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At least 73 records · Page 4

Algorithms for Non-Negative Matrix Factorization on Noisy Data With Negative Values

Non-negative matrix factorization (NMF) is a dimensionality reduction technique that has shown promise for analyzing noisy data, especially astronomical data. For these datasets, the observed data may contain negative values due to noise even when the true underlying physical signal is strictly positive. Prior NMF work has not treated negative data in a statistically consistent manner, which becomes problematic for low signal-to-noise data with many negative values. In this paper we present two algorithms, Shift-NMF and Nearly-NMF, that can handle both the noisiness of the input data and also any introduced negativity. Both of these algorithms use the negative data space without clipping or masking and recover non-negative signals without any introduced positive offset that occurs when clipping or masking negative data. We demonstrate this numerically on both simple and more realistic examples, and prove that both algorithms have monotonically decreasing update rules.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The effects of pressure anisotropy on Birkeland currents in dipole and stretched magnetospheres

Attention is given to two effects which modify the rate of generation of Birkeland currents from the values given by the Vasyliunas (1970) formula in a dipole, namely, nonisotropic plasma pressure and the radial distention of magnetic field lines. The parallel current at any given point is the integrated effect of the diversion of perpendicular currents along the length of the flux tube from the equator. The result for j-parallel in I is fully nonlinear. In a dipole field the effect of anisotropy is modest: j-parallel at the ionosphere is, irrespective of the r0 value, about factor of 2.4 larger for a large P-parallel anisotropy (r = 0.1) than for the isotropic case and factor of 0.2 smaller for r = 10. In the stretched field the comparable values are factor of 10 and factor of 0.06 for a field line intersecting the ionosphere at a dipole colatitude of 16.4 deg and crossing the equator at r0 of 20. The results exhibit differences in plasma density and plasma pressure along field lines between the stretched and dipole models.

Birmingham, Thomas J.↗

Drag Corrections in High-Speed Wind Tunnels

In the vicinity of a body in a wind tunnel the displacement effect of the wake, due to the finite dimensions of the stream, produces a pressure gradient which evokes a change of drag. In incompressible flow this change of drag is so small, in general, that one does not have to take it into account in wind-tunnel measurements; however, in compressible flow it beoomes considerably larger, so that a correction factor is necessary for measured values. Correction factors for a closed tunnel and an open jet with circular cross sections are calculated and compared with the drag - corrections already bown for high-speed tunnnels.

Ludwieg, H.↗

The Unknown Hydrogen Exosphere: Space Weather Implications

Recent studies suggest that the hydrogen (H) density in the exosphere and geocorona might differ from previously assumed values by factors as large as 2. We use the SAMI3 (Sami3 is Also a Model of the Ionosphere) and Comprehensive Inner Magnetosphere-Ionosphere models to evaluate scenarios where the hydrogen density is reduced or enhanced, by a factor of 2, relative to values given by commonly used empirical models. We show that the rate of plasmasphere refilling following a geomagnetic storm varies nearly linearly with the hydrogen density. We also show that the ring current associated with a geomagnetic storm decays more rapidly when H is increased. With respect to these two space weather effects, increased exosphere hydrogen density is associated with reduced threats to space assets during and following a geomagnetic storm.

Krall, J.↗

Design evaluation in technology assessment: Illustrated by auditory impedance and sound distribution problems

Technology is considered as a culture for changing a physical world and technology assessment questions the inherent cultural capability to modify power and material in support of living organisms. A comprehensive goal-parameter-synthesis-criterion specification is presented as a basis for a rational assessment of technology. The thesis queries the purpose of the assessed problems, the factors considered, the relationships between factors, and the values assigned those factors to accomplish the appropriate purpose. Stationary and sequential evaluation of enviro-organismic systems are delegated to the responsible personalities involved in design; from promoter/designer through contractor to occupant. Discussion includes design goals derived from organismic factors, definitions of human responses which establish viable criteria and relevant correlation models, linking stimulus parameters, and parallel problem-discipline centered design organization. A consistent concept of impedance, as a degradation in the performance of a specified parameter, is introduced to overcome the arbitrary inoperative connotations of terms like noise, discomfort, and glare. Applications of the evaluative specification are illustrated through design problems related to auditory impedance and sound distribution.

