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At least 73 records · Page 4

High Throughput Coefficient Thermal Expansion Testing Utilizing Digital Image Correlation

Dr. Fitzgerald, a postdoc at Sandia National Laboratories, works in a materials of mechanics group characterizing material properties of ductile materials. Her presentation focuses specifically on increasing throughput of coefficient of thermal expansion (CTE) measurements with the use of optical strain measurements, called digital image correlation (DIC). Currently, the coefficient of thermal expansion is found through a time intensive process called dilatometry. There are multiple types of dilatometers. One type, a double push rod mechanical dilatometer, uses and LVDT to measure the expansion of a specimen in one direction. It uses a reference material with known properties to determine the CTE of the specimen in question. Testing about 500 samples using the double push rod mechanical dilatometer would take about 2 years if testing Monday through Friday, because the reference material needs to be at a constant temperature and heating must done slowly to ensure no thermal gradients across the rod. A second type, scissors type dilatometer, pinches a sample using a “scissor-like” appendage that also uses a LVDT to measure thermal expansion as the sample is heated. Finally, laser dilatometry, was created to provide a non-contact means to measure thermal expansion. This process greatly reduces the time required to setup a measurement but is still only able to measure one sample at a time. The time required to test 500 samples gets reduced to 3.5 weeks. Additionally, to measure expansion in different directions, multiple lasers must be used. Dr. Fitzgerald solved this conundrum by using an optical measurement technique called digital image correlation to create strain maps in multiple orientations as well as measuring multiple samples at once. Using this technique, Dr. Fitzgerald can test 500 samples, conservatively, in 2 days.

36 MATERIALS SCIENCE↗

Analyzing the Validity of Brazilian Testing Using Digital Image Correlation and Numerical Simulation Techniques

Characterizing the mechanical behavior of rocks plays a crucial role to optimize the fracturing process in unconventional reservoirs. However, due to the intrinsic anisotropy and heterogeneity in unconventional resources, fracture process prediction remains the most significant challenge for sustainable and economic hydrocarbon production. During the deformation tracking under compression, deploying conventional methods (strain gauge, extensometer, etc.) is insufficient to measure the deformation since the physical attachment of the device is restricted to the size of the sample, monitoring limited point-wise deformation, producing difficulties in data retrieval, and a tendency to lose track in failure points, etc. Where conventional methods are limited, the application of digital image correlation (DIC) provides detailed and additional information of strain evolution and fracture patterns under loading. DIC is an image-based optical method that records an object with a camera and monitors the random contrast speckle pattern painted on the facing surface of the specimen. To overcome the existing limitations, this paper presents numerical modeling of Brazilian disc tests under quasi-static conditions to understand the full-field deformation behaviors and finally, it is validated by DIC. As the direct tensile test has limitations in sample preparation and test execution, the Brazilian testing principle is commonly used to evaluate indirectly the tensile strength of rocks. The two-dimensional numerical model was built to predict the stress distribution and full-field deformation on Brazilian disc under compression based on the assumptions of a homogenous, isotropic and linear elastic material. The uniaxial compression test was conducted using the DIC technique to determine the elastic properties of Spider Berea sandstone, which were used as inputs for the simulation model. The model was verified by the analytical solution and compared with the digital image correlation. The numerical simulation results showed that the solutions matched reasonably with the analytical solutions where the maximum deviation of stress distribution was obtained as 14.59%. The strain evolution (normal and shear strains) and displacements along the central horizontal and vertical planes were investigated in three distinguishable percentages of peak loads (20%, 40%, and 90%) to understand the deformation behaviors in rock. The simulation results demonstrated that the strain evolution contours consistently matched with DIC generated contours with a reasonable agreement. The changes in displacement along the central horizontal and vertical planes showed that numerical simulation and DIC generated experimental results were repeatable and matched closely. In terms of validation, Brazilian testing to measure the indirect tensile strength of rocks is still an issue of debate. The numerical model of fracture propagation supported by digital image correlation from this study can be used to explain the fracturing process in the homogeneous material and can be extended to non-homogeneous cases by incorporating heterogeneity, which is essential for rock mechanics field applications.

