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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Microwave Investigation of the Mars Atmosphere and Surface

The Microwave Investigation of the Mars Atmosphere and Surface Experiment (MIMAS) is designed to address two major scientific goals: 1) To understand the three dimensional general circulation of the Martian atmosphere, and 2) To understand the hydrologic cycle of water on Mars, including the time-variable sources, sinks, and atmospheric transport of water vapor. The proposed instrument is a submillimeter wave, heterodyne receiver, with both continuum and very high spectral resolution capability. A small reflector antenna will be used to feed the receiver. Instrument heritage comes from the MIRO receiver, currently under design for the ESA Rosetta Mission, and from SWAS, a NASA astrophysics mission. The instrument will be able to measure atmospheric spectral lines from both water and carbon monoxide and use these lines as tracers of atmospheric winds. Measurement objectives of MIMAS are to measure surface temperature, atmospheric temperature from the surface up to an altitude of 60 km or more, the distribution of CO and H2O in the atmosphere, and certain wind fields (zonal and meridional). The global distribution of CO, as well as temperature distributions, will be used as input data for GCMs (general circulation models). Water vapor profiles will be used to understand the sources and sinks of water on Mars and to understand how it is transported globally by the general circulation. Zonal and meridional wind fields will provide further tests of the GCMs. An important aspect of this experiment is that the temperature and humidity measurements are insensitive to dust and ice condensates thereby making the measurement capability independent of the presence of dust clouds and ice particles. Temperature measurements derived from the data can be used in conjunction with infrared measurements to determine dust profiles.

Gulkis, S.↗

Search for spatial variations of the H2O abundance in the lower atmosphere of Venus from NIMS-Galileo

The spectroscopic data of the Near-Infrared Mapping Spectrometer (NIMS), recorded during the Galileo flyby of Venus, are analysed to retrieve the water vapor abundance variations in the lower atmosphere of Venus at night. The 1.18 micrometer spectral window, which probes altitude levels below 20 km, is used for this purpose. Constraints on the CO2 continuum and far-wing opacity from existing ground-based high-resolution observations are included in the modelling of the NIMS spectra. The NIMS measurements can be fitted with a water vapor mixing ratio of 30 +/- 15 ppm, in agreement with analyses of ground-based nightside observations. The water vapor abundance shows no horizontal variations exceeding 20% over a wide latitude range (40 deg S, 50 deg N) on the nightside of Venus. Within the same selection of NIMS spectra, a large enhancement in the O2 fluorescence emission at 1.27 micrometer is observed at a latitude of 40 deg S, over a spatial area about 100 km wide.

Drossart, P.↗

Submillimeter (Lambda < 1 mm) Continuum Imaging at CSO: A Retrospective

This contribution is submitted on behalf of all students, postdocs, and staff inspired and supported by Tom Phillips to build an instrument and then wait for low precipitable water vapor. Over the 20 plus years of its existence, the Caltech Submillimeter Observatory (CSO) has seen a succession of ever more powerful detectors to measure continuum emission in the shortest submillimeter bands available from Mauna Kea. These instruments have been trained on the nearest solar systems, the most distant galaxies, and objects in between. I show several images collected over the 5 plus year history of the SHARC II camera and anecdotal comparison with past work.

bolometer detectors↗

Atmospheric Pre-Corrected Differential Absorption Techniques to Retrieve Columnar Water Vapor: Theory and Simulations

