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NASA NTRS2018

Modeling Terrestrial Planetary Atmospheres with ROCKE-3D

I will discuss recent work showing the capabilities of ROCKE-3Dto model the atmospheres of a diverse range of terrestrial worlds from tidallylocked Proxima Centauri b to the ancient Moon.Some emphasis will be placed on ancient Venus simulations thatmay indicate that its present atmospheric state is more tied tothe global-scale resurfacing event of the past Gy than to its proximity to a gradually warming sun over the past 4Gy.

Way, Michael↗

NASA NTRS2022

Accurate Modeling of Lyα Profiles and their Impact on Photolysis of Terrestrial Planet Atmospheres

Accurately measuring and modeling the Lyα (Lyα; λ1215.67 Å) emission line from low-mass stars is vital for our ability to build predictive high energy stellar spectra, yet interstellar medium (ISM) absorption of this line typically prevents model-measurement comparisons. Lyα also controls the photodissociation of important molecules, like water and methane, in exoplanet atmospheres such that any photochemical models assessing potential biosignatures or atmospheric abundances require accurate Lyα host star flux estimates. Recent observations of three early M and K stars (K3, M0, M1) with exceptionally high radial velocities (>100 km s −1 ) reveal the intrinsic profiles of these types of stars as most of their Lyα flux is shifted away from the geocoronal line core and contamination from the ISM. These observations indicate that previous stellar spectra computed with the PHOENIX atmosphere code have underpredicted the core of Lyα in these types of stars. With these observations, we have been able to better understand the microphysics in the upper atmosphere and improve the predictive capabilities of the PHOENIX atmosphere code. Since these wavelengths drive the photolysis of key molecular species, we also present results analyzing the impact of the resulting changes to the synthetic stellar spectra on observable chemistry in terrestrial planet atmospheres.

Sarah Peacock↗

NASA NTRS2006

The Development of New Solar Indices for use in Thermospheric Density Modeling

New solar indices have been developed to improve thermospheric density modeling for research and operational purposes. Out of 11 new and 4 legacy indices and proxies, we have selected three (F10.7, S10.7, and M10.7) for use in the new JB2006 empirical thermospheric density model. In this work, we report on the development of these solar irradiance indices. The rationale for their use, their definitions, and their characteristics, including the ISO 21348 spectral category and sub-category, wavelength range, solar source temperature region, solar source feature, altitude region of terrestrial atmosphere absorption at unit optical depth, and terrestrial atmosphere thermal processes in the region of maximum energy absorption, are described. We also summarize for each solar index, the facility and instrument(s) used to observe the solar emission, the time frame over which the data exist, the measurement cadence, the data latency, and the research as well as operational availability. The new solar indices are provided in forecast (http://SpaceWx.com) as well as real-time and historical (http://sol.spacenvironment.net/~jb2006/) time frames. We describe the forecast methodology, compare results with actual data for active and quiet solar conditions, and compare improvements in F10.7 forecasting with legacy High Accuracy Satellite Drag Model (HASDM) and NOAA SEC forecasts.

Tobiska, W. Kent↗

NASA NTRS1994

Nitrogen isotopic components in the early solar system

It is quite common to take the terrestrial atmospheric value of (15)N/(14)N (0.00366) as typical of nitrogen in the early solar system, but in fact there is little reason to suppose that this value had a nebula-wide significance. Indeed, it is not clear that there was a unique solar-system-wide (15)N/(14)N ratio, of whatever value. Here we review what is known about the distribution of the nitrogen isotopes among those solar-system objects that have been sampled so far and conclude that those isotopes reveal widespread inhomogeneity in the early solar system. Whether the isotopically distinct primordial components implied by this analysis were solid or gaseous or a mixture of both is not known. The isotopic composition of N in the Earth's mantle is controversial: estimates range from a 1.1 percent depletion in (15)N to a 1.4 percent enrichment. (Isotopic compositions will be expressed throughout as percent deviations from the terrestrial atmospheric value.) The present-day Martian atmosphere is characterized by a value of plus 62 percent but this enrichment in (15)N is attributed to selective loss of (14)N from the Martian exosphere. Modelling of this fractionation leads to an estimated primordial composition similar to the terrestrial atmospheric value, through the precision of this model-dependent result is unclear.

