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At least 73 records · Page 4

Oxidation Resistant Ti-Al-Fe Diffusion Barrier for FeCrAlY Coatings on Titanium Aluminides

A diffusion barrier to help protect titanium aluminide alloys, including the coated alloys of the TiAl gamma + Ti3Al (alpha2) class, from oxidative attack and interstitial embrittlement at temperatures up to at least 1000 C is disclosed. The coating may comprise FeCrAlX alloys. The diffusion barrier comprises titanium, aluminum, and iron in the following approximate atomic percent: Ti-(50-55)Al-(9-20)Fe. This alloy is also suitable as an oxidative or structural coating for such substrates.

Brady, Michael P.↗

Two-Phase (TiAl+TiCrAl) Coating Alloys for Titanium Aluminides

A coating for protecting titanium aluminide alloys, including the TiAl gamma + Ti3Al (alpha(sub 2)) class, from oxidative attack and interstitial embrittlement at temperatures up to at least 1000 C. is disclosed. This protective coating consists essentially of titanium, aluminum. and chromium in the following approximate atomic ratio: Ti(41.5-34.5)Al(49-53)Cr(9.5-12.5)

Brady, Michael P.↗

Surface Evaluation by XPS of High Performance Foams After Exposure to Oxygen Plasma

This report will present the results of a study done during a 10-week summer faculty fellowship during the summer of 2001 working with Ms. Martha Williams of the Testbeds Group at Kennedy Space Center. The work was in a new area for this faculty and was both interesting and enjoyable. An imide is a compound in which nitrogen is bonded directly to an R group and to two other R groups through carbonyls. Polyimides have a number of properties that make them highly desirable materials for use on structures that are exposed to extreme conditions. They are strong, fire resistant, minimally outgasing, stable over a large temperature range, resistant to chemical attack, transparent to infrared and microwaves, and have a low density. One polyimide, solimide, commercially available as a foam, retains resiliency from -300 F to +500 F, is highly flame retardant, and decomposes with virtually no smoke or toxic byproduct formation. The density of this product is such that its use in place of fiberglass in the lower lobe of a 747 saves 400 lb. Shipboard applications have resulted in literally tons of weight reduction. While polyimide films have been used in structures to be placed in low earth orbit (LEO) for many years, polyimide foams have found only minimal application in this realm. NASA Langley Research Center has developed new technology that allows for the processing of new polyimide foams. The resulting increased availability of these materials, along with their highly desirable properties, has prompted a study to determine the suitability of these materials for use in structures to be placed in LEO.

Hampton, Michael D.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamic maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of Region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicon carbide is the single stable solid phase in Region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4, and SiH. Analysis of the kinetics of reaction for Region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to Regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamics maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicone carbide is the single stable solid phase in region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4 and SiH. Analyses of the kinetics of reaction for region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Deconsolidation and Leach Burn Leach of Seven As Irradiated AGR 5/6/7 TRISO Fuel Compacts from Capsules 2, 3, 4, and 5

Seven as-irradiated Advanced Gas Reactor (AGR) 5/6/7 compacts underwent destructive post-irradiation examination via deconsolidation-leach-burn leach at Idaho National Laboratory (INL). The selection of the compacts extended the upper and lower limits of time-average volume-average (TAVA) temperature for compacts that had gone through deconsolidation-leach-burn leach so far. The measured inventories of fission products and actinides in the compact matrix and outer pyrolytic carbon were reported. Results indicated unexpectedly higher rates of fuel kernel leaching compared to compacts from AGR-1 and AGR-2. These failure rates were attributed to damage during post-irradiation sample handling, rather than irradiation itself. AGR-5/6/7 compacts have little or no matrix coverage for some particles at the top and bottom ends of cylindrical fuel compacts, making them more fragile. Sixty particles were randomly sampled from each compact, and the gamma results were reported. Three SiC shells from were identified, one of which showed signs of chemical attack in the high-irradiation temperature compact.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The Physical and Engineering Limits of Coupled In situ TEM Experiments

