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At least 73 records · Page 4

Investigation of reaction kinetics and interfacial phase formation in Ti3Al + Nb composites

Titanium aluminide metal matrix composites are prominent materials systems being considered for high temperature aerospace applications. One of the major problems with this material is the reactivity between existing reinforcements and the matrix after prolonged thermal exposure. This paper presents results from an investigation of reaction kinetics between Ti-14Al-21Nb (wt pct) and SCS-6 fibers and SiC fibers with surface coatings of TiB2, TiC, TiN, W, and Si. Microstructural evaluation of the reaction layers as well as matrix regions around the fibers is presented.

Wawner, F. E.↗

Oxidation characteristics of Ti-25Al-10Nb-3V-1Mo

Static oxidation kinetics of the super-alpha 2 titanium-aluminide alloy Ti-25Al-10Nb-3V-1Mo (at. percent) were investigated in air over the temperature range of 650 to 1000 C using thermogravimetric analysis. The oxidation kinetics were complex at all exposure temperatures and displayed up to three distinct oxidation rates. Breakaway oxidation occurred after long exposure times at high temperatures. Oxidation products were determined using X-ray diffraction techniques, electron microprobe analysis, and energy dispersive X-ray analysis. Oxide scale morphology was examined by scanning electron microscopy of the surfaces and cross sections of oxidized specimens. The oxides during the parabolic stages were compact and multilayered, consisting primarily of TiO2 doped with Nb, a top layer of Al2O3, and a thin bottom layer of TiN. The transition between the second and third parabolic stage was found to be linked to the formation of a TiAl layer at the oxide-metal interface. Porosity was formed during the third stage, causing degradation of the oxide and the beginning of breakaway oxidation.

Wallace, T. A.↗

Discontinuously reinforced intermetallic matrix composites via XD synthesis

A review is given of recent results obtained for discontinuously reinforced intermetallic matrix composites produced using the XD process. Intermetallic matrices investigated include NiAl, multiphase NiAl + Ni2AlTi, CoAl, near-gamma titanium aluminides, and Ll2 trialuminides containing minor amounts of second phase. Such mechanical properties as low and high temperature strength, compressive and tensile creep, elastic modulus, ambient ductility, and fracture toughness are discussed as functions of reinforcement size, shape, and volume fraction. Microstructures before and after deformation are examined and correlated with measured properties. An observation of interest in many of the systems examined is 'dispersion weakening' at high temperatures and high strain rates. This behavior is not specific to the XD process; rather similar observations have been reported in other discontinuous composites. Proposed mechanisms for this behavior are presented.

Kumar, K. S.↗

Thermomechanical fatigue behavior of SiC/Ti-24Al-11Nb in air and argon environments

A series of tension-tension, load-controlled thermomechanical fatigue (TMF) tests were conducted on a titanium aluminide composite in both laboratory air and a flowing argon environment. Results from these tests show that the environment plays an increasingly important role as applied stress levels are decreased. Differences in damage mechanisms between the two environments were observed which corresponds to observed variations in TMF lives.

Bartolotta, Paul A.↗

Oxidation characteristics of Ti-33Al-6Nb-1.4Ta

Static oxidation kinetics of the gamma titanium-aluminide alloy Ti-33Al-6Nb-1.4Ta (wt pct) have been investigated in air from 700 to 1000 C and in oxygen from 800 to 1000 C using thermogravimetric analysis. The oxidation kinetics were controlled by the presence of alumina for all oxygen exposures and in air below 800 C, while the kinetics in air above 800 C were more complex. Oxidation products were identified using X-ray diffraction techniques. Oxide scale morphology was examined by SEM and TEM of the surfaces and across sections of oxidized specimens. The oxidation products formed depended on the exposure: Al2O3 and TiO2 were identified on all specimens exposed in and air and oxygen; the nitride phases TiN and Ti2AlN were also found on specimens exposed in air.

Wallace, T. A.↗

Advanced composites in Japan

The JTEC Panel on Advanced Composites surveyed the status and future directions of Japanese high-performance ceramic and carbon fibers and their composites in metal, intermetallic, ceramic, and carbon matrices. Because of a strong carbon and fiber industry, Japan is the leader in carbon fiber technology. Japan has initiated an oxidation-resistant carbon/carbon composite program. With its outstanding technical base in carbon technology, Japan should be able to match present technology in the U.S. and introduce lower-cost manufacturing methods. However, the panel did not see any innovative approaches to oxidation protection. Ceramic and especially intermetallic matrix composites were not yet receiving much attention at the time of the panel's visit. There was a high level of monolithic ceramic research and development activity. High temperature monolithic intermetallic research was just starting, but notable products in titanium aluminides had already appeared. Matrixless ceramic composites was one novel approach noted. Technologies for high temperature composites fabrication existed, but large numbers of panels or parts had not been produced. The Japanese have selected aerospace as an important future industry. Because materials are an enabling technology for a strong aerospace industry, Japan initiated an ambitious long-term program to develop high temperature composites. Although just starting, its progress should be closely monitored in the U.S.