Kerridge, J. F.↗

NASA NTRS2012

Filling-in of Far-Red and Near-Infrared Solar Lines by Terrestrial and Atmospheric Effects: Simulations and Space-Based Observations from SCHIAMACHY and GOSAT

Mapping of terrestrial vegetation fluorescence from space is of interest because it can potentially provide global information on the functional status of vegetation including light use efficiency and global primary productivity that can be used for global carbon cycle modeling. Space-based measurement of solar-induced chlorophyll fluorescence is challenging, because its signal is small as compared with the much larger reflectance signal. Ground- and aircraft-based approaches have made use of the dark and spectrally-wide 02-A (approx 760 nm) and O2-B (approx 690 nm) atmospheric features to detect the weak fluorescence signal. More recently, Joiner et a1. and Frankenberg et a1. focused on longer-wavelength solar Fraunhofer lines that can be observed with space-based instruments such as the currently operational GOSAT. They showed that fluorescence can be detected using Fraunhofer lines away from the far-red chlorophyll-a fluorescence peak even when the surface is relatively bright. Here, we build on that work by developing methodology to correct for instrumental artifacts that produce false filling-in signals that can bias fluorescence retrievals. We also examine other potential sources of filling-in at far-red and NIR wavelengths. Another objective is to explore the possibility of making fluorescence measurements from space with lower spectral resolution instrumentation than the GOSAT interferometer. We focus on the 866 nm Ca II solar Fraunhofer line. Very few laboratory and ground-based measurements of vegetation fluorescence have been reported at wavelengths longer than 800 mn. Some results of fluorescence measurements of corn leaves acquired in the laboratory using polychromatic excitation at wavelengths shorter than 665 nm show that at 866 nm, the measured signal is of the order of 0.1-0.2 mw/sq m/nm/sr. In this work we use the following satellite observations: We use SCIAMACHY channel 5 in nadir mode that covers wavelengths between 773 and 1063 nm at a spectral resolution of 0.54 nm. GOSAT has two instrument packages: the Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) and the Cloud and Aerosol Imager (CAI). We use TANSO-FTS band 1, which extends from approximately 758 to 775 mn and we use cloud fraction derived from the CAL We compare satellite-derived fluorescence with the Enhanced Vegetation Index (EVI), an Aqua/MODIS-derived vegetation reflectance-based index that indicates relative greenness and is used to infer photosynthetic function.

Joiner, J.↗

NASA NTRS2012

Filling-in of Far-Red and Near-Infrared Solar Lines by Terrestrial and Atmospheric Effects: Simulations and Space-Based Observations from SCIAMACHY and GOSAT

Mapping of terrestrial vegetation fluorescence from space is of interest because it can potentially provide global information on the functional status of vegetation including light use efficiency and global primary productivity that can be used for global carbon cycle modeling. Space-based measurement of solar-induced chlorophyll fluorescence is challenging, because its signal is small as compared with the much larger reflectance signal. Ground- and aircraft-based approaches have made use of the dark and spectrally-wide O2-A ( approx 760 nm) and O2-B (approx 690 nm) atmospheric features to detect the weak fluorescence signal. More recently, Joiner et al. and Frankenberg et al. focused on longer-wavelength solar Fraunhofer lines that can be observed with space-based instruments such as the currently operational GOSAT. They showed that fluorescence can be detected using Fraunhofer lines away from the far-red chlorophyll-a fluorescence peak even when the surface is relatively bright. Here, we build on that work by developing methodology to correct for instrumental artifacts that produce false filling-in signals that can bias fluorescence retrievals. We also examine other potential sources of filling-in at far-red and NIR wavelengths. Another objective is to explore the possibility of making fluorescence measurements from space with lower spectral resolution instrumentation than the GOSAT interferometer. We focus on the 866nm Ca II solar Fraunhofer line. Very few laboratory and ground-based measurements of vegetation fluorescence have been reported at wavelengths longer than 800 nm. Some results of fluorescence measurements of corn leaves acquired in the laboratory using polychromatic excitation at wavelengths shorter than 665nm show that at 866 nm, the measured signal is of the order of 0.1-0.2 mW/sq m/nm/sr. In this work, we use the following satellite observations: We use SCIAMACHY channel 5 in nadir mode that covers wavelengths between 773 and 1063nm at a spectral resolution of 0.54 nm. GOSAT has two instrument packages: the Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) and the Cloud and Aerosol Imager (CAI). We use TANSO-FTS band 1, which extends from approximately 758 to 775nm and we use cloud fraction derived from the CAI. We compare satellite-derived fluorescence with the Enhanced Vegetation Index (EVI), an Aqua/MODIS-derived vegetation reflectance-based index that indicates relative greenness and is used to infer photosynthetic function.

