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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

On the use of radiative surface temperature to estimate sensible heat flux over sparse shrubs in Nevada

The accurate partitioning of available energy into sensible and latent heat flux is crucial to the understanding of surface atmosphere interactions. This issue is more complicated in arid and semi arid regions where the relative contribution to surface fluxes from the soil and vegetation may vary significantly throughout the day and throughout the season. A three component model to estimate sensible heat flux over heterogeneous surfaces is presented. The surface was represented with two adjacent compartments. The first compartment is made up of two components, shrubs and shaded soil, the second of open 'illuminated' soil. Data collected at two different sites in Nevada (U.S.) during the Summers of 1991 and 1992 were used to evaluate model performance. The results show that the present model is sufficiently general to yield satisfactory results for both sites.

Chehbouni, A.↗

The sensitivity of runoff generation to spatial snowpack uniformity in an alpine watershed: Green Lakes Valley, Niwot Ridge Long-Term Ecological Research station

Seasonal water storage in high-elevation alpine catchments are critical sources of water for mountainous regions like the western U.S. The spatial distribution of snow in these topographically complex catchments is primarily governed by orography, solar radiation, and wind redistribution. While the effect of solar shading is relatively consistent from year-to-year, the redistribution of snow due to wind is more variable–capable of producing snowpacks that have varying degrees of uniformity across these hydrologically-important catchments. A reasonable hypothesis is that a warmer climate will cause snowfall to become more dense (i.e. wetter and heavier), possibly leading to less wind redistribution and thus produce a more uniformly distributed snowpack across the landscape. In this study, we investigate the role of increasingly uniform spatial snowpack distributions on streamflow generation in the Green Lakes Valley Niwot Ridge Long Term Ecological Research station, within the headwaters of the Boulder Creek watershed in Colorado. A set of idealized hydrologic simulation experiments driven by reconstructed snowpacks spanning 2001–2014 show that more a more uniform spatial snowpack distribution leads to an earlier melt-out of31 days on average and tends to produce less total streamflow, with maximum decreases as large as 7.5%. Isolating the role of snowpack heterogeneity from melt-season precipitation, we find that snowpack uniformity reduces total streamflow by as much as 13.2%. Reductions in streamflow are largely explained by greater expo-sure to solar radiation in the uniformly distributed case relative to a more heterogeneous snowpack, with this exposure driving shifts towards earlier snowmelt and changes in soil water storage. Overall, we find that the runoff efficiency from shallower snowpacks is more sensitive to the effects of uniformity than deeper snowpacks, which has potential implications for a warming climate where shallower snowpacks and enhanced sensitivities may be present.

Alpine catchment↗

Agile Satellite Planning for Multi-Payload Observations in Earth Science Models

We present the planner methods and preliminary results for a new paradigm of earth observing systems based on coordinating science observations for a constellation of agile satellites which can quickly maneuver to change viewing angles. Each satellite has multiple heterogeneous instruments.

Satellite Constellation↗

Predicting the Mineral Composition of Dust Aerosols: Representing Key Processes - Part 1

Soil dust aerosols created by wind erosion are typically assigned globally uniform physical and chemical properties within Earth system models, despite known regional variations in the mineral content of the parent soil. Mineral composition of the aerosol particles is important to their interaction with climate, including shortwave absorption and radiative forcing, nucleation of cloud droplets and ice crystals, heterogeneous formation of sulfates and nitrates, and atmospheric processing of iron into bioavailable forms that increase the productivity of marine phytoplankton. Here, aerosol mineral composition is derived by extending a method that provides the composition of a wet-sieved soil. The extension accounts for measurements showing significant differences between the mineral fractions of the wetsieved soil and the emitted aerosol concentration. For example, some phyllosilicate aerosols are more prevalent at silt sizes, even though they are nearly absent at these diameters in a soil whose aggregates are dispersed by wet sieving. We calculate the emitted mass of each mineral with respect to size by accounting for the disintegration of soil aggregates during wet sieving. These aggregates are emitted during mobilization and fragmentation of the original undispersed soil that is subject to wind erosion. The emitted aggregates are carried far downwind from their parent soil. The soil mineral fractions used to calculate the aggregates also include larger particles that are suspended only in the vicinity of the source. We calculate the emitted size distribution of these particles using a normalized distribution derived from aerosol measurements. In addition, a method is proposed for mixing minerals with small impurities composed of iron oxides. These mixtures are important for transporting iron far from the dust source, because pure iron oxides are more dense and vulnerable to gravitational removal than most minerals comprising dust aerosols. A limited comparison to measurements from North Africa shows that the model extensions result in better agreement, consistent with a more extensive comparison to global observations as well as measurements of elemental composition downwind of the Sahara, as described in companion articles.

