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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Catalyst Substrates Remove Contaminants, Produce Fuel

A spacecraft is the ultimate tight building. We don t want any leaks, and there is very little fresh air coming in, says Jay Perry, an aerospace engineer at Marshall Space Flight Center. As a result, there is a huge potential for a buildup of contaminants from a host of sources. Inside a spacecraft, contaminants can be introduced from the materials that make spacecraft components, electronics boxes, or activities by the crew such as food preparation or cleaning. Humans also generate contaminants by breathing and through the body s natural metabolic processes. As part of the sophisticated Environmental Control and Life Support System on the International Space Station (ISS), a trace contaminant control system removes carbon dioxide and other impurities from the cabin atmosphere. To maintain healthy levels, the system uses adsorbent media to filter chemical contaminant molecules and a high-temperature catalytic oxidizer to change the chemical structure of the contaminants to something more benign, usually carbon dioxide and water. In the 1990s, while researching air quality control technology for extended spaceflight travel, Perry and others at Marshall were looking for a regenerable process for the continuous removal of carbon dioxide and trace chemical contaminants on long-duration manned space flights. At the time, the existing technology used on U.S. spacecraft could only be used once, which meant that a spacecraft had to carry additional spare parts for use in case the first one was depleted, or the spacecraft would have to return to Earth to exchange the components.

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A robotically constructed production and supply base on Phobos

PHOBIA Corporation is involved with the design of a man-tenable robotically constructed, bootstrap base on Mars' moon, Phobos. This base will be a pit-stop for future manned missions to Mars and beyond and will be a control facility during the robotic construction of a Martian base. An introduction is given to the concepts and the ground rules followed during the design process. Details of a base design and its location are given along with information about some of the subsystems. Since a major purpose of the base is to supply fuel to spacecraft so they can limit their fuel mass, mining and production systems are discussed. Surface support activities such as docks, anchors, and surface transportation systems are detailed. Several power supplies for the base are investigated and include fuel cells and a nuclear reactor. Tasks for the robots are defined along with descriptions of the robots capable of completing the tasks. Finally, failure modes for the entire PHOBIA Corporation design are presented along with an effects analysis and preventative recommendations.

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A Direct Method for Fuel Optimal Maneuvers of Distributed Spacecraft in Multiple Flight Regimes

We present a method to solve the impulsive minimum fuel maneuver problem for a distributed set of spacecraft. We develop the method assuming a non-linear dynamics model and parameterize the problem to allow the method to be applicable to multiple flight regimes including low-Earth orbits, highly-elliptic orbits (HEO), Lagrange point orbits, and interplanetary trajectories. Furthermore, the approach is not limited by the inter-spacecraft separation distances and is applicable to both small formations as well as large constellations. Semianalytical derivatives are derived for the changes in the total AV with respect to changes in the independent variables. We also apply a set of constraints to ensure that the fuel expenditure is equalized over the spacecraft in formation. We conclude with several examples and present optimal maneuver sequences for both a HE0 and libration point formation.

Hughes, Steven P.↗

Biological effects of fuel and exhaust components from spacecraft descent engines employing hydrazine

The effect of the products of the Viking terminal descent engine fuel upon possible extraterrestrial life at the Martian landing site is examined. The effects of the engine exhaust, the hydrazine fuel, and the breakdown products of the latter on terrestrial microorganisms have been studied. The results indicate that the gaseous exhaust products would probably not be hazardous to microorganisms, but that liquid hydrazine would be lethal.