Two different approaches exist to retrieve columnar water vapor from imaging spectrometer data: (1) Differential absorption techniques based on: (a) Narrow-Wide (N/W) ratio between overlapping spectrally wide and narrow channels; (b) Continuum Interpolated Band Ratio (CIBR) between a measurement channel and the weighted sum of two reference channels. (2) Non-linear fitting techniques which are based on spectral radiative transfer calculations. The advantage of the first approach is computational speed and of the second, improved retrieval accuracy. Our goal was to improve the accuracy of the first technique using physics based on radiative transfer. Using a modified version of the Duntley equation, we derived an "Atmospheric Pre-corrected Differential Absorption" (APDA) technique and described an iterative scheme to retrieve water vapor on a pixel-by-pixel basis. Next we compared both, the CIBR and the APDA using the Duntley equation for MODTRAN3 computed irradiances, transmissions and path radiance (using the DISORT option). This simulation showed that the CIBR is very sensitive to reflectance effects and that the APDA performs much better. An extensive data set was created with the radiative transfer code 6S over 379 different ground reflectance spectra. The calculated relative water vapor error was reduced significantly for the APDA. The APDA technique had about 8% (vs. over 35% for the CIBR) of the 379 spectra with a relative water vapor error of greater than +5%. The APDA has been applied to 1991 and 1995 AVIRIS scenes which visually demonstrate the improvement over the CIBR technique.

Borel, Christoph C.↗

The Hat Creek millimeter-wave interferometer.

A fixed-baseline millimeter-wave interferometer, operating initially at 13.5 mm, has been put into operation at the Hat Creek Observatory as the first step in the development of a two-element aperture synthesis telescope. The first system consists of a 3-m antenna and a 6-m antenna spaced 265 m apart. Large receiver bandwidths may be used at high frequencies, and this system employs an intermediate frequency bandwidth of about 400 MHz. The instrument has been used to derive accurate absolute positions of interstellar water vapor sources, to study Mercury, Venus, and Mars, and to make crude maps of a few complex continuum sources. The synthesis telescope, the next stage, has two 6-m antennas which can be located at various stations on a T-shaped track. The east-west leg is 300 m and the north-south leg is 200 m, permitting full synthesis for sources on the equator and at declinations as low as -30 deg as well as at high declinations.

Hills, R. E.↗

Retrieval of Water Vapor Column Abundance and Aerosol Properties from ChemCam Passive Sky Spectroscopy

We derive water vapor column abundances and aerosol properties from Mars Science Laboratory (MSL) ChemCam passive mode observations of scattered sky light. This paper covers the methodology and initial results for water vapor and also provides preliminary results for aerosols. The data set presented here includes the results of 113 observations spanning from Mars Year 31 L(s) = 291 deg (March 30, 2013) to Mars Year 33 L(s) = 127 deg (March 24, 2016). Each ChemCam passive sky observation acquires spectra at two different elevation angles. We fit these spectra with a discrete-ordinates multiple scattering radiative transfer model, using the correlated-k approximation for gas absorption bands. The retrieval proceeds by first fitting the continuum of the ratio of the two elevation angles to solve for aerosol properties, and then fitting the continuum-removed ratio to solve for gas abundances. The final step of the retrieval makes use of the observed CO 2 absorptions and the known CO 2 abundance to correct the retrieved water vapor abundance for the effects of the vertical distribution of scattering aerosols and to derive an aerosol scale height parameter. Our water vapor results give water vapor column abundance with a precision of +/-0.6 precipitable microns and systematic errors no larger than +/-0.3 precipitable microns, assuming uniform vertical mixing. The ChemCam-retrieved water abundances show, with only a few exceptions, the same seasonal behavior and the same timing of seasonal minima and maxima as the TES, CRISM, and REMS-H data sets that we compare them to. However ChemCam-retrieved water abundances are generally lower than zonal and regional scale from-orbit water vapor data, while at the same time being significantly larger than pre-dawn REMS-H abundances. Pending further analysis of REMS-H volume mixing ratio uncertainties, the differences between ChemCam and REMS-H pre-dawn mixing ratios appear to be much too large to be explained by large scale circulations and thus they tend to support the hypothesis of substantial diurnal interactions of water vapor with the surface. Our preliminary aerosol results, meanwhile, show the expected seasonal pattern in dust particle size but also indicate a surprising interannual increase in water-ice cloud opacities.

