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At least 73 records · Page 4

Methods for stabilizing perovskites

The present disclosure relates to a composition that includes a material of at least one of a perovskite structure, a perovskite-like structure, and/or a perovskitoid structure, where the material includes an isotope of an element, the isotope has more neutrons than protons, and the isotope is incorporated into the perovskite structure, the perovskite-like structure, and/or the perovskitoid structure. In some embodiments of the present disclosure, the isotope may make up between greater than 0% and 100% of the element.

Zhu, Kai↗

Compositions and methods for stabilizing perovskite interfaces

The present disclosure relates to a composition that includes a first layer that includes a perovskite defined by ABX 3 and a second layer that includes a perovskite-like material defined by at least one of A′ 2 B′X′ 4 , A′ 3 B′ 2 X′ 9 , A′B′X′ 4 , A′ 2 B′X′ 6 , and/or A′ 2 AB′ 2 X′ 7 , where the first layer is adjacent to the second layer, A is a first cation, B is a second cation, X is a first anion, A′ is a third cation, B′ is a fourth cation, X′ is a second anion, and A′ is different than A.

Palmstrom, Axel Finn↗

Comparison of several methods for estimating low speed stability derivatives

Methods presented in five different publications have been used to estimate the low-speed stability derivatives of two unpowered airplane configurations. One configuration had unswept lifting surfaces, the other configuration was the D-558-II swept-wing research airplane. The results of the computations were compared with each other, with existing wind-tunnel data, and with flight-test data for the D-558-II configuration to assess the relative merits of the methods for estimating derivatives. The results of the study indicated that, in general, for low subsonic speeds, no one text appeared consistently better for estimating all derivatives.

Fletcher, H. S.↗

Magnets with stabilized conductors

Method fabricates stabilized composite conductor, for use in construction of magnets, using equal amounts of superconducting and metal materials, thus reducing weight, cost and size.

Jones, C. K.↗

Review of computational approaches to predict the thermodynamic stability of inorganic solids

Improvements in the efficiency and availability of quantum chemistry codes, supercomputing centers, and open materials databases have transformed the accessibility of computational materials design approaches. Thermodynamic stability predictions play a central role in the efficacy of these approaches and should be considered carefully. This review covers the fundamentals of calculating thermodynamic stability using first-principles methods. Stability is delineated into two main topics — stability with respect to decomposition into competing phases and stability with respect to phase transition into alternative structures at fixed composition. For each topic, a summary of the state-of-the-art is provided along with a tutorial overview of practical considerations. The application of machine learning to both kinds of stability predictions is also covered. Finally, the limitations of thermodynamic stability predictions are discussed within the context of predicting the synthesizability of materials.

36 MATERIALS SCIENCE↗

Experimental transition and boundary-layer stability analysis for a slotted swept laminar flow control airfoil

A swept, supercritical laminar flow control (LFC) airfoil designated NASA SCLFC(1)-0513F was tested at subsonic and transonic speeds in the NASA Langley eight-foot Transonic Pressure Tunnel. This paper examines Tollmien-Schlichting and crossflow disturbance amplification for this airfoil using the linear stability method. The design methodology using linear stability analysis is evaluated and the results of the incompressible and compressible methods are compared. Experimental data on the swept, supercritical LFC airfoil and reference wind tunnel and flight results are used to correlate and evaluate the N-factor method for transition prediction over a speed range M(infinity) from zero to one.

Harvey, William D.↗

Energy-Casimir, dynamically accessible, and Lagrangian stability of extended magnetohydrodynamic equilibria

The formal stability analysis of Eulerian extended magnetohydrodynamics (XMHD) equilibria is considered within the noncanonical Hamiltonian framework by means of the energy-Casimir variational principle and the dynamically accessible stability method. Specifically, we find explicit sufficient stability conditions for axisymmetric XMHD and Hall MHD (HMHD) equilibria with toroidal flow and for equilibria with arbitrary flow under constrained perturbations. The dynamically accessible, second-order variation of the Hamiltonian, which can potentially provide explicit stability criteria for generic equilibria, is also obtained. Moreover, we examine the Lagrangian stability of the general quasineutral two-fluid model written in terms of MHD-like variables, by finding the action and the Hamiltonian functionals of the linearized dynamics, working within a mixed Lagrangian-Eulerian framework. Upon neglecting electron mass, we derive a HMHD energy principle, and in addition, the perturbed induction equation arises from Hamilton’s equations of motion in view of a consistency condition for the relation between the perturbed magnetic potential and the canonical variables.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Stability of a dual-spin spacecraft with spherical dampers

The present investigation is concerned with the stability characteristics of a specific dual-spin satellite configuration marked by a high degree of symmetry. The configuration includes a platform and a rotor. Both components contain arbitrarily located internal spherical dampers. The symmetry of the system configuration makes it possible to illustrate clearly the relationship between Routhian analysis, energy sink analysis, and digital simulation of the full nonlinear equations. Although the dual-spin spacecraft configuration contains energy dissipating devices on both platform and rotor, it is still possible to employ the rigorous, but relatively simple, Routh stability method. This method, unlike Floquet theory, has the potential of producing closed-form stability criteria. The energy sink method is capable of providing a closed-form stability criterion. Numerical simulation is a necessary requirement in the latter stages of design when the realistic perturbation environment must be considered.

