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The Generation of Mixing Across the Stratospheric Polarvortex Edge By Breaking Gravity Waves

Modern high resolution global atmospheric analyses are capable of resolving larger gravity waves, including their generation, propagation, and breaking. Orographically generated gravity waves that break in the middle stratosphere often appear as disturbances in maps of potential vorticity, a key stratospheric dynamical quantity. Using analyses from the NASA Global Modeling and Assimilation Office, we show how gravity waves not only disturb the local flow above them but can generate flow instabilities leading to eddies that propagate around the stratospheric polar vortex, creating significant mixing across the vortex edge and into the polar region. These disturbances and mixing events are especially noticeable during NH winter months with low planetary scale wave activity such as in January 2022. During January 2022, the initially circular flow around the polar vortex was disrupted by breaking gravity waves, leading to unstable flow that created a chain of eddies around the vortex edge. The mixing associated with this process led to increased ozone in the upper stratosphere polar region.

Polar Vortex↗

NASA NTRS2003

Entrainment and Optical Properties of an Elevated Forest Fire Plume Transported into the Planetary Boundary Layer near Washington, D.C.

Smoke and pollutants from Canadian forest fires were transported over the northeastern United States in July 2002. Lidar observations at the NASA Goddard Space Flight Center show the smoke from these fires arriving in an elevated plume that was subsequently transported to the surface. Trajectory and three-dimensional model calculations confirm the origin of the smoke and show that it mixed to the surface after it was intercepted by the turbulent planetary boundary layer. Modeled smoke optical properties agreed well with aircraft and remote sensing observations provided coagulation of smoke particles was accounted for in the model. Our results have important implications for the long-range transport of pollutants and their subsequent entrainment to the surface, as well as the evolving optical properties of smoke from boreal forest fires.

Colarco, P. R.↗

NASA NTRS1981

Noble gases in E-chondrites

The combination of noble gas data for 12 E-chondrites with literature data shows K-Ar ages greater than 4 AE for 14 out of 18 meteorites, while U, Th-He ages are often shorter. Cosmic ray exposure ages are found to differ systematically between types E4 and E6, with the respective, below-16 Myr and above-30 Myr values implying that the E-chondrite parent body predominantly contains a single petrologic type on the 1 km scale of individual impacts in contrast to the mixed parent bodies of the ordinary chondrites. Amounts of planetary gas in E4-E6 chondrites fall in the range for ordinary chondrites of types 4-6, but fail to correlate with petrologic type or volatile trace element contents, in contrast to the ordinary chondrites. Analyses of mineral separates show that the planetary gases are concentrated in an HFand HCl-insoluble mineral, similar to phase Q. The subsolar gases are located in an HCl- and HNO3-resistant phase.

Crabb, J.↗

NASA NTRS2004

The First Cell Membranes

Organic compounds are synthesized in the interstellar medium and can be delivered to planetary surfaces such as the early Earth, where they mix with endogenous organic mixtures. Some of these compounds are amphiphilic, having polar and non-polar groups on the same molecule. Amphiphilic compounds spontaneously self-assembly into more complex structures such as bimolecular layers, which in turn form closed membranous vesicles. The first forms of cellular life required self-assembled membranes that were likely to be available on the prebiotic Earth. Laboratory simulations show that such vesicles readily encapsulate functional macromolecules, including nucleic acids and polymerases. A goal of future investigations is to fabricate artificial cells as models of the origin of life.