Joiner, J.↗

NASA NTRS1990

Chemical kinetics and modeling of planetary atmospheres

A unified overview is presented for chemical kinetics and chemical modeling in planetary atmospheres. The recent major advances in the understanding of the chemistry of the terrestrial atmosphere make the study of planets more interesting and relevant. A deeper understanding suggests that the important chemical cycles have a universal character that connects the different planets and ultimately link together the origin and evolution of the solar system. The completeness (or incompleteness) of the data base for chemical kinetics in planetary atmospheres will always be judged by comparison with that for the terrestrial atmosphere. In the latter case, the chemistry of H, O, N, and Cl species is well understood. S chemistry is poorly understood. In the atmospheres of Jovian planets and Titan, the C-H chemistry of simple species (containing 2 or less C atoms) is fairly well understood. The chemistry of higher hydrocarbons and the C-N, P-N chemistry is much less understood. In the atmosphere of Venus, the dominant chemistry is that of chlorine and sulfur, and very little is known about C1-S coupled chemistry. A new frontier for chemical kinetics both in the Earth and planetary atmospheres is the study of heterogeneous reactions. The formation of the ozone hole on Earth, the ubiquitous photochemical haze on Venus and in the Jovian planets and Titan all testify to the importance of heterogeneous reactions. It remains a challenge to connect the gas phase chemistry to the production of aerosols.

Yung, Yuk L.↗

NASA NTRS1985

A preliminary spectroscopic assessment of the Spacelab 1/Shuttle optical environment

Attention is given to the Space Lab/Space Shuttle-borne Imaging Spectrometric Observatory's 1150-8000 A spectral data, which was gathered while this instrument package was looking tangentially away from the earth and into the velocity vector. The spectrum is noted to contain the expected atmospheric features, together with bright molecular bands between 6400 and 8000 A. These bands appear to be part of the N2 First Positive system. If most of the emission is due to this system, two excitation mechanisms are implied: direct collisional excitation of the local Shuttle atmosphere by the terrestrial atmosphere, or alternatively a surface interaction which generates metastable N2(A); this subsequently radiates via inverse first positive N2 transitions, followed by first positive transitions.

Torr, M. R.↗

NASA NTRS2016

Noble Gas Inventory of Micrometeorites Collected at the Transantarctic Mountains (TAM) and Indications for Their Provenance

A variety of processes have been considered possibly contributing the volatiles including noble gases to the atmospheres of the terrestrial planets (e.g., [1-3]). Special consideration has been given to the concept of accretion of volatile-rich materials by the forming planets. This might include infalling planetesimals and dust, and could include material from the outer asteroid belt, as well as cometary material from the outer solar system. Currently, the dominant source of extraterrestrial material accreted by the Earth is represented by micrometeorites (MMs) with sizes mostly in the 100-300 micron range [3, 4]). Their role has been assessed by [3], who conclude that accretion of early micrometeorites played a major role in the formation of the terrestrial atmosphere and oceans. We have therefore set out to investigate in more detail the inventory of noble gases in MMs. Here we summarize some of our results obtained on MMs collected in micrometeorite traps of the Transantarctic Mountains [5].

transantarctic↗

NASA NTRS1982

Backscattered UV radiation - Effects of multiple scattering and the lower boundary of the atmosphere

A method is proposed for the calculation of a multiple-scattering correction to the single-scattering calculation of the radiance of the terrestrial atmosphere resulting from backscattered ultraviolet solar radiation in the spectral region used in the ozone profile inversion. This method uses jointly the usual analytical and Monte Carlo methods. Effects of the lower boundary of the atmosphere, cloud tops, and ground surface are investigated both qualitatively and quantitatively. The ratio of multiple to single scattering is determined, and its importance in ozone profile inversion of backscattered UV solar radiation from the terrestrial atmosphere is evaluated. The polarization of the atmospheric radiance is treated briefly.