Mcconnochie, Timothy H.↗

Preliminary analysis of SSME baseline plume emissions

A review of current efforts to establish baseline emission levels from the SSME plume is presented. Recent data obtained under the Optical Plume Anomaly Detector program at the Technology Test Bed at MSFC is examined with an emphasis on interpretation of spectral and temporal features observed during nominal motor operation. In particular, the repeated appearance of Cr, Fe, Mn, Ca, and Li at engine startup and shutdown is discussed, and broadband attenuation due to scattering from water vapor is seen to complicate characterization of baseline levels. Also, emission from the combustion related specie OH, the underlying broadband continuum, and the Na impurity is discussed in relation to changes in Rated Power Level (RPL). Results from a theoretical spectral analysis of engine start-up activity is presented.

Wallace, T. L.↗

A multiphase flow model of water droplets dielectrophoretic-induced air dehumidification phenomena

Air humidity in indoor spaces plays a critical role in human comfort and health. Dehumidification systems are used for building humidity controls, but they can take significant energy consumption, especially in geographic locations with high outdoor humidity and warm climates. Consequently, there is a growing demand for innovative dehumidification processes that consume minimal energy. Dielectrophoretic air dehumidification represents one such promising approach. However, it has not garnered significant attention due to the absence of engineering models and simulation tools capable of evaluating its performance and limitations at large-scale airflows. A new numerical multiphase CFD model, which is also experimentally validated, is developed in a customized Reacting Foam solver based on OpenFOAM® version 9. The newly developed model seeks to decrease substantial energy consumption and lower costs by leveraging the dielectrophoretic phenomenon to regulate moisture levels in the air. The solver integrates a hybrid Eulerian-Lagrangian framework to track the droplet's trajectory and growth rate while solving the continuum equations for the moist air. An electrospray produces electrically charged droplets, which grow during their in-flight trajectories as water vapor condenses onto their surfaces. The role of electrostatic forces in promoting vapor condensation within a high-gradient electrical field is investigated, and the dielectrophoretic vapor nucleation process on charged water droplets is discussed. The CFD model was validated against results from the literature and from proof-of-concept experiments conducted by the authors, which showed a 2 % air dehumidification with a single electrospray and airflow rate of 5 cubic feet per minute. The simulation results indicated that augmenting the number of electrically charged spray droplets increased the dehumidification of the air to 25 %. The initial mean droplet diameter, the orientation of the injector and relative humidity significantly influence the assessment of dehumidification. As a result, scaling up this approach to larger airflow volumes is identified as a potential future research direction.

42 ENGINEERING↗

Dust release rates and dust-to-gas mass ratios of eight comets

Mass release rates of dust and mass ratios of dust-to-gas release rates of Comets Thiele (1985m), Wilson (1986l), P/Borrelly (1987p), Liller (1988a), Bradfield (1987s), Hartley-Good (1985l), P/Giacobini-Zinner (1984e), and P/Halley (1982i) are estimated from the analysis of continuum flux measurements at optical wavelengths. An attempt is made to estimate the size of each comet nucleus on the basis of water-ice sublimation (vaporization), assuming that the nucleus is spherical and only a fraction of its surface area is active. Where possible, the dust mass release rates are compared with those obtained by other investigators in the optical and IR wavelength regions. Good agreement with results based on IR observations is found.

Singh, P. D.↗

Recovery of Atmospheric Water Vapor Total Column Abundance from Imaging Spectrometer Data Around 940 nm - Sensitivity Analysis and Application to Airborne Visible/Infrared Imaging Spectrometer (AVIRI

Twosimple techniques to retrieve path precipitable water fromthe Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) high spectral resolution radiance data (Continuum Interpolated Band Ratio, CIBR, and Narrow/Wide Ratio, N/W), using the 940 nm water absorption band, are compared.

water present surface reflectance atmospheric catt↗

Validation of MIPAS IMK-IAA Temperature, Water Vapor, and Ozone Profiles with MOHAVE-2009 Campaign Measurements