Diefendorf, R. Judd↗

Scanning and Transmission Electron Microscopy of High Temperature Materials

Software and hardware updates to further extend the capability of the electron microscope were carried out. A range of materials such as intermetallics, metal-matrix composites, ceramic-matrix composites, ceramics and intermetallic compounds, based on refractory elements were examined under this research. Crystal structure, size, shape and volume fraction distribution of various phases which constitute the microstructures were examined. Deformed materials were studied to understand the effect of interfacial microstructure on the deformation and fracture behavior of these materials. Specimens tested for a range of mechanical property requirements, such as stress rupture, creep, low cycle fatigue, high cycle fatigue, thermomechanical fatigue, etc. were examined. Microstructural and microchemical stability of these materials exposed to simulated operating environments were investigated. The EOIM Shuttle post-flight samples were also examined to understand the influence of low gravity processing on microstructure. In addition, fractographic analyses of Nb-Zr-W, titanium aluminide, molybdenum silicide and silicon carbide samples were carried out. Extensive characterization of sapphire fibers in the fiber-reinforced composites made by powder cloth processing was made. Finally, pressure infiltration casting of metal-matrix composites was carried out.

Source record↗

Design for Oxidation Resistance

Alloys intended for use in high-temperature environment rely on the formation of a continuous, compact, slow-growing oxide layer for oxidation and hot corrosion resistance. To be protective, this oxide layer must be chemically, thermodynamically stable. Successful alloy design for oxidative environment is best achieved by developing alloys that are capable of forming adherent scales of either alumina (Al2O3), chromia (Cr2O3), or silica (SiO2). In this article, emphasis has been placed on the issue related to high-temperature oxidation of superalloys used in gas turbine engine application. Despite the complexity of these alloys, optimal performance has been associated with protective alumina scale formation. As will be described below, both compositional makeup and protective coatings play key role in providing oxidation protection. Other high-temperature materials described include nickel and titanium aluminide intermetallics, refractory metal, and ceramics.

Smialek, James L.↗

TiAl Sheet Development for Axisymmetric Hypersonic Structures

Gamma Titanium aluminide sheet structure technologies are focused on in this effort, including experiments to evaluate laser beam welding of thin sheet structure; superplastic forming and diffusion bonding of thin sheet structure; and, demonstration of fabricability of a hot-formed "egg crate" type core with brazed top and bottom face sheets. The fabricated subelement is known as "gator hide" and has the potential to replace more conventional honeycomb structure. All three area demonstrations were successful.

Das, Gopal↗

Preliminary Study on Fatigue Strengths of Fretted Ti-48Al-2Cr-2Nb

The fatigue behavior (stress-life curve) of gamma titanium aluminide (Ti-48Al-2Cr-2Nb, atomic percent) was examined by conducting two tests: first, a fretting wear test with a fatigue specimen in contact with a typical nickel-based superalloy contact pad in air at temperatures of 296 and 823 K and second, a high-cycle fatigue test of the prefretted Ti-48Al-2Cr-2Nb fatigue specimen at 923 K. Reference high-cycle fatigue tests were also conducted with unfretted Ti-48Al-2Cr-2Nb specimens at 923 K. All Ti-48Al-2Cr-2Nb fatigue specimens were machined from cast slabs. The results indicate that the stress-life results for the fretted Ti-48Al-2Cr-2Nb specimens exhibited a behavior similar to those of the unfretted Ti-48Al-2Cr-2Nb specimens. The values of maximum stress and life for the fretted specimens were almost the same as those for the unfretted specimens. The resultant stress-life curve for the unfretted fatigue specimens was very flat. The flat appearance in the stress-life curve of the unfretted specimens is attributed to the presence of a high density of casting pores. The fatigue strengths of both the fretted and unfretted specimens can be significantly affected by the presence of this porosity, which can decrease the fatigue life of Ti-48Al-2Cr-2Nb. The presence of the porosity made discerning the effect of fretting damage on fatigue strength and life of the specimens difficult.

