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DOE OSTI2025

Biermann-Battery-Driven Magnetized Collisionless Shock Precursors in Laser-Produced Plasmas

This Letter reports the first complete observation of magnetized collisionless shock precursors formed through the compression of Biermann-battery magnetic fields in laser produced plasmas. At OMEGA, lasers produce a supersonic CH plasma flow which is magnetized with Biermann-battery magnetic fields. The plasma flow collides with an unmagnetized hydrogen gas jet plasma to create a magnetized shock precursor. The situation where the flowing plasma carries the magnetic field is similar to the Venusian bow shock. Imaging 2⁢𝜔 Thomson scattering confirms that the interaction is collisionless and shows density and temperature jumps. Proton radiographs have regions of strong deflections and FLASH magnetohydrodynamic (MHD) simulations show the presence of Biermann fields in the Thomson scattering region. Electrons are accelerated to energies of up to 100 keV in a power-law spectrum. Here, OSIRIS particle-in-cell (PIC) simulations, initialized with measured parameters, show the formation of a magnetized shock precursor and corroborate the experimental observables.

High-energy-density plasmas↗

DOE OSTI2024

Development of APCVD BSG and POCl 3 Codiffusion Process for Double-Side TOPCon Solar Cell Precursor Fabrication

This paper presents a commercially viable process for fabricating a high-quality double-side tunnel oxide passivating contact (DS-TOPCon) cell precursor using APCVD-deposited boron silicate glass and ex-situ POCl 3 diffusion in a single high-temperature step, eliminating the need for additional masking and diffusion processes. A two-tier temperature profile was developed, involving a pre-annealing at above 900°C in nitrogen (N2) ambient followed by POCl 3 diffusion at 840°C. We investigated the effect of varying pre-annealing temperatures, ranging from 875°C to 950°C, on the passivation quality and metal-Si contact properties of both n-TOPCon and p-TOPCon layers. The resultant DS-TOPCon cell precursor after silicon nitride (SiNX) passivation exhibited an excellent iV OC of close to 730 mV. In addition, a rapid asymmetric poly-Si thinning technique, developed in this work, enabled adjustment of the front n + poly-Si thickness while maintaining the rear p + poly-Si thickness. Two types of DS-TOPCon cell architectures can be fabricated: i) full-area thin (≈40nm) n-TOPCon layer on the front and ii) selective-area thick (≈200nm) n-TOPCon fingers underneath the metal grid. Device simulations suggest that full-area DS-TOPCon cell with 40 nm n + poly-Si and selective-area DS-TOPCon cell with 200 nm n + poly fingers on the front, fabricated from our current DS-TOPCon cell precursor, can achieve cell efficiencies of 22.1 and 23.5%, respectively. Detailed power loss analysis and device simulation reveal that further improvements in material and device parameters have potential to push the cell efficiencies of DS-TOPCon cell structure beyond 25%, making it a promising alternative to fabricate a high-efficiency next-generation solar cells at low cost.

14 SOLAR ENERGY↗

DOE OSTI2024

Enhanced nucleation mechanism in ruthenium atomic layer deposition: Exploring surface termination and precursor ligand effects with RuCpEt(CO)2

Miniaturization of microelectronic devices necessitates atomic precision in manufacturing techniques, particularly in the deposition of thin films. Atomic layer deposition (ALD) is recognized for its precision in controlling film thickness and composition on intricate three-dimensional structures. This study focuses on the ALD nucleation and growth mechanisms of ruthenium (Ru), a metal that has significant future implications for microelectronics. Despite its advantages, the deposition of a high surface-free energy material like Ru on a low surface-free energy material such as an oxide often faces challenges of large nucleation delays and non-uniform growth. To address these challenges, we explored the effectiveness of organometallic surface pretreatments using trimethylaluminum (TMA) or diethylzinc (DEZ) to enhance Ru film nucleation and growth. Our study employed a less-studied Ru precursor, cyclopentadienylethyl(dicarbonyl)ruthenium [RuCpEt(CO)2], which demonstrated promising results in terms of reduced nucleation delay and increased film continuity. Ru ALD was performed on silicon substrates with native oxide, using RuCpEt(CO)2 and O2 as coreactants. Our findings reveal that surface pretreatment significantly improves nucleation density and film thickness within the initial 60 ALD cycles, achieving up to a 3.2-fold increase in Ru surface coverage compared to nonpretreated substrates. Supported by density functional theory calculations, we propose that the enhanced nucleation observed with RuCpEt(CO)2 compared to previously-studied Ru(Cp)2 is due to two key mechanisms: the facilitated removal of CO ligands during deposition, which enhances the reactivity of the precursor, and a hydrogen-abstraction reaction involving the ethyl ligand of RuCpEt(CO)2 and the metal-alkyl groups on the surface. This study not only advances our understanding of Ru ALD processes but also highlights the significant impact of precursor chemistry and surface treatments in optimizing ALD for advanced microelectronic applications.

