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DOE OSTI2015

Light Water Reactor Sustainability Accomplishments Report

Welcome to the 2014 Light Water Reactor Sustainability (LWRS) Program Accomplishments Report, covering research and development highlights from 2014. The LWRS Program is a U.S. Department of Energy research and development program to inform and support the long-term operation of our nation’s commercial nuclear power plants. The research uses the unique facilities and capabilities at the Department of Energy national laboratories in collaboration with industry, academia, and international partners. Extending the operating lifetimes of current plants is essential to supporting our nation’s base load energy infrastructure, as well as reaching the Administration’s goal of reducing greenhouse gas emissions to 80% below 1990 levels by the year 2050. The purpose of the LWRS Program is to provide technical results for plant owners to make informed decisions on long-term operation and subsequent license renewal, reducing the uncertainty, and therefore the risk, associated with those decisions. In January 2013, 104 nuclear power plants operated in 31 states. However, since then, five plants have been shut down (several due to economic reasons), with additional shutdowns under consideration. The LWRS Program aims to minimize the number of plants that are shut down, with R&D that supports long-term operation both directly (via data that is needed for subsequent license renewal), as well indirectly (with models and technology that provide economic benefits). The LWRS Program continues to work closely with the Electric Power Research Institute (EPRI) to ensure that the body of information needed to support SLR decisions and actions is available in a timely manner. This report covers selected highlights from the three research pathways in the LWRS Program: Materials Aging and Degradation, Risk-Informed Safety Margin Characterization, and Advanced Instrumentation, Information, and Control Systems Technologies, as well as a look-ahead at planned activities for 2015. If you have any questions about the information in the report, or about the LWRS Program, please contact me, Richard A. Reister (the Federal Program Manager), or the respective research pathway leader (noted on pages 26 and 27), or visit the LWRS Program website (www.inl.gov/lwrs). The annually updated Integrated Program Plan and Pathway Technical Program Plans are also available for those seeking more detailed technical Information.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2017

Final Report for the Contractor Readiness Assessment of the Transient Reactor Test Facility Resumption of Transient Testing Activity at the Idaho National Laboratory

The purpose of this review was to verify readiness for the TREAT restart of transient testing activity at the INL and inform the startup authorization authority decision-making for startup authorization by providing a deliberate and managed determination of the state of readiness preparation and determination of whether operations can be performed safely. Verification of readiness included assuring that equipment operability, procedure viability, and personnel knowledge, skills, and performance are adequate for operations. Because the TREAT (including restart of transient testing activity) is a hazard category-2 nuclear facility and because reactor operation and transient testing activities were suspended for programmatic and funding reasons in excess of a year, DOE O 425.1D required that both a contractor and DOE RA be satisfactorily completed prior to startup of the TREAT and restart of transient testing activity. To this end, DOE directed that a CRA and federal RA be conducted. The CRA IP defined the depth of the CRA through the objectives and CRADs, delineated in Appendix A of the IP; established roles and responsibilities for CRA team activities; and established processes, practices, and protocols for preparation, conduct, documentation, and reporting of the CRA. The approaches and methodologies identified in the IP were used to verify that the BEA management team has established SSCs, developed personnel capabilities and competencies, and implemented safety features, programs, and procedures in a manner that provides reasonable assurance for adequate protection of workers, the public, and the environment in preparation for and execution of the TREAT restart of transient testing activity. This CRA was intended to confirm that (1) the facility is in a state of readiness to safely conduct operations in accordance with the safety basis; and (2) the management control programs are in place to ensure safe operations can be sustained. This equated to mature implementation of the integrated safety management (ISM) in conjunction with implementation of the individual facility authorization basis. This CRA was structured to verify the readiness to conduct restart of transient testing activity safely, and that facility programs were in place to support the restart of transient testing activity.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2013

High-Resolution Hypernuclear Spectroscopy at JLab Hall A. Results and perspectives