Miyoshi, Kazuhisa↗

High Speed Research: Propulsion Project Accomplishments

This past year has been one of great accomplishment for the propulsion element of NASA's High Speed Research (HSR) Program. The HSR Program is a NASA/industry partnership to develop the high-risk/high-payoff airframe and propulsion technologies applicable to a second-generation supersonic commercial transport, or High Speed Civil Transport (HSCT). The propulsion element, which also involves industry partners, is managed by the NASA Lewis Research Center. These technologies will contribute greatly to U.S. industry's ability to make an informed product launch decision for an HSCT vehicle. Specific NASA Lewis accomplishments in 1997 include: 1. Small-scale combustor sector tests conducted in Lewis' Engine Research Building contributed to the evolution of approaches to developing a combustor with ultralow NOx emissions. 2. Components were tested in Lewis' CE-9 facility (in Lewis' Engine Research Building) to assess the performance of candidate ceramic matrix composite (CMC) materials in this realistic combustion environment. Test results were promising, and acceptable levels of structural durability were demonstrated for the ceramic matrix composite material tested. Ceramic matrix composites continue to show great promise for use in HSCT combustor liners. 3. Engine emissions tests in Lewis' Propulsion Systems Laboratory provided insight into other classes of emissions (e.g., particulates and aerosols) which will be important to control in HSCT propulsion system designs. 4. Small-scale nozzle tests conducted in Lewis' Aero-Acoustic Propulsion Laboratory are contributing to the design of a low-noise, high-performance mixer/ejector nozzle configuration for HSCT engines. Over 18,000 hours of durability testing were completed in Lewis' materials laboratories to evaluate superalloy and g-titanium aluminide performance for HSCT nozzle applications. A two-dimensional supersonic inlet concept was tested in Lewis' 10- by 10-Foot Supersonic Wind Tunnel. The extensive database and the knowledge gained contributed to the selection of a two-dimensional inlet as the preferred inlet concept for the HSR Program.

Shaw, Robert J.↗

Third-Generation TiAl Alloy Tested: Exhibits Promising Properties for Rotating Components

The Revolutionary Turbine Accelerator/Turbine-Based Combined Cycle (RTA/TBCC) Program for the next-generation launch vehicle has targeted gamma titanium aluminide as a potential compressor and structural material. Because of the high compressor inlet and exit temperatures, the TBCC engine requires higher temperature materials than conventional Ti alloys, and because of its stringent thrust-to-weight requirements, the engine requires low-density material to be utilized wherever possible. Third-generation gamma alloys offer higher temperature capability along with low density and high stiffness. A high-temperature, high-strength *-TiAl alloy with a high Nb-content (Gamma MET PX1) was selected for evaluation. The microstructure and mechanical properties of Gamma Met PX (GMPX) in both the as-extruded and a lamellar heat-treated condition and the influence of the microstructure on the tensile, creep, and fatigue properties were investigated in-house.

Draper, Susan L.↗

Ti-48Al-2Cr-2Nb Evaluated Under Fretting Conditions

Material parameters govern many of the design decisions in any engineering task. When two materials are in contact and microscopically small, relative motions (either vibratory or creeping) occur, and fretting fatigue can result. Fretting fatigue is a material response influenced by the materials in contact as well as by such variables as loading and vibratory conditions. Fretting produces fresh, clean interacting surfaces and induces adhesion, galling, and wear in the contact zone. Time, money, and materials are unnecessarily wasted when galling and wear result in excessive fretting fatigue that leads to poorly performing, unreliable mechanical systems. Fretting fatigue is a complex problem of significant interest to aircraft engine manufacturers. It can occur in a variety of engine components. Numerous approaches, depending on the component and the operating conditions, have been taken to address the fretting problems. The components of interest in this investigation were the low-pressure turbine blades and disks. The blades in this case were titanium aluminide, Ti-48Al-2Cr- 2Nb, and the disk was a nickel-base superalloy, Inconel 718 (IN 718). A concern for these airfoils is the fretting in fitted interfaces at the dovetail where the blade and disk are connected. Careful design can reduce fretting in most cases, but not completely eliminate it, because the airfoils frequently have a skewed (angled) blade-disk dovetail attachment, which leads to a complex stress state. Furthermore, the local stress state becomes more complex when the influence of the metal-metal contact and the edge of contact are considered.