58 GEOSCIENCES↗

Measurement of the forming limit stress curve using a multi-axial tube expansion test with a digital image correlation system

A servo-controlled tension-internal pressure testing machine with an optical 3D deformation analysis system (ARAMIS) was used to measure the multi-axial plastic deformation behavior of a high-strength steel sheet for a range of strain from initial yield to fracture. The testing machine is capable of applying arbitrary principal stress or strain paths to a tubular specimen using an electrical, closed-loop servo-control system for axial force and internal pressure. Tubular specimens with an inner diameter of 44.6 mm were fabricated from a high-strength steel sheet with a tensile strength of 590 MPa and a thickness of 1.2 mm by roller bending and laser welding. Several linear and non-linear stress paths in the first quadrant of the stress space were applied to the tubular specimens in order to measure the forming limit curve (FLC) and forming limit stress curve (FLSC) of the as-received test material, in addition to the contours of plastic work and the directions of plastic strain rates. The contours of plastic work and the directions of plastic strain rates measured for the linear stress path experiments were compared with those calculated using selected yield functions in order to identify the most appropriate yield function for the test material. Moreover, a Marciniak-Kuczyński type (M-K) forming limit analysis was performed using the most appropriate yield function. The calculated and measured FLC and FLSC were compared in order to validate the M-K approach. The path-dependence of the FLC and FLSC was also investigated.

97 MATHEMATICS AND COMPUTING↗

Analysis of Serum Total and Free PSA Using Immunoaffinity Depletion Coupled to SRM: Correlation with Clinical Immunoassay Tests

Sandwich immunoassay is the standard technique used in clinical labs for quantifying protein biomarkers for disease detection, monitoring and therapeutic intervention. Albeit highly sensitive, the development of a specific immunoassay is rather time-consuming and associated with extremely high cost due to the requirement for paired immunoaffinity reagents of high specificity. Recently, mass spectrometry-based methods, specifically selected reaction monitoring mass spectrometry (SRM-MS), have been increasingly applied to measure low abundance biomarker candidates in tissue and biofluids, owing to high sensitivity and specificity, simplicity of assay configuration, and great multiplexing capability. In this study, we report for the first time the development of immunoaffinity depletion-based workflows and SRM-MS assays that enable sensitive and accurate quantification of total and free prostate-specific antigen (PSA) in serum without the requirement for specific PSA antibodies. With stable isotope dilution and external calibration, low ng/mL level detection of both total and free PSA was consistently achieved in both PSA-spiked female serum samples and actual patient serum samples. Moreover, comparison of the results obtained when SRM PSA assays and conventional immunoassays were applied to the same samples showed very good correlation (R2 values ranging from 0.90 to 0.99) in several independent clinical serum sample sets, including a set of 33 samples assayed in a blinded test. These results demonstrate that the workflows and SRM assays developed here provide an attractive alternative for reliably measuring total and free PSA in human blood. Furthermore, simultaneous measurement of free and total PSA and many other biomarkers can be performed in a single analysis using high-resolution liquid chromatographic separation coupled with SRM-MS.

59 BASIC BIOLOGICAL SCIENCES↗

Experimental Validation of Subsystem Models for a Novel Variable Displacement Hydraulic Motor

A novel, variable displacement, low-speed high-torque hydraulic motor is being developed that is expected to be highly efficient across a broad operating range. To ensure the final hardware achieves the expected performance, the models used in the development of the motor must be experimentally validated and revised, as necessary. The specific focus in this work is on mechanical energy loss models that were used to guide the design of a single-cylinder motor prototype and on experimental tests used for model validation. Ideally each model, whether friction loss in a piston/cylinder interface or energy loss due to leakage in a valve , would be individually validated by an independent test. This granular approach would remove any question of where the error lies and result in highly accurate models. However, many motor components have multiple forms of energy loss, creating difficulty in validating individual losses. Additionally, it is not physically realizable to divide many components into an individual model equivalent test. Testing the motor as a full assembly is possible, but pinpointing the source of discrepancies between the model and the hardware becomes difficult with dozens of models potentially being partially responsible. A compromise was found by separating the motor into functional component groups that are characterized by the type of loss and ability to test each subcomponent independently. By checking for correlation between test observations and model predictions, revisions could be implemented into the models. This allows future solutions to be more accurately predicted in the design phase to drive the design of better machines.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Benchmarking the performance of density functional theory and point charge force fields in their description of sI methane hydrate against diffusion Monte Carlo