aerosols↗

Evaluating the Utility of Satellite Soil Moisture Retrievals over Irrigated Areas and the Ability of Land Data Assimilation Methods to Correct for Unmodeled Processes

Earth's land surface is characterized by tremendous natural heterogeneity and human-engineered modifications, both of which are challenging to represent in land surface models. Satellite remote sensing is often the most practical and effective method to observe the land surface over large geographical areas. Agricultural irrigation is an important human-induced modification to natural land surface processes, as it is pervasive across the world and because of its significant influence on the regional and global water budgets. In this article, irrigation is used as an example of a human-engineered, often unmodeled land surface process, and the utility of satellite soil moisture retrievals over irrigated areas in the continental US is examined. Such retrievals are based on passive or active microwave observations from the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E), the Advanced Microwave Scanning Radiometer 2 (AMSR2), the Soil Moisture Ocean Salinity (SMOS) mission, WindSat and the Advanced Scatterometer (ASCAT). The analysis suggests that the skill of these retrievals for representing irrigation effects is mixed, with ASCAT-based products somewhat more skillful than SMOS and AMSR2 products. The article then examines the suitability of typical bias correction strategies in current land data assimilation systems when unmodeled processes dominate the bias between the model and the observations. Using a suite of synthetic experiments that includes bias correction strategies such as quantile mapping and trained forward modeling, it is demonstrated that the bias correction practices lead to the exclusion of the signals from unmodeled processes, if these processes are the major source of the biases. It is further shown that new methods are needed to preserve the observational information about unmodeled processes during data assimilation.

land data↗

Session on coupled land surface/hydrological/atmospheric models

The current model capabilities in the context of land surface interactions with the atmosphere include only one-dimensional characteristics of vegetation and soil surface heat, moisture, momentum, and selected other trace gas fluxes (e.g., CO2). The influence of spatially coherent fluxes that result from landscape heterogeneity were not included. Valuable representations of several aspects of the landscape pattern currently exist. These include digital elevation data and measures of the leaf area index (i.e., Normalized Difference Vegetation Index (NDVI) from Advanced Very High Resolution Radiometer (AVHRR) data). A major deficiency, however, is the lack of an ability to sample spatially representative shallow and (especially) deep soil moisture. Numerous mesoscale modeling and observed studies demonstrated the sensitivity of planetary boundary layer structure and deep convection to the magnitude of the surface moisture flux.

Pielke, Roger↗

Detection techniques for tenuous planetary atmospheres

The research for the development of new types of detectors for analysis of planetary atmospheres is summarized. Topics discussed include: corona discharge humidity detector, surface catalysis and exo-electron emission, and analysis of soil samples by means of exo-electron emission. A report on the exo-electron emission during heterogeneous catalysis is included.

Hoenig, S. A.↗

Automated Subpixel Snow Parameter Mapping with AVIRIS Data

We describe an automated algorithm (MEMSCAG) for mapping subpixel snow covered area (SCA) and snow grain size with AVIRIS data. The algorithm is based on the multiple endmember approach to spectral mixture analysis in which the spectral endmembers and the number of endmembers can vary on a pixel-by-pixel basis. This approach accounts for surface cover heterogeneity within a scene. The mixture analysis runs on endmembers from a spectral library of snow, vegetation, rock, soil, and lake ice spectra. Snow endmembers of varying grain size were produced with a radiative transfer model. All non-snow endmembers were collected with a portable field spectrometer. Mapping is performed through sequential 2-endmember, 3-endmember, and 4- endmember mixture model runs, each subject to constraints on RMS, residuals, fractions and priority. Grain size is determined by the grain size of the snow endmember used in the optimal mixture model. We apply MEMSCAG to AVIRIS data collected over Mammoth Mountain, CA and the northern site of the BOREAS in Manitoba, Canada. MEMSCAG produces appropriate snow covered area estimates in all regions. A preliminary comparison of grain size estimates from MEMSCAG with field measurements demonstrates high accuracy.

