantle dynamics

Over the two years of the NASA grant, this project has produced a significant amount of research results related to the plate subduction process and the surface crustal deformation at convergent boundaries (i.e., above subduction zones). While some research objectives are completely accomplished, other research tasks remain active and continue to be investigated at present. A steady state analytic thermal model for subducting slabs was used to examine the torques acting on a descending slab. It is found that gravitational torque vanishes when a slab is dipping either vertically or horizontally, unlike previous studies indicating that the magnitude of gravitational torque decreases as dip angle increases. Subsequently, a new time-dependent, analytic thermal model for a subducting slab was developed. The new model enables us to study transient phenomena associated with plate subduction analytically. On the basis of this model, the nature of slab dip angles was evaluated. Slab dip angles are found to be transient features. As they penetrate into the mantle and increase their lengths, the associated gravitational torque also increases resulting in a downward pulling of the slab to the steeper dip angle. This is especially true once a slab penetrates the olivine-spinel phase boundary at about 400 km depth. However, if the phase transformation does not follow the equilibrium condition, the gravitational torque may have a different behavior. This problem was investigated. Except for fast descending slabs, non-equilibrium phase transformation can only slow down the transient increase of slab dip angles discussed earlier. Its effect is not sufficiently strong to reverse the downward pulling for most of the slabs. However, when slabs subducting at 10 cm/yr or faster, a sufficient amount of metastable olivine can exist beneath 400 km. Because of its low density compared with the surrounding spinel, an upward buoyancy is produced resulting in an upward bending of the slab and possibly an upward rotation of the slab such that smaller dip angles are formed. Seismic studies of the Japanese Slab seem to support this interpretation. The development of oroclinal geometries at convergent boundaries was also examined to study plate obduction which is an important ingredient to the initiation of plate subduction. Although the study suggests that surface features are better modeled by block models, the large scale deformation can be adequately studied by viscous models. Such a model is now under development to complete our original objective to study the initiation of plate subduction. Finally, a three-dimensional, finite element, spherical convective model is developed to study dynamic plate subductions. The model development is now complete and it is being tested to ensure its proper operation. The model is able to generate convection results with a viscosity contrast of about 100. Our research continues to push the viscosity contrast to a level that is appropriate for a subducting slab.

Hsui, Albert T.↗

Subduction of hydrated basalt of the oceanic crust: Implications for recycling of water into the upper mantle and continental growth

Subduction zones are presently the dominant sites on Earth for recycling and mass transfer between the crust and mantle; they feed hydrated basaltic oceanic crust into the upper mantle, where dehydration reactions release aqueous fluids and/or hydrous melts. The loci for fluid and/or melt generation will be determined by the intersection of dehydration reaction boundaries of primary hydrous minerals within the subducted lithosphere with slab geotherms. For metabasalt of the oceanic crust, amphibole is the dominant hydrous mineral. The dehydration melting solidus, vapor-absent melting phase relationships; and amphibole-out phase boundary for a number of natural metabasalts have been determined experimentally, and the pressure-temperature conditions of each of these appear to be dependent on bulk composition. Whether or not the dehydration of amphibole is a fluid-generating or partial melting reaction depends on a number of factors specific to a given subduction zone, such as age and thickness of the subducting oceanic lithosphere, the rate of convergence, and the maturity of the subduction zone. In general, subduction of young, hot oceanic lithosphere will result in partial melting of metabasalt of the oceanic crust within the garnet stability field; these melts are characteristically high-Al2O3 trondhjemites, tonalites and dacites. The presence of residual garnet during partial melting imparts a distinctive trace element signature (e.g., high La/Yb, high Sr/Y and Cr/Y combined with low Cr and Y contents relative to demonstrably mantle-derived arc magmas). Water in eclogitized, subducted basalt of the oceanic crust is therefore strongly partitioned into melts generated below about 3.5 GPa in 'hot' subduction zones. Although phase equilibria experiments relevant to 'cold' subduction of hydrated natural basalts are underway in a number of high-pressure laboratories, little is known with respect to the stability of more exotic hydrous minerals (e.g., ellenbergite) and the potential for oceanic crust (including metasediments) to transport water deeper into the mantle.

