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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Enhanced Transport of TiO 2 in Unsaturated Sand and Soil after Release from Biodegradable Plastic during Composting

Biodegradable plastics can reach full degradation when disposed of appropriately and thus alleviate plastic pollution caused by conventional plastics. But additives can be released into the environment during degradation, and the fate of these additives can be affected by the degradation process. In this study, we characterized TiO 2 particles released from a biodegradable plastic mulch during composting and studied the transport of the released TiO 2 particles in inert sand and agricultural soil columns under unsaturated flow conditions. TiO 2 microparticles were released from the biodegradable plastic mulch in both single particle and cluster forms. The released TiO 2 microparticles were fully retained in unsaturated soil columns due to its ne texture, slow flow rate, and favorable attachment conditions. But in unsaturated sand columns, the released TiO 2 microparticles were highly mobile. Additionally, comparison with the pristine TiO 2 microparticles revealed that the enhanced mobility of the released TiO 2 microparticles was caused by the presence of compost residues which blocked attachment sites on the sand surface. This study demonstrates that TiO 2 microparticles can be released during composting of biodegradable plastics, and the transport potential of the released TiO 2 microparticles in the terrestrial environment can be enhanced by the presence of compost material.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Biochar-compost-based controlled-release nitrogen fertilizer intended for an active microbial community

Nitrogen (N) fertilizers in agriculture suffer losses by volatilization of N to the air, surface runoff and leaching into the soil, resulting in low N use efficiency (NUE) (< 50%) and raising severe environmental pollutions. Controlled- release nitrogen fertilizers (CRNFs) can control the release of N nutrients to NUE in crop production. Different methods were used to develop new CRNFs. However, different CRNF technologies are still underdeveloped due to inadequate controlling on N releasing time and/or unsustainable diffusion. The study on the influences of CRNF processing parameters on microbial conditions are lacking when the CRNFs composed of various bio-ingredients such as biochar, composts, and biowaste. The complexity of processing methods, material biodegradability, and other physical properties make current CRNFs of questionable value in agricultural production. This research aims to develop a novel biochar-compost-based controlled-release urea fertilizer (BCRUF) to preserve microbial properties carried by the compost. The BCRUF was synthesized by pelletizing the 50:50 (dry, wt/wt) mixture of biochar and compost. BCRUF was loaded with urea and then spray-coated with polylactic acid (PLA). The releasing time of two types of BCRUFs, coated and uncoated with PLA, for 80% of N release in water was up to 6 h at three different temperatures (4, 23, and 40 °C), compared to conventional urea fertilizer and commercial environmentally smart N (ESN) fertilizer. The releasing time of coated BCRUF for 80% N release in soil was up to 192 h (8 days). Fourier-transform infrared spectroscopy (FTIR) analysis revealed that no new functional groups were found in the release solution, indicating no new chemical hazards generated. The differential scanning calorimetry (DSC) tests also verified that its thermal stability could be up to 160 °C. The microbe populations in the BCRUF pellets were reduced after the pelleting and drying processes in BCRUF fabrication, but a few bacteria can endure in the air-drying process. BCRUF pellets soaked in water for 4 days retained some bacteria. The BCRUF showed very promising characteristics to improve NUE and sustainability in agricultural production.

58 GEOSCIENCES↗
DOE OSTI2023

Influence of aluminum incorporation and aqueous conditions on metal ion release of high-Ni transition metal oxide nanomaterials

Developing a materials perspective of how to control the degradation and negative impact of complex metal oxides requires an integrated understanding of how these nanomaterials transform in the environment and interact with biological systems. Doping with aluminum is known to stabilize oxide materials, but has not been assessed cohesively from synthesis to environmental fate and biological impact. In the present study, the influence of aluminum doping on metal ion release from transition metal oxides was investigated by comparing aqueous transformations of lithium nickel cobalt aluminum oxide (LiNi 0.82 Co 0.15 Al 0.03 O 2 ; NCA) and lithium nickel cobalt oxide (LiNi 0.80 Co 0.20 O 2 ; NC) nanoparticles and by calculating the energetics of metal release using a density functional theory (DFT) and thermodynamics method. Two model environmental organisms were used to assess biological impact, and metal ion release was compared for NCA and NC nanoparticles incubated in their respective growth media: moderately hard reconstituted water (MHRW) for the freshwater invertebrate Daphnia magna (D. magna) and minimal growth medium for the Gram-negative bacterium Shewanella oneidensis MR-1 (S. oneidensis). Further, the amount of metal ions released was reduced for NCA compared to NC in MHRW, which correlated to changes in the modeled energetics of release upon Al substitution in the lattice. In minimal medium, metal ion release was approximately an order of magnitude higher compared to MHRW and was similar to the stoichiometry of the bulk nanoparticles for both NCA and NC. Interpretation of the release profiles and modeling indicated that the increase in total metal ion release and the reduced influence of Al doping arises from lactate complexation of metal ions in solution. The relative biological impacts of NC and NCA exposure for both S. oneidensis and D. magna were consistent with the metal release trends observed for minimal medium and MHRW, respectively. Together, these results demonstrate how a combined experimental and computational approach provides valuable insight into the aqueous transformations and biological impacts of complex metal oxide nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1994

