Quantum-mechanical kinetic theory of loaded spheres. II.
Quantum mechanical kinetic theory of gas loaded spheres to obtain limit of transport coefficients and relaxation time
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Quantum mechanical kinetic theory of gas loaded spheres to obtain limit of transport coefficients and relaxation time
Transfer of water through nonwettable vinyl fluoride membranes has two unique features - /1/ very low water transfer rates can be held constant by holding temperature and solute concentrations constant, /2/ the pressure gradient against which water is transported is limited only by solution breakthrough or membrane strength.
Recent studies of the space power system (SPS) are integrated into a total social cost framework developed for terrestrial central electric power systems. Total social costs include the projection of commercial economics to the time frame of interest as well as the federal research, development and demonstration (RD&D) costs, the health impacts, the resources required, the environmental impacts and other social costs. The SPS system is limited to transporting all materials from the earth's surface to geosynchronous orbit. Only silicon photovoltaic is considered as the SPS energy conversion technique. Costs and impacts of the LWR are considered as a reference for nuclear systems, and the low BTU coal gasification with combined cycle gas and steam turbines is considered as a reference for a fossil central electric plant. The ground solar systems considered are solar thermal using the central receiver approach with thermal storage, and solar photovoltaic using the silicon cell with battery storage.
In space, limits on transportation effectiveness are set by requirements for reaction mass, since reaction mass must be carried on board and often comprises the majority of the launch mass of a space system. Thus, applications where a tether can be used for propulsion with no requirement of reaction mass are extremely attractive for space development. It is a remarkable fact that tethers can be used to increase orbital energy with no requirement for reaction mass.
The sodium-sulfur battery is emerging as a prime high-temperature energy storage technology for space flight applications. A Na-S cell demonstration is planned for a 1995-96 NASA Space Shuttle flight which focuses on the microgravity effects on individual cells. The experiment is not optimized for battery performance as such. Rather, it maximizes the variety of operating conditions which the Na-S cell is capable of in a relatively short 5-day flight. The demonstration is designed to reveal the effects of microgravity by comparison with ground test control cells experiencing identical test conditions but with gravity. Specifically, limitations of transport dynamics and associated cell performance characteristics should be revealed. The Na-S Cell Technology Flight Experiment consists of three separate experiments designed to determine cell operating characteristics, detailed electrode kinetics and reactant distributions.
The development of an algorithm for the solution of the compressible Euler equations at high Mach numbers on unstructured tetrahedral meshes is described. The basic algorithm is constructed in the form of a central difference scheme plus an explicit added artificial viscosity based upon fourth order differences of the solution. The stability of the solution in the vicinity of strong gradients is preserved by the incorporation of an additional artificial viscosity based upon a second order difference. Higher order accuracy is regained by using the ideas of flux corrected transport to limit the amount of added viscosity. The solution is advanced to steady state by means of an explicit multi-stage time-stepping method. The computational efficiency of the complete process is improved by incorporating an unstructured multigrid acceleration procedure. A number of flows of practical interest are analyzed to demonstrate the numerical performance of the proposed approach.
Two classes of material processing scenarios will feature prominently in future interplanetary exploration: in situ production using locally available materials in lunar or planetary landings and high performance structural materials which carve out a set of properties for uniquely hostile space environments. To be competitive, high performance materials must typically offer orders of magnitude improvements in thermal conductivity or insulation, deliver high strength-to-weight ratios, or provide superior durability (low corrosion and/or ablative character, e.g., in heat shields). The space-related environmental parameters of high radiation flux, low weight, and superior reliability limits many typical aerospace materials to a short list comprising high performance alloys, nanocomposites and thin-layer metal laminates (Al-Cu, Al-Ag) with typical dimensions less than the Frank-Reed-type dislocation source. Extremely light weight carbon-carbon composites and carbon aerogels will be presented as novel examples which define broadened material parameters, particularly owing to their extreme thermal insulation (R-32-64) and low densities (<0.01 g/cu cm) approaching that of air itself. Even with these low-weight payload additions, rocket thrust limits and transport costs will always place a premium on assembling as much structural and life support resources upon interplanetary, lunar, or asteroid arrival. As an example, for in situ lunar glass manufacture, solar furnaces reaching 1700 C for pure silica glass manufacture in situ are compared with sol-gel technology and acid-leached ultrapure (<0.1% FeO) silica aerogel precursors.