Hypernuclear spectroscopy via electromagnetic induced reactions is a valuable and powerful way to study hypernuclei, hadronic systems with non-zero strangeness content, providing an alternative to the hadron induced reactions mainly studied so far. Electron-induced hypernuclear spectroscopy has been studied in Hall A at Je!erson Lab [1] on three nuclei, 12C, 16O, and 9Be with unprecedented resolution and with an improved particle identification system, using a RICH detector, in order to unambiguously identify kaons, thus allowing the measurement of high-quality, almost backgroundfree, hypernuclear spectra. Two superconducting septum magnets were added to the existing apparatus in order to permit particle detection at very forward angle providing a reasonable counting rate. These studies have provided the first quantitative information on core-excited states in hypernuclei. In the case of oxygen, a waterfall target has been employed allowing for the simultaneous measurement of hypernuclear production on oxygen and of elementary kaon-? electro-production on protons: a crucial measurement to disentangle the contribution of the elementary reaction from the measured hypernuclear production cross section, yielding direct access to the nucleus-hypernucleus transition structure. A ? binding energy value for 16 ?N calibrated against the elementary (e, e?K+) reaction on hydrogen, has been obtained. Final results for 12C, 16O, 9Be will be presented [1-3]. Results of Hall C experiments will be presented in another talk in this Conference. Since it is essential for further theoretical study of hypernuclei to collect enough information about L production on nucleons and about excitation spectra of a wide variety of ? hypernuclei, a continuation of the successful hypernuclear program at JLab is very desirable. For these reasons Hall A and Hall C Jefferson Lab hypernuclear collaborations decided to merge and propose a new layout for the 12 GeV Jefferson Lab era that has the advantages of both the experimental setups. In fact the new experimental design not only widens and deepens the physics range but also dramatically improves production yield and efficiency allowing to study both mass spectroscopy on a wide range of nuclei (from few body to 208Pb) and pion decay spectroscopy at the same time [4]. Figs.1, 2 show the results obtained for 12C and 16O. Fig. 3 shows the new layout.

Garibaldi, Franco↗
DOE OSTI2015

Re-Defining Photovoltaic Efficiency Through Molecule Scale Control. Final Report

The direct conversion of sunlight into electricity represents one of the most important general means for sustainable energy production. Most modern photovoltaic cells are based on some form of semiconductor material such as silicon that is described by a characteristic energy or ''bandgap''. For solar rays with photon energy lower than the bandgap no absorption occurs and thus no energy is generated. For solar rays with photon energy greater than the bandgap, light may be absorbed to create a pair of electrical charges but only one bandgap of energy is created, leaving any additional energy lost as heat. Thus low bandgap materials can use a great part of the spectrum but can lose much of that energy; high bandgap materials fail to capture much of the spectrum. Thus there is a limit to the efficiency of such a solar cell that turns out to be about 32%. This limit is known as the Shockely-Queisser Limit. The Columbia EFRC program is dedicated to exploration of concepts that in principle can provide for efficiencies beyond this limit. One concept that this EFRC has explored for enhancing the efficiency of solar photovoltaic cells is called “Singlet Fission.” In this concept the absorption of light rays with photon energy at least twice the value of the basic bandgap for the system can produce two pairs of electrical charge carriers. If properly implemented this in principle can significantly reduce the energy lost as heat and give rise to solar cell efficiencies greater than the Shockley-Queisser limit. The problem is that there are virtually no materials that can undergo this process effectively. We have developed new materials that have demonstrated singlet fission efficiencies of almost 100%. We understand how these materials work and we have learned how to design many more systems in the future. So far we have only demonstrated the basic capability for efficient singlet fission. Much more work will be required to design and engineer specific materials that can be used practically in a solar cell system. In addition much work will be required to envision and demonstrate effective device structures that can utilize this concept. However these discoveries do provide the basis for an entirely new set of opportunities for more efficient solar energy generation moving beyond the Shockley-Queisser limit. A second part of the EFRC research program has been to investigate the material and device properties of an entirely new set of materials based on two-dimensional sheets (“ultra-thin”) with thicknesses of only one atom, or a single molecule or just a few atoms. These materials can exhibit conducting, insulating, and semiconducting character and thus they can form the basis for entirely new types of electrical devices. Recent fundamental investigations of these materials, at Columbia and elsewhere, demonstrate clearly that the flow of electrical charges in these systems is fundamentally different from the nature of electrical current flow in conventional materials. This fact presents many possibilities for new photovoltaic device concepts. The EFRC research team has achieved world leadership in the creation and understanding of these materials and in developing the fabrication techniques necessary to create useful devices from them. We have developed the basic fabrication methodology to build structures of these materials into complex device structures, layer by layer. Our EFRC research team has pioneered the synthesis and understanding for graphene, perhaps the simplest of these materials. Graphene can function as a highly transparent conducting material, capable of funneling an electrical charge over reasonable distances without significant energy loss. The EFRC program has also pioneered the development of ultra-thin sheets that function in a way analogous to semiconductor materials as well as sheets that act as electrical insulators. These developments therefore enable the construction of solar cells based on totally different physics from conventional cells. Because the electrons in these ultra-thin sheets interact strongly they will exhibit behaviors quite different from conventional materials with potential to operate at efficiencies beyond the Shockley-Queisser limit. In our EFRC program we have laid out many of the fundamental properties of these materials including the development of unique fabrication techniques. We discovered several new effects that demonstrate strong electron coupling. We have demonstrated the first solar cell that can actually generate electrical power at a high basic efficiency from these fundamentally new materials. There is much more science and technology required before these devices can become practical, but there is also very strong activity worldwide to build electronic devices from these materials, thus providing infrastructure and technical capability to develop these concepts.