Laskin, R. A.↗

High-Fidelity, Low-Dissipation/Symmetry-Preserving Numerical Scheme for Solving the Euler Equations with Unstructured, Metric-Based Mesh Adaptation

This work presents an overview of a high-fidelity compressible Euler solver that utilizes the continuous Galerkin (CG) method with added artificial numerical diffusion for stabilization to solve a variety of unsteady and steady benchmark inviscid flow problems. This work shows that discretizing the Euler equations with this CG approach and first order basis functions produces a cost-effective stencil as well as simple well-posed boundary conditions. We show through convergence testing with manufactured solutions that the reduced stencil of CG, combined with the low amount of artificial diffusion required when using the stabilization method outlined in this work, leads to stable and highly accurate results for a variety of unsteady and steady applications. When combined with the adaptive mesh refinement approach used for many of the cases in this work, our results show that the flow solver achieves even more accurate results. A variety of inviscid flow cases are presented in this work, including transient 2D cases with complex shock structures and several steady 3D airfoils sections with a constant span.

Doetsch, Kevin [ORNL] (ORCID:0000000267051705)↗

Impact of solvation on the electronic resonances in uracil

Interactions of low-energy electrons with the DNA and RNA nucleobases are known to form metastable states, known as electronic resonances. In this work, we study electron attachment to solvated uracil, an RNA nucleobase, using the orbital stabilization method at the Equation of Motion-Coupled Cluster for Electron Affinities with Singles and Doubles (EOM-EA-CCSD) level of theory with the Effective Fragment Potential (EFP) solvation method. We benchmarked the approach using multireference methods, as well as by comparing EFP and full quantum calculations. The impact of solvation on the first one particle (1p) shape resonance, formed by electron attachment to the π* LUMO orbital, as well as the first two particle one hole (2p1h) resonance, formed by electron attachment to neutral uracil's π–π* excited state, was investigated. We used molecular dynamics simulations for solvent configurations and applied charge stabilization technique-based biased sampling to procure configurations adequate to cover the entire range of the electron attachment energy distribution. The electron attachment energy in solution is found to be distributed over a wide range of energies, between 4.6 eV to 6.8 eV for the 2p1h resonance, and between −0.1 eV to 2 eV for the 1p resonance. The solvent effects were similar for the two resonances, indicating that the exact electron density of the state is not as important as the solvent configurations. Multireference calculations extended the findings showing that solvation effects are similar for the lowest four resonances, further indicating that the specific solute electron density is not as important, but rather the water configurations play the most important role in solvation effects. Lastly, by comparing bulk solvation to clusters of uracil with a few water molecules around it, we find that the impact of microsolvation is very different from that of bulk solvation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A comparison of two methods of extracting stability derivatives from flight test data

Two methods for extracting stability derivatives from flight data are compared. A modified Newton-Raphson quasilinearization minimization technique and a digital-analog (hybrid) matching technique were used to analyze the same data maneuvers obtained from two aircraft. About 70 maneuvers from an F-111E aircraft were analyzed over a Mach number range of 0.3 to 2.0 and an angle of attack range of 3 to 19 degrees. About 20 maneuvers were analyzed for the X-24A lifting body at Mach numbers of 0.5, 0.8, and 0.9, and an angle of attack range of 4 to 13 degrees. Stability derivatives were extracted from these maneuvers and the results from the two techniques, along with wind tunnel results, were compared.

Kirsten, P. W.↗

Methods of predicting helicopter stability

Some of the methods of predicting rotor stability derivatives have been reviewed. The methods by which these rotor derivatives are employed to estimate helicopter stability characteristics have been summarized. It is concluded that, although these methods are not always feasible for predicting absolute values of the stability of the helicopter, the effects on stability of changes in individual derivatives can generally be estimated satisfactorily.

Robert J Tapscott↗

System and method for determining stability of a neural system

Disclosed are methods, systems, and computer-readable media for determining stability of a neural system. The method includes tracking a function world line of an N element neural system within at least one behavioral space, determining whether the tracking function world line is approaching a psychological stability surface, and implementing a quantitative solution that corrects instability if the tracked function world line is approaching the psychological stability surface.

Curtis, Steven A.↗

Shape regulation of high-index facet nanoparticles by dealloying

Tetrahexahedral particles (~10 to ~500 nanometers) composed of platinum (Pt), palladium, rhodium, nickel, and cobalt, as well as a library of bimetallic compositions, were synthesized on silicon wafers and on catalytic supports by a ligand-free, solid-state reaction that used trace elements [antimony (Sb), bismuth (Bi), lead, or tellurium] to stabilize high-index facets. Both simulation and experiment confirmed that this method stabilized the {210} planes. A study of the PtSb system showed that the tetrahexahedron shape resulted from the evaporative removal of Sb from the initial alloy—a shape-regulating process fundamentally different from solution-phase, ligand-dependent processes. The current density at a fixed potential for the electro-oxidation of formic acid with a commercial Pt/carbon catalyst increased by a factor of 20 after transformation with Bi into tetrahexahedral particles.

Huang, Liliang (ORCID:0000000234740846)↗