Aruga, T.↗

NASA NTRS1989

Atmospheric occultation of a solar flare in hard x rays

The objective of this study is two-fold: to investigate the absorption of hard x rays along a tangential path through the terrestrial atmosphere, and to locate, other than the use of imaging devices, the flare source of x ray emission in the sun. Observational data were taken with the Hard X Ray Burst Spectrometer (HXRBS) on board the Solar Maximum Mission satellite (SMM). The occultation event chosen for investigation is the flare on 14 October 1981. Night fell on SMM during the decaying phase of the flare. In about fifteen seconds, the x ray flux decreased to zero. The model for computing synthetic light curve, which is directly comparable to the observed curve, consists of two computing programs. One is a modified version of an existing code, which compute the coordinates of the tangent points of the SMM-sun lines. The other program computed the atmospheric densities along the angles (N to S and E to W) measured from the center of the sun. The various model also depends on the destination of the terrestrial atmosphere at geocentric positions of SMM and the sun, the mean atmospheric densities at different heights and latitudes, and the x ray absorption cross of nitrogen, oxygen, and argon. The optical length, at a given time and for a x ray energy, is computed with the two angular parameters. The fit of a particular synthetic light, curve, i.e., the exponentials of the optical lengths, to the observed eclipse curve, yields the desired angular parameters.

Chen, Kwan-Yu↗

NASA NTRS2001

The Mechanism Responsible for High Concentrations of Be-7 in the Near Space

In 1990 an unexpectedly high concentration of Be-7 was discovered on the LDEF satellite surface, facing in the RAM direction. The search for an explanation of this high concentration of Be-7 which is in thermal equilibrium in the upper atmosphere, led the researchers to the hypothesis of Be-7 transport by vertical turbulent fluxes from deeper layers in the Earth's atmosphere, where Be-7 is produced as a result of nuclear reactions between solar energetic protons (which penetrated there after a solar flare) and terrestrial atmosphere elements. The experiments carried out during 1995-1999 on 'Resource F1' and 'Cosmos' satellites not only confirmed the existence of high Be-7 concentrations at altitudes of about 200 km, but also permitted to establish correlation between the concentration of Be-7 in the upper atmosphere and flare activity on the Sun. More detailed analysis of the whole set of experimental data on Be-7 measurements at satellite altitudes showed, that the appearance of high Be-7 concentrations in the upper atmosphere of the Earth is a more complicated phenomenon. Two more mechanisms , explaining the observed effect can be indicated. Firstly, the observed concentrations could be associated with direct penetration of energetic Be-7 nuclei, originating in flares, into the terrestrial atmosphere. Calculations show, that in solar cosmic rays the flux of Be-7 nuclei should be maximum in comparison to the fluxes of other Beryllium isotopes. Secondly, the high concentration of Be-7 in the upper atmosphere of the Earth could be explained by solar wind penetration through the polar zones. Theoretical analysis of active processes including flares, occurring in the solar atmosphere, leads to the conclusion, that radioactive Beryllium is constantly present in the solar atmosphere, and, possibly, is the main isotope of solar Beryllium.

Panasyuk, M. I.↗

NASA NTRS1987

Mechanisms and observations for isotope fractionation of molecular species in planetary atmospheres

Chemcial and physical processes which may give rise to isotope fractionation of molecular species in the atmospheres of both earth and other planets are reviewed, along with observations of isotopically substituted molecules in planetary atmospheres. Mechanisms for production of isotope fractionation considered include atmospheric escape and the effect of isotope substitution on equilibrium constants (including those of phase changes), photolysis rates, and chemical reaction rates. The isotopes considered for compounds in the terrestrial atmosphere include D, T, C-13, C-14, N-15, O-18, and S-34. Compounds for which data about isotopic composition in the terrestrial atmosphere are summarized include CO, CO2, O3, N2O, NH3, SO2, H2S, H2O, H, H2, and CH4. Planetary atmospheres discussed include those of Venus, Mars, Jupiter, Saturn, Uranus, and Titan; isotopes reviewed are D, C-13, N-15, and O-18. Suggestions for additional research in the area of isotopically substituted molecules in atmospheres are offered.