Halldane, J. F.↗

Factors which Limit the Value of Additional Redundancy in Human Rated Launch Vehicle Systems

The National Aeronautics and Space Administration (NASA) has embarked on an ambitious program to return humans to the moon and beyond. As NASA moves forward in the development and design of new launch vehicles for future space exploration, it must fully consider the implications that rule-based requirements of redundancy or fault tolerance have on system reliability/risk. These considerations include common cause failure, increased system complexity, combined serial and parallel configurations, and the impact of design features implemented to control premature activation. These factors and others must be considered in trade studies to support design decisions that balance safety, reliability, performance and system complexity to achieve a relatively simple, operable system that provides the safest and most reliable system within the specified performance requirements. This paper describes conditions under which additional functional redundancy can impede improved system reliability. Examples from current NASA programs including the Ares I Upper Stage will be shown.

Anderson, Joel M.↗

Intensity and spectral variations of Cyg X-1 observed from balloons

Observations of Cyg X-1 with a 20 to 200 keV balloon carried X-ray telescope in 1969, 1970, and 1972 are presented. These results reveal the following characteristics of Cyg X-1: The steep spectrum observed at E 10 keV during the radio quiet phase can extend to 200 keV. This phase may have lasted 21 months (July 1969 to March 1971). The low flux values are factors of 3 and 8 below the normal values at 30 and 100 keV respectively, are rarely observed, and may be associated with the early phase of the 1971 April X-ray transition. During some one hour periods, the intensity remained constant to approximately 20% and during other periods it varied a factor 2 in 5 minutes and a factor 10 in 1 hour. Complex spectral variations accompanied the intensity changes.

Matteson, J. L.↗

The Shape Factor for Pits and Its Impact on Pit Stability

This study employs the finite element method (FEM) to predict the impact of pit shape on pit stability via shape factors of various pit geometries relevant to localized corrosion. Lower values of the shape factor indicate an increased ease in maintaining pit stability. Analyzed geometries include undercut pits, bispherical pit-within-pit structures, and covered pits with perforated (lacy) covers. The effect of the water layer thickness, transport properties of the electrolyte inside and outside the pit, and cathode location on the pit shape factor were also explored. Results show that occluded pits exhibit lower shape factors than open ones, with disk-shaped pits decreasing further as c/r ratio and occlusion angle increase. The findings also suggest minimal influence from a secondary pit if the primary remains active. An equation is presented that quantifies the impact of lacy covers, revealing significant shape factor value reduction. Additionally, high salt concentrations inside pits have a limited stabilizing effect compared to geometry, while thin water layers and adjacent cathodic/sinks reduce pit stability.

Shehi, A. (ORCID:0009000271548041)↗

Impact of symmetry breaking and spin-orbit coupling on the band gap of halide perovskites

Halide perovskite (HP) materials have recently emerged as a class of semiconductors with immense promise for various optoelectronic applications, ranging from solar cells to light-emitting diodes. One of the unique attributes of HPs is their tunable band gaps with different factors governing their value. Furthermore, the first factor is related to relativistic corrections [“mass-Darwin,” connected to the ns 2 lone pairs, and spin-orbit coupling (SOC)] that induce an orbital shift or degeneracy splitting, resulting in a band-gap reduction. The second factor involves the structural configuration: in HPs the local symmetry of each Wyckoff position tends to be broken, inducing an opening of the band gap. Based on high-throughput density functional theory calculations, this paper systematically studies a possible self-cancelation on the band-gap correction for HPs when the polymorphous configuration—structural effects—and the SOC—electronic effects—are included. Our results indicate that the nature of interplay between SOC and symmetry breaking (SB) is that they are independent decoupling effects to describe the band-gap magnitude in halide perovskites. As a result of that, we observe a transitivity of the band-gap description; i.e., if we know the band gap of halide perovskites without SB and SOC, we can independently add the effects of band-gap reduction due to SOC and band-gap opening due to SB, regardless of the order in which these effects are considered.

14 SOLAR ENERGY↗

Exposure Value /EV/ system expanded to include filter factors and transmittance

Application of the exposure value system requires that the system be extended to high brightness level and expanded to include filter factors. A minimum of four photographic factors are involved in the evaluation of an exposure which, when determined from tables of 1-stop interval, could introduce noticeable error.

