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At least 73 records · Page 4

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NASA NTRS1981

Systematics of ground-state potential minima between two main-group atoms or ions

A diagram is presented illustrating the internuclear separations between diatomic molecules or quasi-molecules with the exception of those containing transition metal and rare-earth atoms. As plotted as a function of the atomic numbers of the constituent atoms, the ground-state separations are observed to exhibit dramatic periodicities, as well as a gradual rise with increasing atomic number. The data for van der Waals molecules are not sufficient to predict the results of future experiments, although it is noted that the greatest internuclear separations are those of the alkali earth-rare gas molecules. Finally, it is found that to within the resolution of the diagram, isoelectronic molecules or quasi-molecules along the homonuclear direction have a constant internuclear separation.

Hefferlin, R.↗

NASA NTRS1982

Hydrodynamic performance of an annular liquid jet: Production of spherical shells

An annular jet flow of liquid surrounding a flow of gas at its core is extremely unstable. Axisymmetric oscillations arise spontaneously, and grow with such rapidity along the axial dimension that a pinch-off of the liquid and an encapsulation of the core gas occurs within as few as four jet diameters. The shells which result thereby may be described as thick-wall bubbles, for which van der Waals forces are unimportant. A description is given of the fluid dynamic processes by which the shells are formed, and of means for preserving and promoting the geometrical of the product. The forming of metallic shells is mentioned.

Kendall, J. M.↗

NASA NTRS1981

Measurement of the oscillator strengths and autoionization widths of the neutral-aluminum multiplet 3s2 3p2 P0 - 3s 3p2 2P

The hook method is used in conjunction with absorption equivalent width measurements to determine the oscillator strengths and line widths of the Al I multiplet 3s2 3p2 P0 - 3s 3p2 2P at 176 nm. Autoionization is found to be the dominant decay channel for the two levels of the 3p2 2P term, with autoionizing widths of 4.0 and 0.87 x 10 to the 10th/sec for J of 3/2 and 1/2, respectively. The van der Waals scattering cross section for the Al I transition at 176.91 nm by He is determined to be (1.3 + or - 0.3) x 10 to the -14th sq cm at 2400 K, and a solar spectrum calculation centered at 176 nm shows that the Al I features are possible diagnostic probes of (1) solar non-LTE processes, and (2) the temperature minimum and structure of the lower chromosphere.

Lombardi, G. G.↗

NASA NTRS1981

Relatively low-temperature pyrolysis of silane in free space

The continuous flow pyrolyzer is a free space reactor that is used to study the effects of concentration, flow rate and temperature in making solar-grade silicon by pyrolysis of silane gas. Work with the continuous flow pyrolyzer is within the DOE-sponsored Low-Cost Solar Array Project. The work has led to a new theoretical treatment of silane pyrolysis in free space at relatively low temperatures (550 C to 750 C). It involves a sequential, three-step mechanism of particle growth: first, silicon atom generation by homogeneous reaction; second, coagulation to a 0.1 micron particle due to Brownian motion and van der Waals forces; and finally, chemical vapor deposition by heterogeneous reaction to final particle size.

Levin, H.↗

NASA NTRS1984

Capillary rise, wetting layers, and critical phenomena in confined geometry

Interferometric procedures have been used to measure the thickness of the wetting layers of liquid SF6 which intrude between SF6 vapor and the walls of an interferometer. Close to the critical temperature the measurements show that the layers become thicker as the height at which they are observed approaches the height of the bulk liquid-vapor meniscus. The functional form of the thickness increase agrees with the dependence expected from models in which the layers' thicknesses are governed by a competition between gravitational and van der Waals forces. The layers are a factor of three thicker than a simple estimate based on such models. No evidence is found of a transition from three-dimensional critical behavior towards two-dimensional critical behavior in the available temperature and size ranges. This contrasts with the interpretation of experiments in binary liquid mixtures carried out with comparable size and temperature resolution.

