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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Phase 1 of the near team hybrid passenger vehicle development program. Appendix C: Preliminary design data package. Volume 2: Appendices

The design, development, efficiency, manufacturability, production costs, life cycle cost, and safety of sodium-sulfur, nickel-zinc, and lead-acid batteries for electric hybrid vehicles are discussed. Models are given for simulating the vehicle handling quality, and for finding the value of: (1) the various magnetic quantities in the different sections in which the magnetic circuit of the DC electric machine is divided; (2) flux distribution in the air gap and the magnetization curve under load conditions; and (3) the mechanical power curves versus motor speed at different values of armature current.

Piccolo, R.↗

Regenerative fuel cell systems for mid- to high-orbit satellites

An assessment of the present and projected capabilities of selected hydrogen-oxygen and hydrogen-halogen fuel cell and electrolyzer combinations for energy storage systems (ESS) in configurations useful for spacecraft missions operating in the 10- to 50-kW range for many years in midaltitude to geosynchronous orbits has recently been completed. Results of the study indicate that regenerative fuel cell ESS are feasible for the intended application. A computer model was used to provide tradeoff analyses for optimizing the various ESS fuel cell concepts. When appropriately configured to be compatible with the mission needs of the selected model spacecraft, the specific energy for these ESS are intermediate between that presently available for nickel-hydrogen batteries and that expected for the newly emerging sodium-sulfur technology.

Taenaka, R. K.↗

Advanced Energy Storage for Space Applications

NASA is planning a number of space science and space exploration missions into the early 21st century. The JPL Advanced Battery Program, which has the goal of developing batteries for these missions, is described. Under program consideration are Li-SOCl(sub 2) cells, secondary lithium cells, advanced metal hydride cells, and high-temperature sodium-nickel chloride cells.

JPL Advanced Battery Program energy storage batter↗

Ceramic-metal seals for advanced battery systems

The search for materials which are electrochemically compatible with the lithium sulfur and sodium sulfur systems is discussed. The use liquid or braze alloys, titanium hydrite coatings, and tungsten yttria for bonding beryllium with ceramic is examined.

Reed, L.↗

Application of electrochemical energy storage in solar thermal electric generation systems

This paper assesses the status, cost, and performance of existing electrochemical energy storage systems, and projects the cost, performance, and availability of advanced storage systems for application in terrestrial solar thermal electric generation. A 10 MWe solar plant with five hours of storage is considered and the cost of delivered energy is computed for sixteen different storage systems. The results indicate that the five most attractive electrochemical storage systems use the following battery types: zinc-bromine (Exxon), iron-chromium redox (NASA/Lewis Research Center, LeRC), sodium-sulfur (Ford), sodium-sulfur (Dow), and zinc-chlorine (Energy Development Associates, EDA).

Das, R.↗

Investigation of electrode materials for alkaline batteries

A number of amalgam electrode systems were investigated for possible use as high rate anodes and cathodes. The systems examined include: lithium, sodium, and potassium in Group 1, magnesium, calcium, and barium in Group 2, aluminum in Group 3, lead in Group 4, copper in Group 1b, and zinc and cadmium in Group 2b. The K(Hg) and Na(Hg) anodes in 10 VF and 15 VF (an unambiguous expression of concentration that indicates the number of formula weights of solute dissolved in a liter of solution) hydroxide solutions have proven satisfactory; some of these have produced current densities of more than 8 A/sq cm. None of the amalgam cathodes have approached this performance although the TI(Hg) has delivered 1 A/sq cm. Se(Hg) and Te(Hg) cathodes have given very stable discharges. Zn(Hg) and Cd(Hg) electrodes did not show good high rate characteristics, 200 to 300 mA/sq cm being about the maximum current densities obtainable. Both anodes are charged through a two-step process in which M(Hg) is first formed electrochemically and subsequently reduces Zn(II or Cd(II) to form the corresponding amalgam. The second step is extremely rapid for zinc and very slow for cadmium.

Arcand, G. M.↗

Air Force electrochemical power research and technology program for space applications

An overview is presented of the existing Air Force electrochemical power, battery, and fuel cell programs for space application. Present thrusts are described along with anticipated technology availability dates. Critical problems to be solved before system applications occur are highlighted. Areas of needed performance improvement of batteries and fuel cells presently used are outlined including target dates for key demonstrations of advanced technology. Anticipated performance and current schedules for present technology programs are reviewed. Programs that support conventional military satellite power systems and special high power applications are reviewed. Battery types include bipolar lead-acid, nickel-cadmium, silver-zinc, nickel-hydrogen, sodium-sulfur, and some candidate advanced couples. Fuel cells for pulsed and transportation power applications are discussed as are some candidate advanced regenerative concepts.

Allen, Douglas↗

Current Regulator For Sodium-Vapor Lamps

Regulating circuit maintains nearly-constant alternating current in sodium-vapor lamp. Regulator part of dc-to-ac inverter circuit used to supply power to street lamp from battery charged by solar-cell array.

Mclyman, W. T.↗

Effect of microstructure on Na/+/ diffusion in beta alumina

The effect of microstructural features, such as grain size and orientation, on sodium ion diffusion in polycrystalline beta alumina is investigated; the ionic solid is suitable for use in high-energy and power density batteries. Two types of hot-pressed polycrystalline samples are studied, one with grains highly oriented in the direction normal to the pressing direction, the other with significantly less preferred orientation normal to the pressing direction. Results of the experimental assessments indicate that grain size and diffusion path tortuosity have little effect on diffusion kinetics, while grain boundary type and grain aspect ratio are important factors in determining the diffusion rate.

