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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

The Dominant Effect of Electrolyte Concentration on Rechargeability of γ -MnO 2 Cathodes in Alkaline Batteries

Achieving high cycle life rechargeableγ-MnO 2 cathodes in alkaline batteries face many challenges. Chief among these is the inability of theγ-MnO 2 polymorph to retain its structural integrity when cycled to high utilization of its theoretical capacity ∼300 mAh g −1 . In this paper, we investigate the root cause of failure of MnO 2 cathodes under deep cycling in the one-electron discharge range and establish a strong link between capacity fade and the amount of birnessite formed. We uncover the underlying cause of failure by cycling industrial scaleγ-MnO 2 cathodes at various levels of theoretical capacity utilization (100%, 50%, and 30%) and in different KOH concentrations (37, 25, and 10 wt%). To determine materials evolution the cycled cathodes were dissected, characterized and analyzed using SEM, XRD, FIB/SEM, EIS, and XPS. Based on our findings, we propose that one major cause of failure of MnO 2 cathodes stems from the solubility of Mn +3 formed during discharge which effectively results in destruction of theγ-MnO 2 phase and amorphization of the cathode. The results show that the bulk of theγ-MnO 2 phase is preserved only in ∼10 wt% KOH, which indicates the attractive range of KOH concentration for cycling of rechargeableγ-MnO 2 cathodes.

Electrochemistry↗
DOE OSTI2023

The QBO–MJO Connection: A Possible Role for the SST and ENSO

We examine the hypothesis that the observed connection between the stratospheric quasi-biennial oscillation (QBO) and the strength of the Madden–Julian oscillation (MJO) is modulated by the sea surface temperature (SST)—for example, by El Niño–Southern Oscillation (ENSO). A composite analysis shows that, globally, La Niña SSTs are remarkably similar to those that occur during the easterly phase of the QBO. A maximum covariance analysis suggests that MJO power and SST are strongly linked on both the ENSO time scale and the QBO time scale. We analyze simulations with a modified configuration of version 2 of the Community Earth System Model, with a high top and fine vertical resolution. The model is able to simulate ENSO, the QBO, and the MJO. The ocean-coupled version of the model simulates the QBO, ENSO, and MJO, but does not simulate the observed QBO–MJO connection. When driven with prescribed observed SST anomalies based on composites for QBO east and QBO west (QBOE and QBOW), however, the same atmospheric model produces a modest enhancement of MJO power during QBOE relative to QBOW, as observed. We explore the possibility that the SST anomalies are forced by the QBO itself. Indeed, composite Hovmöller diagrams based on observations show the propagation of QBO zonal wind anomalies all the way from the upper stratosphere to the surface. Also, subsurface ocean temperature composites reveal a similarity between the western Pacific and Indian Ocean subsurface signal between La Niña and QBOE.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Protecting Biodiversity through Forest Management: Lessons Learned and Strategies for Success

The strong links among biodiversity, forests, and climate change require that forces affecting them be addressed simultaneously. Here we summarize findings and lessons learned from decades of field work exploring ways to balance conservation with development, while effectively addressing drivers of deforestation and biodiversity loss. Examples are provided for approaches to forest management that support both biodiversity conservation and greenhouse gas mitigation. Causes of deforestation are reviewed and recommendations provided for specific steps that would slow the loss of high conservation-value forests.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Reduced Petroleum Use Through Easily Reformed Fuels and Dedicated Exhaust Gas Recirculation

This project was proposed to demonstrate a >25% reduction in petroleum usage for a light duty SI vehicle by synergistically combining the Dedicated EGR combustion system developed at SwRI with modified fuel formulations incoroporating biofuel components. Typically, a D-EGR engine yields a 10% gain in fuel efficiency relative to the base engine through a combination of improved thermodynamic efficiency from the EGR application and the significant increase in compression ratio realized through the knock reduction benefits of EGR and hydrogen addition. As the D-EGR performance is strongly linked to hydrogen production, the proposal team anticipated that gasoline formulation changes could enhance the hydrogen production rate relative to a conventional gasoline. This was expected to provide additional efficiency gains to the engine. The final step of incorporating biofuel components would then yield a final result meeting the >25% petroleum reduction target.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Differences In High Burnup Fuel Management Strategies to Minimize FFRD and Increase Economic Viability