Two classes of material processing scenarios will feature prominently in future interplanetary exploration- in situ production using locally available materials in lunar or planetary landings and high performance structural materials which carve out a set of properties for uniquely hostile space environments. To be competitive, high performance materials must typically offer orders of magnitude improvements in thermal conductivity or insulation, deliver high strength-to-weight ratios, or provide superior durability (low corrosion and/or ablative character, e.g. in heat shields). The space-related environmental parameters of high radiation flux, low weight and superior reliability limits many typical aerospace materials to a short list comprising high performance alloys, nanocomposites and thin-layer metal laminates (Al-Cu, Al-Ag) with typical dimensions less than the Frank-Reed-type dislocation source. Extremely light weight carbon-carbon composites and car on aerogels will be presented as novel examples which define broadened material parameters, particularly owing to their extreme thermal insulation (R-32-64) and low densities (less than 0.01 g/cc) approaching that of air itself. Even with these low weight payload additions, rocket thrust limits and transport costs will always place a premium on assembling as much structural and life support resources upon interplanetary, lunar or asteroid arrival. As an example for in situ lunar glass manufacture, solar furnaces reaching 1700 C for pure silica glass manufacture in situ are compared with sol-gel technology and acid-leached ultrapure (less than 0.1% FeO) silica aerogel precursors.
CVD SiC and sintered alpha-SiC samples were exposed at 1316 C in a high pressure burner rig at total pressures of 5.7, 15, and 25 atm for times up to 100h. Variations in sample emittance for the first nine hours of exposure were used to determine the thickness of the silica scale as a function of time. After accounting for volatility of silica in water vapor, the parabolic rate constants for Sic in water vapor pressures of 0.7, 1.8 and 3.1 atm were determined. The dependence of the parabolic rate constant on the water vapor pressure yielded a power law exponent of one. Silica growth on Sic is therefore limited by transport of molecular water vapor through the silica scale.
Plant culture in oxygen concentrations below ambient is known to stimulate vegetative growth, but apart from reports on increased leaf number and weight, little is known about development at subambient oxygen concentrations. Arabidopsis thaliana (L.) Heynh. (cv. Columbia) plants were grown full term in pre-mixed atmospheres with oxygen partial pressures of 2.5, 5.1, 10.1, 16.2, and 21.3 kPa O2, 0.035 kPa CO2 and the balance nitrogen under continuous light. Fully expanded leaves were harvested and processed for light and transmission electron microscopy or for starch quantification. Growth in subambient oxygen concentrations caused changes in leaf anatomy (increased thickness, stomatal density and starch content) that have also been described for plants grown under carbon dioxide enrichment. However, at the lowest oxygen treatment (2.5 kPa), developmental changes occurred that could not be explained by changes in carbon budget caused by suppressed photorespiration, resulting in very thick leaves and a dwarf morphology. This study establishes the leaf parameters that change during growth under low O2, and identifies the lower concentration at which O2 limitation on transport and biosynthetic pathways detrimentally affects leaf development. Grant numbers: NAG5-3756, NAG2-1020, NAG2-1375.
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Agricultural intensification in South Asia has resulted in the expansion and intensification of surface irrigation over the twentieth century. The resulting changes to the surface energy balance could affect the temperature contrasts between the South Asian land surface and the equatorial Indian Ocean, potentially altering the South Asian Summer Monsoon (SASM) circulation. Prior studies have noted apparent declines in the monsoon intensity over the twentieth century and have focused on how altered surface energy balances impact the SASM rainfall distribution. Here, we use the coupled Goddard Institute for Space Studies ModelE-R general circulation model to investigate the impact of intensifying irrigation on the large-scale SASM circulation over the twentieth century, including how the effect of irrigation compares to the impact of increasing greenhouse gas (GHG) forcing. We force our simulations with time-varying, historical estimates of irrigation, both alone and with twentieth century GHGs and other forcings. In the irrigation only experiment, irrigation rates correlate strongly with lower and upper level temperature contrasts between the Indian sub-continent and the Indian Ocean (Pearson's r = -0.66 and r = -0.46, respectively), important quantities that control the strength of the SASM circulation. When GHG forcing is included, these correlations strengthen: r = -0.72 and r = -0.47 for lower and upper level temperature contrasts, respectively. Under irrigated conditions, the mean SASM intensity in the model decreases only slightly and insignificantly. However, in the simulation with irrigation and GHG forcing, inter-annual variability of the SASM circulation decreases by *40 %, consistent with trends in the reanalysis products. This suggests that the inclusion of irrigation may be necessary to accurately simulate the historical trends and variability of the SASM system over the last 50 years. These findings suggest that intensifying irrigation, in concert with increased GHG forcing, is capable of reducing the variability of the simulated SASM circulation and altering the regional moisture transport by limiting the surface warming and reducing land-sea temperature gradients.