Almost all future energy systems (advanced nuclear reactors, fusion energy system, concentrating solar-thermal power (CSP), and wind technologies) are limited by degradation of key material systems exposed to multiple environmental stressors. The degradation during exposure to high temperatures, radiation, mechanical loading, and chemical attack is often dictated by mechanisms active at the microstructural level. The nature of these mechanisms and the associated variations between sequential and concurrent interplay can be explored if the transmission electron microscope (TEM) is utilized as a toolbox for exploration [1]. One such tool developed at Sandia National Laboratories to couple several of these environments is the In situ Ion Irradiation TEM (I3TEM) [2]. Several studies over the last decade utilizing this tool have shown that the scientific intuition developed over decades of sequential experiments is not always a good indicator of concurrent mechanisms or failure routes. This presentation will highlight the recent and planned additions into the I3TEM facility of a Waviks gas injection system and Raman system, respectively, as can be seen in Fig. 1, permitting environmental degradation from gas species leaked into the pole piece region during quantitative mechanical loading (indentation, monotonic loading, high temperature creep, irradiation induced creep, and high-cycle fatigue); multi-beam ion irradiation (energies ranging from 1 keV to 48 MeV and species from H to Au); laser exposure (20 W and 1064 nm), or various combinations thereof that are already possible [3]. This addition permits the facility to explore both sequential or concurrently the four axes of stressors: thermal, mechanical, radiation, and chemical. This information can be directly coupled to modeling, expediting the refinement and validation of both atomistic and mesoscale models.

degradation↗

Effects of wall cooling and angle of attack on boundary layer transition on sharp cones at free stream Mach 7.4

Tests were conducted on 5 deg and 15 deg half-angle sharp cones at wall-to-total-temperature ratios of 0.08 to 0.4, and angles of attack from 0 deg to 20 deg. The results indicate that (1) transition Reynolds numbers decrease with decreasing temperature ratio, (2) local transition Reynolds numbers decrease from the windward to the leeward side of the model, and (3) transition data on the windward ray of cones can be correlated in terms of the crossflow velocity gradient, momentum thickness Reynolds number, local Mach number, and cone half-angle.

Mateer, G. G.↗

Corrosion of aluminum alloys by chlorinated hydrocarbon/methanol mixtures

Laboratory investigations show that water-free mixtures of Freon MF /trichlorofluoromethane/ and methanol vigorously attack aluminum alloys which contain significant amounts of copper. Freon MF alone did not attack the aluminum alloys at room temperature. Pure methanol had only a slight corrosive effect on the alloy.

De Forest, W. S.↗

Improved elastomer for use with oxygen difluoride

Method improves resistance of CIS-1,4-poly(butadiene) elastomers to attack by oxygen difluoride at low temperatures by replacing silica reinforcement with less reactive substances. Improved elastomeric compound is utilized in bladders, diaphragms, valves, O-rings and seals.

Martin, J. W.↗

Thin coatings for protecting titanium aluminides in high-temperature oxidizing environments

Titanium aluminides have high specific strengths at high temperatures but are susceptible to environmental attack. Their use in many aerospace applications would require that they be protected with coatings that, for structural efficiency, must be thin. It is conceivable that acceptable coatings might be found in several oxide systems, and consequently, oxide coatings of many compositions were prepared from sol-gels for study. Response-surface methodology was used to refine coating compositions and factorial experiments were used to develop coating strategies. Oxygen permeability diagrams of two-layer coatings for several oxide systems, an analysis of multiple-layer coatings on rough and polished surfaces, and modeling of the oxidation weight gain are presented.