High quality reference data from diffusion Monte Carlo calculations are presented for bulk sI methane hydrate, a complex crystal exhibiting both hydrogen-bond and dispersion dominated interactions. The performance of some commonly used exchange-correlation functionals and all-atom point charge force fields is evaluated. Our results show that none of the exchange-correlation functionals tested are sufficient to describe both the energetics and the structure of methane hydrate accurately, while the point charge force fields perform badly in their description of the cohesive energy but fair well for the dissociation energetics. By comparing to ice I{sub h}, we show that a good prediction of the volume and cohesive energies for the hydrate relies primarily on an accurate description of the hydrogen bonded water framework, but that to correctly predict stability of the hydrate with respect to dissociation to ice I{sub h} and methane gas, accuracy in the water-methane interaction is also required. Our results highlight the difficulty that density functional theory faces in describing both the hydrogen bonded water framework and the dispersion bound methane.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cladding Ring Tension Testing (RTT) of unirradiated cladding materials using Digital Image Correlation (DIC)

Cladding Ring Tension Testing (RTT) of unirradiated cladding materials using Digital Image Correlation (DIC). RTT is an important tool for determining hoop strength of thin-walled tubing, especially in anisotropic materials such as zirconium fuel cladding. The goal is to set up a DIC system to a tensile test on these RTT specimens and study the mechanical properties.

36 MATERIALS SCIENCE↗

Use of high throughput screening methods to study dual-functional crosslinkable latexes

Herein, structure-formulation-property relationships for crosslinkable core-shell latexes were studied initially using high throughput screening methods and then using conventional experimental methods to determine optimum coating formulations. Two approaches that are used within coatings technology to improve sustainability are reduction in volatile organic compounds (VOC) and reduction in energy needed to cure coatings. Hybrid crosslinkable core-shell latexes have shown potential in meeting these challenges where film properties provided by particle coalescence are not sufficient and chemical crosslinking is needed. However, with numerous parameters involved such as latex particle architecture, nature and amount of crosslinker, and curing conditions, the screening of formulations via conventional coating testing methods becomes laborious and time-consuming. The results from high-throughput dye extraction and puncture testing were compared to data from conventional testing methods such as chemical resistance (MEK double rubs), pendulum hardness, and tensile testing to identify correlations. The dye extraction results have shown a strong correlation to solvent resistance and pendulum hardness data whereas toughness from puncture testing data correlated to tensile testing. Both high throughput dye extraction and puncture testing methods can be used for the accelerated screening of crosslinkable coating formulations to optimize curing parameters to achieve the best coating performance.

36 MATERIALS SCIENCE↗

Ensemble v-representable ab initio density-functional calculation of energy and spin in atoms: A test of exchange-correlation approximations

The total energies and the spin states for atoms and their first ions with Z=1-86 are calculated within the the local spin-density approximation (LSDA) and the generalized-gradient approximation (GGA) to the exchange-correlation (xc) energy in density-functional theory. Atoms and ions for which the ground-state density is not pure-state v-representable are treated as ensemble v-representable with fractional occupations of the Kohn-Sham system. A recently developed algorithm which searches over ensemble v-representable densities [E. Kraisler et al., Phys. Rev. A 80, 032115 (2009)] is employed in calculations. It is found that for many atoms, the ionization energies obtained with the GGA are only modestly improved with respect to experimental data, as compared to the LSDA. However, even in those groups of atoms where the improvement is systematic, there remains a non-negligible difference with respect to the experiment. The ab initio electronic configuration in the Kohn-Sham reference system does not always equal the configuration obtained from the spectroscopic term within the independent-electron approximation. It was shown that use of the latter configuration can prevent the energy-minimization process from converging to the global minimum, e.g., in lanthanides. The spin values calculated ab initio fit the experiment for most atoms and are almost unaffected by the choice of the xc functional. Among the systems with incorrectly obtained spin, there exist some cases (e.g., V, Pt) for which the result is found to be stable with respect to small variations in the xc approximation. These findings suggest a necessity for a significant modification of the exchange-correlation functional, probably of a nonlocal nature, to accurately describe such systems.