Lehwalt, M. E.↗

Solid Fuel Ignition and Extinction (SoFIE) Project on ISS

The Solid Fuel Ignition and Extinction (SoFIE) project studies ignition and flammability of solid spacecraft materials (fuels) in practical geometries and realistic atmospheric conditions. It is an experiment insert designed for use within the existing Combustion Integrated Rack (CIR). The CIR chamber provides a level of containment and permits testing at variable oxygen concentrations and pressures representative of current and planned NASA Space Exploration Atmospheres. The applications of SoFIE include: (1) Determining safer selection of cabin materials and validating NASA materials flammability selection using 1-g test protocols for low-gravity fires, (2) Improving understanding of early fire growth behavior, (3) Validating material flammability numerical models, (4) Determining optimal suppression techniques for burning materials by diluents, flow reduction, and venting, (5) Obtaining burning behavior of actual engineering materials planned for spacecraft, (6) Developing corresponding models of microgravity flame spread, flammability, and extinction, and use the results to improve normal gravity combustion models for terrestrial applications. The hardware permits a wide range of solid-material combustion and fire suppression studies. It supports multiple investigations using common infrastructure including sample holders, flow control, test sections, external radiant heaters, igniters, and diagnostics. SoFIE has been developed to meet the requirements of five unique investigations. It is currently being built and slated to begin operations on the ISS in July 2021. Given the general capabilities of the hardware insert, it is intended to be used as a facility for future researchers who can propose to NASA for related solid combustion studies.

Ferkul, Paul↗

Analysis and Test of a Proton Exchange Membrane Fuel Cell Power System for Space Power Applications

An effort is underway to develop a prototype Proton Exchange Membrane (PEM) Fuel Cell breadboard system for fuhlre space applications. This prototype will be used to develop a comprehensive design basis for a space-rated PEM fuel cell powerplant. The prototype system includes reactant pressure regulators, ejector-based reactant pumps, a 4-kW fuel cell stack and cooling system, and a passive, membranebased oxygen / water separator. A computer model is being developed concurrently to analytically predict fluid flow in the oxidant reactant system. Fuel cells have historically played an important role in human-rated spacecraft. The Gemini and Apollo spacecraft used fuel cells for vehicle electrical power. The Space Shuttle currently uses three Alkaline Fuel Cell Powerplants (AFCP) to generate all of the vehicle's 15-20kW electrical power. Engineers at the Johnson Space Center have leveraged off the development effort ongoing in the commercial arena to develop PEM fuel cel ls for terrestrial uses. The prototype design originated from efforts to develop a PEM fuel cell replacement for the current Space Shuttle AFCP' s. In order to improve on the life and an already excellent hi storical record of reliability and safety, three subsystems were focused on. These were the fuel cell stack itself, the reactant circulation devices, and reactant / product water separator. PEM fuel cell stack performance is already demonstrating the potential for greater than four times the useful life of the current Shuttle's AFCP. Reactant pumping for product water removal has historically been accomplished with mechanical pumps. Ejectors offer an effective means of reactant pumping as well as the potential for weight reduction, control simplification, and long life. Centrifugal water separation is used on the current AFCP. A passive, membrane-based water separator offers compatibility with the micro-gravity environment of space, and the potential for control simplification, elimination of moving parts in an oxygen environment, and long life. The prototype system has been assembled from components that have previously been tested and evaluated at the component level. Preliminary data obtained from tests performed with the prototype system, as well as other published data, has been used to validate the analytical component models. These components have been incorporated into an integrated oxidant fluid system model. Results obtained from both the performance tests and the analytical model are presented.