Kaye, Jack A.↗

NASA NTRS1986

Xenon and other noble gases in shergottites

The isotopic composition of the xenon component trapped in EETA 79001's lithologies B and C has been determined, and other noble gases were measured in some samples. The Xe component was found to have light isotope ratios indistinguishable from those of the terrestrial atmosphere. The trapped component has a Xe-129/Xe-132 ratio of about 2.4, and is enhanced in Xe-134 and Xe-136 relative to the terrestrial atmosphere or the average carbonaceous chondrite. Similarities between values for Ar-40/Ar-36, Xe-129/Xe-132, and N-15/N-14 and the corresponding Martian atmospheric values suggest Martian origin of the trapped gases.

Swindle, T. D.↗

NASA NTRS2003

Space, Atmospheric, and Terrestrial Radiation Environments

The progress on developing models of the radiation environment since the 1960s is reviewed with emphasis on models that can be applied to predicting the performance of microelectronics used in spacecraft and instruments. Space, atmospheric, and ground environments are included. It is shown that models must be adapted continually to account for increased understanding of the dynamics of the radiation environment and the changes in microelectronics technology. The IEEE Nuclear and Space Radiation Effects Conference is a vital forum to report model progress to the radiation effects research community.

Barth, Janet L.↗

NASA NTRS1972

High resolution solar observations from space.

Present ground-based solar observations are limited by the transmission properties of the terrestrial atmosphere, the design of instruments, and the choice of observing locations. Recent improvements in the latter two have made possible observations with MTF around 7% at .5 arc sec and 15% at 1 arc sec. However, the instruments now appear to have been developed as far as the terrestrial atmosphere will permit, and new information will only be determined by space observations. The problems of construction, alignment and thermal control of a very high resolution solar telescope in space are discussed together with various optical systems. The problems of solar physics in which we would expect new information are also discussed, on the basis of recent high-resolution observations from the ground.

Zirin, H.↗

NASA NTRS1981

Interplanetary dust - Its physical nature and entry into the atmosphere of terrestrial planets

Studies of extraterrestrial particles collected in the stratosphere and from the sea floor indicate that the majority of interplanetary dust is a black, fine grained material similar to carbonaceous chondrites but different from known meteorites in mineralogy and structure. If the analyzed samples are typical interplanetary particles then they are probably cometary materials similar to the vast numbers of cometary particles which have continuously entered the earth's atmosphere for the lifetime of the solar system. If comets do not contain large strong rocks capable of producing conventional meteorites then dust is the only form in which organic materials from comets can be accreted by the earth.

Brownlee, D. E.↗

NASA NTRS2001

Quantitative Assessment of the Integrated Response in Global Heat and Moisture Budgets to Changing Solar Irradiance

Earlier, we found time sequences of basin- and global-average upper ocean temperature (that is, diabatic heat storage above the main pycnocline) for 40 years from 1955-1994 and of sea surface temperature for 95 years from 1900-1994 associated with changes in the Sun's radiative forcing on decadal and interdecadal timescales, lagging by 10 deg.- 30 deg. of phase and confined to the upper 60-120 m. Yet, the observed changes in upper ocean temperature (approx. 0.1 K) were approximately twice those expected from the Stefan-Boltzmann black-body radiation law for the Earth's surface, with phase lags (0 deg. to 30 deg. of phase) much shorter than the 90 deg. phase shift expected as well. Moreover, White et al. (1997, 1998) found the Earth's global decadal mode in covarying SST and SLP anomalies phase locked to the decadal signal in the Sun's irradiance. Yet, Allan (2000) found this decadal signal also characterized by patterns similar to those observed on biennial and interannual time scales; that is, the Troposphere Biennial Oscillation (TBO) and the El Nino and the Southern Oscillation (ENSO). This suggested that small changes in the Sun's total irradiance could excite this global decadal mode in the Earth's ocean-atmosphere-terrestrial system similar to those excited internally on biennial and interannual period scales. This is a significant finding, proving that energy budget models (that is, models based on globally-averaged radiation balances) yield unrealistic responses. Thus, the true response must include positive and negative feedbacks in the Earth's ocean-atmosphere-terrestrial system as its internal mode (that is, the natural mode of the system) respond in damped resonance to quasi-periodic decadal changes in the Sun's irradiance. Moreover, these responses are not much different from those occurring internally on biennial and interannual period scales.

White, Warren B.↗