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At least 73 records · Page 4

Modification of the Surface Properties of Polyimide Films using POSS Deposition and Oxygen Plasma Exposure

Topographically rich surfaces were generated by spray-coating organic solutions of a polyhedral oligomeric silsesquioxane, octakis (dimethylsilyloxy) silsesquioxane (POSS), on Kapton HN films and exposing them to radio frequency generated oxygen plasma. Changes in both surface chemistry and topography were observed. High-resolution scanning electron microscopy indicated substantial modification of the POSS-coated polyimide surface topographies as a result of oxygen plasma exposure. Water contact angles varied from 104 deg for unexposed POSS-coated surfaces to approximately 5 deg, for samples exposed for 5 h. Modulation of the dispersive and polar contributions to the surface energy was determined using van Oss Good Chaudhury theory.

Wohl, Christopher J.↗

Martian surface properties indicated by the opposition effect

Radiative transfer expressions are used to derive average surface particle single-scattering albedos, phase functions and porosities from a photometric comparison of Viking Orbiter opposition measurements of the Martian Arabia, Syrtis Major and Elysium Planitia regions with several generic features. The best functional fit to the data includes consideration of atmospheric scattering, two-particle populations and surface roughness. It is found that (1) the presence of high albedo, high porosity surface particles is ubiquitous, (2) opposition surge is absent in the Syrtis Major region, and (3) the Chryse areas possess the largest surface roughness.

Thorpe, T. E.↗

Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries

Impact craters are a natural probe of planetary sub-surfaces, both from the excavated material and from crater geometries, which are sensitive to material properties of the target. One of the most intriguing aspects of Martian craters is the morphology of the ejecta blankets. All fresh and many older Martian craters larger than a few km are surrounded by ejecta blankets which appear fluidized, with morphologies believed to form by entrainment of liquid water. In addition to the ejecta morphology, quantitative information about the subsurface composition may be derived from geometrical measurements, e.g., rim uplift height and ejecta blanket volumes. In order to use craters to derive subsurface composition or test rampart morphology formation hypotheses, accurate measurements with quantified error estimates are required. We have developed and tested a toolkit for measurements of crater geometry using the MOLA altimetry data. Here, we present the results from geometry measurements on fresh craters in Lunae Planum and Utopia Planitia.

Valiant, G. J.↗

Multi-Satellite Estimates of Land-Surface Properties for Determination of Energy and Water Budgets

Using the WETNET database, existing methods for the estimation of surface wetness from SSM/I data have been assessed and further developed. A physical-statistical method for optimal estimation of daily surface heat flux and Bowen ratio on the mesoscale has been developed and tested. This method is based on observations of daytime planetary boundary layer (PBL) growth from operational ravansonde and daytime land-surface temperature amplitude from Geostationary Operational Environmental (GOES) satellites. The mesoscale patterns of these heat fluxes have been compared with an AVHRR-based vegetation index and surface wetness (separately estimated from SSM/I and in situ observations). Cases of the 1988 Midwest drought and a surface/atmosphere moisture gradient (dry-line) in the southern Plains were studied. The analyses revealed significant variations in sensible heat flux (S(sub 0), and Bowen ratio, B(sub 0)) associated with vegetation cover and antecedent precipitation. Relationships for surface heat flux (and Bowen ratio) from antecedent precipitation and vegetation index have been developed and compared to other findings. Results from this project are reported in the following reviewed literature.

Menzel, W. Paul↗

Radar measurements of Martian topography and surface properties - The 1971 and 1973 oppositions

The Goldstone radar system was used at a wavelength of 12.6 cm to probe the Martian surface during the 1973 opposition. Measurements of range and reflected power were made at least weekly between July 12 and November 24. Surface cells isolated by the radar system were 8 km E-W by 110 km N-S. Altitudes were calculated from signal time delays measured relative to a triaxial ellipsoid and were combined with altitudes measured during the 1971 opposition. Contours of constant altitude were calculated at 200 m intervals between latitudes -14 and -22 deg. These contours are presented in conjunction with Mars charts derived from Mariner 9 television pictures. Reflected power was measured at angles of incidence between -5 and +5 deg. These measurements were combined with those obtained during the 1971 opposition.

