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At least 73 records · Page 4

NO versus N2O emissions from an NH4(+)-amended Bermuda grass pasture

An enclosure technique is used to monitor soil NO and N2O emissions during early summer regrowth of Bermuda grass (Cynodon dactylon) on sandy loam in a humid, subtropical region of southern Texas. The evolution of both gases was substantially higher from plots harvested at the beginning of the experiment and fertilized five days later with 52 kg N/ha as (NH4)2SO4 than from plots not harvested or fertilized. Emission of NO, but not N2O, was stimulated by clipping and removing the grass, probably because eliminating the shading provided by the dense grass canopy changed these plots from cooler to warmer than unharvested plots, thereby stimulating the activity of soil microorganisms responsible for NO production. Neither gas flux was significantly affected by application of N until the next rainfall dissolved and moved the surface-applied fertilizer into the soil. Immediately thereafter, emissions of NO and N2O increased dramatically to peaks of 160 and 12 g N/ha/d, respectively, and then declined at rates that closely parallel the nitrification rate of added NH4(+), indicating that the gases resulted from the activity of nitrifying microorganisms, rather than denitrifiers. Nitric oxide emissions during the nine-week measurement period averaged 7.2 times greater than N2O emissions and accounted for 3.2 percent of the added N. The data indicate that humid, subtropical grasslands, which not only have large geographical extent but also have been subject to intense anthropogenic disturbance, contribute significantly to the global atmospheric NO(x) budget.

Hutchinson, G. L.↗

Global Partitioning of NOx Sources Using Satellite Observations: Relative Roles of Fossil Fuel Combustion, Biomass Burning and Soil Emissions

This document contains the following abstract for the paper "Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions." Satellite observations have been used to provide important new information about emissions of nitrogen oxides. Nitrogen oxides (NOx) are significant in atmospheric chemistry, having a role in ozone air pollution, acid deposition and climate change. We know that human activities have led to a three- to six-fold increase in NOx emissions since pre-industrial times, and that there are three main surface sources of NOx: fuel combustion, large-scale fires, and microbial soil processes. How each of these sources contributes to the total NOx emissions is subject to some doubt, however. The problem is that current NOx emission inventories rely on bottom-up approaches, compiling large quantities of statistical information from diverse sources such as fuel and land use, agricultural data, and estimates of burned areas. This results in inherently large uncertainties. To overcome this, Lyatt Jaegle and colleagues from the University of Washington, USA, used new satellite observations from the Global Ozone Monitoring Experiment (GOME) instrument. As the spatial and seasonal distribution of each of the sources of NOx can be clearly mapped from space, the team could provide independent topdown constraints on the individual strengths of NOx sources, and thus help resolve discrepancies in existing inventories. Jaegle's analysis of the satellite observations, presented at the recent Faraday Discussion on "Atmospheric Chemistry", shows that fuel combustion dominates emissions at northern mid-latitudes, while fires are a significant source in the Tropics. Additionally, she discovered a larger than expected role for soil emissions, especially over agricultural regions with heavy fertilizer use. Additional information is included in the original extended abstract.

Jaegle, Lyatt↗

Agricultural land cover mapping in the context of a geographically referenced digital information system

The introduction of soil map information to the land cover mapping process can improve discrimination of land cover types and reduce confusion among crop types that may be caused by soil-specific management practices and background reflectance characteristics. Multiple dates of LANDSAT MSS digital were analyzed for three study areas in northern Missouri to produce cover types for major agricultural land cover classes. Digital data bases were then developed by adding ancillary data such as digitized soil and transportation network information to the LANDSAT-derived cover type map. Procedures were developed to manipulate the data base parameters to extract information applicable to user requirements. An agricultural information system combining such data can be used to determine the productive capacity of land to grow crops, fertilizer needs, chemical weed control rates, irrigation suitability, and trafficability of soil for planting.