MIPAS observations of temperature, water vapor, and ozone in October 2009 as derived with the scientific level-2 processor run by Karlsruhe Institute of Technology (KIT), Institute for Meteorology and Climate Research (IMK) and CSIC, Instituto de Astrofısica de Andalucıa (IAA) and retrieved from version 4.67 level-1b data have been compared to co-located field campaign observations obtained during the MOHAVE-2009 campaign at the Table Mountain Facility near Pasadena, California in October 2009. The MIPAS measurements were validated regarding any potential biases of the profiles, and with respect to their precision estimates. The MOHAVE-2009 measurement campaign provided measurements of atmospheric profiles of temperature, water vapor/relative humidity, and ozone from the ground to the mesosphere by a suite of instruments including radiosondes, ozonesondes, frost point hygrometers, lidars, microwave radiometers and Fourier transform infrared (FTIR) spectrometers. For MIPAS temperatures (version V4O_T_204), no significant bias was detected in the middle stratosphere; between 22 km and the tropopause MIPAS temperatures were found to be biased low by up to 2 K, while below the tropopause, they were found to be too high by the same amount. These findings confirm earlier comparisons of MIPAS temperatures to ECMWF data which revealed similar differences. Above 12 km up to 45 km, MIPAS water vapor (version V4O_H2O_203) is well within 10% of the data of all correlative instruments. The well-known dry bias of MIPAS water vapor above 50 km due to neglect of non-LTE effects in the current retrievals has been confirmed. Some instruments indicate that MIPAS water vapor might be biased high by 20 to 40% around 10 km (or 5 km below the tropopause), but a consistent picture from all comparisons could not be derived. MIPAS ozone (version V4O_O3_202) has a high bias of up to +0.9 ppmv around 37 km which is due to a non-identified continuum like radiance contribution. No further significant biases have been detected. Cross-comparison to co-located observations of other satellite instruments (Aura/MLS, ACE-FTS, AIRS) is provided as well.

MIPAS validation↗

Natural radio noise - A mini-review

Natural radio noise in telecommunication systems can be accounted for by the contribution which it makes to antenna noise temperature. Attenuation due to water vapor and oxygen, clouds, and precipitation is accompanied by thermal noise which further degrades the applicable signal-to-noise ratio. Extraterrestrial noise may be of thermal or nonthermal origin and may cover a continuum of frequencies or occur at discrete frequencies. The spectral index n (the exponent giving the variation of noise power density with wavelength) is -2 for a black body and between 0 and -2 for thermal emission in general. The mechanism responsible for much of the extensive nonthermal extraterrestrial noise is synchrotron radiation, characterized by a positive spectral index.

Flock, W. L.↗

Evaporation of Water Nanodroplets on Heated Surfaces: Does Nano Matter?

While experiments and continuum models have provided a relatively good understanding of the evaporation of macroscopic water droplets, elucidating how sessile nanodroplets evaporate is an open question critical for advancing nanotechnological applications where nanodroplets can play an essential role. In this study, using molecular dynamics simulations, we find that evaporating nanodroplets, in contrast to their macroscopic counterparts, are not always in thermal equilibrium with the substrate and that the vapor concentration on the nanodroplet surface does not reach a steady state. As a result, the evaporative behavior of nanodroplets is significantly different. Regardless of hydrophobicity, nanodroplets do not follow conventional evaporation modes but instead exhibit dynamic wetting behavior characterized by huge, non-equilibrium, isovolumetric fluctuations in the contact angle and contact radius. For hydrophilic nanodroplets, the evaporation rate, controlled by the vapor concentration, decays exponentially over time. Hydrophobic nanodroplets follow stretched exponential kinetics arising from the slower thermalization with the substrate. The evaporative half-lifetime of the nanodroplets is directly related to the thermalization time scale and therefore increases monotonically with the hydrophobicity of the substrate. Finally, the evaporative flux profile along the nanodroplet surface is highly nonuniform but does not diverge at the contact line as the macroscopic continuum models predict.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elucidating the Mechanism of Helium Evaporation from Liquid Water