Wiedemann, K. E.↗

A Robust, Gravity-Insensitive, High-Temperature Condenser for Water Recovery

Regenerative life support systems are vital for NASA's future long-duration human space exploration missions. A Heat Melt Compactor (HMC) system is being developed by NASA to dry and compress trash generated during space missions. The resulting water vapor is recovered and separated from the process gas flow by a gravity-insensitive condenser. Creare is developing a high-temperature condenser for this application. The entire condenser is constructed from metals that have excellent resistance to chemical attack from contaminants and is suitable for high-temperature operation. The metal construction and design configuration also offer greatest flexibility for potential coating and regeneration processes to reduce biofilm growth and thus enhancing the reliability of the condenser. The proposed condenser builds on the gravity-insensitive phase separator technology Creare developed for aircraft and spacecraft applications. This paper will first discuss the design requirements for the condenser in an HMC system that will be demonstrated on the International Space Station (ISS). Then, it will present the overall design of the condenser and the preliminary thermal test results of a subscale condenser. Finally, this paper will discuss the predicted performance of the full-size condenser and the development plan to mature the technology and enhance its long-term reliability for a flight system.

Chen, Weibo↗

Experimental Results on the Feasibility of an Aerospike for Hypersonic Missiles

A series of wind tunnel tests have been performed on an aerospike-protected missile dome at a Mach number of 6 to obtain quantitative surface pressure and temperature-rise data, as well as qualitative flow visualization data. These data were used to determine aerospike concept feasibility and will also provide a database to be used for calibration of computational fluid dynamics codes. Data were obtained on the hemispherical missile dome with and without an aerospike that protrudes ahead of the dome along the axisymmetric center line. Data were obtained on two models (one pressure, one temperature) in the NASA Langley 20-Inch Mach 6 Tunnel at a freestream Reynolds number of 8.0 x 10(exp 6) per feet and angles of attack from 0 to 40 degrees. Surface pressure and temperature-rise results indicate that the aerospike is effective for very low angles of attack (less than 5 degrees) at Mach 6. Above 5 degrees, impingement of the aerospike bow shock and the flow separation shock from the recirculation region created by the aerospike causes pressure and temperature increases on the windward side of the dome which exceed values observed in the same region with the aerospike removed. Flow characterization obtained via oil-flow and schlieren photographs provides some insight into the quantitative surface data results, including vortical flow and shock-wave impingement.

Huebner, Lawrence D.↗

Thermal Model Correlation for Mars Reconnaissance Orbiter

The Mars Reconnaissance Orbiter (MRO) launched on August 12, 2005 and began aerobraking at Mars in March 2006. In order to save propellant, MRO used aerobraking to modify the initial orbit at Mars. The spacecraft passed through the atmosphere briefly on each orbit; during each pass the spacecraft was slowed by atmospheric drag, thus lowering the orbit apoapsis. The largest area on the spacecraft, most affected by aeroheating, was the solar arrays. A thermal analysis of the solar arrays was conducted at NASA Langley Research Center to simulate their performance throughout the entire roughly 6-month period of aerobraking. A companion paper describes the development of this thermal model. This model has been correlated against many sets of flight data. Several maneuvers were performed during the cruise to Mars, such as thruster calibrations, which involve large abrupt changes in the spacecraft orientation relative to the sun. The data obtained from these maneuvers allowed the model to be well-correlated with regard to thermal mass, conductive connections, and solar response well before arrival at the planet. Correlation against flight data for both in-cruise maneuvers and drag passes was performed. Adjustments made to the model included orientation during the drag pass, solar flux, Martian surface temperature, through-array resistance, aeroheating gradient due to angle of attack, and aeroheating accommodation coefficient. Methods of correlation included comparing the model to flight temperatures, slopes, temperature deltas between sensors, and solar and planet direction vectors. Correlation and model accuracy over 400 aeroheating drag passes were determined, with overall model accuracy better than 5 C.