14 SOLAR ENERGY↗
DOE OSTI2016

Polarized Substructural Session Types

Concurrent processes can be extremely difficult to reason about, both for programmers and formally. One approach to coping with this difficulty is to study new programming languages and type features such as Session Types. Session types take as their conceptual notion of concurrency as a collection of processes linked together via channels and provide type-level coordination between processes using these channels. Logically motivated programming languages exploit the idea that providing a proof of a theorem in a logic is similar to proving that a given term has a particular type in a programming language and vice versa. These connections can be interesting for a few different reasons. First, when language and logic are independently discovered and independently useful, the existence of a connection suggests that both are onto some fundamentally important idea. Additionally, a connection provides a basis both for sanity checking our ideas and also can be fruitful grounds for inspiration by seeing how variants of either the logic or the language are reflected through the connection. This thesis primarily describes an exploration of logically motivated session types, SILL. Polarization, classifying propositions as either positive or negative, provides a natural way to describe a logically based session typing language with asynchronous communication while retaining a semantics that is reasonably implementable. Additionally, polarization gives us a way to smoothly integrate synchronous channels into SILL without needing a semantic extension. When combined with Adjoint Logic, this gives us an ability to incorporate a variety of modalities with relatively little work. From a practical perspective, this gives SILL access to persistent processes and garbage collection. We additionally explore a trio of loosely related extensions to SILL, and their logical connections, inspired by the above results: bundled message passing to reduce the number of communications performed by processes; racy programs, enabled by a select/epoll-like mechanism; and asynchronous receiving, an almost generalization of the basic asynchronous semantics. We have three different implementations of SILL: a simple but relatively full featured interpreter written in OCaml; a fragment of SILL as an embedded domain specific language in Haskell; and a cleaner version of the same in Idris. Lastly, we show that Liquid Types and Session Types are compatible. This gives us one notion of a dependently session typed language.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2015

Energy Savings from Industrial Water Reductions

Although it is widely recognized that reducing freshwater consumption is of critical importance, generating interest in industrial water reduction programs can be hindered for a variety of reasons. These include the low cost of water, greater focus on water use in other sectors such as the agriculture and residential sectors, high levels of unbilled and/or unregulated self-supplied water use in industry, and lack of water metering and tracking capabilities at industrial facilities. However, there are many additional components to the resource savings associated with reducing site water use beyond the water savings alone, such as reductions in energy consumption, greenhouse gas emissions, treatment chemicals, and impact on the local watershed. Understanding and quantifying these additional resource savings can expand the community of businesses, NGOs, government agencies, and researchers with a vested interest in water reduction. This paper will develop a methodology for evaluating the embedded energy consumption associated with water use at an industrial facility. The methodology developed will use available data and references to evaluate the energy consumption associated with water supply and wastewater treatment outside of a facility’s fence line for various water sources. It will also include a framework for evaluating the energy consumption associated with water use within a facility’s fence line. The methodology will develop a more complete picture of the total resource savings associated with water reduction efforts and allow industrial water reduction programs to assess the energy and CO2 savings associated with their efforts.