Long-duration, deep-space exploration and habitation missions demand robust and reliable technologies to ensure crew health, safety, and mission success. Local food production will be essential for crew nutrition and morale. However, at $10,000/lb, the payload costs and mass/volume limitations to transport and provide the necessary resources, including fertilizer, for an anticipated 30-month mission become challenging over time. For mission success and sustainability, the Environmental Control and Life Support System (ECLSS) of the near future will need to recover resources from all “waste” sources and be near-closed loop. Organic wastes (e.g., fecal and food) offer a renewable source of C, N, P, water and other trace elements necessary to sustain crop production. However, these high solidwastes are often difficult to treatdue to factors includingheterogeneity, complexity, high organic strength, and the presence of pathogens. To date, there is no flight-ready technology capable of treating mixed organic wastes, creating a technology gap for future space missions. To address this need, a prototype Organic Processor Assembly (OPA) was developed through collaboration between the University of South Florida (USF) and NASA’s Kennedy Space Center (KSC). The OPA is based on the anaerobic membrane bioreactor (AnMBR), a hybrid technology coupling high-rate anaerobic digestion with membrane filtration. The system is designed for an early planetary base (EPB) scenario to aid in closing the resource recovery loop and decreaseresupply dependence. This presentation discusses initial research pertaining to: 1) design challenges in maximizing hydraulic/organic throughputandReliability, Availability, Maintainability, and Safety(RAMS)while minimizingmass and volume; 2) create capabilities for treating simulated high solids waste under steady and non-steady state conditions; and 3) measuresolids performance parameter(s). Future research and development pertaining to further optimization on system operation, performance, and expanded treatment capabilities arepresented.
An initial assessment of a proposed High-Speed Civil Transport (HSCT) was conducted in the fall of 1995 at the NASA Langley Research Center. This configuration, known as the Industry Reference-H (Ref.-H), was designed by the Boeing Aircraft Company as part of their work in the High Speed Research program. It included a conventional tail, a cranked-arrow wing, four mixed-flow turbofan engines, and capacity for transporting approximately 300 passengers. The purpose of this assessment was to evaluate and quantify operational aspects of the Reference-H configuration from a pilot's perspective with the additional goal of identifying design strengths as well as any potential configuration deficiencies. This study was aimed at evaluating the Ref.-H configuration at many points of the aircraft's envelope to determine the suitability of the vehicle to accomplish typical mission profiles as well as emergency or envelope-limit conditions. Pilot-provided Cooper-Harper ratings and comments constituted the primary vehicle evaluation metric. The analysis included simulated real-time piloted evaluations, performed in a 6 degree of freedom motion base NASA Langley Visual-Motion Simulator, combined with extensive bath analysis. The assessment was performed using the third major release of the simulation data base (known as Ref.-H cycle 2B).
Based on the observed density of impact craters on the Venus surface obtained from Venera 15-16 radar images, a formalism to estimate the upper bounds on the contributions made to lithospheric heat transport by volcanism and lithospheric recycling is presented. The Venera 15-16 data, if representative of the entire planet, limit the average rate of volcanic resurfacing on Venus to less than 2 cu km/yr (corresponding to less than 1 percent of the global heat loss), and limit the rate of lithospheric recycling to less than 1.5 sq km/yr (and probably to less than 0.5 sq km/yr), corresponding to 25 percent (and to 9 percent) of the global heat loss. The present results indicate that heat loss at lithospheric levels in Venus is dominated by conduction.