Lindsey, W. F.↗

Performance Assessment for the E-Area Low-Level Radioactive Waste Disposal Facility at the Savannah River Site: Appendix F

As a supplement to Chapter 6, Section 6.1.1.3, Table F-1 through Table F-24 provide tabular results of the sensitivity analysis calculations for waste disposal timing (Sensitivity Case S6) in NR07E (Cases 3 and 4) and NR26E (Cases 1 through 4). The title of each table identifies the DU, sensitivity case, and performance measure. Section F.1.1 (Table F-1 through Table F-8) presents results for NR07E and Section F.1.2 (Table F-9 through Table F-24) presents results for NR26E. In each table, radionuclides are sorted from highest to lowest nominal concentration or dose factor. Nominal values are when waste disposal occurs at the start of operations; timeline values are when waste disposal occurs at the end of operations. The differences (Δ values) in the last column of each table equal the timeline concentration or dose factor minus the nominal concentration or dose factor, where DF and CF are shorthand designations for dose factor and concentration factor, respectively.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Data Assimilation using Non-invasive Monte Carlo Sensitivity Analysis of Reactor Kinetics Parameters

Accurately predicting the criticality of an experiment before interacting with the experimental components is very important for criticality safety. Radiation transport software can be utilized to calculate the effective neutron multiplication factor of a nuclear system. Because of the integral nature of the effective neutron multiplication factor, the value calculated contains various sources of nuclear-data induced uncertainty. The sensitivity analysis and data assimilation technique presented in this paper exhibit one possible method of identifying and reducing the effective neutron multiplication factor nuclear-data induced uncertainty. The results presented in this work show that it is possible to use relative sensitivity coefficients of the prompt neutron decay constant and the effective delayed neutron fraction to 239 Pu nuclear data to reduce nuclear-data induced uncertainties in the effective neutron multiplication factor. This work has been utilized by members of the Los Alamos National Laboratory project EUCLID (Experiments Underpinned by Computational Learning for Improvements in Nuclear Data) for optimally designing a new experiment, which will be used to reduce compensating errors in 239 Pu nuclear data.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Comparison of modern icing cloud instruments

Intercomparison tests with Particle Measuring Systems (PMS) were conducted. Cloud liquid water content (LWC) measurements were also taken with a Johnson and Williams (JW) hot-wire device and an icing rate device (Leigh IDS). Tests include varying cloud LWC (0.5 to 5 au gm), cloud median volume diameter (MVD) (15 to 26 microns), temperature (-29 to 20 C), and air speeds (50 to 285 mph). Comparisons were based upon evaluating probe estimates of cloud LWC and median volume diameter for given tunnel settings. Variations of plus or minus 10% and plus or minus 5% in LWC and MVD, respectively, were determined of spray clouds between test made at given tunnel settings (fixed LWC, MVD, and air speed) indicating cloud conditions were highly reproducible. Although LWC measurements from JW and Leigh devices were consistent with tunnel values, individual probe measurements either consistently over or underestimated tunnel values by factors ranging from about 0.2 to 2. Range amounted to a factor of 6 differences between LWC estimates of probes for given cloud conditions. For given cloud conditions, estimates of cloud MVD between probes were within plus or minus 3 microns and 93% of the test cases. Measurements overestimated tunnel values in the range between 10 to 20 microns. The need for improving currently used calibration procedures was indicated. Establishment of test facility (or facilities) such as an icing tunnel where instruments can be calibrated against known cloud standards would be a logical choice.

Takeuchi, D. M.↗

A conceptual design study of point focusing thin-film solar concentrators

Candidates for reflector panel design concepts, including materials and configurations, were identified. The large list of candidates was screened and reduced to the five most promising ones. Cost and technical factors were used in making the final choices for the panel conceptual design, which was a stiffened steel skin substrate with a bonded, acrylic overcoated, aluminized polyester film reflective surface. Computer simulations were run for the concentrator optics using the selected panel design, and experimentally determined specularity and reflectivity values. Intercept factor curves and energy to the aperture curves were produced. These curves indicate that surface errors of 2 mrad (milliradians) or less would be required to capture the desired energy for a Brayton cycle 816 C case. Two test panels were fabricated to demonstrate manufacturability and optically tested for surface error. Surface errors in the range of 1.75 mrad and 2.2 mrad were measured.