Deamer, David↗

NASA NTRS2014

An Advanced Neutron Spectrometer for Future Manned Exploration Missions

An Advanced Neutron Spectrometer (ANS) is being developed to support future manned exploration missions. This new instrument uses a refined gate and capture technique that significantly improves the identification of neutrons in mixed radiation fields found in spacecraft, habitats and on planetary surfaces. The new instrument is a composite scintillator comprised of PVT loaded with litium-6 glass scintillators. We will describe the detection concept and show preliminary results from laboratory tests and exposures at particle accelerators

Christl, Mark↗

NASA NTRS2023

Detail Enhancement of AIRS/AMSU Temperature and Moisture Profiles Using a 3D Deep Neural Network

In recent decades, spaceborne microwave and hyperspectral infrared sounding instruments have significantly benefited weather forecasting and climate science. However, existing retrievals of lower troposphere temperature and humidity profiles have limitations in vertical resolution, and often cannot accurately represent key features such as the mixed layer thermodynamic structure and the inversion at the planetary boundary layer (PBL) top. Because of the existing limitations in PBL remote sensing from space, there is a compelling need to improve routine, global observations of the PBL and enable advances in scientific understanding and weather and climate prediction. To address this, we have developed a new 3D deep neural network (DNN) which enhances detail and reduces noise in Level 2 granules of temperature and humidity profiles from the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit (AMSU) sounder instruments aboard NASA’s Aqua spacecraft. We show that the enhancement improves accuracy and detail including key features such as capping inversions at the top of the PBL over land, resulting in improved accuracy in estimations of PBL height.

Adam B Milstein↗

NASA NTRS1981

Simulation of the planetary boundary layer with the UCLA general circulation model

A planetary boundary layer (PBL) model is presented which employs a mixed layer entrainment formulation to describe the mass exchange between the mixed layer with the upper, laminar atmosphere. A modified coordinate system couples the mixed layer model with large scale and sub-grid scale processes of a general circulation model. The vertical coordinate is configured as a sigma coordinate with the lower boundary, the top of the PBL, and the prescribed pressure level near the tropopause expressed as coordinate surfaces. The entrainment mass flux is parameterized by assuming the dissipation rate of turbulent kinetic energy to be proportional to the positive part of the generation by convection or mechanical production. The results of a simulation of July are presented for the entire globe.

Suarez, M. J.↗

NASA NTRS1993

Convex set and linear mixing model

A major goal of optical remote sensing is to determine surface compositions of the earth and other planetary objects. For assessment of composition, single pixels in multi-spectral images usually record a mixture of the signals from various materials within the corresponding surface area. In this report, we introduce a closed and bounded convex set as a mathematical model for linear mixing. This model has a clear geometric implication because the closed and bounded convex set is a natural generalization of a triangle in n-space. The endmembers are extreme points of the convex set. Every point in the convex closure of the endmembers is a linear mixture of those endmembers, which is exactly how linear mixing is defined. With this model, some general criteria for selecting endmembers could be described. This model can lead to a better understanding of linear mixing models.

Xu, P.↗

NASA NTRS1999

Observations of Middle Atmosphere CO from the UARS ISAMS during the Early Northern Winter 1991/92

Structure and kinematics of carbon monoxide in the upper stratosphere and lower mesosphere (10-0.03 hPa) are studied for the early northern winter 1991/92 using the Upper Atmosphere Research Satellite Improved Stratospheric and Mesospheric Sounder (ISAMS) measurements. The study is aided by data from a 6-week parameterized-chemistry run of the Goddard Space Flight Center 3D Chemistry and Transport Model (CTM), initialized on 8 December 1991. Generally, CO mixing ratios increase with height due to the increasing source contribution from CO, photolysis. In the tropical upper stratosphere. however, a local maximum in CO mixing ratio occurs. A simple photochemical model is used to show that this feature results largely from methane oxidation. In the extratropics the photochemical lifetime of CO is long, and therefore its evolution is dictated by large-scale motion of air. evidenced by strong correlation with Ertel potential vorticity. This makes CO one of the few useful observable tracers at the stratopause level and above. Thus CO maps are used to study the synoptic evolution of the polar vortex in early January 1992. Modified Lagrangian mean mixing diagnostics are applied to ISAMS and CTM data to examine the strength of the mixing barrier at the polar vortex edge. It is demonstrated that planetary wave activity weakens the barrier. promoting vortex erosion. The vortex erosion first appears in the lower mesosphere and subsequently descends through the upper stratosphere. and is attributed to effects of planetary wave dissipation. Agreement between ISAMS and CTM is good in the horizontal distribution of CO throughout the examined period, but vertical CO gradients in the CTM weaken with time relative to the ISAMS observations.