Rapp, R. P.↗

Effects of Dopant on Depoling Temperature in Modified BiScO3 - PbTiO3

In recent years there has been a renewed interest for high temperature piezoelectrics for both terrestrial and aerospace applications. These applications are limited in part by the operating temperature, which is usually taken as one half of the Curie temperature (Tc), and is 200C for one of the most widely used commercial piezoelectrics, Pb(Zr,Ti)O3 (PZT). In an effort to increase Tc, subsequent research into high temperature Bi(BB)O3 PbTiO3 piezoelectrics led to the discovery of the morphotropic phase boundary (MPB) in the high-Tc BiScO3 PbTiO3 (BS-PT) system with a Tc of 460C and a d33 of 460 pmV. The Tc marks the ferroelectric to paraelectric phase transformation and while, in general, a phase transformation leads to thermal depoling in piezoelectrics with low or moderate Tcs, for high Tc piezoelectrics thermally assisted dipole rotation can lead to randomization of domains at temperatures below Tc. It becomes necessary to determine the depoling temperature (Td) which dictates the actual working temperature range. By doping for Sc and Ti the Td can be shifted while maintaining similar electromechanical properties as a function of temperature. The effect of this B-site doping on depoling temperature has been explored through the characterization of microstructure and weakhigh field measurements.

Actuator↗

Pressureless sintered beta prime-Si3N4 solid solution: Fabrication, microstructure, and strength

Si3N4, AlN, and Al2O3 were used as basic constituents in a study of the pressureless sintering of beta prime-Si3N4 solid solution as a function of temperature. Y2O3-SiO2 additions were used to promote liquid-phase sintering. The sintered specimens were characterized with respect to density, microstructure, strength, oxidation, and thermal shock resistance. Density greater than 98 percent of theoretical was achieved by pressureless sintering at 1750 C. The microstructure consisted essentially of fine-grained beta prime-Si3N4 solid solution as the major phase. Modulus of rupture strengths up to 483 MPa were achieved at moderate temperature (1000 C), but decreased to 228 MPa at 1380 C. This substantial strength loss was attributed to a glassy grain boundary phase formed during cooling from the sintering temperature. The best oxidation resistance was exhibited by a composition containing 3 mol % Y2O3-SiO2 additives. Water quench thermal shock resistance was equivalent to that of reaction sintered silicon nitride but lower than hot-pressed silicon nitride.

Dutta, S.↗

Pressureless sintered beta-prime-Si3N4 solid solution - Fabrication, microstructure, and strength

Pressureless sintering of beta-prime-Si3N4 solid solution was studied as a function of temperature using Si3N4, A1N, and Al2O3 as basic constituents. Y2O3-SiO2 additions were used to promote liquid-phase sintering. The sintered specimens were characterized with respect to density, microstructure, strength, oxidation, and thermal shock resistance. Density greater than 98 percent of theoretical was achieved by pressureless sintering at 1750 C. The microstructure consisted essentially of fine-grained beta-prime-Si3N4 solid solution as the major phase. Modulus of rupture strengths up to 483 M Pa were achieved at moderate temperature (1000 C), but decreased to 228 M Pa at 1380 C. This substantial strength loss was attributed to a 'glassy' grain boundary phase formed during cooling from the sintering temperature. The best oxidation resistance was exhibited by a composition containing 3 mol % Y2O3-SiO2 additives. Water quench thermal shock resistance was equivalent to that of reaction sintered silicon nitride but lower than hot-pressed silicon nitride.

Dutta, S.↗

Studies on aqueous two phase polymer systems useful for partitioning of biological materials

The two phase systems that result when aqueous solutions of dextran and poly(ethylene glycol) (PEG) are mixed above a critical concentration of a few percent provide a useful medium for the separation of biological cell subpopulations via partition between the top, PEG-rich phase and the liquid-liquid phase boundary. Interfacial tensions of such systems have been measured by the rotating drop technique and found to range between 0.1-100 micro-N/m. The tension was found to depend on the length of the tie line describing the system on a phase diagram, via a power law relationship which differed depending on the concentration of Na phosphate buffer present. The electrokinetic properties of drops of one phase suspended in the other were studied for a variety of systems. It was found that the droplet electrophoretic mobility increased monotonically with phosphate concentration and drop diameter but exhibited the opposite sign from that anticipated from phosphate partition measurements. It was possible to take advantage of these electrokinetic properties and dramatically enhance the speed of phase separation through application of relatively small electric fields.

Brooks, D. E.↗

Calculation of Phase Equilibria in the Y2O3-Yb2O3-ZrO2 System

Rare earth oxide stabilized zirconias find a wide range of applications. An understanding of phase equilibria is essential to all applications. In this study, the available phase boundary data and thermodynamic data is collected and assessed. Calphad-type databases are developed to completely describe the Y2O3-ZrO2, Yb2O3-ZrO2, and Y2O3-Yb2O3 systems. The oxide units are treated as components and regular and subregular solution models are used. The resultant calculated phase diagrams show good agreement with the experimental data. Then the binaries are combined to form the database for the Y2O3-Yb2O3-ZrO2 psuedo-ternary.