Vasquez, Arturo↗

Hydrophobicity of Cryogenic Fluids for Fuel Transfer in Space Applicaitons

Introduction Hydrophobicity is the tendency of a fluid to repel another material or fluid. Hydrophobiciy can be measured through the wetting angle of the fluid on the surface of the other material. The greater the wetting angle, the more hydrophobic the surface is against the fluid. Hydrophobicity properties can be caused by one of two means, either through physical properties or chemical properties [\citenum{NARBUTT2020121}]. Physical hydrophobicity due to the surface of a solid creating surface roughness/patterning, minimizing the contact area between the fluid and the surface. This can be observed throughout nature, such as the surface of lotus leaves or butterfly wings. This physical property can be induced on a variety of surfaces, namely through laser etching, allowing a surface to be finely lineated to imitate these natural surfaces while controlling quantity, depth, and patterns of the etching on the surface [\citenum{10.1063/1.4905616}]. Physical hydrophobicity is therefore dependent on several variables, including the surface that the fluid is on and properties of the fluid itself, such as density and surface tension, both of which are dependent on temperature and/or pressure. Chemical hydrophobicity [\citenum{MadeiraHydrophobocicicici}] is due to the inherent chemical properties of the materials being used. This is most commonly due to the molecular structures changing the polarity of the materials. Depending on a nonpolar material will repel a polar material, proving to be hydrophobic, conversely if the polarity of the materials is the same (polar – polar, nonpolar – nonpolar), they will attract each other. Cryogenics refers to the behavior of materials at very low temperatures (<\ang{-100} C) [\citenum{ZOHURI20181}]. In space applications many things are inherently cryogenic, therefore this is an important field. There has been little research in how hydrophobicity changes at cryogenic temperatures. Cryogenic fluids are commonly used as fuels for spacecraft, therefore, integrating a hydrophobic surface can increase the transfer rate of the fuel. To test this, several experiments were set up to determine the hydrophobic properties of cryogenic fluids, including nitrogen (LN2), argon (LAr), oxygen (LOx), hydrogen (LH2), and methane (CH4), at cryogenic temperatures. Etched Wafer Testing A silicon wafer cut from a crystal of silicon [100] was used to model the potential hydrophobicity of various cryogenic fluids. Silicon [100] references to the crystallographic orientation of the silicon crystals in the wafer. These wafers were then laser etched to create a surface that is more likely to be hydrophobic. To test the hydrophobicity of the wafers at cryogenic temperatures, the temperatures of the wafers must be reduced to the same temperature as the cryogenic fluid being used to prevent rapid boil-off. To achieve this a double-walled vacuum insulated glass chamber was utilized. The chamber is open, with a double-walled glass that can be placed in a vacuum to remove condensation from the outside to allow easier viewing of the experiment. Furthermore, the silicon wafer's temperature must be lowered to the temperature of LN2, as well as maintain the temperature throughout the experiment. To achieve this a piece of 6061 aluminum was used, creating a stand-off for the wafer and it would allow for the insulation of the temperature of the wafers. The container was then filled with LN2 and once the LN2 stabilized the vaporization and the levels of LN2 dropped under the height of the wafer, the wafer was then allowed to air dry. Once the wafer was dry from the LN2, drops of LN2 were placed on the surface of the wafer for observation. During the first trial, the LN2 that was dropped on the surface displayed nonhydrophobic behaviors, spreading out along the surface, with a minimal wetting angle (too small to be measured). This process was repeated for liquid argon. Further testing with other cryogenic liquids will require different testing apparatuses due to being more volatile. Furthermore, several papers [\citenum{voltvolt7}] have suggested that running a voltage can induce a hydrophobic effect throughout a surface, further testing will include a voltage (constant and oscillating) to determine if voltage influences inducing hydrophobicity at cryogenic temperatures. Chemical Testing Coating the interior walls of the fuel tanks and fuel lines can successfully create a hydrophobic surface. The inherent problem is finding a material that can be used to coat the surface, furthermore, at these temperatures, the coating will remain solid, which could pose issues in maintaining the hydrophobic properties. To test this water (polar) is hydrophobic against oils and fats (nonpolar), therefore the same experiment as the etched wafer testing was conducted to determine if the hydrophobic properties will persist as the nonpolar material remains solid and the polar material remains a fluid. The water remained hydrophobic, allowing testing can expand to the cryogenic fluids. However, another hurdle is faced in finding a chemically opposite material to the cryogenic fluids being tested. As many of the cryogenic fluids being tested are diatomic, they are inherently nonpolar, therefore, the material used for the hydrophobic coating must be polar. Polar greases and lubricants are difficult to come by, however, lithium stearate, appears to be a potential candidate for creating a coated hydrophobic surface for cryogenic fluids at cryogenic temperatures.