Here, we investigate the evaporation of trace amounts of helium solvated in liquid water using molecular dynamics simulations and theory. Consistent with experimental observations, we find a super-Maxwellian distribution of kinetic energies of evaporated helium. This excess of kinetic energy over typical thermal expectations is explained by an effective continuum theory of evaporation based on a Fokker–Planck equation, parametrized molecularly by a potential of mean force and position-dependent friction. Using this description, we find that helium evaporation is strongly influenced by the friction near the interface, which is anomalously small near the Gibbs dividing surface due to the ability of the liquid–vapor interface to deform around the gas particle. Our reduced description provides a mechanistic interpretation of trace gas evaporation as the motion of an underdamped particle in a potential subject to a viscous environment that varies rapidly across the air–water interface. From it we predict the temperature dependence of the excess kinetic energy of evaporation, which is yet to be measured.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A nonisothermal emissivity and absorptivity formulation for water vapor

An emissivity approach is taken to modeling fluxes and cooling rates in the atmosphere. The nonisothermal water vapor long wave radiation emissivity and absorptivity model that is developed satisfies the requirements of defining a monochromatic transfer equation for predicting water vapor emissions. Predictions made with the model compare favorably with fluxes predicted by a radiation model for narrow-band emissions in 5 kayser intervals. The spectral resolution assumed in narrow-band models is shown to be an arbitrary parameter and, if a far wing continuum-type opacity is included in the emissivity scheme presented, results can be obtained which are as accurate as predictions made with state of the art line-by-line (LBL) calculations.

Ramanathan, V.↗

Atmospheric water mapping with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), Mountain Pass, California

Observations are given of the spatial variation of atmospheric precipitable water using the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over a desert area in eastern California, derived using a band ratio method and the 940 nm atmospheric water band and 870 nm continuum radiances. The ratios yield total path water from curves of growth supplied by the LOWTRAN 7 atmospheric model. An independent validation of the AVIRIS-derived column abundance at a point is supplied by a spectral hygrometer calibrated with respect to radiosonde observations. Water values conform to topography and fall off with surface elevation. The edge of the water vapor boundary layer defined by topography is thought to have been recovered. The ratio method yields column abundance estimates of good precision and high spatial resolution.

Conel, James E.↗

Analysis of Liquids Using the Submerged Plasma for Isotopic Detection and Elemental Resolution (SPIDER)

We developed a sensor called the Submerged Plasma for Isotopic Detection and Elemental Resolution (SPIDER) probe, which uses an atmospheric pressure glow discharge below the surface of liquids to excite species in the liquid. Through emission spectroscopy of molten salts, liquid metals, and heavy water, we demonstrated the SPIDER probe’s high resolution, accuracy, and versatility. We successfully identified trace concentrations of transition and rare-earth metals in molten salts and detected the isotopic shift of the H β → D β emission line. Our analysis revealed unconventional spectral alkali line shapes, indicating two competing excitation modes: film explosion and droplet vaporization. The film explosion mode, characterized by dense plasma, exhibited self-reversal and broadband continuum emission, while the droplet vaporization mode, associated with diffusive plasma, produced narrow-line emissions. Furthermore, by analyzing circuit transients alongside individual plasma events, we observed that film explosions generate higher currents, likely due to a shorter plasma length as the current preferentially flows through the thin liquid layer. Altogether, our results highlight the SPIDER probe’s efficacy and flexibility, making it well-suited for online material quantification of liquids in extreme environments.

AES↗

Theoretical brightness temperature profiles of atmospheric pure H2 rotational quadrupole lines - Jupiter and Uranus

With the advent of high-resolution instruments and their use high above most of the telluric water vapor, the hydrogen pure rotational quadrupole lines at 28, 17, and 12 microns from the atmospheres of the outer planets may be observed. Best values for the line strengths, pressure-broadening coefficients, diffusion constants, and pressure shifts for these rotational transitions are calculated. The collisionally narrowed Galatry profile is used to calculate brightness temperature line profiles for these H2 transitions for the outer planets, Jupiter and Uranus. The effects of the H2 rotational-translational continuum and of the NH3 v2 band are also included.

Goorvitch, D.↗