Materials Science↗

DOE OSTI2024

Development of Metal Boride/Carbide Precursors for MOCVD Applications

This report describes the proposed efforts for a three-year (CY23-25) program to develop refractory metal boride/carbide precursors for metal-organic chemical vapor deposition (MOCVD) applications. Reported are the CY24 results on the thermal processing of bis-cyclopentadienyl dialkyl and tetra-alkyl precursors to obtain metal carbide products. Precursors evaluated are commercially available. Materials were processed within in a custom-built MOCVD system at 1000 ⁰C, as well as in a hot isostatic press (HIP) at temperatures of 1000 ⁰C or 1650 ⁰C at pressures of 5000 psi. The products were identified as metal carbide, metal oxide, or a mixture of carbide and oxide phases depending on the starting material and process used. Density functional theory calculations were performed to determine the decomposition mechanism and to inform how ligand choice led to the products.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Effect of Mo precursors in Microwave-assisted Methane Dehydroaromatization over Mo/HZSM5 catalysts

Natural gas flaring occurs in remote shale regions due to limited pipeline takeaway capacity. The conversion of the associated natural gas into aromatics in modular microwave reactors is a viable alternative to monetize the wasted gas. Microwaves offer rapid, selective heating in compact reactor systems that can enable on-demand chemical production at the well-site. Mo-HZSM-5 catalysts are widely used for aromatic production, but the location and nature of the active sites are still under debate. This study focuses on the use of 6 different Mo precursors to elucidate insights into the Mo properties that are desirable for BTX production. The catalysts were characterized by different methods (XPS, TPR, Raman, etc) to determine differences in Mo catalytic properties that may affect performance and understand these differences through performance testing under microwave at 700C for methane dehydroaromatization. Metal precursors that enable a better distribution of Mo into the pores and over the surface lead to improved benzene yield, whereas those that limited Mo to primarily the surface suffer rapid deactivation and low benzene yields. Additionally, strong Lewis acidity that arises from the sodium containing precursor drastically shifts the product selectivity towards dehydrogenation, which produces more ethylene and carbon. This catalyst had the highest deactivation constant of all catalysts tested.

gas flaring reduction↗

DOE OSTI2025

Magnetosphere Evolution and Precursor-driven Electromagnetic Signals in Merging Binary Neutron Stars

We detail new force-free simulations to investigate magnetosphere evolution and precursor electromagnetic (EM) signals from binary neutron stars. Our simulations fully follow a representative inspiral motion, capturing the intricate magnetospheric dynamics and their impact on EM outflows. We explore a range of stellar magnetic moment orientations and relative strengths, finding that the magnetospheres and Poynting flux evolution are strongly configuration dependent. The Poynting flux exhibits pulsations at twice the orbital frequency, 2Ω, and is highly anisotropic, following a power-law dependence on orbital frequency. The index ranges from 1 to 6, shaped by the intricate dynamics of the magnetospheres. Furthermore, we present the first computation of (1) the EM forces acting on the star surfaces, revealing the presence of torques that, for highly magnetized stars, could influence the orbital dynamics or break the crust; (2) the high-energy emission signals from these systems by adopting the established isolated pulsar theory. Assuming curvature radiation in the radiation-reaction limit, we find that photons could reach TeV–PeV energies in the last ∼ms for magnetic field strengths 10 10 –10 15 G. However, our analysis of single photon magnetic pair production suggests that these photons are unlikely to escape, with the MeV band emerging as a promising observational window for precursor high-energy emission. In this framework, we construct high-energy emission skymaps and light curves, exploring observational implications. Finally, we propose potential precursor radio emission and delayed afterglow echoes from magnetized outflows, which may contribute to late-time rebrightening in short gamma-ray bursts or to orphan afterglows.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2024

The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition

Abstract. In this study, we present and analyze the first continuous time series of relevant aerosol precursor vapors from the central Arctic (north of 80° N) during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. These precursor vapors include sulfuric acid (SA), methanesulfonic acid (MSA), and iodic acid (IA). We use FLEXPART simulations, inverse modeling, sulfur dioxide (SO2) mixing ratios, and chlorophyll a (chl a) observations to interpret the seasonal variability in the vapor concentrations and identify dominant sources. Our results show that both natural and anthropogenic sources are relevant for the concentrations of SA in the Arctic, but anthropogenic sources associated with Arctic haze are the most prevalent. MSA concentrations are an order of magnitude higher during polar day than during polar night due to seasonal changes in biological activity. Peak MSA concentrations were observed in May, which corresponds with the timing of the annual peak in chl a concentrations north of 75° N. IA concentrations exhibit two distinct peaks during the year, namely a dominant peak in spring and a secondary peak in autumn, suggesting that seasonal IA concentrations depend on both solar radiation and sea ice conditions. In general, the seasonal cycles of SA, MSA, and IA in the central Arctic Ocean are related to sea ice conditions, and we expect that changes in the Arctic environment will affect the concentrations of these vapors in the future. The magnitude of these changes and the subsequent influence on aerosol processes remains uncertain, highlighting the need for continued observations of these precursor vapors in the Arctic.