Stoner, E. R.↗

Cross-system comparisons of soil nitrogen transformations and nitrous oxide flux in tropical forest ecosystems

Soil nitrogen transformations and nitrous oxide flux across the soil-air interface have been measured in a variety of tropical forest sites and correlated with patterns of nitrogen circulation. Nitrogen mineralizaton and nitrification potentials were found to be high in the relatively fertile Costa Rica sites and the Amazonian oxisol/ultisols, intermediate in Amazonian white sand soils, and low in the Hawaiian montane sites. Nitrous oxide fluxes ranged from 0 to 6.2 ng/sq cm per h, and the mean flux per site was shown to be highly correlated with mean nitrogen mineralization.

Matson, Pamela A.↗

Amplification of Heat Extremes by Plant CO2 Physiological Forcing

Plants influence extreme heat events by regulating land-atmosphere water and energy exchanges. The contribution of plants to changes in future heat extremes will depend on the responses of vegetation growth and physiology to the direct and indirect effects of elevated CO2. Here we use a suite of earth system models to disentangle the radiative versus vegetation effects of elevated CO2 on heat wave characteristics. Vegetation responses to a quadrupling of CO2 increase summer heat wave occurrence by 20 days or more-30-50% of the radiative response alone-across tropical and mid-to-high latitude forests. These increases are caused by CO2 physiological forcing, which diminishes transpiration and its associated cooling effect, and reduces clouds and precipitation. In contrast to recent suggestions, our results indicate CO2-driven vegetation changes enhance future heat wave frequency and intensity in most vegetated regions despite transpiration-driven soil moisture savings and increases in aboveground biomass from CO2 fertilization.

Skinner, Christopher B.↗

Experiments Advance Gardening at Home and in Space

Aeroponics, the process of growing plants suspended in air without soil or media, provides clean, efficient, and rapid food production. Crops can be planted and harvested year-round without interruption, and without contamination from soil, pesticides, and residue. Aeroponic systems also reduce water usage by 98 percent, fertilizer usage by 60 percent, and eliminate pesticide usage altogether. Plants grown in aeroponic systems have been shown to absorb more minerals and vitamins, making the plants healthier and potentially more nutritious. The suspended system also has other advantages. Since the growing environment can be kept clean and sterile, the chances of spreading plant diseases and infections commonly found in soil and other growing media are greatly reduced. Also, seedlings do not stretch or wilt while their roots are forming, and once the roots are developed, the plants can be easily moved into any type of growing media without the risk of transplant shock. Lastly, plants tend to grow faster in a regulated aeroponic environment, and the subsequent ease of transplant to a natural medium means a higher annual crop yield. For example, tomatoes are traditionally started in pots and transplanted to the ground at least 28 days later; growers using an aeroponic system can transplant them just 10 days after starting the plants in the growing chamber. This accelerated cycle produces six tomato crops per year, rather than the traditional one to two crop cycles. These benefits, along with the great reduction in weight by eliminating soil and much of the water required for plant growth, illustrate why this technique has found such enthusiastic support from NASA. Successful long-term missions into deep space will require crews to grow some of their own food during flight. Aeroponic crops are also a potential source of fresh oxygen and clean drinking water, and every ounce of food produced and water conserved aboard a spacecraft reduces payload weight, decreasing launch costs and freeing room for other cargo.

Source record↗

Nitrous oxide flux and nitrogen transformations across a landscape gradient in Amazonia

Nitrous oxide flux and nitrogen turnover were measured in three types of Amazonian forest ecosystems within Reserva Florestal Ducke near Manaus, Brazil. Nitrogen mineralization and nitrate production measured during 10-day laboratory incubations were 3-4 times higher in clay soils associated with 'terra firme' forests on ridge-top and slope positions than in 'campinarana' forests on bottomland sand soils. In contrast, nitrous oxide fluxes did not differ significantly among sites, but were highly variable in space and time. The observed frequency distribution of flux was positively skewed, with a mean overall sites and all sampling times of 1.3 ng N2O-N/sq cm per hr. Overall, the flux estimates were comparable to or greater than those of temperature forests, but less than others reported for Amazoonia. Results from a field fertilization experiment suggest that most nitrous oxide flux was associated with denitrification of soil nitrate.