Jacobson, Nathan S.↗

Modelling Equilibrium and Fractional Crystallization in the System MgO-FeO-CaO-Al2O3-SiO2

A mathematical modelling technique for use in petrogenesis calculations in the system MgO-FeO-CaO-Al2O3-SiO2 is reported. Semiempirical phase boundary and elemental distribution information was combined with mass balance to compute approximate equilibrium crystallization paths for arbitrary system compositions. The calculation is applicable to a range of system compositions and fractionation calculations are possible. The goal of the calculation is the computation of the composition and quantity of each phase present as a function of the degree of solidification. The degree of solidification is parameterized by the heat released by the solidifying phases. The mathematical requirement for the solution of this problem is: (1) An equation constraining the composition of the magma for each solid phase in equilibrium with the liquidus phase, and (2) an equation for each solid phase and each component giving the distribution of that element between that phase and the magma.

Herbert, F.↗

Strength and microstructure of Si3N4 sintered with ZrO2 additions

Densities greater than 99 percent of theoretical were obtained with stabilized ZrO2 additions to Si3N4. Material sintered at 2140 C under 2.5 MPa nitrogen overpressure with 3.8, 9.9, and 13.4 wt pct ZrO2 had a predominantaly equiaxed grain size ranging from 0.2 to 7.0 microns. At 1370 C, the latter composition exhibited a flexural strength of about 487 MPa, equal to that of a finer-grain-size, hot-pressed Si3N4 + ZrO2 material having excellent high-temperature static fatigue properties. Transmission electron microscopy of the sintered Si3N4 revealed a glassy grain-boundary phase at all three ZrO2 levels and partially crystalline triple points for the 9.9 and 13.4 wt pct ZrO2-containing materials. Slow crack growth was observed for 1370 C flexure tests and correlated with nonlinear load deflection traces for stresses greater than 503 MPa. The crystallization of the grain-boundary glass is insterpreted as beneficial to the attainment of high (1370 C) flexural strength.

Sanders, W. A.↗

Liquid-Liquid Phase Separation in Supersaturated Lysozyme Solutions and Associated Precipitate Formation/Crystallization

Using cloud point determinations, the phase boundaries (binodals) for metastable liquid-liquid (L-L) separation in supersaturated hen egg white lysozyme solutions with 3%, 5%, and 7% (wlv) NaCl at pH= 4.5 and protein concentrations c between 40 and 400 mg/ml were determined. The critical temperature for the binodal increased approximately linearly with salt concentration. The coexisting liquid phases both remained supersaturated but differed widely in protein concentration. No salt repartitioning was observed between the initial and the two separated liquid phases. After the L-L separation, due to the presence of the high protein concentration phase, crystallization occurred much more rapidly than in the initial solution. At high initial protein concentrations, a metastable gel phase formed at temperatures above the liquid binodal. Both crystal nucleation and gel formation were accelerated in samples that had been cycled through the binodal. Solutions in the gel and L-L regions yielded various types of precipitates. Based on theoretical considerations, previous observations with other proteins, and our experimental results with lysozyme, a generic phase diagram for globular proteins is put forth. A limited region in the (T,c) plane favorable for the growth of protein single crystals is delineated.

Muschol, Martin↗

A microstructural study of the Tishomingo meteorite

Metallography, electron microscopy, and X-ray diffraction techniques were employed to study a fragment of the Tishomingo iron meteorite. The results suggest the following thermal-mechanical history: The fragment was originally a large crystal of taenite (gamma). Cooling through the alpha + gamma phase boundary did not result in accompanying precipitation of kamacite (alpha). Transformation to a martensitic structure initiated between -25 and -65 C. Transformation continued as the temperature fell to -75 to -115 C, resulting in approx 80% martensite (alpha-prime). Subsequent shock deformation and thermal aging processes substantially modified the taenite and martensite microstructures. Twins in the retained taenite phase are attributed to shock deformation at a pressure estimated for a single event at about 170 kbar. The existing complex altered martensite structure containing both taenite and kamacite (3-15% Ni) particles was apparently the product of both shock deformation and thermal aging processes. The maximum temperature reached during thermal aging is estimated to be less than 400 C and perhaps below 310 C.

Ives, L. K.↗

Direct numerical simulations of fluid flow, heat transfer and phase changes

Direct numerical simulations of fluid flow, heat transfer, and phase changes are presented. The simulations are made possible by a recently developed finite difference/front tracking method based on the one-field formulation of the governing equations where a single set of conservation equations is written for all the phases involved. The conservation equations are solved on a fixed rectangular grid, but the phase boundaries are kept sharp by tracking them explicitly by a moving grid of lower dimension. The method is discussed and applications to boiling heat transfer and the solidification of drops colliding with a wall are shown.