The nuclear industry is pursuing approval of an increase in the length of the pressurized water reactor (PWR) cycle from 18 months to 24 months to reduce reactor downtime and enhance the economic competitiveness of nuclear energy. Such an increase in reactor cycle length will require that the maximum rod average burnup exceeds the current regulatory limit of 62 GWd/MTU, and it could peak at approximately 75 GWd/MTU, posing potential reactor safety and performance concerns. One such concern is that fuel fragmentation, relocation, and dispersal (FFRD) could occur during a severe loss-of coolant accident (LOCA) in which a fuel rod balloons and bursts, and pulverized fuel fragments are dispersed throughout the reactor’s primary coolant system. Previous analyses have identified which reactor operating conditions leave the core more susceptible to FFRD and have shown that FFRD susceptibility is strongly linked to fuel rod burnup and linear heat rate (LHR) history. The work described in this report uses an optimization strategy known as parallel simulated annealing (PSA) and a coarse mesh Purdue Advanced Reactor Core Simulator (PARCS) reactor physics model to develop two core fuel loading patterns, each with a different optimization objective. One core optimization maximized the core’s cycle length while still respecting regulatory limits on the radial peaking factor and soluble boron concentration with a peak rod average burnup of 75 GWd/MTU. The second optimization was aimed at minimizing FFRD susceptibility while still targeting a 24-month cycle length and respecting regulatory limits. PARCS model predictions were verified using the high-fidelity Virtual Environment for Reactor Applications (VERA). The two core designs were compared to highlight core design strategies to minimize FFRD susceptibility and to maximize economic viability.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

University of Dayton Industrial Assessment Center

The University of Dayton Industrial Assessment Center (UD-IAC) was established in 1981. Since then, the UD-IAC has completed 1,050 industrial energy assessments for the Department of Energy. The UD-IAC is committed to an ethic of continuous improvement, building upon the enormous knowledge and commitment it has developed over the past four decades and developing strong links to educational, research, and DOE initiatives. We feel lucky to be part of this great IAC program and pledge our best and most sustained efforts toward its continued success.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

Impacts of wind field characteristics and non-steady deterministic wind events on time-varying main-bearing loads

Abstract. This work considers the characteristics and drivers of the loads experienced by wind turbine main bearings. Simplified load response models of two different hub and main-bearing configurations are presented, representative of both inverting direct-drive and four-point-mounted geared drivetrains. The influences of deterministic wind field characteristics, such as wind speed, shear, yaw offset, and veer, on the bearing load patterns are then investigated for similarity scaled 5, 7.5, and 10 MW reference wind turbine models. Main-bearing load response in cases of deterministic gusts and extreme changes in wind direction are also considered for the 5 MW model. Perhaps surprisingly, veer is identified as an important driver of main-bearing load fluctuations. Upscaling results indicate that similar behaviour holds as turbines become larger, but with mean loads and load fluctuation levels increasing at least cubically with the turbine rotor radius. Strong links between turbine control and main-bearing load response are also observed.

17 WIND ENERGY↗
NASA NTRS1972

To evaluate ERTS-1 data for usefulness as a geological sensor in the diverse geological terranes of New York State

The author has identified the following significant results. In the present imagery, obtained during the full foliage of summer and fall, the greatest amount of spectral geology is displayed in the Adirondack region where bedrock geology is strongly linked to topography. Of the four spectral bands imaged, band 5 and 7 provide the most geological information. The boundary between the basement rocks of the Adirondack Dome and the surrounding Lower Paleozoic rocks is well delineated except in the Northwest Lowlands and along parts of the eastern Adirondacks. Within the basement complex, the most prominently displayed features are numerous north-northeast trending faults and topographic lineaments, and arcuate east-west valleys developed in some of the weaker metasedimentary rocks. The majority of the faults and lineaments shown on the geologic map of New York appear in the ERTS-1 imagery. In addition, many new linears were detected, as well as a number of anomalous curvilinear elements, some circular in plan and measuring up to 25 km in diameter, which do not bear any clear relationship to mapped geological contacts. The possibility that it is an astrobleme will be investigated after snow melts in the spring.

Isachsen, Y. W.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for geological sensing over the diverse geological terrains of New York State

Film positives of ERTS-1 imagery, both as received from NASA and photographically reprocessed, are analyzed by conventional and color additive viewing methods. The imagery reveals bedrock and surficial geological information at various scales. Features which can be identified to varying degrees include boundaries between major tectonic provinces, lithological contacts, foliation trends within massive gneisses, faults, and topographic lineaments. In the present imagery the greatest amount of spectral geology is displayed in the Adirondack region where bedrock geology is strongly linked to topography. Within this basement complex, the most prominantly displayed features are numerous north-northeast trending faults and topographic lineaments, and arcuate east-west valleys developed in some of the weaker metasedimentary rocks. The majority of the faults and lineaments shown on the geologic Map of New York at 1:250,000 appear in the ERTS imagery.