Downs, G. S.↗

Surface properties of ancient cratered terrain in the northern hemisphere of Mars

Viking high resolution IR data is used in an examination of the hilly and cratered material of Scott and Carr (1978), supposed to be the oldest extensively exposed surface on Mars. Measured nighttime temperatures at 11 and 20 microns indicate inertia blocks, surrounded by lower thermal inertia soil. Geologic features crossed by the Viking data generally show no difference from the regional properties. Imaging data from within and around the Arabia low thermal inertia region indicate that subdued surface morphology is not always associated with low thermal inertias. The mantling of ancient northern hemisphere cratered terrain by fine grained material does not allow thermal measurements to be directly related to rock unit properties, but less mantling may be present in southern hemisphere locations of this material.

Zimbelman, J. R.↗

Surface properties of the Orgueil meteorite - Implications for the early history of solar system volatiles

The Kr and H2O adsorption properties of Orgueil were studied. Dehydration by stepwise calcination produced a tenfold change in its B.E.T. surface area, which increased to 120 and then fell to 40 square meters per gram. Water exchangeability was measured by water regain from lab air between calcination cycles. Dehydration at room temperature showed that Orgueil contained 6 per cent by weight of water adsorbed on free surfaces. These results are consistent with an identification of Orgueil as montmorillonite, although chemical data conflict with this. High D/H ratios in CI carbonaceous chondrites may result from D enrichment in OH- groups during equilibration of dispersed phyllosilicate dust with preplanetary nebula gas at temperatures much less than 0 C.

Fanale, F. P.↗

The surface properties of fluorinated polyimides exposed to VUV and atomic oxygen

The effect of atomic oxygen flux and VUV radiation alone and in combination on the surface of fluorinated polyimide films was studied using XPS spectroscopy. Exposure of fluorinated polyimides to VUV radiation alone caused no observable damage to the polymer surface, while an atomic oxygen flux resulted in substantial oxidation of the surface. On the other hand, exposure to VUV radiation and atomic oxygen in combination caused extensive oxidation of the polymer surface after only 2 minutes of exposure. The amount of oxidized carbon on the polymer surface indicated that there is aromatic ring opening oxidation. The changes in the O1s/C1s, N1s/C1s, and F1s/C1s ratios suggested that an ablative degradation process is highly favorable. A synergistic effect of VUV radiation in the presence of atomic oxygen is clearly evidenced from the XPS study. The atomic oxygen could be considered as the main factor in the degradation process of fluorinated polyimide films exposed to a low earth orbit environment.

Forsythe, John S.↗

Martian topography and surface properties as seen by radar - The 1971 opposition.

Taking advantage of the favorable opposition of 1971, the Goldstone radar system, operating at 2388 MHz, was used to scan the Martian surface. Measurements of altitude and reflected power were taken approximately every 3 days. Each measurement represents an area 8 km E-W by 80 km N-S, the highest resolution attained to date. Altitude measurements obtained on different observing days were combined to produce altitude profiles for three complete rotations, each at different latitudes. Large-scale variations in altitudes cover a range of 14 km. Altitude changes of 5 in 30 km of longitude were observed. The altitude profiles show the heavy cratering of the surface, and several large craters (50-100 km) 1-2 km deep are easily seen.

Downs, G. S.↗

Preliminary Results of a New Type of Surface Property Measurement Ideal for a Future Mars Rover Mission

The success of the recent rover missions to Mars has stressed the importance of acquiring the maximum amount of geological information with the least amount of data possible. We have designed, tested and implemented special sensors mounted on a rover s wheel capable of detecting minute changes in surface topology thus eliminating the need for specially- made science platforms. These sensors, based on the previously designed, flight qualified Mars Environmental Compatibility Assessment (MECA) Electrometer, measure the static electricity (triboelectricity) generated between polymer materials and the Martian regolith during rover transverses. The sensors are capable of detecting physical changes in the soil that may not be detectable by other means, such as texture, size and moisture content. Although triboelectricity is a surface phenomenon, the weight of a rover will undoubtedly protrude the sensors below the dust covered layers, exposing underlying regolith whose properties may not be detectable through other means.