Boyer, Matthew↗

NASA NTRS1972

Amino acid precursors in lunar samples.

The use of hot water to extract lunar samples, followed by the hydrolysis of the aqueous extract, appears to be the method of choice for identification and quantitation of amino acid precursors in extraterrestrial sources. The net inferences from the analyses to date are (1) that amino acid precursors are verifiably present in lunar dust, and (2) that they are quite certainly not the consequence of contamination by terrestrial organisms, including man. It is suggested that prebiotic evolutionary pathways such as have been traversed on the earth were terminated on the moon for lack of sufficient water. Although some or all of the amino acid precursors may be indigenous, the low level observed suggests that they may also result from onfall of organic compounds from interstellar matter, comets, tails, solar wind, or meteorites.

Fox, S. W.↗

NASA NTRS1976

Nozzle designs with pitch precursor ablatives

Recent developments in carbon phenolic ablatives for solid rocket motor nozzles have yielded a pitch precursor carbon fiber offering significant raw material availability and cost saving advantages as compared to conventional rayon precursor material. This paper discusses the results of an experimental program conducted to assess the thermal performance and characterize the thermal properties of pitch precursor carbon phenolic ablatives. The end result of this program is the complete thermal characterization of pitch fabric, pitch mat, hybrid pitch/rayon fabric and pitch mat molding compound. With these properties determined an analytic capability now exists for predicting the thermal performance of these materials in rocket nozzle liner applications. Further planned efforts to verify material performance and analytical prediction procedures through actual rocket motor firings are also discussed.

Blevins, H. R.↗

NASA NTRS1977

Radiation induced precursor flow field ahead of a Jovian entry body

The change in flow properties ahead of the bow shock of a Jovian entry body, resulting from absorption of radiation from the shock layer, is investigated. Ultraviolet radiation is absorbed by the free stream gases, causing dissociation, ionization, and an increase in enthalpy of flow ahead of the shock wave. As a result of increased fluid enthalpy, the entire flow field in the precursor region is perturbed. The variation in flow properties is determined by employing the small perturbation technique of classical aerodynamics as well as the thin layer approximation for the preheating zone. By employing physically realistic models for radiative transfer, solutions are obtained for velocity, pressure, density, temperature, and enthalpy variations. The results indicate that the precursor effects, in general, are greater for lower altitudes and higher entry velocities. At higher altitudes precursor effects are felt farther in the free-stream. Just ahead of the shock the effects are larger at lower altitudes.

Tiwari, S. N.↗

NASA NTRS1978

Influence of precursor heating on viscous flow around a Jovian entry body

The influence of changes in precursor region flow properties (resulting from the absorption of radiation from the shock layer) on the entire shock layer flow phenomena is investigated. Axially symmetric case is considered for both the preheating zone (precursor region) and shock layer. The flow in the shock layer is considered to be viscous with chemical equilibrium but radiative nonequilibrium. Realistic thermo-physical and spectral models are employed and results are obtained by implicit finite difference and iterative procedures. The results indicate that precursor heating increases the radiative heating of the body by a maximum of 7.5% for a 116 KM entry conditions.

Tiwari, S. N.↗

NASA NTRS1978

SAS 3 observations of two X-ray transient events with precursors

SAS 3 has observed two unusual fast transient X-ray events from different sources, one lasting about 150 s and one, approximately 1500 s. Both events were preceded by precursor pulses which lasted a few seconds and which rose and fell in less than 0.4 s. The precursors were separated from the 'main' events by several seconds, during which no X-rays were detected. There are similarities between the two main events and X-ray bursts in both their temporal and spectral evolution. The spectra of the main events started out much softer than the spectra of the precursors, became harder as they approached maximum intensity, and softened as they decayed. In the 1500-s event, X-rays with energies greater than 10 keV were delayed by about 80 s compared with 1.5-6-keV X-rays. A blackbody fit to the spectral data of the main event of approximately 1500-s duration gives a maximum temperature of 29 million K and a radius for the emitting region of at least about 9 km (at a distance of 10 kpc); this is similar to the temperature and sizes found for several X-ray burst sources.