Results of critical velocity experiments with barium, strontium, and calcium releases from CRRES satellite

As part of the NASA Combined Release and Radiation Effects Satellite (CRRES) chemical release program in September 1990, two Ba and also one each Sr and Ca canisters of a boron-titanium thermite mixture, which vaporizes the element on ignition, were released near perigee after dusk in the South Pacific to study the critical velocity effect proposed by Alfven. The critical velocities of these three elements are 2.7, 3.5, and 5.4 km/s respectively, all well below the orbital velocity of 9.4 km/s. On September 10, 1990, a Sr and Ba pair (G-13, or critical ionization velocity (CIV) I) was released near Rarotonga at approximately 515 km altitude in a background electron density of 3.4 x 10(exp 6)/cu cm. On September 14, 1990, G-14 or CIV II released a Ca and Ba pair west of New Caledonia near 595 km at an electron density of 1.5 x 10(exp 6)/cu cm. Ions of all three elements were observed with low-light level imagers from two aircraft after they had transited up the magnetic field lines into the sunlight. Emissions from the spherically expanding neutral gas shells below the solar terminator, observed with cameras filtered for the Ba(+) ion line at 4554 A and also in unfiltered imagers for approximately 15 s after release, are probably due to excitation by hot electrons created in the CIV process. The ions created clearly lost much of their energy, which we now show can be explained by elastic collisions: Ba(+) + O. Inventories of the observed ions indicate yields of 0.15% and 1.84% for Ba in the first and second experiments, 0.02% for Sr and 0.27% for Ca. Ionization from all the releases continued along the satellite trajectory much longer (greater than 45 s) than expected for a CIV process. The ion production along the satellite track versus time typically shows a rapid rise to a peak in a few seconds followed by an exponential decrease to a level essentially constant rate. The characteristic distances for CIV I and II are 47 and 62 km, respectively. We interpret the early time rise and exponential fall to be due to CIV ionization, of 0.014% (CIV I) and 0.40% (CIV II) for the Ba releases. The later ions produced at a constant rate probably have origins from other such processes as stripping and associative ionization collisions with atmospheric constituents primarily O, and charge exchange with O(+), He(+), and H(+). We suggest that the much larger Ba ionization rate in CIV II than CIV I is due to the fact that the release occurred in the peak Ca density where hot electrons were already present.

Wescott, E. M.↗
NASA NTRS2017

Miniature Release Mechanism or Diminutive Assembly for Nanosatellite Deployables (DANY)

Miniature release mechanisms constrain objects, such as deployables during the launch of space vehicles, such as small satellites and nanosatellites, and enable the release of the objects once a desired destination is reached by the space vehicle. Constraint and release of the objects are achieved by providing a secure threaded interface that may be released by the release mechanisms. The release mechanisms include a housing structure; a release block can include a threaded interface; one or more retracting pins; one or more release springs; a breakable link, such as a plastic link; a cable harness clamp; and a circuit board. The release mechanism can be 0.1875 inches (approximately 4.8 mm) thick.

Santos Soto, Luis H.↗
DOE OSTI2022

Mechanisms of stored energy release in silicon carbide materials neutron-irradiated at elevated temperatures