Amundsen, Ruth M.↗

Designing Ni- and Co-Base Superalloys To Resist Oxidation

Analysis of experimental cyclic-oxidation data yields quantitative design criterion. Equation characterizing abilities of superalloys to resist oxidation at high temperatures proves useful for designing new alloy compositions to resist oxidation. Rates tendency to become oxidized in terms of single attack parameter, K(a), as function of composition and temperature: decrease in K(a) signifies increase in resistance to oxidation.

Barrett, Charles A.↗

Preliminary Investigation of Cyclic De-Icing of an Airfoil Using an External Electric Heater

An investigation was conducted in the NACA Lewis icing research tunnel to determine the characteristics and requirements of cyclic deicing of a 65,2-216 airfoil by use of an external electric heater. The present investigation was limited to an airspeed of 175 miles per hour. Data are presented to show the effects of variations in heat-on and heat-off periods, ambient air temperature, liquid-water content, angle of attack, and. heating distribution on the requirements for cyclic deicing. The external heat flow at various icing and heating conditions is also presented. A continuously heated parting strip at the airfoil leading edge was found necessary for quick, complete, and consistent ice removal. The cyclic power requirements were found to be primarily a function of the datum temperature and heat-on time, with the other operating and meteorological variables having a second-order effect. Short heat-on periods and high power densities resulted in the most efficient ice removal, the minimum energy input, and the minimum runback ice formations. The optimum chordwise heating distribution pattern was found to consist of a uniform distribution of cycled power density in the impingement region. Downstream of the impingement region the power density decreased to the limits of heating which, for the conditions investigated, extended from 5.7 percent chord on the upper surface of the airfoil to 8.9 percent chord on the lower surface. Ice removal did not take place at a heater surface temperature of 32 F; surface temperatures of approximately 50 to 100 F were required to effect removal. Better de-icing performance and greater energy savings would be possible with a heater having a higher thermal efficiency.

Lewis, James P.↗

Effects of impurities in coal-derived liquids on accelerated hot corrosion of superalloys

A Mach 0.3 burner rig was used to determine the effects of potential coal derived liquid fuel impurity combustion of products on hot corrosion in IN-100, IN-792, IN_738, U-700, Mar M-509, and 304 stainless steel. The impurities, added as aqueous solutions to the combustor, were salts of sodium, potassium, vanadium, molybdenum, tungsten, phosphorus, and lead. Extent of attack was determined by metal consumption and compared to the effects of sodium alone. Vanadium, molybdenum, tungsten, phosphorous, and lead in combination with sodium all resulted in increased attack as compared with sodium alone at some temperatures, apparently due in large part to the extension of the formation of liquid deposits. Varying the sodium-potassium ratio had little effect for ratios less than 1:3 for which reduced, but measurable, attack was observed.

Deadmore, D. L.↗

Transition of the Laminar Boundary Layer on a Delta Wing with 74 degree Sweep in Free Flight at Mach Numbers from 2.8 to 5.3

The tests were conducted at Mach numbers from 2.8 to 5.3, with model surface temperatures small compared to boundary-layer recovery temperature. The effects of Mach number, temperature ratio, unit Reynolds number, leading-edge diameter, and angle of attack were investigated in an exploratory fashion. The effect of heat-transfer condition (i.e., wall temperature to total temperature ratio) and Mach number can not be separated explicitly in free-flight tests. However, the data of the present report, as well as those of NACA TN 3473, were found to be more consistent when plotted versus temperature ratio. Decreasing temperature ratio increased the transition Reynolds number. The effect of unit Reynolds number was small as was the effect of leading-edge diameter within the range tested. At small values of angle of attack, transition moved forward on the windward surface and rearward on the leeward surface. This trend was reversed at high angles of attack (6 deg to 18 deg). Possible reasons for this are the reduction of crossflow on the windward side and the influence of the lifting vortices on the leeward surface. When the transition results on the 740 delta wing were compared to data at similar test conditions for an unswept leading edge, the results bore out the results of earlier research at nearly zero heat transfer; namely, sweep causes a large reduction in the transition Reynolds number.

Chapman, Gary T.↗