Painter, Thomas H.↗

Indigenous Carbon Embedded in Apollo 17 Black Volcanic Glass Surface Deposits

The assessment of indigenous organic matter in returned lunar samples was one of the primary scientific goals of the Apollo program. The levels of such organic material were expected to be and found to be small. Previous work on this topic includes Murphy et al. [1] who reported the presence of anthropogenic organics with sub-ppm concentrations in Apollo 11 fines. In Apollo 12 samples, Preti et al. [2] detected low levels, < 10 ppb or below, of more complex organic material that may have been synthesized by abrupt heating during analysis. Kvenvolden et al. [3] detected porphyrin-like pigments at the ng to pg level in an Apollo 11 bulk sample. Hodgson et al. [4] and Ponnamperuma et al. [5] suggested that most if not all porphyrins were synthesized from rocket fuel during module landing. Chang et al. [6] reported indigenous carbon ranging from 5-20 g/g in the form of metal carbides in Apollo 11 fines. Hare et al. [7] reported amino acids at he 50 ng/g level in Apollo 11 samples but suggested the results may be explained as contamination. More recently, Clemett et al. [8] reported simple polycyclic aromatic hydrocarbons at concentrations of < 1ppm in an Apollo 16 soil. Low concentrations of lunar organics may be a consequence not only of its paucity, but also its heterogeneous distribution. If the sample size required for a measurement is large relative to the localization of organics, detection is limited not by ultimate sensitivity but rather by the ability to distinguish an indigenous signature from background contamination [9].

Thomas-Keprta, Kathie L.↗

Assessment of landscape-scale fluxes of carbon dioxide and methane in subtropical coastal wetlands of South Florida

Coastal wetlands play a significant role in the storage of “blue carbon,” indicating their importance in the carbon biogeochemistry in the coastal zone and in global climate change mitigation strategies. We present airborne eddy covariance observations of CO 2 and CH 2 fluxes collected in southern Florida as part of the NASA BlueFlux mission during April 2022, October 2022, February 2023, and April 2023. The flux data generated from this mission consists of over 100 flight hours and more than 6,000 km of horizontal distance over coastal saline and freshwater wetlands. We find that the spatial and temporal heterogeneity in CO 2 and CH 2 exchange is primarily influenced by season, vegetation type, ecosystem productivity, and soil inundation. The largest CO 2 uptake fluxes of more than 20 μmol m -2 s -1 were observed over mangroves during all deployments and over swamp forests during flights in April. The greatest CH 4 effluxes of more than 250 nmol m -2 s -1 were measured at the end of the wet season in October 2022 over freshwater marshes and swamp shrublands. Although the combined Everglades National Park and Big Cypress National Preserve region was a net sink for carbon, CH 4 emissions reduced the ecosystem carbon uptake capacity (net CO 2 exchange rates) by 11%–91%. Average total net carbon exchange rates during the flight periods were −4 to −0.2 g CO 2 -eq m -2 d -1 . Our results highlight the importance of preserving mangrove forests and point to potential avenues of further research for greenhouse gas mitigation strategies.

atmosphere↗

Conceptual aspects of a statistical-dynamical approach to represent landscape subgrid-scale heterogeneities in atmospheric models

A parameterization of land surfaces based on a statistical-dynamical approach is presented. With this approach, the most important characteristics of the soil-plant-atmosphere system that affect the partition of energy (e.g., plant stomatal conductance, soil humidity, and surface roughness) are represented by a pdf rather than by a single 'representative' value. A primary simplified version of this parameterization is used to estimate the land-surface energy fluxes that are produced at the grid scale by various distributions of stomatal conductance under a broad range of environmental conditions. To demonstrate the approach's potential, results are compared with the same fluxes calculated with a big leaf model using the mean stomatal conductance that corresponds to the distributions. Large absolute and relative differences are obtained between the two schemes for many combinations of stomatal conductance pdfs and environmental conditions.

Avissar, Roni↗

Relationships between vegetation indices, radiation absorption, and net photosynthesis evaluated by a sensitivity analysis

A two-stream approximation to the radiative-transfer equation is used to calculate the vegetation indices (simple ratio and normalized difference), the fraction of incident photosynthetically active radiation (PAR) absorbed by the canopy, and the daily mean canopy net photosynthesis under clear-sky conditions. The model calculations are tested against field observations over wheat, cotton, corn, and soybean. The relationships between the vegetation indices and radiation absorption or net photosynthesis are generally found to be curvilinear, and changes in the soil reflectance affected these relationships. The curvilinearity of the relationship between normalized differences and PAR absorption decreases as the magnitude of soil reflectance increases. The vegetation indices might provide the fractional radiation absorption with some a priori knowledge about soil reflectance. The relationship between the vegetation indices and net photosynthesis must be distinguished for C3 and C4 crops. Effects of spatial heterogeneity are discussed.