Isachsen, Y. W.↗
NASA NTRS1982

Cultural and environmental effects on the spectral development patterns of corn and soybeans: Field data analysis

An overall approach to crop spectral understanding is presented which serves to maintain a strong link between actual plant responses and characteristics and spectral observations from ground based and spaceborne sensors. A specific technique for evaluating field reflectance data, as a part of the overall approach, is also described. Results of the application of this technique to corn and soybeans reflectance data collected by and at Purdue/LARS indicate that a number of common cultural and environmental factors can significantly affect the temporal spectral development patterns of these crops in tasseled cap greenness (a transformed variable of LANDSAT MSS signals).

Crist, E. P.↗
NASA NTRS1984

Optical fibers and components experiment (A0138-7)

Fiber optics permanent damages induced by ionizing radiation after a long exposure in space and after laboratory tests were examined. Irradiation tests performed with radioactive sources (Sr90 - Y90) were validataed, computer coses used for the fluence and dose profile were verified. The performance of fiber optics waveguides in a low altitude orbit, and the origin of transmission losses in the material were dtermined. High sensitivity to ionizing radiations, however, may be a restriction for optic fiber use on satellites. Irradiation tests on these components using neutrons, gamma rays, and X-rays are carried out. Radiation damage on opticao materials, however, is strongly linked to the test conditions.

Bourrieau, J.↗
NASA NTRS1986

X-ray spectra of PG quasars. I - The continuum from X-rays to infrared

Einstein IPC X-ray spectra for a sample of eight optically selected quasars from the Palomar Bright Quasar survey are presented. The quasars have a mean power law energy slope which in five individual cases is inconsistent with the value found in hard X-ray selection criterion rather than luminosity, redshift, or U-B color. New IUE and optical continuum spectra and infrared photometry are presented for these quasars. The data are combined into log vf(v) and log v distributions which support the decomposition of the overall quasar spectrum into a power law plus a superposed optical-UV 'big bump' which may be due to an accretion disk. At least six of the quasars have vf(v)s which are roughly constant between their infrared and X-ray power laws, suggesting a strong link between the two regions.

Elvis, Martin↗
NASA NTRS1988

A diagnostic study of vertical fluxes in cumulus clouds using model output data

Midlatitude supercell, Florida sea-breeze convection, and tropical squall line simulations were performed using the Colorado State University Regional Atmospheric Modeling System which employed the non-hydrostatic, fully compressible, equations with parameterized microphysics. The time evolution of the vertical velocity variance (VVV) is especially interesting since it is a measure of the strength of convection. This variance exhibits striking similarities when analyzed for the aforementioned cases which may indicate that all convection is fundamentally similar. Vertical mass and moisture covariances appear strongly linked to VVV, so it may be the appropriate variable on which to base a hybrid cumulus parameterization scheme.

Weissbluth, M. J.↗
NASA NTRS1989

Influence of the annual cycle in meridional transport on the quasi-biennial oscillation in total ozone

The equatorial stratospheric quasi-biennial oscillation (QBO) in zonal wind and temperature is observed to be symmetric about the equator. The QBO in column ozone, although it is believed to be caused primarily by vertical displacements due to the meridional circulation associated with the equatorial temperature QBO, is asymmetric with respect to the equator, and is strongly linked to the phase of the annual cycle. In this note a simple one-layer model is used to demonstrate that the gross features of the observed QBO in total ozone can be attributed to meridional advection of the ozone perturbation by the annually reversing mean meridional Hadley circulation. This advection causes a displacement of the equatorial ozone anomaly toward the winter hemisphere, and thus produces an asymmetry with respect to the equator. It also modulates the amplitude of the ozone QBO, since the phase of the equatorial wind QBO with respect to the annual cycle may produce either constructive or destructive interference beween the effects of the annually reversing meridional transport and the vertical advection by the equatorial wind QBO.