Understanding the stored energy release behavior of SiC is crucial for the design of SiC-based fuel cladding for light water reactors because stored energy release affects response during accident conditions. Differential scanning calorimetry was used to evaluate the stored energy of monolithic SiC and SiC fiber–reinforced SiC matrix composite variants following neutron irradiation under light water reactor–relevant dose and temperature conditions. The tests were performed at heating rates of 0.5, 3, and 20 K/min up to 1,273 K. The onset temperature of the energy release roughly corresponded to the irradiation temperature, and energy release was delayed as the heating rate increased. The monolithic and composite specimens exhibited similar stored energy release behavior up to ~1,000 K, and above that temperature, the energy release depended more on material type. The energy release measured in this study is below the material-specific heat capacity at temperatures below ~1,000 K but exceeds it under certain material and annealing conditions at temperatures above ~1,000 K. The amount of irradiation-induced volumetric swelling of the specimens was an indication of the total stored energy. Based on this observation, the energy release behavior was described by a swelling recovery model.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Engineering microalgal cell wall-anchored proteins using GP1 PPSPX motifs and releasing with intein-mediated fusion

AbstractHarnessing and controlling the localization of recombinant proteins is critical for advancing applications in synthetic biology, industrial biotechnology, and drug delivery. This study explores protein anchoring and controlled release inChlamydomonas reinhardtii, providing innovative tools for these fields. Using truncated variants of the GP1 glycoprotein fused to the plastic-degrading enzyme PHL7, we identified the PPSPX motif as essential for anchoring proteins to the cell wall. Constructs with increased PPSPX content exhibited reduced secretion but improved anchoring, pinpointing the potential anchor-signal sites of GP1 and highlighting the distinct roles of these motifs in protein localization. Building on the anchoring capabilities established with these glycomodules, we also demonstrated a controlled release system using a pH-sensitive intein derived from RecA fromMycobacterium tuberculosis. This intein efficiently cleaved and released PHL7 and mCherry that was fused to GP1 under acidic conditions, enabling precise temporal and environmental control. At pH 5.5, fluorescence kinetics demonstrated significant mCherry release from the pJPW4mCherry construct within 4 hours. In contrast, release was minimal under pH 8.0 conditions and negligible for the pJPW2mCherry (W2) control, irrespective of the pH. Additionally, bands on the Western blot at the expected size of mCherry also showed its efficient release from the mCherry::intein::GP1 fusion protein at pH 5.5. Conversely, at pH 8.0, no bands were detected. This anchor-release approach offers significant potential for drug delivery, biocatalysis, and environmental monitoring applications. By integrating glycomodules and pH-sensitive inteins, this study establishes a versatile framework for optimizing protein localization and release inC. reinhardtii, with broad implications for proteomics, biofilm engineering, and scalable therapeutic delivery systems.Graphical Abstract

Kang, Kalisa (ORCID:0009000619398129)↗
DOE OSTI2022

Identifying Hydrometeorological Factors Influencing Reservoir Releases Using Machine Learning Methods

Simulation of reservoir releases plays a critical role in social-economic functioning and our nation's security. How-ever, it is challenging to predict the reservoir release accurately because of many influential factors from natural environments and engineering controls such as the reservoir inflow and storage. Moreover, climate change and hydrological intensification causing the extreme precipitation and temperature make the accurate prediction of reservoir releases even more challenging. Machine learning (ML) methods have shown some successful applications in simulating reservoir releases. However, previous studies mainly used inflow and storage data as inputs and only considered their short-term influences (e.g, previous one or two days). In this work, we use long short-term memory (LSTM) networks for reservoir release prediction based on four input variables including inflow, storage, precipitation, and temperature and consider their long-term influences. We apply the LSTM model to 30 reservoirs in Upper Colorado River Basin, United States. We analyze the prediction performance using six statistical metrics. More importantly, we investigate the influence of the input hydrometeorological factors, as well as their temporal effects on reservoir release decisions. Results indicate that inflow and storage are the most influential factors but the inclusion of precipitation and temperature can further improve the prediction of release especially in low flows. Additionally, the inflow and storage have a relatively long-term effect on the release. These findings can help optimize the water resources management in the reservoirs.

Fan, Ming↗
DOE OSTI2026

Alginate–Amorphous Calcium Carbonate Hydrogels for Controlled Therapeutic Release