Choudhury, Bhaskar J.↗

Systematic Relationships Between Lidar Observables and Sizes And Mineral Composition Of Dust Aerosols

The physical and chemical properties of soil dust aerosol particles fundamentally affect their interaction with climate, including shortwave absorption and radiative forcing, nucleation of cloud droplets and ice crystals, heterogeneous formation of sulfates and nitrates on the surface of dust particles, and atmospheric processing of iron into bioavailable forms that increase the productivity of marine phytoplankton. Lidar measurements, such as extinction-to-backscatter, color and depolarization ratios, are frequently used to distinguish between aerosol types with different physical and chemical properties. The chemical composition of aerosol particles determines their complex refractive index, hence affecting their backscattering properties. Here we present a study on how dust aerosol backscattering and depolarization properties at wavelengths of 355, 532 and 1064 nm are related to size and complex refractive index, which varies with the mineral composition of the dust. Dust aerosols are represented by collections of spheroids with a range of prolate and oblate aspect ratios and their optical properties are obtained using T-matrix calculations. We find simple, systematic relationships between lidar observables and the dust size and complex refractive index that may aid the use of space-based or airborne lidars for direct retrieval of dust properties or for the evaluation of chemical transport models using forward simulated lidar variables. In addition, we present first results on the spatial variation of forward-simulated lidar variables based on a dust model that accounts for the atmospheric cycle of eight different mineral types plus internal mixtures of seven mineral types with iron oxides, which was recently implemented in the NASA GISS Earth System ModelE2.

Dust↗

Composition of the Cayley Formation at Apollo 16 as inferred from impact melt splashes

Abundances of major and trace elements and magnetic properties of 50 impact melt splashes (IMSs) from the Apollo 16 landing site are analzyed to determine the composition of their meteoritic component. MgO-Sc and Ca-Sc variation diagrams and least-squares mixing models are utilized to analyze the IMS, soil, and rock data. Consideration is given to progenitor lithologies of the IMS, the number of impact events represented by the IMS, and the heterogeneity of impact melts from single events. It is observed that the IMSs are composed of either a mixture of anorthosite and low-Sc impact melt rocks or anorthositic norite. It is determined that the surface Cayley layer is composed of TiO2, MgO, Sc, and La concentrations of 0.69, and 7.1 wt pct and 10.5 and 21.2 microg/g, respectively and 0.38 and 5.9 wt pct and 6.1 and 11.8 microg/g, respectively, for the subsurface Cayley layer. The Descartes Formation composition is estimated as TiO2, MgO, Sc, and La concentrations of 0.25, and 3.5 wt pct and 7.7 and 2.2 microg/g, respectively.

Morris, Richard V.↗

Simulating fluxes from heterogeneous land surfaces: Explicit subgrid method employing the biosphere-atmosphere transfer scheme (BATS)

A vectorized version of the biosphere-atmosphere transfer scheme (VBATS) is used to study moisture, energy, and momentum fluxes from heterogeneous land surfaces st the scale of an atmospheric model (AM) grid cells. To incorporate subgrid scale inhomogeneity, VBATS includes two important features: (1) characterization of the land surface (vegetation and soil parameters) at N subgrid points within an AM grid cell and (2) explicit distribution of climate forcing (precipitation, clouds, etc.) over the subgrid. In this study, VBATS is used in stand-alone mode to simulate a single AM grid cell and to evaluate the effects of subgrid scale vegetation and climate specification on the surface fluxes and hydrology. It is found that the partitioning of energy can be affected by up to 30%, runoff by 50%, and surface stress in excess of 60%. Distributing climate forcing over the AM grid cell increases the Bowen ratio, as a result of enhanced sensible heat flux and reduced latent heat flux. The combined effect of heterogeneous vegetation and distribution of climate is found to be dependent on the dominat vegetation class in the AM grid cell. Development of this method is part of a larger program to explore the importance of subgrid scale processes in regional and global climate simulations.