Livingston, Gerald P.↗

Slow-Release Fertilizers For Plants

Synthetic mineral provides growing plants with nutrients, including micronutrients. Dissolves slowly in moist soil or in hydroponic solution, releasing constituents. Mineral synthetic apatite into which nutrients calcium, phosphorous, iron, manganese, copper, zinc, molybdenum, chlorine, boron, and sulfur incorporated in form of various salts. Each pellet has homogeneous inorganic composition. Composition readily adjusted to meet precise needs of plant.

Ming, Douglas W.↗

Enhanced Representation of Soil NO Emissions in the Community Multiscale Air Quality (CMAQ) Model Version 5.0.2

Modeling of soil nitric oxide (NO) emissions is highly uncertain and may misrepresent its spatial and temporal distribution. This study builds upon a recently introduced parameterization to improve the timing and spatial distribution of soil NO emission estimates in the Community Multiscale Air Quality (CMAQ) model. The parameterization considers soil parameters, meteorology, land use, and mineral nitrogen (N) availability to estimate NO emissions. We incorporate daily year-specific fertilizer data from the Environmental Policy Integrated Climate (EPIC) agricultural model to replace the annual generic data of the initial parameterization, and use a 12km resolution soil biome map over the continental USA. CMAQ modeling for July 2011 shows slight differences in model performance in simulating fine particulate matter and ozone from Interagency Monitoring of Protected Visual Environments (IMPROVE) and Clean Air Status and Trends Network (CASTNET) sites and NO2 columns from Ozone Monitoring Instrument (OMI) satellite retrievals. We also simulate how the change in soil NO emissions scheme affects the expected O3 response to projected emissions reductions.

remote sensing↗

Comparison of N2O Emissions from Soils at Three Temperate Agricultural Sites

Nitrous oxide (N2O) flux simulations by four models were compared with year-round field measurements from five temperate agricultural sites in three countries. The field sites included an unfertilized, semi-arid rangeland with low N2O fluxes in eastern Colorado, USA; two fertilizer treatments (urea and nitrate) on a fertilized grass ley cut for silage in Scotland; and two fertilized, cultivated crop fields in Germany where N2O loss during the winter was quite high. The models used were daily trace gas versions of the CENTURY model, DNDC, ExpertN, and the NASA-Ames version of the CASA model. These models included similar components (soil physics, decomposition, plant growth, and nitrogen transformations), but in some cases used very different algorithms for these processes. All models generated similar results for the general cycling of nitrogen through the agro-ecosystems, but simulated nitrogen trace gas fluxes were quite different. In most cases the simulated N20 fluxes were within a factor of about 2 of the observed annual fluxes, but even when models produced similar N2O fluxes they often produced very different estimates of gaseous N loss as nitric oxide (NO), dinitrogen (N2), and ammonia (NH3). Accurate simulation of soil moisture appears to be a key requirement for reliable simulation of N2O emissions. All models simulated the general pattern of low background fluxes with high fluxes following fertilization at the Scottish sites, but they could not (or were not designed to) accurately capture the observed effects of different fertilizer types on N2O flux. None of the models were able to reliably generate large pulses of N2O during brief winter thaws that were observed at the two German sites. All models except DNDC simulated very low N2O fluxes for the dry site in Colorado. The US Trace Gas Network (TRAGNET) has provided a mechanism for this model and site intercomparison. Additional intercomparisons are needed with these and other models and additional data sets; these should include both tropical agro-ecosystems and new agricultural management techniques designed for sustainability.