Rao, Prakash↗
DOE OSTI2022

Multi-technology building system retrofits for utility incentive programs: Savings, costs and baseline considerations

Utility incentive programs are an important channel to support the deployment of energy efficiency in buildings. To date, these programs have largely been limited to single-component strategies. However, many utilities are now motivated to identify and develop multi-component system retrofits to achieve deeper energy savings, which are essential to achieving broader energy and greenhouse gas reduction goals in the buildings sector. In this paper we present the energy savings, demand reductions, and cost-effectiveness of 16 systems retrofit packages in six utility regions in the United States. These results are being used by these utilities to inform and develop incentive programs for systems retrofits. Our analysis shows that packages with proven lighting and HVAC measures can provide 5–22% whole building annual energy savings, and 13–22% annual energy costs savings, using utility incentive program baselines (code and existing building). The packages are reasonably cost effective for replace-on-burnout but generally not for a retrofit scenario prior to end of equipment life. Demand response can increase both the energy savings and energy cost savings, further improving the cost effectiveness of these packages. We analyzed the impact of using existing building vs. code baselines for calculating savings, showing that the choice of baseline in developing utility incentive programs has a substantial impact on the attributable energy savings to a program, with significant implications for the overall viability of a program (generally savings against existing building condition are higher and improve project and program cost-effectiveness).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Analysis of US Industrial Assessment Centers (IACs) implementation

Industrial energy assessments are a fundamental action toward developing a decarbonization strategy at any level. They provide an understanding of where energy efficiency opportunities exist and help to make informed business decisions about the costs and benefits of implementing sustainable policies and practices. This paper examines the effectiveness of the Department of Energy's Industrial Assessment Centers Program at providing useful energy-efficiency audits as well as the barriers faced by the program and plans for future growth and improvement. This paper presents an analysis of the program between 1981 and 2022, covering 20,290 industrial assessments and 151,198 recommendations, with $2.6 billion of recommended savings. The analysis includes a breakdown of the IAC recommendations and implemented projects based on both the industrial subsectors according to the Standard Industrial Classification code, energy type, and systems evaluated. The results include a 47 % implementation rate, a gap analysis to understand the missed opportunities, and a discussion about reasons for recommendation rejection. A comparison of the IAC Program with other country-level energy auditing or assessment programs was conducted, and suggestions for improving implementation rates were mentioned.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Color Maintenance of LEDs in Laboratory and Field Applications

Synopsis: To date, consideration for parametric failure of LED products has largely been focused on lumen maintenance. However, color shift is a cause of early failure for some products, and is especially important to consider in certain applications, like museums, where visual appearance is critical. Example data collected by the GATEWAY program for LED lamps installed in museums shows that many have changed color beyond a reasonable tolerance well before their rated lifetime was reached, necessitating replacement. Similar data collected by the CALiPER program between 2008 and 2010 reveals that many early products shifted beyond acceptable tolerances in as little as a few thousand hours. In contrast, data from the L Prize program illustrates that commercially available LED products can have exemplary color stability that is unmatched by traditional light sources. Beyond presenting data from the aforementioned DOE programs, this report discusses the metrics used for communicating color shift—namely MacAdam ellipses and Δu'v'—as well as providing guidance for end users on how to monitor color shift and what to look for in manufacturer warranties. Also included are descriptions of the physical changes that have been documented as leading to color shift in some example types of LED packages. As with complete products, the data presented herein for LED packages shows that a wide variety of products are available; in order for specifiers and consumers to make educated choices, more detailed and standardized information should be made available.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Color Maintenance of LEDs in Laboratory and Field Applications

To date, consideration for parametric failure of LED products has largely been focused on lumen maintenance. However, color shift is a cause of early failure for some products, and is especially important to consider in certain applications, such as museum lighting, where visual appearance is critical. Field data collected by the U.S. Department of Energy's (DOE) GATEWAY program for LED lamps installed in museums shows that many have changed color beyond a reasonable tolerance well before their rated lifetimes have been reached. Laboratory data collected by DOE's CALiPER program between 2008 and 2010 reveals that many early LED products shifted beyond acceptable tolerances in as little as a few thousand hours. In contrast, data from the L Prize® program illustrates that commercially available LED products can have exemplary color stability that is unmatched by traditional light sources. In addition to presenting data from the aforementioned DOE programs, this report discusses the metrics used for communicating color shift, and provides guidance for end users on how to monitor chromaticity and what to look for in manufacturer warranties. Also covered are the physical changes that have been shown to lead to color shift in some types of LED packages. As with lamps and luminaires, the data presented for LED packages shows that a wide variety of products are available; in order for specifiers and consumers to make educated choices, more detailed and standardized information is necessary.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Memory operation mechanism of fullerene-containing polymer memory