Seth, Anji↗

Considering Combined or Separated Roughness and Vegetation Effects in Soil Moisture Retrievals

For more than six years, the Soil Moisture and Ocean Salinity (SMOS) mission has provided multi angular and full-polarization brightness temperature (TB) measurements at L-band. Geophysical products such as soil moisture (SM) and vegetation optical depth at nadir (tau(sub nad)) are retrieved by an operational algorithm using TB observations at different angles of incidence and polarizations. However, the quality of the retrievals depends on several surface effects, such as vegetation, soil roughness and texture, etc. In the microwave forward emission model used in the retrievals (L-band Microwave Emission Model, L-MEB),soil roughness is modeled with a semi-empirical equation using four main parameters (Q(sub r), H(sub r), N(sub rp), with p = H or V polarizations). At present, these parameters are calibrated with data provided by airborne studies and in situ measurements made at a local scale that is not necessarily representative of the large SMOS footprints (43 km on average) at global scale. In this study, we evaluate the impact of the calibrated values of N(sub rp) and H(sub r) on the SM and tau(sub nad) retrievals based on SMOS TB measurements (SMOS Level 3 product) over the Soil Climate Analysis Network (SCAN) network located in North America over five years (2011-2015). In this study, Qr was set equal to zero and we assumed that N(sub rH)= N(sub rV). The retrievals were performed by varying N(sub rp) from −1 to 2 by steps of 1 and H(sub r) from 0 to 0.6 by steps of 0.1. At satellite scale, the results show that combining vegetation and roughness effects in a single parameter provides the best results in terms of soil moisture retrievals, as evaluated against the in situ SM data. Even though our retrieval approach was very simplified, as we did not account for pixel heterogeneity, the accuracy we obtained in the SM retrievals was almost systematically better than those of the Level 3 product. Improved results were also obtained in terms of optical depth retrievals. These new results may have key consequences in terms of calibration of roughness effects within the algorithms of the SMOS (ESA) and the SMAP (NASA) space missions.

full-polarization↗

Influences of Solar Irradiation and Aerosol Surface Area on Nitrous Acid Production in Western U.S. Wildfire Smoke

Biomass burning has been identified as a primary emission source for a host of gas and aerosol phase compounds which can damage environmental and human health. During FIREX-AQ collaborators from UNH, NASA Langley Aerosol Research Group Experiment (LARGE), and Brown University conducted measurements out of NASA Langley’s mobile laboratory during July and August of 2019. Nitrous acid (HONO) and nitric acid (HNO3) concentrations were measured at nominal 5-minute resolution using a dual mist chamber-ion chromatograph system resulting in approximately 1,200 total samples from five separate fires in the western US. Enhancement ratios between PM2.5 and carbon monoxide were used to discriminate between young and aged smoke plumes. Average HONO concentrations were significantly higher (P << 0.01) in young daytime compared to nighttime smoke while no statistical differences (P > 0.05) were observed between young and aged smoke during day or night. In daytime smoke from the Williams Flats fire (75 km SE of Spokane, WA on the Columbia River) UV-A irradiation was highly correlated with HONO to nitrogen dioxide (NO2) ratios; indicating that heterogenous NO2 to HONO conversion more than compensated for rapid photolytic loss of HONO. Black carbon (BC) may serve as a stable proxy for total available aerosol surface area in biomass burning plumes when total aerosol size distributions are unavailable. During the day HONO/NO2 is weakly correlated to BC when BC abundance exceeds 1 ug/m3 but at lower BC concentrations the relationship breaks down. At night this relationship was stronger, partly due to consistently high BC concentrations. These observations suggest that heterogenous conversion of NO2 to HONO on aerosol is a significant source of HONO in dense smoke plumes. In more diffuse smoke conversion on other surfaces (soil, foliage) becomes more important.

J. H. Kaspari↗

Martian spectral units derived from ISM imaging spectrometer data

Based on results of the Viking mission, the soil layer of Mars has been thought to be fairly homogeneous and to consist of a mixture of as few as two components, a 'dark gray' basaltic material and a 'bright red' altered material. However, near-infrared reflectance spectra measured recently both telescopically and from spacecraft indicate compositional heterogeneity beyond what can be explained by just two components. In particular, data from the ISM imaging spectrometer, which observed much of the equatorial region at a spatial resolution of approximately 22 km, indicate spatial differences in the presence and abundance of Fe-containing phases, hydroxylated silicates, and H2O. The ISM data was used to define, characterize, and map soil 'units' based on their spectral properties. The spatial distribution of these 'units' were compared to morphologic, visible color, and thermal inertia features recognized in Viking data.

Murchie, S.↗