Frolking, S. E.↗

Calcium Solubility and Cation Exchange Properties in Zeoponic Soil

An important aspect of a regenerative life support system at a Lunar or Martian outpost is the ability to produce food. Essential plant nutrients, as well as a solid support substrate, can be provided by: (1) treated Lunar or Martian regolith; (2) a synthetic soil or (3) some combination of both. A synthetic soil composed of ammonium- and potassium-saturated chinoptlolite (a zeolite mineral) and apatite, can provide slow-release fertilization of plants via dissolution and ion-exchange reactions. Previous equilibrium studies (Beiersdorfer, 1997) on mixtures of synthetic hydroxyapatite and saturated-clinoptilolite indicate that the concentrations of macro-nutrients such as ammonium, phosphorous, potassium, magnesium, and calcium are a function of the ratio of chinoptilolite to apatite in the sample and to the ratio of potassium to ammonium on the exchange sites in the clinoptilolite. Potassium, ammonium, phosphorous, and magnesium are available to plants at sufficient levels. However, calcium is deficient, due to the high degree of calcium adsorption by the clinoptilolite. Based on a series of batch-equilibration experiments, this calcium deficiency can be reduced by (1) treating the clinoptilolite with CaNO3 or (2) adding a second Ca-bearing mineral (calcite, dolomite or wollastonite) to the soil. Treating the Cp with CaNO3 results in increased Ca in solution, decreased P in solution and decreased NH4 in solution. Concentrations of K were not effected by the CaNO3 treatment. Additions of Cal, Dol and Wol changed the concentrations of Ca and P in solution in a systematic fashion. Cal has the greatest effect, Dol the least and Wol is intermediate. The changes are consistent with changes expected for a common ion effect with Ca. Higher concentrations of Ca in solution with added Cal, Dol or Wol do not result in changes in K or NH4 concentrations.

Beiersdorfer, Raymond E.↗

Increasing Impacts of Extreme Droughts on Vegetation Productivity Under Climate Change

Terrestrial gross primary production (GPP) is the basis of vegetation growth and food production globally and plays a critical role in regulating atmospheric CO2 through its impact on ecosystem carbon balance. Even though higher CO2 concentrations in future decades can increase GPP, low soil water availability, heat stress and disturbances associated with droughts could reduce the benefits of such CO2 fertilization. Here we analysed outputs of 13 Earth system models to show an increasingly stronger impact on GPP by extreme droughts than by mild and moderate droughts over the twenty-first century. Due to a dramatic increase in the frequency of extreme droughts, the magnitude of globally averaged reductions in GPP associated with extreme droughts was projected to be nearly tripled by the last quarter of this century (2075-2099) relative to that of the historical period (1850-1999) under both high and intermediate GHG emission scenarios. By contrast, the magnitude of GPP reductions associated with mild and moderate droughts was not projected to increase substantially. Our analysis indicates a high risk of extreme droughts to the global carbon cycle with atmospheric warming; however, this risk can be potentially mitigated by positive anomalies of GPP associated with favourable environmental conditions.

Xu, Chonggang↗

Solubility and Cation Exchange Properties of Synthetic Hydroxyapatite and Clinoptilolite Mixtures