The memory operation mechanism in fullerene-containing nanocomposite gate insulators was investigated while varying the kind of fullerene in a polymer gate insulator. It was cleared what kind of traps and which positions in the nanocomposite the injected electrons or holes are stored in. The reason for the difference in the easiness of programming was clarified taking the role of the charging energy of an injected electron into account. The dependence of the carrier dynamics on the kind of fullerene molecule was investigated. A nonuniform distribution of injected carriers occurred after application of a large magnitude programming voltage due to the width distribution of the polystyrene barrier between adjacent fullerene molecules. Through the investigations, we demonstrated a nanocomposite gate with fullerene molecules having excellent retention characteristics and a programming capability. This will lead to the realization of practical organic memories with fullerene-containing polymer nanocomposites.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Topology optimization of 3D photonic crystals with complete bandgaps

The design of photonic crystals with complete bandgaps has recently received considerable research focus for numerous reasons. This work leverages well-known nonlinear programming techniques to alleviate the non-smoothness caused by degenerate eigenvalues such that topology optimization problems can be solved with the open-source IPOPT software. A fully-vectorial plane wave expansion technique is used with an iterative eigensolver to efficiently predict dispersion properties of candidate structures. Nonlinear programming is employed to solve the inverse problem of designing three-dimensional periodic structures that exhibit complete two-dimensional (2D) and three-dimensional (3D) photonic bandgaps. Mesh refinement is performed to alleviate the large computational burden of designing and analyzing photonic crystals, and a periodic density filter is implemented to impose a minimum feature size for manufacturability considerations.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Connecting Minds: AI Use Cases to Bridge Power Systems and Large Language Models for Practical Applications

Recent advances in artificial intelligence (AI) and development of large language models (LLMs) present the opportunity to develop a new generation of power systems applications. In contrast with early power system AI applications based on structured numerical data, LLMs offer unique capabilities to perform logical reasoning using text documents, unstructured data, and application programming interface (API) calls to computational software. This paper seeks to bridge the knowledge gap between power systems engineers and LLM developers through a crosscutting explanation of use cases, characteristics, requirements, practical considerations from the perspectives of both LLM capabilities and industry needs. Specific focus is given to applications that can be realistically deployed by electric utilities. After introducing the architecture of LLMs and unique challenges of the power systems domain, this paper proposes twenty representative LLM applications grouped into categories of 1) power system operations, 2) asset management, 3) system planning and analytics, and 4) energy management and protection systems. Five use cases are presented within each category with descriptions of the motivation, objectives, approaches, example inputs / outputs, and benefits of each use case.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2017

The Difficulty of Defining the Terms Credible and Unlikely for Nuclear Criticality Safety Purposes

During the last revision of the ANSI/ANS-8.1-2014, extensive efforts were made by the working group (ANS-8.1) to ensure the statements in the standard clearly reflected their intent This effort involved the review of each requirement and recommendation in the standard. In some cases, definitions were added to the standard glossary to minimize ambiguity in the standard (e.g., “process conditions” or “parameter”). The working group also considered adding definitions for the words “credible” and “unlikely” because definitions had been provided to the nuclear criticality safety (NCS) community from the US Department of Energy that caused confusion at some sites. A Nuclear Regulatory Commission document intends for licensees to provide appropriate definitions for these words in their site license. The purpose of this paper is to discuss why the working group ultimately decided not to include definitions for credible and unlikely in the 2014 revision of ANS-8.1

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗
DOE OSTI2017

AGR Equipment and Materials Disposition

Fabrication of low-enriched experimental nuclear reactor fuel for the Advanced Gas Reactor (AGR) Fuel Development and Qualification program has concluded after several years of effort. Residual chemicals, uranium compounds, fuel intermediates and fuel compacts need to be dispositioned in an economically and environmentally sound manner that maximizes, within reason, the preservation and repurposing of valuable materials. Government Furnished Equipment (GFE), procured with AGR program funds, are also to be dispositioned as economically as reasonably possible while seeking to maintain the functionality of BWXT equipment and repurposing of stand-alone GFE. Any stand-alone equipment that cannot be repurposed will either be abandoned in place, with BWXT consent, or discarded to an appropriate waste repository.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