Source record↗

Using Whispering-Gallery-Mode Resonators for Refractometry

A method of determining the refractive and absorptive properties of optically transparent materials involves a combination of theoretical and experimental analysis of electromagnetic responses of whispering-gallery-mode (WGM) resonator disks made of those materials. The method was conceived especially for use in studying transparent photorefractive materials, for which purpose this method affords unprecedented levels of sensitivity and accuracy. The method is expected to be particularly useful for measuring temporally varying refractive and absorptive properties of photorefractive materials at infrared wavelengths. Still more particularly, the method is expected to be useful for measuring drifts in these properties that are so slow that, heretofore, the properties were assumed to be constant. The basic idea of the method is to attempt to infer values of the photorefractive properties of a material by seeking to match (1) theoretical predictions of the spectral responses (or selected features thereof) of a WGM of known dimensions made of the material with (2) the actual spectral responses (or selected features thereof). Spectral features that are useful for this purpose include resonance frequencies, free spectral ranges (differences between resonance frequencies of adjacently numbered modes), and resonance quality factors (Q values). The method has been demonstrated in several experiments, one of which was performed on a WGM resonator made from a disk of LiNbO3 doped with 5 percent of MgO. The free spectral range of the resonator was approximately equal to 3.42 GHz at wavelengths in the vicinity of 780 nm, the smallest full width at half maximum of a mode was approximately equal to 50 MHz, and the thickness of the resonator in the area of mode localization was 30 microns. In the experiment, laser power of 9 mW was coupled into the resonator with an efficiency of 75 percent, and the laser was scanned over a frequency band 9 GHz wide at a nominal wavelength of approximately equal to 780 nm. Resonance frequencies were measured as functions of time during several hours of exposure to the laser light. The results of these measurements, plotted in the figure, show a pronounced collective frequency drift of the resonator modes. The size of the drift has been estimated to correspond to a change of 8.5 x 10(exp -5) in the effective ordinary index of refraction of the resonator material.

Matsko, Andrey↗

Evaluation of Load Behavior for Select Analytes in Hanford Tank Waste

Crystalline silicotitanate (CST) inorganic ion exchanger is a candidate material for remediation of highly alkaline (pH > 14) aqueous nuclear waste streams containing high sodium concentrations (>5 M). In this work, ion exchange column testing with wastes from Hanford tanks AP-105, AP-107, and AW-102 was carried out to study the uptake of 137 Cs to estimate the decontamination factor (DF) value. Additionally, DF values for uptake of Al, Ca, Pb, Np, Pu, U, and Sr were determined and the ion exchange capacity of CST toward these analytes was estimated. Limited data is available on the load behavior of other minor and trace elements with recent CST production lots and this characterization will help improve understanding of the behavior of CST and assist in identifying potential disposition pathways as well as assessing removal capabilities of CST for other components.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Extracting meaningful standard enthalpies and entropies of activation for surface reactions from kinetic rates

While analyses based on the Arrhenius kinetic model have been successfully applied since its introduction, the Arrhenius model neglects to describe pre-exponential factor in a scientifically meaningful fashion. Since the 1930s, transition-state theory (TST), has met with success in interpreting the pre-exponential factor’s value, allowing a standard entropy of activation to be estimated. However, analyses based on TST’s assumptions have been applied inconsistently in the literature, particularly in corrosion science, leading to difficulty in comparison of standard entropy of activations from different studies. In this work, the foundational principles of TST and standard states are discussed and a standard method to apply TST in analyzing rates of surface reactions is recommended. When full details are not available, reacting species’ concentrations should be normalized to the concentration of active surface sites. For corrosion reactions, conversion relationships are given to convert from units of corrosion rate to surface reaction rate, consistent with TST. This method is dubbed a surface reactant equi-density approximation. Application of this standard to reported data results in adjustments of the standard entropy of activation between - 65 and +50 J/mol K and brings reported entropies into a narrower range of values.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