A zeoponic plant growth system is defined as the cultivation of plants in artificial soils, which have zeolites as a major component. These systems: 1) can serve as a controllable and renewable fertilization system to provide plant growth nutrients; 2) can mitigate the adverse effects of contamination due to leaching of highly soluble and concentrated fertilizers; and 3) are being considered as substrates for plant growth in regenerative life-support systems for long-duration space missions. Batch-equilibrium studies of the dissolution and ion-exchange properties of mixtures of naturally-occurring Wyoming clinoptilolite (a zeolite) exchanged with K(+) or NH4(+); and synthetic hydroxyapatite were conducted to determine: 1) the plant availability of the macro-nutrients NH4-N, P, K, Ca, and Mg and 2) the effects of varying the clinoptilolite to hydroxyapatite ratio and the ratio of exchangeable cations (K(+) vs. NH4(+)) on clinoptilolite extraframework sites. The nutrients NH4-N (19.7 to 73.6 mg L(sup -1), P (0.57 to 14.99 mg L(sup- 1), K (14.8 to 104.9 mg L(sup -1), and Mg (0.11 to 6.68mg L(sup -1) are available to plants at sufficient levels. Solution Ca concentrations (0.47 to 3.40 mg L(sup -1) are less than optimal. Solution concentrations of NH4(+), K(+), Ca(2+), and Mg(2+) all decreased with increasing clinoptilolite to hydroxyapatite ratio in the sample. Solution concentrations of phosphorous initially increased, reached a maximum value and then decreased with increasing clinoptilolite to hydroxyapatite ratio in the sample. The NH4(+) -exchanged clinoptilolite is more efficient in dissolving synthetic hydroxyapatite than the K(+) -exchanged clinoptilolite. This suggests that NH4(+), which is less selective at clinoptilolite extraframework sites than K(+) is exchanged more readily by Ca(2+) and thereby enhances the dissolution of the synthetic hydroxyapatite.

Beiersdorfer, Raymond E.↗

Global Patterns of Crop Yield Stability Under Additional Nutrient and Water Inputs

Agricultural production must increase to feed a growing and wealthier population, as well as to satisfy increasing demands for biomaterials and biomass-based energy. At the same time, deforestation and land-use change need to be minimized in order to preserve biodiversity and maintain carbon stores in vegetation and soils. Consequently, agricultural land use needs to be intensified in order to increase food production per unit area of land. Here we use simulations of AgMIP's Global Gridded Crop Model Intercomparison (GGCMI) phase 1 to assess implications of input-driven intensification (water, nutrients) on crop yield and yield stability, which is an important aspect in food security. We find region- and crop-specific responses for the simulated period 1980+/-2009 with broadly increasing yield variability under additional nitrogen inputs and stabilizing yields under additional water inputs (irrigation), reflecting current patterns of water and nutrient limitation. The different models of the GGCMI ensemble show similar response patterns, but model differences warrant further research on management assumptions, such as variety selection and soil management, and inputs as well as on model implementation of different soil and plant processes, such as on heat stress, and parameters. Higher variability in crop productivity under higher fertilizer input will require adequate buffer mechanisms in trade and distribution/storage networks to avoid food price volatility.

Maize↗

Calcium Solubility In Zeolite Synthetic-Apatite Mixtures

Life support systems at a lunar or martian outpost will require the ability to produce food growing in 1) treated lunar or martian regolith; 2) a synthetic soil, or 3) some combination of both. Zeoponic soil, composed of NH4 (-) and K-exchanged clinoptilolite (Cp) and synthetic apatite (Ap), can provide slow-release fertilization via dissolution and ion-exchange. Equilibrium studies indicate that KNH4, P, and Mg are available to plants at sufficient levels, however, Ca is deficient. Ca availability can be increased by adding a second Ca-bearing mineral: calcite (Cal); dolomite (Dol); or wollastonite (Wol). Additions of Cal, Dol, and Wol systematically change the concentrations of Ca and P in solution. Cal has the greatest effect, Dol the least, and Wol is intermediate.

Beiersdorfer, R.↗

Development of a Land Use Mapping and Monitoring Protocol for the High Plains Region: A Multitemporal Remote Sensing Application