Sarian, S.↗

Moderate temperature sodium cells. V - Discharge reactions and rechargeability of NiS and NiS2 positive electrodes in molten NaAlCl4

NiS2 and NiS have been characterized as high energy density rechargeable positive electrodes for moderate-temperature Na batteries of the configuration, Na(1)/beta double prime-Al2O3/NaAlCl4(1), NiSx. The batteries operate in the temperature range 170 - 190 C. Positive electrode reactions during discharge/charge cycles have been characterized. Excellent rechargeability of the batteries has been demonstrated by extended cell cycling. A Na/NiS2 cell, operating at 190 C, exceeded 600 deep discharge/charge cycles with practically no capacity deterioration. The feasibility of secondary Na/NiSx batteries with specific energies equal to or greater than 50 Wh/lb and cycle lifes exceeding 1000 deep discharge/charge cycles has been demonstrated.

Abraham, K. M.↗

The 1991 NASA Aerospace Battery Workshop

The proceedings from the workshop are presented. The subjects covered include nickel-cadmium, nickel-hydrogen, silver-zinc, and lithium based technologies, as well as advanced technologies including nickel-metal hydride and sodium-sulfur.

Brewer, Jeffrey C.↗

Determination of the zincate diffusion coefficient and its application to alkaline battery problems

The diffusion coefficient for the zincate ion at 24 C was found to be 9.9 x 10 to the -7th power sq cm/sec + or - 30% in 45% potassium hydroxide and 1.4 x 10 to the -7th power sq cm/sec + or - 25% in 40% sodium hydroxide. Comparison of these values with literature values at different potassium hydroxide concentrations show that the Stokes-Einstein equation is obeyed. The diffusion coefficient is characteristic of the zincate ion (not the cation) and independent of its concentration. Calculations with the measured value of the diffusion coefficient show that the zinc concentration in an alkaline zincate half-cell becomes uniform throughout in tens of hours by diffusion alone. Diffusion equations are derived which are applicable to finite-size chambers. Details and discussion of the experimental method are also given.

May, C. E.↗

The value of the 4-day headdown bedrest model for screening countermeasures

In order to evaluate the benefits of periodic exposure to the +G(z) vector as a countermeasure to the physiological responses to minus 6 degree head down bedrest (HDT), we considered a two-tiered approach: (a) to use 4 days HDT as a quick and inexpensive means of screening countermeasures, (b) to use a 60 day HDT to validate the most promising candidates. The approach and results of a 4 day study are described here. Methods: Nine males were admitted to our Human Research Facility for one ambulatory control day followed by 4 days HDT and were released on the next day after completion of a peak oxygen consumption test (VO(sub 2 peak)). A battery of tests was selected and standardized to evaluate the known early effects of HDT on plasma volume, early bone markers, orthostatic tolerance, physical performance, and fluid and electrolytes and their hormone regulation. Fluid sodium (Na) and potassium (K) intake and output in the urine were monitored throughout. Plasma volume was determined with a modified Evans Blue method and orthostatic tolerance with a 60 degree head-up tilt test for 30 minutes - both of which were determined on the ambulatory control day and on day 4 of HDT. Immediately after completion of the tilt test subjects were returned to the minus 6 degree position until the next morning when a VO(sub 2 peak) (horizontal ergometer) was done. This was compared to a similar control test determined on 2 separate occasions before subject admission. Results: Four hours after going HDT produced significant decreases (p less than 0.05) in the circulating concentration of fluid and electrolyte regulating hormones. Plasma volume, orthostatic tolerance and VO(sub 2 peak) changed significantly after 4 days HDT. There was also the expected natriuresis on day 1 of HDT but no significant diuresis. The consistency of the pre-bedrest VO(sub 2 peak) tilt tests and plasma volumes was remarkable. Conclusions: The 4 day HDT model seems highly promising for screening a variety of countermeasures alone and in combination before validating their benefits in extended bedrest or flight experiments.

Vernikos, J.↗

Sodium Sulfur Technology Program Nastec

The NaSTEC program focuses on developing currently available sodium sulfur cells for use in space applications and investigating the operational parameters of the cells. The specific goals of the program are to determine the operational parameters and verify safety limits of Na/S technology battery cells; test long term zero-g operation; and create a life test database. The program approach and ground and flight test objectives are described in textual and graphic form.

Highley, Bob↗

Electrical screening procedure for solid ionic conductors

An electrical screening method has been developed for preliminary evaluation of polycrystalline specimens of candidates for use as solid ionic conductive electrolytes in batteries. The procedure measures dielectric loss and capacitance, from which are calculated an ac conductivity attributed provisionally to ions and an activation energy for that conductivity. Electronic conductivity is directly measured. The screening procedure applied to sodium beta-alumina yielded acceptable values for conductivity and activation energy.

Kautz, H. E.↗

Determination of the zincate diffusion coefficient and its application to alkaline battery problems

The diffusion coefficient for the zincate ion at 24 C was found to be 9.9 X 10 to the minus 7th power squared cm per sec + or - 30 percent in 45 percent potassium hydroxide and 1.4 x 10 to the minus 7 squared cm per sec + or - 25 percent in 40 percent sodium hydroxide. Comparison of these values with literature values at different potassium hydroxide concentrations show that the Stokes-Einstein equation is obeyed. The diffusion coefficient is characteristic of the zincate ion (not the cation) and independent of its concentration. Calculations with the measured value of the diffusion coefficient show that the zinc concentration in an alkaline zincate half cell becomes uniform throughout in tens of hours by diffusion alone. Diffusion equations are derived which are applicable to finite size chambers. Details and discussion of the experimental method are also given.

May, C. E.↗