Holton, James R.↗
NASA NTRS1993

Venus Interior Structure Mission (VISM): Establishing a Seismic Network on Venus

Magellan radar data show the surface of Venus to contain a wide range of geologic features (large volcanoes, extensive rift valleys, etc.). Although networks of interconnecting zones of deformation are identified, a system of spreading ridges and subduction zones like those that dominate the tectonic style of the Earth do not appear to be present. In addition, the absence of a mantle low-viscosity zone suggests a strong link between mantle dynamics and the surface. As a natural follow-on to the Magellan mission, establishing a network of seismometers on Venus will provide detailed quantitative information on the large scale interior structure of the planet. When analyzed in conjunction with image, gravity, and topography information, these data will aid in constraining mechanisms that drive surface deformation.

Stofan, E. R.↗
NASA NTRS1992

Ramgarh Crater, Rajasthan, India - Study of multispectral images obtained by Indian remote sensing satellite (IRS-IA)

Ramgarh Crater, Rajasthan, India is a potential impact crater that has not been studied so far. The proximity of Ramgarh Crater to the Deccan flood basalt terrain makes it important to examine the spatial and temporal relationship of this crater to Deccan Volcanism because recent studies propose a strong link between impact cratering and major flood basalt eruptions. A detailed multidisciplinary study is necessary to evaluate the structure and lithology of Ramgarh Crater and its temporal relationship to the emplacement of Deccan eruptions in India. Application of the IRS-IA data to study the lithologic/surface characteristics of Ramgarh Crater (attempted for the first time) indicates the potential application of remote sensing data in these studies. The IRS-IA data are of good quality and resolution. Our preliminary assessment has shown that these data are helpful in generating lithology soil vegetation profiles of Ramgarh Crater region. These 'profile maps' would be useful for targeting the specific areas in the region for a closer look and ground truth verification during the field work and sample collection in the region.

Murali, A. V.↗
NASA NTRS1995

Numerical simulations of the flow in the HYPULSE expansion tube

Axisymmetric numerical simulations with finite-rate chemistry are presented for two operating conditions in the HYPULSE expansion tube. The operating gas for these two cases is nitrogen and the computations are compared to experimental data. One test condition is at a total enthalpy of 15.2 MJ/Kg and a relatively low static pressure of 2 kPa. This case is characterized by a laminar boundary layer and significant chemical nonequilibrium in the acceleration gas. The second test condition is at a total enthalpy of 10.2 MJ/Kg and a static pressure of 38 kPa and is characterized by a turbulent boundary layer. For both cases, the time-varying test gas pressure predicted by the simulations is in good agreement with experimental data. The computations are also found to be in good agreement with Mirels' correlations for shock tube flow. It is shown that the nonuniformity of the test gas observed in the HYPULSE expansion tube is strongly linked to the boundary layer thickness. The turbulent flow investigated has a larger boundary layer and greater test gas nonuniformity. In order to investigate possibilities of improving expansion tube flow quality by reducing the boundary layer thickness, parametric studies showing the effect of density and turbulent transition point on the test conditions are also presented. Although an increase in the expansion tube operating pressure level would reduce the boundary layer thickness, the simulations indicate that the reduction would be less than what is predicted by flat plate boundary layer correlations.

Wilson, Gregory J.↗
NASA NTRS1995

Small main-belt asteroid spectroscopic survey: Initial results

The spectral characterization of small asteroids is important for understanding the evolution of their compositional and mineralogical properties. We report the results of a CCD spectroscopic survey of small main-belt asteroids which we call the Small Main-belt Asteroid Spectroscopic Survey (SMASS). Spectra of 316 asteroids were obtained, with wavelength coverage ranging from 4000 to 10000 A (0.4 to 1 micrometers). More than half of the objects in our survey have diameters less than 20 km. Survey results include the identification of the first object resembling ordinary chondrite meteorites among the main-belt asteroids (Binzel, R. P., et al, 1993) and observations of more than 20 asteroids showing basaltic achondrite spectral absorption features that strongly link Vesta as the parent body for the basaltic achondrite meteorites (Binzel, R. P., and S. Xu 1993). A potential Mars-crossing asteroid analog to ordinary chondrite meteorites (H chondrites), 2078 Nanking, is reported here. Through a principal component analysis, we have assigned classifications to the members of our sample. The majority of the small main-belt asteroids belong to S and C classes, similar to large asteroids. Our analysis shows that two new classes are justified which we label as J and O. Small asteroids display more diversity in spectral absorption features than the larger ones, which may indicate a greater variation of compositions in the small asteroid population. We found a few candidates for olivine-rich asteroids within the S class. Although the total number of olivine-rich candidates is relatively small, we present evidence suggesting that such objects are more prevalent at smaller sizes.

Xu, Shui↗