The purpose of this project was to develop a practical protocol that employs multitemporal remotely sensed imagery, integrated with environmental parameters to model and monitor agricultural and natural resources in the High Plains Region of the United States. The value of this project would be extended throughout the region via workshops targeted at carefully selected audiences and designed to transfer remote sensing technology and the methods and applications developed. Implementation of such a protocol using remotely sensed satellite imagery is critical for addressing many issues of regional importance, including: (1) Prediction of rural land use/land cover (LULC) categories within a region; (2) Use of rural LULC maps for successive years to monitor change; (3) Crop types derived from LULC maps as important inputs to water consumption models; (4) Early prediction of crop yields; (5) Multi-date maps of crop types to monitor patterns related to crop change; (6) Knowledge of crop types to monitor condition and improve prediction of crop yield; (7) More precise models of crop types and conditions to improve agricultural economic forecasts; (8;) Prediction of biomass for estimating vegetation production, soil protection from erosion forces, nonpoint source pollution, wildlife habitat quality and other related factors; (9) Crop type and condition information to more accurately predict production of biogeochemicals such as CO2, CH4, and other greenhouse gases that are inputs to global climate models; (10) Provide information regarding limiting factors (i.e., economic constraints of pumping, fertilizing, etc.) used in conjunction with other factors, such as changes in climate for predicting changes in rural LULC; (11) Accurate prediction of rural LULC used to assess the effectiveness of government programs such as the U.S. Soil Conservation Service (SCS) Conservation Reserve Program; and (12) Prediction of water demand based on rural LULC that can be related to rates of draw-down of underground water supplies.

Price, Kevin P.↗

A global model of carbon-nutrient interactions

The global biogeochemical model presented has two primary objectives. First, it characterizes natural elemental cycles and their linkages for the four elements significant to Earth's biota: C, N, S, and P. Second, it describes changes in these cycles due to human activity. Global nutrient cycles were studied within the drainage basins of several major world rivers on each continent. The initial study region was the Mississippi drainage basin, concentrating on carbon and nitrogen. The model first establishes the nutrient budgets of the undisturbed ecosystems in a study region. It then uses a data set of land use histories for that region to document the changes in these budgets due to land uses. Nutrient movement was followed over time (1800 to 1980) for 30 ecosystems and 10 land use categories. A geographically referenced ecological information system (GREIS) was developed to manage the digital global data bases of 0.5 x 0.5 grid cells needed to run the model: potential vegetation, drainage basins, precipitation, runoff, contemporary land cover, and FAO soil maps of the world. The results show the contributions of land use categories to river nutrient loads on a continental scale; shifts in nutrient cycling patterns from closed, steady state systems to mobile transient or open, steady state systems; soil organic matter depletion patterns in U.S. agricultural lands; changing nutrient ratios due to land use changes; and the effect of using heavy fertilizer on aquatic systems.

Moore, Berrien, III↗

Comparison of Measurements and FluorMOD Simulations for Solar Induced Chlorophyll Fluorescence and Reflectance of a Corn Crop under Nitrogen Treatments [SIF and Reflectance for Corn]

The FLuorescence Explorer (FLEX) satellite concept is one of six semifinalist mission proposals selected in 2006 for pre-Phase studies by the European Space Agency (ESA). The FLEX concept proposes to measure passive solar induced chlorophyll fluorescence (SIF) of terrestrial ecosystems. A new spectral vegetation Fluorescence Model (FluorMOD) was developed to include the effects of steady state SIF on canopy reflectance. We used our laboratory and field measurements previously acquired from foliage and canopies of corn (Zea mays L.) under controlled nitrogen (N) fertilization to parameterize and evaluate FluorMOD. Our data included biophysical properties, fluorescence (F) and reflectance spectra for leaves; reflectance spectra of canopies and soil; solar irradiance; plot-level leaf area index; and canopy SIF emissions determined using the Fraunhofer Line Depth principal for the atmospheric telluric oxygen absorption features at 688 nm (O2-beta) and 760 nm (O2-alpha). FluorMOD simulations implemented in the default "look-up-table" mode did not reproduce the observed magnitudes of leaf F, canopy SIF, or canopy reflectance. However, simulations for all of these parameters agreed with observations when the default FluorMOD information was replaced with measurements, although N treatment responses were underestimated. Recommendations were provided to enhance FluorMOD's potential utility in support of SIF field experiments and studies of agriculture and ecosystems.

Middleton, Elizabeth M.↗