Hoffman, J. A.↗

NASA NTRS1979

Effects of precursor heating on radiative and chemically reacting viscous flow around a Jovian entry body

The influence of change in the precursor region flow properties on the entire shock layer flow phenomena around a Jovian entry body was investigated. The flow in the shock layer was assumed to be steady, axisymmetric, and viscous. Both the chemical equilibrium and the nonequilibrium composition of the shock layer gas were considered. The effects of transitional range behavior were included in the analysis of high altitude entry conditions. Realistic thermophysical and radiation models were used, and results were obtained by employing the implicit finite difference technique in the shock layer and an iterative procedure for the entire shock layer precursor zone. Results obtained for a 45 degree angle hyperboloid blunt body entering Jupiter's atmosphere at zero angle of attack indicates that preheating the gas significantly increases the static pressure and temperature ahead of the shock for entry velocities exceeding 36 km/sec. The nonequilibrium radiative heating rate to the body is found to be significantly higher than the corresponding equilibrium heating. The precursor heating generally increases the radiative and convective heating of a body. That increase is slightly higher for the nonequilibrium conditions.

Tiwari, S. N.↗

NASA NTRS1979

Influence of precursor heating on viscous flow around a Jovian entry body

The influence of changes in precursor region flow properties (resulting from the absorption of radiation from the shock layer) on the entire shock layer flow phenomena was investigated. The axially symmetric case is considered for both the preheating zone (precursor region) and shock layer. The flow in the shock layer is assumed to be viscous with chemical equilibrium but radiative nonequilibrium. Realistic thermophysical and spectral models are employed, and results are obtained by implicit finite difference and iterative procedures. The results indicate that precursor heating increases the radiative heating of the body by a maximum of 7.5 percent for 116 km entry conditions.

Tiwari, S. N.↗

NASA NTRS1983

Oxidation and formation of deposit precursors in hydrocarbon fuels

The oxidation of two jet turbine fuels and some pure hydrocarbons was studied at 130 C with and without the presence of small amounts of N-methyl pyrrole (NMP) or indene. Tendency to form solid-deposit precursors was studied by measuring soluble gum formation as well as dimer and trimer formation using field ionization mass spectrometry. Pure n-dodecane oxidized fastest and gave the smallest amount of procursors. An unstable fuel oil oxidized much slower but formed large amounts of precursors. Stable Jet A fuel oxidized slowest and gave little precursors. Indene either retarded or accelerated the oxidation of n-dodecane, depending on its concentration, but always caused more gum formation. The NMP greatly retarded n-dodecane oxidation but accelerated Jet A oxidation and greatly increased the latter's gum formation. In general, the additive reacted faster and formed most of the gum. Results are interpreted in terms of classical cooxidation theory. The effect of oxygen pressure on gum formation is also reported.

Mayo, F. R.↗

NASA NTRS1985

Preparation of silicon carbide-silicon nitride fibers by the pyrolysis of polycarbosilazane precursors

The development of silicon carbide-silicon nitride fibers (SiC-Si3N4) by the pyrolysis of polycarbosilazane precursors is reviewed. Precursor resin, which was prepared by heating tris(N-methylamino)methylsilane or tris(N-methylamino)phenylsilane to about 520 C, was drawn into fibers from the melt and then made unmeltable by humidity conditioning at 100 C and 95 percent relative humidity. The humidity treated precursor fibers were pyrolyzed to ceramic fibers with good mechanical properties and electrical resistivity. For example, SiC-Si3N4 fibers derived from tris(N-methylamino)methylsilane had a tensile rupture modulus of 29 million psi and electrical resistivity of 6.9 x ten to the 8th power omega-cm, which is ten to the twelfth power times greater than that obtained for graphite fibers.

Penn, B. G.↗

NASA NTRS1986

Lunar granulites and their precursor anorthositic norites of the early lunar crust

Lunar granulities, which are ancient and KREEP-free, represent the best samples of early lunar crust. They can be divided into ferroan and magnesium groups, and each group can be subdivided on the basis of mineral composition and REE concentrations. It is shown that some of the granulites may be derived from distinct anorthitic norite precursors, while some others are clearly polymict, though it is believed that even these granulites had anorthositic norites as their dominant precursors. The granulites have compositions similar to those of the two lunar meteorites, one of which is ferroan, the other magnesian. These meteorites are soil breccias from an unknown location distant from the Apollo landing sites and contain anorthositic norites as abundant clasts. Granulite and lunar-meteorite compositions more closely resemble the average composition of lunar highlands than those of any other returned lunar samples. The predominance of plutonic anorthositic norite precursors in material having the composition typical of highlands suggests that plutonic anorthositic norites were more abundant in the early lunar crust than is implied by their scarcity in Apollo pristine rocks.

Lindstrom, M. M.↗

NASA NTRS1986

Preparation of silicon carbide-silicon nitride fibers by the pyrolysis of polycarbosilazane precursors - A review

Penn, B. G.↗