74 ATOMIC AND MOLECULAR PHYSICS↗

Monte Carlo burnup code acceleration with the correlated sampling method. Preliminary test on an UOX cell with TRIPOLI-4{sup R}

For several years, Monte Carlo burnup/depletion codes have appeared, which couple a Monte Carlo code to simulate the neutron transport to a deterministic method that computes the medium depletion due to the neutron flux. Solving Boltzmann and Bateman equations in such a way allows to track fine 3 dimensional effects and to get rid of multi-group hypotheses done by deterministic solvers. The counterpart is the prohibitive calculation time due to the time-expensive Monte Carlo solver called at each time step. Therefore, great improvements in term of calculation time could be expected if one could get rid of Monte Carlo transport sequences. For example, it may seem interesting to run an initial Monte Carlo simulation only once, for the first time/burnup step, and then to use the concentration perturbation capability of the Monte Carlo code to replace the other time/burnup steps (the different burnup steps are seen like perturbations of the concentrations of the initial burnup step). This paper presents some advantages and limitations of this technique and preliminary results in terms of speed up and figure of merit. Finally, we will detail different possible calculation scheme based on that method. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

TU-H-206-01: An Automated Approach for Identifying Geometric Distortions in Gamma Cameras

Purpose: To develop a clinically-deployable, automated process for detecting artifacts in routine nuclear medicine (NM) quality assurance (QA) bar phantom images. Methods: An artifact detection algorithm was created to analyze bar phantom images as part of an ongoing QA program. A low noise, high resolution reference image was acquired from an x-ray of the bar phantom with a Philips Digital Diagnost system utilizing image stitching. NM bar images, acquired for 5 million counts over a 512×512 matrix, were registered to the template image by maximizing mutual information (MI). The MI index was used as an initial test for artifacts; low values indicate an overall presence of distortions regardless of their spatial location. Images with low MI scores were further analyzed for bar linearity, periodicity, alignment, and compression to locate differences with respect to the template. Findings from each test were spatially correlated and locations failing multiple tests were flagged as potential artifacts requiring additional visual analysis. The algorithm was initially deployed for GE Discovery 670 and Infinia Hawkeye gamma cameras. Results: The algorithm successfully identified clinically relevant artifacts from both systems previously unnoticed by technologists performing the QA. Average MI indices for artifact-free images are 0.55. Images with MI indices < 0.50 have shown 100% sensitivity and specificity for artifact detection when compared with a thorough visual analysis. Correlation of geometric tests confirms the ability to spatially locate the most likely image regions containing an artifact regardless of initial phantom orientation. Conclusion: The algorithm shows the potential to detect gamma camera artifacts that may be missed by routine technologist inspections. Detection and subsequent correction of artifacts ensures maximum image quality and may help to identify failing hardware before it impacts clinical workflow. Going forward, the algorithm is being deployed to monitor data from all gamma cameras within our health system.

60 APPLIED LIFE SCIENCES↗

In-situ thermomechanical measurements during burst testing of Zr claddings using digital image correlation and infrared thermography techniques

Burst testing has long been a relied-on method for assessing fuel cladding materials in light-water reactoraccident scenarios. However, burst testing historically provided minimal in-situ observations beyond a few thermocouple readings, pressure from transducers, and post-test deformation measurements. Acquisition of full cladding thermomechanical data throughout a burst test would be invaluable to fuel system qualification, material model development and fuel performance code validation, such as the BISON fuel performance code. Recently, methodologies for simultaneously applying 2-dimensional digital image correlation and infrared thermography techniques to quantify the relationship between temperature, internal cladding pressure, and deformation during burst testing were developed. This work details results from the application of these techniques to burst testing of Zircaloy-4 cladding segments subjected to loss-of-coolant accident transients in an air environment. Two types of tests were performed with: (a) cladding segments connected to a fixed pressure reservoir as well as (b) closed systems where internal pressure increased during transients. In-situ thermomechanical measurements including strain and thermal gradient data are presented, demonstrating the effectiveness of applying combined surface measurement techniques to burst testing