Alginate hydrogels are widely explored as biocompatible matrices for transdermal delivery of therapeutic compounds but burst release and mechanical stability remain persistent challenges in drug delivery systems. This experimental study investigated alginate–amorphous calcium carbonate (ACC) hydrogel composites designed to regulate release of model anti-inflammatory compound, ibuprofen. Hydrogels containing 1.6–2.0 wt% sodium alginate were crosslinked with CaCl₂ and combined with ACC through two incorporation pathways: (i) separate addition of ACC and ibuprofen or (ii) co-precipitation of ACC onto ibuprofen prior to hydrogel incorporation. Hydrogels without ACC served as Control. Biocomposite structure and properties were characterized and release profiles quantified using Korsmeyer–Peppas (KP) model.Burst release was curbed as crosslinking time increased, highlighting importance of network density in diffusion control. Co-precipitating ACC with ibuprofen prior to incorporating into the hydrogel suppressed burst release and sustained release for > ~72 h. Rheological measurements indicate ACC reinforces hydrogel network, increasing storage modulus while maintaining hydration and flexibility. KP model indicates release is diffusion-controlled, with deviations reflecting contributions from diffusion barriers and morphologic/structural changes near the ACC coated ibuprofen. ACC within alginate hydrogels provides a strategy for tuning drug release while preserving mechanical properties relevant to transdermal applications.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Composite Analysis Solid Waste Release Data Reduction of Activity Flux from Waste Sites to the Vadose Zone for Baseline Assessment

This environmental calculation file (ECF) describes the data reduction methodology for the solid waste release datasets generated by the Composite Analysis Solid Waste Release (CASWR) model (CP-62766, Model Package Report: Composite Analysis Solid Waste Release Model [CASWR Model]) and documents the resulting reduced datasets for the updated Composite Analysis (CA) baseline assessment. This ECF is in support of the updated Hanford Site CA. The purpose of the updated Hanford Site CA is to provide an estimate of the cumulative radiological impacts from active and planned low-level radioactive waste disposals and other potentially interacting radioactive waste disposal sources that will remain following Hanford Site closure. The vadose zone modeling activities associated with the CA includes solid waste forms as contaminant sources. To support the modeling of solid waste transport from the vadose zone to the groundwater at the Hanford Site, the CASWR model was designed to generate deterministic radionuclide release rates for the Hanford Site Central Plateau solid waste disposal sites. The complete CASWR model-generated dataset for the CA Baseline Assessment consists of 2,378,831 sets of time and release rates (1,073,869 sets for the 200 East Area and 1,304,962 sets for the 200 West Area), representing a course of the simulation from year 1953 to year 12,069, 16 radiological contaminants of potential concern (COPCs), and 237 solid waste sources as documented in ECFHANFORD- 19-0112, Solid Waste Release Calculations for the Composite Analysis Baseline Assessment. For several of the STOMP vadose zone models, the number of release rate data pairs required for release at all waste sites would exceed the limitations imposed by the STOMP modelling software package used to simulate contaminant transport through the vadose zone. As a result, a data reduction of the CASWR dataset is required prior to its use as a source input for the CA vadose zone modeling activities.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

High Burnup Transient Fission Gas Release Testing and Post-Test Examinations

The contribution of transient fission gas release (tFGR) to the burst behavior of high burnup fuel during a loss of coolant accident (LOCA) for commercial light water reactors is a complex phenomenon that is not fully understood. During the temperature ramp associated with a LOCA, there is significant additional transient fission gas release in excess of the steady state fission gas release from normal operation. An addition to the Oak Ridge National Laboratory Severe Accident Test Station (SATS) was created to explore the different conditions that impact transient fission gas release. Four tests on commercially irradiated zirconium clad uranium dioxide nuclear fuel were performed to support transient fission gas release study. These experiments and their post-test analyses are discussed. The first test on high burnup fuel revealed a LOCA relevant transient fission gas release of 5.3% for an unpressurised segment. Subsequent tests have measured transient fission gas release at different conditions that span from 4.8% to 14.4 % transient fission gas release.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2026

Radiological Releases from Novel Fuel Forms in Advanced Reactors During Severe Accidents for Consequence Analyses