AGR Equipment and Materials Disposition

Fabrication of low-enriched experimental nuclear reactor fuel for the Advanced Gas Reactor (AGR) Fuel Development and Qualification program has concluded after several years of effort. Residual chemicals, uranium compounds, fuel intermediates and fuel compacts need to be dispositioned in an economically and environmentally sound manner that maximizes, within reason, the preservation and repurposing of valuable materials. Government Furnished Equipment (GFE), procured with AGR program funds, are also to be dispositioned as economically as reasonably possible while seeking to maintain the functionality of BWX Technologies, Inc. (BWXT) equipment and repurposing of stand-alone GFE. Any stand-alone equipment that cannot be repurposed will either be abandoned in place, with BWXT consent, or discarded to an appropriate waste repository. Representatives for the United States Department of Energy may intervene in intended disposition of specific equipment or materials. Revision 3 on document

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

AGR Equipment and Materials Disposition

Fabrication of low-enriched experimental nuclear reactor fuel for the Advanced Gas Reactor (AGR) Fuel Development and Qualification program has concluded after several years of effort. Residual chemicals, uranium compounds, fuel intermediates and fuel compacts need to be dispositioned in an economically and environmentally sound manner that maximizes, within reason, the preservation and repurposing of valuable materials. Government Furnished Equipment (GFE), procured with AGR program funds, are also to be dispositioned as economically as reasonably possible while seeking to maintain the functionality of BWX Technologies, Inc. (BWXT) equipment and repurposing of stand-alone GFE. Any stand-alone equipment that cannot be repurposed will either be abandoned in place, with BWXT consent, or discarded to an appropriate waste repository. Representatives for the United States Department of Energy may intervene in intended disposition of specific equipment or materials.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

CRADA FINAL REPORT FOR CRADA NO. CR-08-001 CEMENTITIOUS BARRIERS PARTNERSHIPS

The Cementitious Barriers Partnership (CBP), led by the Savannah River National Laboratory, has achieved its ultimate purpose to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex. The CBP achieved its goal by developing experimental programs with results that supported the development of a reasonable and credible set of software tools to improve understanding and prediction of the structural, hydraulic and chemical performance of cementitious barriers and waste forms used in nuclear applications. These experimental data and software tools are and will continue to reduce the uncertainties in the current methodologies for assessing cementitious barrier performance and increase the consistency and transparency of the assessment process. The CBP has made a significant impact in reducing risk and uncertainties in the performance assessments that directly impact U.S. Department of Energy (DOE) environmental cleanup and closure programs. The CBP has developed an experimentally-based, integrated modeling tool that serves as a screening tool known as the CBP Software Toolbox, Version 3.0. The CBP products reduce the uncertainties of current methodologies for assessing cementitious barrier performance and increasing the consistency and transparency of the DOE assessment process. This CBP Software Toolbox predicts the hydraulic properties and chemical stability of cement matrix phases and release fluxes of constituents, in response to variable boundary conditions. Therefore, the CBP tools are reducing the uncertainty by coupling multiscale and multi-physics processes, including physical-chemical evolution and transport phenomena applied to heterogeneous materials with changing boundary conditions. In addition, the CBP Experimental and Characterization Program has provided test data to support chemical and physical degradation mechanisms for cementitious barriers. These tools have application to low activity waste forms, high level waste tank closure, D&D and entombment of major nuclear facilities, landfill waste acceptance criteria, and in-situ grouting and immobilization of vadose zone contamination. The CBP also provided: 1) a forum for DOE-NRC technical exchange, 2) material characterization to support performance assessment (PA) predictions, 3) uncertainty reduction in PA predictions, 4) base case performance to improve PA predictions, and 5) improvement in understanding and quantification of moisture and contaminant transport used in PAs. Additional CBP accomplishments include: sponsorship of a national test bed workshop to obtain collaboration in establishing the path forward to obtain actual data supporting future predictions of cementitious barrier performance, and participation in an International Atomic Energy Agency (IAEA) Cooperative Research Project on the use of cementitious barriers for low-level radioactive waste treatment and disposal.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