Moldover, M. R.↗

NASA NTRS1985

Thermodynamics of clathrate hydrate at low and high pressures with application to the outer solar system

The thermodynamic stability of clathrate hydrate is calculated to predict the formation conditions corresponding to a range of solar system parameters. The calculations were performed using the statistical mechanical theory developed by van der Waals and Platteeuw (1959) and existing experimental data concerning clathrate hydrate and its components. Dissociation pressures and partition functions (Langmuir constants) are predicted at low pressure for CO clathrate (hydrate) using the properties of chemicals similar to CO. It is argued that nonsolar but well constrained noble gas abundances may be measurable by the Galileo spacecraft in the Jovian atmosphere if the observed carbon enhancement is due to bombardment of the atmosphere by clathrate-bearing planetesimals sometime after planetary formation. The noble gas abundances of the Jovian satellite Titan are predicted, assuming that most of the methane in Titan is accreted as clathrate. It is suggested that under thermodynamically appropriate conditions, complete clathration of water ice could have occurred in high-pressure nebulas around giant planets, but probably not in the outer solar nebula. The stability of clathrate in other pressure ranges is also discussed.

Lunine, J. I.↗

NASA NTRS1987

Calculating Theromodynamic And Transport Properties Of Fluids

Computer program incorporates van der Waals equation and correction tables. FLUID program developed to calculate thermodynamic and transport properties of pure fluids in both liquid and gas phases. Properties calculated by use of simple gas model, empirical corrections, and efficient numerical interpolation scheme. Produces results that agree very well with measured values. Much faster than older, more complex programs developed for same purpose.

Proctor, Margaret P.↗

NASA NTRS1986

Non-solar noble gas abundances in the atmosphere of Jupiter

Lunine, Jonathan I.↗

NASA NTRS1987

Improving the interlaminar shear strength of carbon fiber-epoxy composites through carbon fiber bromination

The use of bromine to improve the interlaminar shear strength of PAN-based carbon fibers was investigated. Composite test specimens fabicated from brominated T-300 fibers and a MY720 matrix exhibited on average a 30% improvement in ILSS over their pristine counterparts. Mass, electrical resistivity, density, contact angle, and scanning Auger microscopy results suggested a mechanism in which the bromine was covalently bonded to the surface of the fiber, and this resulted in an increased van der Waal's adhesion between fiber and matrix.

Jaworske, Donald A.↗

NASA NTRS1988

The equation of state for stellar envelopes. I - An occupation probability formalism for the truncation of internal partition functions

An equation of state for material in stellar envelopes, subject to the limits of temperature less than about 10 to the 7th K and density less than about .01 g/cu cm is presented. The equation makes it possible to express free energy as the sum of several terms representing effects such as partial degeneracy of the electron, Coulomb interactions among charged particles, finite-volume, hard sphere repulsion, and van der Waals attraction. An occupation probability formalism is used to represent the effects of the plasma in establishing a finite partition function. It is shown that the use of the static screened Coulomb potential to calculate level shifts and to estimate the cutoff of the internal partition function is invalid. For most of the parameter space relevant to stellar envelopes, perturbations arising from the plasma ions are shown to be dominant in establishing the internal partition function.

Hummer, D. G.↗

NASA NTRS1990

Numerical methods for systems of conservation laws of mixed type using flux splitting

The essentially non-oscillatory (ENO) finite difference scheme is applied to systems of conservation laws of mixed hyperbolic-elliptic type. A flux splitting, with the corresponding Jacobi matrices having real and positive/negative eigenvalues, is used. The hyperbolic ENO operator is applied separately. The scheme is numerically tested on the van der Waals equation in fluid dynamics. Convergence was observed with good resolution to weak solutions for various Riemann problems, which are then numerically checked to be admissible as the viscosity-capillarity limits. The interesting phenomena of the shrinking of elliptic regions if they are present in the initial conditions were also observed.

Shu, Chi-Wang↗

NASA NTRS1990

Theoretical line shapes for rotational spectra of HCl in Ar

An interaction potential for HCl-Ar recently derived from spectra of van der Waals complexes (Hutson,1988) has been used to obtain converged close-coupling scattering S matrices from which pressure broadening (linewidth, line shift, and line coupling) cross sections have been computed within the Fano-Ben-Reuven formalism. Linewidths agree well with experimental data with the exception of the 0-1 line at low temperatures (an error of about 15 percent at 125 K). Line shifts, especially the largest, for the 0-1 line, are also in reasonable accord with experimental data. Line coupling is predicted to be quite small. The coupled-states molecular scattering approximation is found to be accurate except at very low collision energies. The infinite-order sudden approximations, on the other hand, is not reliable for this system. Inelastic scattering out of the spectroscopic levels accounts for only a fraction of the linewidth at thermal energies, especially in the lower rotational levels.