Bell, Sam↗

Correlation of Qualification and Accelerated Testing with Field Degradation

Qualification testing of solar photovoltaic (PV) modules per IEC 61215 standard encompasses a set of well-defined accelerated stress tests (irradiation, environmental, mechanical and electrical) with strict pass/fail criteria based on functionality/performance, electrical and mechanical safety, and visual requirements. The qualification testing does not identify all the possible reliability failures or durability issues witnessed in the actual field. However, it does identify the major/catastrophic design quality issues (infant mortality), which could occur early in a module’s field life. Unfortunately, in the industry, there is no consensus-based standard or protocol available to validate manufacturers’ warranty period claims based on the end-of-life wear-out failure mechanisms. Being able to predict the field degradation rates and lifetime using mode-specific accelerated tests on moderately field-aged modules, for example 10 years, for certain commonly occurring degradation modes would be a powerful contribution to all the stakeholders of the PV industry. There is a need to formulate guidelines to find the correlation of accelerated testing with field degradation for individual degradation modes observed in the field. Potential approaches to fulfill this need were experimented in this project and are presented in this report. Two of the most commonly seen degradation modes – encapsulant browning and solder bond thermomechanical fatigue – are addressed in this report through presenting the accelerated testing methods and physical modelling approaches. Two accelerated test methods (UV and thermal cycling) were designed to induce the wear-out mechanisms in the modules and not infant mortality failures. To focus on the wear-out failure modes, the tests were performed on field-aged modules, instead of fresh modules, with known degradation rates and degradation modes. The degradation rates were measured based on the degradation rates of individual cell parameters (short-circuit current, I sc and series resistance, R s ) instead of the degradation rate of maximum power (P max ) which cannot be used to study any specific/limited degradation mode as the P max degradation could be caused by many different degradation modes. The key characteristic parameter considered for encapsulant discoloration and solder bond degradation is I sc and R s , respectively. The developed physical models/equations relating the testing degradation data and field weather data were utilized to determine the acceleration factor (AF) and to predict the degradation rate for a specific degradation mode of PV modules installed in two different climates, Arizona (hot) and New York (cold). The predicted degradation rates for encapsulant browning and solder bond degradation have also been validated against the actual measured field degradation rates. UV testing cost reduction: To determine acceleration factor, single UV chamber was used for accelerated UV testing at three different temperatures simultaneously, instead of three chambers for three temperatures (or one chamber sequentially which is an extremely time-consuming approach). A passive heating approach was successfully used to achieve and maintain multiple temperatures in the accelerated UV chamber. Foam insulation boards of varying thicknesses were utilized to obtain three different temperatures for UV testing. However, these foam materials tend to disintegrate in the presence of moisture. To alleviate this problem, silicone heating blankets with temperature controls and humidifier can be used if the UV testing is to be performed under hot-humid conditions instead of conventional hot-dry conditions. Thermal cycling testing cost reduction: Single thermal cycling chamber was used for accelerated thermal cycling testing at three different upper temperatures simultaneously, instead of three chambers for three upper temperatures (or one chamber sequentially which is an extremely time-consuming approach). An active heating approach based on silicone heating blankets was successfully used to achieve and maintain multiple upper temperatures in the accelerated thermal cycling chamber. Such blankets provide stable temperature control and thereby more reliable and repeatable for replicate experiments.

14 SOLAR ENERGY↗

COVID-19–Related School Closures, United States, July 27, 2020–June 30, 2022

As part of a multiyear project that monitored illness-related school closures, we conducted systematic daily online searches during July 27, 2020–June 30, 2022, to identify public announcements of COVID-19–related school closures (COVID-SCs) in the United States lasting ≥1 day. We explored the temporospatial patterns of COVID-SCs and analyzed associations between COVID-SCs and national COVID-19 surveillance data. COVID-SCs reflected national surveillance data: correlation was highest between COVID-SCs and both new PCR test positivity (correlation coefficient [r] = 0.73, 95% CI 0.56–0.84) and new cases (r = 0.72, 95% CI 0.54–0.83) during 2020–21 and with hospitalization rates among all ages (r = 0.81, 95% CI 0.67–0.89) during 2021–22. The numbers of reactive COVID-SCs during 2020–21 and 2021–22 greatly exceeded previously observed numbers of illness-related reactive school closures in the United States, notably being nearly 5-fold greater than reactive closures observed during the 2009 influenza (H1N1) pandemic.

60 APPLIED LIFE SCIENCES↗

Handling Handles: Nonplanar Integrability in N = 4 Supersymmetric Yang-Mills Theory

We propose an integrability setup for the computation of correlation functions of gauge-invariant operators in N=4 supersymmetric Yang-Mills theory at higher orders in the large N c genus expansion and at any order in the ’t Hooft coupling g$2\atop{YM}$N c . In this multistep proposal, one polygonizes the string world sheet in all possible ways, hexagonalizes all resulting polygons, and sprinkles mirror particles over all hexagon junctions to obtain the full correlator. We test our integrability-based conjecture against a nonplanar four-point correlator of large 1/2 Bogomol’nyi-Prasad-Sommerfield operators at one and two loops.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