Cryogenics↗

Fuel optimal propulsive reboost of flexible spacecraft

This paper presents for the first time an exact solution to the fuel optimal propulsive reboost problem for flexible spacecraft. The spacecraft undergoes rigid-body motion and flexible-body motion and reboost is achieved propulsively through the use of reaction control jets. The exact fuel optimal solution to the associated minimization problem is found numerically based on an adaptive grid bisection search. The reboost of the floating harmonic oscillator reveals properties of the fuel optimal solution. Nondimensional plots of minimum fuel versus maneuver time expose the nature of the solution classes depending on the maneuver time. Some very interesting properties are observed, among them, the shifting of impulses to the smaller oscillator mass, and comparisons are made with near fuel optimal solutions obtained by other investigators.

Silverberg, Larry↗

A Common Habitat Deep Space Exploration Vehicle for Transit and Orbital Operations

When outfitted as a habitat, the SLS Core Stage Liquid Oxygen Tank is a pressure vessel that can be used to support human exploration in deep space. An exploration spacecraft can be constructed with this habitat, known as the Common Habitat, as its central element. More than just a transit vehicle, this spacecraft is a Deep Space Exploration Vehicle – a microgravity science laboratory capable of conducting research with onboard human crews throughout the inner solar system. Supplied with propellant by LEO depots, preliminary trajectory and v estimates indicate that the spacecraft can perform fly-by or orbital missions with trajectories close enough to the sun to intersect the orbit of Mercury or far enough away to fly by the main belt asteroid Vesta. Its primary mission, however, is to support human expeditions to Mars. Many, though not all, of the pressurized and unpressurized elements that compose the Deep Space Exploration Vehicle can also be used in surface base camps on the Moon and Mars. In additional to traditional space science disciplines, the spacecraft offers unique potential for small asteroid retrieval and for artificial gravity research. Three launches are used to deploy the spacecraft, but thirty-nine launches are used to deliver propellant to orbit to fully fuel the spacecraft for deep space missions. Key operations in a Mars crewed mission are described to illustrate how the vehicle is used and forward work is listed to mature the spacecraft concept.

Robert L. Howard Jr.↗

Fuel cell powerplant operation in Apollo spacecraft.

Primary electrical power for loads in the Apollo Command and Service Modules is furnished by a system of three fuel cell powerplants. The powerplants convert cryogenic hydrogen and oxygen into direct current. Water formed in the fuel cell reactions is supplied to the spacecraft for crew use. Waste heat is rejected through a coolant loop to a spacecraft radiator. The ability of the fuel cell to meet its voltage-power requirements and to control its own operating temperature under the environmental extremes of launch, ascent, earth orbit, translunar flight, and lunar orbit was demonstrated on successively more difficult missions leading up to the first lunar landing.

Ching, A. C.↗

The Development of Fuel Cell Technology for Electric Power Generation - From Spacecraft Applications to the Hydrogen Economy

The fuel cell uses a catalyzed reaction between a fuel and an oxidizer to directly produce electricity. Its high theoretical efficiency and low temperature operation made it a subject of much study upon its invention ca. 1900, but its relatively high life cycle costs kept it as "solution in search of a problem" for its first half century. The first problem for which fuel cells presented a cost effective solution was, starting in the 1960's that of a power source for NASA's manned spacecraft. NASA thus invested, and continues to invest, in the development of fuel cell power plants for this application. However, starting in the mid-1990's, prospective environmental regulations have driven increased governmental and industrial interest in "green power" and the "Hydrogen Economy." This has in turn stimulated greatly increased investment in fuel cell development for a variety of terrestrial applications. This investment is bringing about notable advances in fuel cell technology, but these advances are often in directions quite different from those needed for NASA spacecraft applications. This environment thus presents both opportunities and challenges for NASA's manned space program.

Scott, John H.↗