Various advanced reactor developers are exploring the potential for reductions in the size of physical security forces and emergency planning zones. These reductions are based on robust fuel forms and inherently safe reactor designs. However, such reductions in physical protection measures could increase the risk of sabotage. To assess the possibility of reducing these measures, sabotage-induced radiological consequence analyses were carried out. These analyses considered accident scenarios that were beyond design basis accidents and overly conservative (Shah, 2025a; Shah, 2025b; Shah and Hartanto, 2026), yielding very large release fractions. These fractions, which can be used to evaluate physical protection and emergency planning requirements, have been crudely determined and applied as demonstrations for a sodium-cooled fast reactor (SFR) (Shah and Hartanto, 2025a), a high-temperature gas-cooled reactor (HTGR) (Shah and Hartanto, 2025b), a heat pipe–cooled reactor (HPR) (Shah and Hartanto, 2025c), and a molten salt–cooled reactor (MSR) (Shah et al., 2026). A Sandia National Laboratories (SNL) team used MELCOR—a fully integrated severe accident analysis code—to demonstrate the code’s capability to analyze advanced (i.e., not light water–cooled) reactors (including a fluoride salt–cooled high-temperature reactor [FHR]) and calculate radiological releases to the environment during severe accidents (Wagner et al., 2022a, 2022b, 2022c, 2023a, and 2023b). Although the analyses were carried out to demonstrate MELCOR’s growing capability, the release source terms were estimated for advanced reactors, providing valuable insights into the accident progression and radiological releases. These findings from prior SNL studies, including estimated source terms and related sensitivity studies, were leveraged to derive source terms for postulated sabotage-induced accidents. Insights from these sensitivity studies informed the scaling of SNL’s estimated source terms for the defined accident scenarios. The derived release fractions for the severe accident scenarios for the respective reactor designs can be used to perform more nuanced dose consequence analyses to evaluate the reactors’ physical protection and emergency planning zone requirements. These analyses are in accordance with the risk-informed, performance-based approach proposed under 10 CFR Part 53. This study builds on the prior source term analyses and associated sensitivity studies by SNL to derive time-dependent and design-informed release fractions. Section 2 describes the diverse advanced reactor designs analyzed by the SNL team. Section 3 discusses the severe accident analyses, the release fractions calculated, and the limitations and assumptions of the demonstration project. Section 4 presents the release percentages derived for the hypothetical sabotage-induced severe accidents at the advanced reactors. Section 5 summarizes the study’s findings and conclusions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1988

A comparison of the plasma wave spectra for the eight AMPTE chemical releases

The Active Magnetospheric Particle Tracer Explorers (AMPTE) IRM spacecraft performed a series of eight chemical releases in essentially comparable pairs. There were two lithium releases in the solar wind, two lithium and two barium releases in the near-Earth magnetotail, and two barium releases to simulate artificial comets, one in the solar wind and the other in the magnetosheath. A variety of plasma waves were observed in conjunction with each of the releases. Although there were unique features associated with some of the individual releases, the comparable releases generally produced similar wave emissions. This paper discusses the similarities and differences among the releases.

Koons, H. C.↗
NASA NTRS1990

The Combined Release and Radiation Effects Satellite (CRRES) program: A unique series of scientific experiments

The Defense Department and NASA have joined in a program to study the space environment which surrounds the earth and the effects of space radiation on modern satellite electronic systems. The Combined Release and Radiation Effects Satellite (CRRES) will carry an array of active experiments including chemical releases and a complement of sophisticated scientific instruments to accomplish these objectives. Other chemical release active experiments will be performed with sub-orbital rocket probes. The chemical releases will 'paint' the magnetic and electric fields of earthspace with clouds of glowing ions. Earthspace will be a laboratory, and the releases will be studied with an extensive network of ground-, aircraft-, and satellite-based diagnostic instruments. Some of the topics discussed include the following: the effects of earthspace; the need for active experiments; types of chemical releases; the CRRES program schedule; international support and coordinated studies; photographing chemical releases; information on locating chemical releases for observation by the amateur; and CRRES as a program.

Reasoner, David L.↗
NASA NTRS1990

Serotonin release varies with brain tryptophan levels

This study examines directly the effects on serotonin release of varying brain tryptophan levels within the physiologic range. It also addresses possible interactions between tryptophan availability and the frequency of membrane depolarization in controlling serotonin release. We demonstrate that reducing tryptophan levels in rat hypothalamic slices (by superfusing them with medium supplemented with 100 microM leucine) decreases tissue serotonin levels as well as both the spontaneous and the electrically-evoked serotonin release. Conversely, elevating tissue tryptophan levels (by superfusing slices with medium supplemented with 2 microM tryptophan) increases both the tissue serotonin levels and the serotonin release. Serotonin release was found to be affected independently by the tryptophan availability and the frequency of electrical field-stimulation (1-5 Hz), since increasing both variables produced nearly additive increases in release. These observations demonstrate for the first time that both precursor-dependent elevations and reductions in brain serotonin levels produce proportionate changes in serotonin release, and that the magnitude of the tryptophan effect is unrelated to neuronal firing frequency. The data support the hypothesis that serotonin release is proportionate to intracellular serotonin levels.