Buhler, C. R.↗

Atmospheric and surface properties of Mars obtained by infrared spectroscopy on Mariner 9

The infrared spectroscopy experiment on Mariner 9 obtained data over much of Mars. Interpretation of the thermal emission of Mars in terms of atmospheric temperatures, wind fields and dynamics, surface temperatures, surface pressure and topography, mineral composition, and minor atmospheric constituents including isotopic ratios, as well as a search for unexpected phenomena are reported.

Conrath, B.↗

Pioneer Venus radar results - Altimetry and surface properties

A topographic map of 93% of the Venus globe was depicted by the radar altimeter of the Pioneer Venus orbiter with a resolution better than 150 km. Extremes in relief expressed as a center-of-mass-to-surface radius extend from 6049 to 6062 km; the elevated terrain is dominated by a massive equatorial area equal in size to South America. The distribution of average meter-scale surface slopes is determined for the same regions in the 1 to 10 deg range; elevated areas have higher slopes, so that most features observed in the earth-based images are also evident in the vertical-incidence spacecraft measurements.

Pettengill, G. H.↗

Space-based Swath Imaging Laser Altimeter for Cryospheric Topographic and Surface Property Mapping

Uncertainties in the response of the Greenland and Antarctic polar ice sheets to global climatic change inspired the development of ICESat/GLAS as part of NASA's Earth Observing System. ICESat's primary purpose is the measurement of ice sheet surface elevation profiles with sufficient accuracy, spatial density, and temporal coverage so that elevation changes can be derived with an accuracy of <1.5 cm/year for averages of measurements over the ice sheets with areas of 100 x 100 km. The primary means to achieve this elevation change detection is spatial averaging of elevation differences at cross-overs between ascending and descending profiles in areas of low ice surface slope. Additional information is included in the original extended abstract.

Abshire, James↗

The influence of land surface properties on Sahel climate. Part 1: Desertification

This is a general circulation model sensitivity study of the physical mechanisms of the effects of desertification on the Sahel drought. The model vegetation types were changed in the prescribed desertification area, which led to changes in the surface characteristics. The model was integrated for three months (June, July, August) with climatological surface conditions (control) and desertification conditions (anomaly) to examine the summer season response to the changed surface conditions. The control and anomaly experiments consisted of five pairs of integrations with different initial conditions and/or sea surface temperature boundary conditions. In the desertification experiment, the moisture flux convergence and rainfall were reduced in the test area and increased to the immediate south of this area. The simulated anomaly dipole pattern was similar to the observed African drought patterns in which the axis of the maximum rainfall shifts to the south. The circulation changes in the desertification experiment were consistent with those observed during sub-Saharan dry years. The tropical easterly jet was weaker and the African easterly jet was stronger than normal. Further, in agreement with the observations, the easterly wave disturbances were reduced in intensity but not in number. Descending motion dominated the desertification area. The surface energy budget and hydrological cycle were also changed substantially in the anomaly experiment.

Xue, Yongkang↗

Microwave signatures and surface properties of Ovda Regio and surroundings, Venus

Magellan observations of horizontally and vertically polarized emissivity and radar specific cross sections are jointly modeled to separate dielectric constants from textural effect for lobate plains, fractured plains, fracture belts, festoon flows, and tessera in Ovda Regio and surroundings. The model assumes surface emission and scattering dominate and that signatures are controlled by a combination of quasi-specular and diffuse-scale mechanisms. Textural parameters are found to correlate with geology whereas dielectric constants are found to depend on elevation. A gradual increase in dielectric constant from rock-like values (4 to 5) to a value of approximately 50 is evident over the interval from 6054 to 6056 km, where elevations are derived from Magellan altimetry observations. Stereo radargrammetric analyses demonstrate that a return to rock-like values occurs over approximately 0.5 km above the terrain with highest dielectric constants. The abrupt return to rock-like values occurs independently of geology and reinforces the hypothesis of elevation control on dielectric constant values. Variations in dielectric constant with elevation are modeled using an 1000-ppm concentration of a ferroelectric mineral with a Curie temperature of 707 K. The model reproduces the abrupt change at highest elevations, as the Curie temperature is reached, and the gradual change as lower elevations are encountered. To our knowledge no other model explains the trends with such simplicity.

Arvidson, R. E.↗