Allen, D. R.↗

NASA NTRS2012

Comets as Messengers from the Early Solar System - Emerging Insights on Delivery of Water, Nitriles, and Organics to Earth

The question of exogenous delivery of water and organics to Earth and other young planets is of critical importance for understanding the origin of Earth's volatiles, and for assessing the possible existence of exo-planets similar to Earth. Viewed from a cosmic perspective, Earth is a dry planet, yet its oceans are enriched in deuterium by a large factor relative to nebular hydrogen and analogous isotopic enrichments in atmospheric nitrogen and noble gases are also seen. Why is this so? What are the implications for Mars? For icy Worlds in our Planetary System? For the existence of Earth-like exoplanets? An exogenous (vs. outgassed) origin for Earth's atmosphere is implied, and intense debate on the relative contributions of comets and asteroids continues - renewed by fresh models for dynamical transport in the protoplanetary disk, by revelations on the nature and diversity of volatile and rocky material within comets, and by the discovery of ocean-like water in a comet from the Kuiper Belt (cf., Mumma & Charnley 2011). Assessing the creation of conditions favorable to the emergence and sustenance of life depends critically on knowledge of the nature of the impacting bodies. Active comets have long been grouped according to their orbital properties, and this has proven useful for identifying the reservoir from which a given comet emerged (OC, KB) (Levison 1996). However, it is now clear that icy bodies were scattered into each reservoir from a range of nebular distances, and the comet populations in today's reservoirs thus share origins that are (in part) common. Comets from the Oort Cloud and Kuiper Disk reservoirs should have diverse composition, resulting from strong gradients in temperature and chemistry in the proto-planetary disk, coupled with dynamical models of early radial transport and mixing with later dispersion of the final cometary nuclei into the long-term storage reservoirs. The inclusion of material from the natal interstellar cloud is probable, for comets formed in the outer solar system.

Mumma, Michael J.↗

NASA NTRS2021

PBL Height from AIRS, GPS RO, and MERRA-2 Products in NASA GES DISC and Their 10 Year Seasonal Mean Intercomparison

Within the planetary boundary layer (PBL), surface forcing response, drag, turbulence, and vertical mixing are important processes and play a more critical role here than in the overlying “free atmosphere”. The PBL Height (PBLH) is an important parameter in climate models, weather forecasts, and air quality prediction. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) provides data processing, archiving, and distribution services for numerous Earth science products. PBLH is a parameter in three products served by GES DISC, which are from the Atmospheric Infrared Sounder (AIRS), the Global Positioning System (GPS) radio occultation (RO) experiment, and the NASA reanalysis product Modern-Era Retrospective analysis for Research and Applications – 2 (MERRA-2). These products have different spatial and temporal resolutions and coverages, and their PBLH definitions are also different. To better serve the PBL research community, we have summarized the specifications of these products. A ten-year seasonal mean intercomparison is also conducted to provide further guidance to users. The intercomparison results show that MERRA-2 has a much shallower PBL than AIRS and GPS RO. An experimental study indicates the different PBLH definition in MERRA-2 caused smaller values of PBLH. The improvement of the water vapor retrieval in AIRS version 7 over version 6 results in the version 7 PBLH agreeing better with GPS RO and MERRA-2 than version 6, especially near the equator and low latitudes.

Feng Ding↗

NASA NTRS2010

Abundances of Jupiter's Trace Hydrocarbons from Voyager and Cassini. Data Tables: Cassini CIRS Observations Planetary and Space Science, Forthcoming 2010

The following six tables give the retrieved temperatures and volume mixing ratios of C2H2 and C2H6 and the formal errors on these results from the retrieval, as described in the manuscript. These are in the form of two-dimensional tables, specified on a latitudinal and vertical grid. The first column is the pressure in bar, and the second column gives the altitude in kilometers calculated from hydrostatic equilibrium, and applies to the equatorial profile only. The top row of the table specifies the planetographic latitude.