Ironically, the limiting factor to a national heavy lift strategy may not be the rocket technology needed to throw a heavy payload, but rather the terrestrial infrastructure - roads, bridges, airframes, and buildings - necessary to transport, acceptance test, and process large spacecraft. Failure to carefully consider how large spacecraft are designed, and where they are manufactured, tested, or launched, could result in unforeseen cost to modify/develop infrastructure, or incur additional risk due to increased handling or elimination of key verifications. During test and verification planning for the Altair project, a number of transportation and test issues related to the large payload diameter were identified. Although the entire Constellation Program - including Altair - was canceled in the 2011 NASA budget, issues identified by the Altair project serve as important lessons learned for future payloads that may be developed to support national "heavy lift" strategies. A feasibility study performed by the Constellation Ground Operations (CxGO) project found that neither the Altair Ascent nor Descent Stage would fit inside available transportation aircraft. Ground transportation of a payload this large over extended distances is generally not permitted by most states, so overland transportation alone would not have been an option. Limited ground transportation to the nearest waterway may be permitted, but water transportation could take as long as 66 days per production unit, depending on point of origin and acceptance test facility; transportation from the western United States would require transit through the Panama Canal to access the Kennedy Space Center launch site. Large payloads also pose acceptance test and ground processing challenges. Although propulsion, mechanical vibration, and reverberant acoustic test facilities at NASA s Plum Brook Station have been designed to accommodate large spacecraft, special handling and test work-arounds may be necessary, which could increase cost, schedule, and technical risk. Once at the launch site, there are no facilities currently capable of accommodating the combination of large payload size and hazardous processing (which includes hypergolic fuels, pyrotechnic devices, and high pressure gasses).
Conducting human exploration missions beyond Low Earth Orbit (LEO) will present unique challenges in the areas of supportability and maintainability. The durations of proposed missions can be relatively long and re-supply of logistics, including maintenance and repair items, will be limited or non-existent. In addition, mass and volume constraints in the transportation system will limit the total amount of logistics that can be flown along with the crew. These constraints will require that new strategies be developed with regards to how spacecraft systems are designed and maintained. NASA is currently developing Design Reference Missions (DRMs) as an initial step in defining future human missions. These DRMs establish destinations and concepts of operation for future missions, and begin to define technology and capability requirements. Because of the unique supportability challenges, historical supportability data and models are not directly applicable for establishing requirements for beyond LEO missions. However, supportability requirements could have a major impact on the development of the DRMs. The mass, volume, and crew resources required to support the mission could all be first order drivers in the design of missions, elements, and operations. Therefore, there is a need for enhanced analysis capabilities to more accurately establish mass, volume, and time requirements for supporting beyond LEO missions. Additionally, as new technologies and operations are proposed to reduce these requirements, it is necessary to have accurate tools to evaluate the efficacy of those approaches. In order to improve the analysis of supportability requirements for beyond LEO missions, the Space Missions Analysis Branch at the NASA Langley Research Center is developing the Exploration Maintainability Analysis Tool (EMAT). This tool is a probabilistic simulator that evaluates the need for repair and maintenance activities during space missions and the logistics and crew requirements to support those activities. Using a Monte Carlo approach, the tool simulates potential failures in defined systems, based on established component reliabilities, and then evaluates the capability of the crew to repair those failures given a defined store of spares and maintenance items. Statistical analysis of Monte Carlo runs provides probabilistic estimates of overall mission safety and reliability. This paper will describe the operation of the EMAT, including historical data sources used to populate the model, simulation processes, and outputs. Analysis results are provided for a candidate exploration system, including baseline estimates of required sparing mass and volume. Sensitivity analysis regarding the effectiveness of proposed strategies to reduce mass and volume requirements and improve mission reliability is included in these results.
A study of the mechanisms of flammability limits and the dynamics of flame extinguishment in premixed gas flames is described, a novel feature of which is the use of diluent gases having a wide range of radiative and diffusive transport properties. This feature enables an assessment of the importance of volumetric heat losses and Lewis number effects on these mechanisms. Additionally, effects of flame dynamics and flame front curvature are studied by employing spherically expanding flames obtained in a microgravity environment whereby natural convection is eliminated. New diagnostics include chamber pressure measurements and the first reported species concentration measurements in a microgravity combustion experiment. The limit mechanisms and extinguishment phenomena are found to be strongly influenced by the combined effects of radiant heat loss, Lewis number and flame curvature. Two new and as yet not well understood phenomena are reported: 'double flames' in rich H2-O2-CO2 mixtures and an 'inverse flammability region' in rich C3H8-O2-CO2 mixtures.