Phase Transformations↗

Microstructure and property characterization of sintered Si3N4, SiC, and SiAlON

Commercially-produced, pressureless sintered Si3N4, SiC, and SiAlON were characterized with respect to density, phases present, bend strength, and oxidation resistance. The room-temperature bend strengths of sintered Si3N4, SiC, and SiAlON are comparable. However, the room-temperature strengths are much lower (approximately 40 to 50%) than the room-temperature strength of hot-pressed Si3N4 (NC-132). The strength loss in Si3N4 and SiAlON materials at high temperature was attributed to a viscous grain-boundary phase, retained during cooling from the sintering temperature. The oxidation resistance of sintered alpha-SiC was the best of any materials tested.

Dutta, S.↗

The shock wave equation of state of brucite Mg(OH)2

New shock equation of state (EOS) data on magnesium hydroxide between 12 and 60 GPa is presented. It is found that the brucite EOS data between 12 and 97 GPa can be fit with a single linear U(s) - u(p) relationship: U(s) = 4.76(0.11) + 1.35(0.05)u(p). The third order Birch-Murnaghan equation parameters are K(os) = 51 + or - 4 GPa and K(os)prime = 5.0 + or - 0.4. The first partial release states measured for brucite Mg(OH)2 are reported. Calculated phase boundaries using the EOS data are found to be consistent with the experimental data and indicate that brucite is unlikely to be stable under lower mantle conditions. At high pressure, bulk sound velocities calculated for MgO and Mg(OH)2 are very similar, indicating that the presence of hydrous assemblages in the lower mantle may not produce anomalous bulk seismic velocities. A comparison of densities in brucite and other high-pressure phases under mantle conditions shows that the water content of the lower mantle is between 0 and 3 wt pct.

Duffy, Thomas S.↗

CFD Modeling of Tank Pressurization and Axial Jet Mixing Experiments with and without Non-Condensable Gas in the Ullage

A two-phase CFD model for tank pressurization and following jet mixing of a cryogenic storage tank is presented using VOF approach for representing the phase boundary and the associated interfacial heat, mass and momentum transfer between the liquid and vapor regions. The CFD model was validated against pressurization and liquid jet mixing data for a 110-inch diameter tank provided by Bullard1. Cases with like-gas and non-condensable gas pressurization are studied. The results of the cases with like-gas pressurization and following mixing are presented first, focusing on the effects of turbulence at the vapor-liquid interface on the tank pressure and phase change rates predictions. The second part of this paper is devoted to testing and validating the CFD model against non-condensable gas pressurization and following mixing. Tank pressures predicted in both cases are compared with each other and with the experimental data.

Computational Fluid Dynamics↗

CFD Modeling of Tank Pressurization and Axial Jet Mixing Experiments with and without Non-Condensable Gas in the Ullage

A two-phase CFD model for tank pressurization and following jet mixing of a cryogenic storage tank is presented using VOF approach for representing the phase boundary and the associated interfacial heat, mass and momentum transfer between the liquid and vapor regions. The CFD model was validated against pressurization and liquid jet mixing data for a 110-inch diameter tank provided by Bullard. Cases with like-gas and non-condensable gas pressurization are studied. The results of the cases with like-gas pressurization and following mixing are presented first, focusing on the effects of turbulence at the vapor-liquid interface on the tank pressure and phase change rates predictions. The second part of this paper is devoted to testing and validating the CFD model against non-condensable gas pressurization and following mixing. Tank pressures predicted in both cases are compared with each other and with the experimental data.

Computational Fluid Dynamics↗

Investigations of Physical Processes in Microgravity Relevant to Space Electrochemical Power Systems

NASA has performed physical science microgravity flight experiments in the areas of combustion science, fluid physics, material science and fundamental physics research on the International Space Station (ISS) since 2001. The orbital conditions on the ISS provide an environment where gravity driven phenomena, such as buoyant convection, are nearly negligible. Gravity strongly affects fluid behavior by creating forces that drive motion, shape phase boundaries and compress gases. The need for a better understanding of fluid physics has created a vigorous, multidisciplinary research community whose ongoing vitality is marked by the continuous emergence of new fields in both basic and applied science. In particular, the low-gravity environment offers a unique opportunity for the study of fluid physics and transport phenomena that are very relevant to management of fluid - gas separations in fuel cell and electrolysis systems. Experiments conducted in space have yielded rich results. These results provided valuable insights into fundamental fluid and gas phase behavior that apply to space environments and could not be observed in Earth-based labs. As an example, recent capillary flow results have discovered both an unexpected sensitivity to symmetric geometries associated with fluid container shape, and identified key regime maps for design of corner or wedge-shaped passive gas-liquid phase separators. In this presentation we will also briefly review some of physical science related to flight experiments, such as boiling, that have applicability to electrochemical systems, along with ground-based (drop tower, low gravity aircraft) microgravity electrochemical research. These same buoyancy and interfacial phenomena effects will apply to electrochemical power and energy storage systems that perform two-phase separation, such as water-oxygen separation in life support electrolysis, and primary space power generation devices such as passive primary fuel cell.

energy storage↗