Cassini CIRS observations↗

NASA NTRS2010

Abundances of Jupiter's Trace Hydrocarbons from Voyager and Cassini. Data Tables: Voyager IRIS Observations Planetary and Space Science, Forthcoming 2010

Voyager↗

NASA NTRS2000

PV Theories For Planetary Atmospheric Circulations

Potential vorticity (or PV) has become an important tool for the diagnosis and modeling of the Earth's atmospheric and oceanic circulations. More recently, the application of PV thinking to numerical simulations and spacecraft observations of other atmospheres, including those of Mars, Venus, and Titan, has encouraged the hope for a unified understanding of planetary circulation regimes encompassing a wide range of rotation, stratification, and forcing parameters. Specifically, the accumulated evidence suggests that zonal-mean winds and temperatures at upper tropospheric levels approximate a state of zero potential vorticity within the bounding latitudes of the westerly jets, while the poleward regions of cyclonic shear conform to a PV state that is well mixed with respect to its polar limit. This review of the prospects for conceptual planetary circulation models will explore the possibility that the zonal-mean state of an atmosphere can be calculated in terms of a simple link between the latitudinal PV and potential temperature variation at an upper baroclinic steering level.

Allison, Michael↗

NASA NTRS2016

Apatite-Melt Partitioning at 1 Bar: An Assessment of Apatite-Melt Exchange Equilibria Resulting from Non-Ideal Mixing of F and Cl in Apatite

The mineral apatite [Ca5(PO4)3(F,Cl,OH)] is present in a wide range of planetary materials. Due to the presence of volatiles within its crystal structure (X-site), many recent studies have attempted to use apatite to constrain the volatile contents of planetary magmas and mantle sources. In order to use the volatile contents of apatite to precisely determine the abundances of volatiles in coexisting silicate melt or fluids, thermodynamic models for the apatite solid solution and for the apatite components in multi-component silicate melts and fluids are required. Although some thermodynamic models for apatite have been developed, they are incomplete. Furthermore, no mixing model is available for all of the apatite components in silicate melts or fluids, especially for F and Cl components. Several experimental studies have investigated the apatite-melt and apatite-fluid partitioning behavior of F, Cl, and OH in terrestrial and planetary systems, which have determined that apatite-melt partitioning of volatiles are best described as exchange equilibria similar to Fe-Mg partitioning between olivine and silicate melt. However, McCubbin et al. recently reported that the exchange coefficients may vary in portions of apatite compositional space where F, Cl, and OH do not mix ideally in apatite. In particular, solution calorimetry data of apatite compositions along the F-Cl join exhibit substantial excess enthalpies of mixing. In the present study, we conducted apatite-melt partitioning experiments in evacuated, sealed silica-glass tubes at approximately 1 bar and 950-1050 degrees Centigrade on a synthetic Martian basalt composition equivalent to the basaltic shergottite Queen Alexandria Range (QUE) 94201. These experiments were conducted dry, at low pressure, to assess the effects of temperature and apatite composition on the partitioning behavior of F and Cl between apatite and basaltic melt along the F-Cl apatite binary join, where there is non-ideal mixing of F and Cl in apatite.