Schaechter, Judith D.↗
NASA NTRS1994

On the maximum energy release in flux-rope models of eruptive flares

We determine the photospheric boundary conditions which maximize the magnetic energy released by a loss of ideal-magnetohydrodynamic (MHD) equilibrium in two-dimensional flux-rope models. In these models a loss of equilibrium causes a transition of the flux rope to a lower magnetic energy state at a higher altitude. During the transition a vertical current sheet forms below the flux rope, and reconnection in this current sheet releases additional energy. Here we compute how much energy is released by the loss of equilibrium relative to the total energy release. When the flux-rope radius is small compared to its height, it is possible to obtain general solutions of the Grad-Shafranov equation for a wide range of boundary conditions. Variational principles can then be used to find the particular boundary condition which maximizes the magnetic energy released for a given class of conditions. We apply this procedure to a class of models known as cusp-type catastrophes, and we find that the maximum energy released by the loss of equilibrium is 20.8% of the total energy release for any model in this class. If the additional restriction is imposed that the photospheric magnetic field forms a simple arcade in the absence of coronal currents, then the maximum energy release reduces to 8.6%

Forbes, T. G.↗
NASA NTRS1997

Kinetics, Ca2+ dependence, and biophysical properties of integrin-mediated mechanical modulation of transmitter release from frog motor nerve terminals

Neurotransmitter release from frog motor nerve terminals is strongly modulated by change in muscle length. Over the physiological range, there is an approximately 10% increase in spontaneous and evoked release per 1% muscle stretch. Because many muscle fibers do not receive suprathreshold synaptic inputs at rest length, this stretch-induced enhancement of release constitutes a strong peripheral amplifier of the spinal stretch reflex. The stretch modulation of release is inhibited by peptides that block integrin binding of natural ligands. The modulation varies linearly with length, with a delay of no more than approximately 1-2 msec and is maintained constant at the new length. Moreover, the stretch modulation persists in a zero Ca2+ Ringer and, hence, is not dependent on Ca2+ influx through stretch activated channels. Eliminating transmembrane Ca2+ gradients and buffering intraterminal Ca2+ to approximately normal resting levels does not eliminate the modulation, suggesting that it is not the result of release of Ca2+ from internal stores. Finally, changes in temperature have no detectable effect on the kinetics of stretch-induced changes in endplate potential (EPP) amplitude or miniature EPP (mEPP) frequency. We conclude, therefore, that stretch does not act via second messenger pathways or a chemical modification of molecules involved in the release pathway. Instead, there is direct mechanical modulation of release. We postulate that tension on integrins in the presynaptic membrane is transduced mechanically into changes in the position or conformation of one or more molecules involved in neurotransmitter release, altering sensitivity to Ca2+ or the equilibrium for a critical reaction leading to vesicle fusion.

Non-NASA Center↗
NASA NTRS2012

Organic Combustion in the Presence of Ca-Carbonate and Mg-Perchlorate: A Possible Source for the Low Temperature CO2 Release Seen in Mars Phoenix Thermal and Evolved Gas Analyzer Data

Two of the most important discoveries of the Phoenix Lander were the detection of approx.0.6% perchlorate [1] and 3-5% carbonate [2] in landing site soils. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Phoenix lander could heat samples up to approx.1000 C and monitor evolved gases with a mass spectrometer. TEGA detected a low (approx.350 C) and high (approx.750 C) temperature CO2 release. The high temp release was attributed to the thermal decomposition of Ca-carbonate (calcite). The low temperature CO2 release could be due to desorption of CO2, decomposition of a different carbonate mineral, or the combustion of organic material. A new hypothesis has also been proposed that the low temperature CO2 release could be due to the early breakdown of calcite in the presence of the decomposition products of certain perchlorate salts [3]. We have investigated whether or not this new hypothesis is also compatible with organic combustion. Magnesium perchlorate is stable as Mg(ClO4)2-6H2O on the martian surface [4]. During thermal decomposition, this perchlorate salt releases H2O, Cl2, and O2 gases. The Cl2 can react with water to form HCl which then reacts with calcite, releasing CO2 below the standard thermal decomposition temperature of calcite. However, when using concentrations of perchlorate and calcite similar to what was detected by Phoenix, the ratio of high:low temperature CO2 evolved is much larger in the lab, indicating that although this process might contribute to the low temp CO2 release, it cannot account for all of it. While H2O and Cl2 cause calcite decomposition, the O2 evolved during perchlorate decomposition can lead to the combustion of any reduced carbon present in the sample [5]. We investigate the possible contribution of organic molecules to the low temperature CO2 release seen on Mars.

Archer, Douglas↗