Green, Sheldon↗

NASA NTRS1990

Raman Q-branch line shapes as a test of the H2-Ar intermolecular potential

The line-shape cross sections of vibrational Raman Q-branch spectra are determined theoretically for D2 and H2 in Ar. The calculations are based on accurate close-coupling matrices and the intermolecular potential obtained by Le Roy and Hutson (1987) from spectra of van der Waals complexes. The calculation techniques applied are explained, and the results are presented in tables and graphs and discussed in detail with reference to published experimental data. Agreement to within about 25 percent is obtained for the line widths, but the line shifts are found to be a factor of two smaller than the measured values, and a temperature dependence of line-width cross sections is predicted which is not observed experimentally.

Green, Sheldon↗

NASA NTRS1990

Rheology of solid methane and nitrogen - Applications of Triton

The existing information about the rheological properties of solid methane and nitrogen is reviewed. The main limitation is the absence of creep data for solid nitrogen, but estimated properties are derived on the basis of simple scaling arguments for van der Waals bonded materials. On Triton solid methane and most likely nitrogen are too soft to support any topography over billions of years. Topographic support by water ice-rich materials seems almost certain. Nitrogen and methane do not intermix by solid-state diffusion. The weakness (absence?) of the opposition effect on Triton can be explained by annealing of nitrogen grains, provided the latter have sizes characteristic of freshly deposited frost.

Eluszkiewicz, Janusz↗

NASA NTRS1989

Dust coagulation in ISM

Coagulation is an important mechanism in the growth of interstellar and interplanetary dust particles. The microphysics of the coagulation process was theoretically analyzed as a function of the physical properties of the coagulating grains, i.e., their size, relative velocities, temperature, elastic properties, and the van der Waal interaction. Numerical calculations of collisions between linear chains provide the wave energy in individual particles and the spectrum of the mechanical vibrations set up in colliding particles. Sticking probabilities are then calculated using simple estimates for elastic deformation energies and for the attenuation of the wave energy due to absorption and scattering processes.

Chokshi, Arati↗

NASA NTRS1991

Pressure broadening data as a test of a recently proposed Ar-H2O interaction potential

An interaction potential for H2O-Ar that was recently determined from spectra of the van der Waals complex by Cohen and Saykally (1990) is used with accurate molecular scattering calculations to predict line broadening parameters for the 183 and 380 GHz transitions of water vapor. Theoretical values are about 15 percent higher than experiment. A comparison of experimental and theoretical pressure broadening cross sections for water in argon is presented.

Green, Sheldon↗

NASA NTRS1992

Gibbs free energy of reactions involving SiC, Si3N4, H2, and H2O as a function of temperature and pressure

Silicon carbide and silicon nitride are considered for application as structural materials and coating in advanced propulsion systems including nuclear thermal. Three-dimensional Gibbs free energy were constructed for reactions involving these materials in H2 and H2/H2O. Free energy plots are functions of temperature and pressure. Calculations used the definition of Gibbs free energy where the spontaneity of reactions is calculated as a function of temperature and pressure. Silicon carbide decomposes to Si and CH4 in pure H2 and forms a SiO2 scale in a wet atmosphere. Silicon nitride remains stable under all conditions. There was no apparent difference in reaction thermodynamics between ideal and Van der Waals treatment of gaseous species.

Isham, M. A.↗

NASA NTRS1992

Microwave properties of peeled HEMT devices sapphire substrates

The focus of this research is to demonstrate the first full radio frequency characterization of high electron mobility transistor (HEMT) device parameters. The results of this research are used in the design of circuits with peeled HEMT devices, e.g. 10 GHz amplifiers. Devices were fabricated using two HEMT structures grown by molecular beam epitaxy methods. A 500 A AlAs release layer for 'peel off' was included under the active layers of the structure. The structures are a homogeneously doped Al(0.3)GA(0.7)As/GaAs and a delta doped square well Al(.23)Ga(.77)As/GaAs HEMT structure. Devices were fabricated using a mesa isolation process. Contacts were done by sequentially evaporating Au/Ge/Au/Ni/Au followed by rapid thermal anneal at 400 C for 15 seconds. Gates were wet etch recessed and 1 to 1.4 micron Ti/Au gate metal was deposited. Devices were peeled off the GaAs substrate using Apiezon wax to support the active layer and a HF:DI (1:10) solution to remove the AlAs separation layer. Devices were then attached to sapphire substrates using van der Waals bonding.

Young, Paul G.↗