McCubbin, F. M.↗

NASA NTRS1995

The role of small missions in planetary and lunar exploration

The Space Studies Board of the National Research Council charged its Committee on Planetary and Lunar Exploration (COMPLEX) to (1) examine the degree to which small missions, such as those fitting within the constraints of the Discovery program, can achieve priority objectives in the lunar and planetary sciences; (2) determine those characteristics, such as level of risk, flight rate, target mix, university involvement, technology development, management structure and procedures, and so on, that could allow a successful program; (3) assess issues, such as instrument selection, mission operations, data analysis, and data archiving, to ensure the greatest scientific return from a particular mission, given a rapid deployment schedule and a tightly constrained budget; and (4) review past programmatic attempts to establish small planetary science mission lines, including the Planetary Observers and Planetary Explorers, and consider the impact management practices have had on such programs. A series of small missions presents the planetary science community with the opportunity to expand the scope of its activities and to develop the potential and inventiveness of its members in ways not possible within the confines of large, traditional programs. COMPLEX also realized that a program of small planetary missions was, in and of itself, incapable of meeting all of the prime objectives contained in its report 'An Integrated Strategy for the Planetary Sciences: 1995-2010.' Recommendations are provided for the small planetary missions to fulfill their promise.

Source record↗

NASA NTRS2018

Relationships Between the Planetary Boundary Layer Height and Surface Pollutants Derived from Lidar Observations over China: Regional Pattern and Influencing Factors

The frequent occurrence of severe air pollution episodes in China has been a great concern and thus the focus of intensive studies. Planetary boundary layer height (PBLH) is a key factor in the vertical mixing and dilution of near-surface pollutants. However, the relationship between PBLH and surface pollutants, especially particulate matter (PM) concentration across China, is not yet well understood. We investigate this issue at 1600 surface stations using PBLH derived from space-borne and ground-based lidar, and discuss the influence of topography and meteorological variables on the PBLH–PM relationship. Albeit the PBLH–PM correlations are roughly negative for most cases, their magnitude, significance, and even sign vary considerably with location, season, and meteorological conditions. Weak or even uncorrelated PBLH–PM relationships are found over clean regions (e.g., Pearl River Delta), whereas nonlinearly negative responses of PM to PBLH evolution are found over polluted regions (e.g., North China Plain). Relatively strong PBLH–PM interactions are found when the PBLH is shallow and PM concentration is high, which typically corresponds to wintertime cases. Correlations are much weaker over the highlands than the plains regions, which may be associated with lighter pollution loading at higher elevations and contributions from mountain breezes. The influence of horizontal transport on surface PM is considered as well, manifested as a negative correlation between surface PM and wind speed over the whole nation. Strong wind with clean upwind air plays a dominant role in removing pollutants, and leads to obscure PBLH–PM relationships. A ventilation rate is used to jointly consider horizontal and vertical dispersion, which has the largest impact on surface pollutant accumulation over the North China Plain. As such, this study contributes to improved understanding of aerosol–planetary boundary layer (PBL) interactions and thus our ability to forecast surface air pollution.

Su, Tianning↗

NASA NTRS1989

Aerosol backscatter studies supporting LAWS

Optimized Royal Signals and Radar Establishment (RSRE), Laser True Airspeed System (LATAS) algorithm for low backscatter conditions was developed. The algorithm converts backscatter intensity measurements from focused continuous-wave (CW) airborne Doppler lidar into backscatter coefficients. The performance of optimized algorithm under marginal backscatter signal conditions was evaluated. The 10.6 micron CO2 aerosol backscatter climatologies were statistically analyzed. Climatologies reveal clean background aerosol mode near 10(exp -10)/kg/sq m/sr (mixing ratio units) through middle and upper troposhere, convective mode associated with planetary boundary layer convective activity, and stratospheric mode associated with volcanically-generated aerosols. Properties of clean background mode are critical to design and simulation studies of Laser Atmospheric Wind Sounder (LAWS), a MSFC facility Instrument on the Earth Observing System (Eos). Previous intercomparisons suggested correlation between aerosol backscatter at CO2 wavelength and water vapor. Field measurements of backscatter profiles with MSFC ground-based Doppler lidar system (GBDLS) were initiated in late FY-88 to coincide with independent program of local rawinsonde releases and overflights by Multi-spectral Atmospheric Mapping Sensor (MAMS), a multi-channel infrared radiometer capable of measuring horizontal and vertical moisture distributions. Design and performance simulation studies for LAWS would benefit from the existence of a relationship between backscatter and water vapor.

Rothermel, Jeffry↗