Miyoshi, Kazuhisa↗

Fretting Wear of Ti-48Al-2Cr-2Nb

An investigation was conducted to examine the wear behavior of gamma titanium aluminide (Ti-48Al-2Cr-2Nb in atomic percent) in contact with a typical nickel-base superalloy under repeated microscopic vibratory motion in air at temperatures from 296-823 K. The surface damage observed on the interacting surfaces of both Ti-48Al-2Cr-2Nb and superalloy consisted of fracture pits, oxides, metallic debris, scratches, craters, plastic deformation, and cracks. The Ti-48Al-2Cr-2Nb transferred to the superalloy at all fretting conditions and caused scuffing or galling. The increasing rate of oxidation at elevated temperatures led to a drop in Ti-48Al-2Cr-2Nb wear at 473 K. Mild oxidative wear was observed at 473 K. However, fretting wear increased as the temperature was increased from 473-823 K. At 723 and 823 K, oxide disruption generated cracks, loose wear debris, and pits on the Ti-48Al-2Cr-2Nb wear surface. Ti-48Al-2Cr-2Nb wear generally decreased with increasing fretting frequency. Both increasing slip amplitude and increasing load tended to produce more metallic wear debris, causing severe abrasive wear in the contacting metals. Keywords

Miyoshi, Kazuhisa↗

Micromechanical Characterization and Texture Analysis of Direct Cast Titanium Alloys Strips

This research was conducted to determine a post-processing technique to optimize mechanical and material properties of a number of Titanium based alloys and aluminides processed via Melt Overflow Solidification Technique (MORST). This technique was developed by NASA for the development of thin sheet titanium and titanium aluminides used in high temperature applications. The materials investigated in this study included conventional titanium alloy strips and foils, Ti-1100, Ti-24Al-11Nb (Alpha-2), and Ti-48Al-2Ta (Gamma). The methodology used included micro-characterization, heat-treatment, mechanical processing and mechanical testing. Characterization techniques included optical, electron microscopy, and x-ray texture analysis. The processing included heat-treatment and mechanical deformation through cold rolling. The initial as-cast materials were evaluated for their microstructure and mechanical properties. Different heat-treatment and rolling steps were chosen to process these materials. The properties were evaluated further and a processing relationship was established in order to obtain an optimum processing condition. The results showed that the as-cast material exhibited a Widmanstatten (fine grain) microstructure that developed into a microstructure with larger grains through processing steps. The texture intensity showed little change for all processing performed in this investigation.

Source record↗

Chemical stability of titanium diboride reinforcement in nickel aluminide matrices

Chemical stability of TiB2 reinforcement in NiAl (45 at percent Al) and Ni3Al (24 at percent Al) matrices has been theoretically and experimentally investigated. Calculations were made using thermodynamic properties of the systems to predict behavior at temperatures between 1173 and 1573 K. Experimental investigation of hot-press consolidated TiB2 particulate/prealloyed matrix powder blends were conducted using energy dispersive X-ray analysis, XRD, AES, and TEM. The theoretical and experimental analyses suggest that TiB2 is chemically stable in both matrices up to 1573 K; however, TiB2 was found to be less active in NiAl than in Ni3Al due to lower nickel activity in NiAl.

Rigney, J. D.↗

Cost-Effective TiAl based Materials

Because of their inherent low ductility, TiAl-based materials are difficult to fabricate, especially thin gage titanium gamma aluminide (TiAl) sheet and foil. In this paper, an innovative powder metallurgy approach for producing cost-effective thin gage TiAl sheets (with 356 mm long and 235 mm wide, and a thickness of 0.74, 1.09, 1.55, and 2.34 mm, respectively) is presented. The microstructures and tensile properties at room and elevated temperatures of the thin gage TiAl are studied. Results show that these TiAl sheets have a relatively homogenous chemistry, uniform microstructure, and acceptable mechanical properties. This work demonstrates a cost-effective method for producing both flat products (sheet/foil) and complex chunky parts of TiAl for various advanced applications including aerospace and automotive industries.

Moxson, V. S.↗

Fatigue Behavior of Coated Titanium Alloys

Advanced multi-component TiAlCrTaSiN-based multilayered coatings were developed and processed onto Ti-6Al-4V (Ti-6-4) and GammaMet PX (GMPX or TiAl) alloys by a magnetron-enhanced physical vapor deposition technique. The coatings have recently been in development with the goal of improving advanced titanium alloy, turbine engine component durability and oxidation-erosion resistance. In this work, the performance of the multi-component coating system (including the outer layer nitride based coating and inner TiAlCrSi oxidation barrier bond coat) was studied, and the coating's influence on the fatigue behavior of the titanium-based alloys were compared. Although the multi-component coating was initially optimized to improve the coating's high temperature oxidation and erosion resistance, the lower ductility nitride-based coating needs further work on microstructure or composition to improve its mechanical stress resistance and strain tolerance for use in cyclically loaded, turbine blade operating conditions. This is particularly true for GMPX and other γ-TiAl alloys because these intermetallic titanium alloys have limited ductility and are very sensitive to defects such as coating cracks. However, the inner layer TiAlCrSi-coating had better adhesion and ductility, and may be a suitable choice to improve the oxidation resistance of titanium alloys.

Oxidation Barrier Coatings↗