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DOE OSTI2023

Molecular Dynamics Simulations of Calcite Fracture in Water

Calcite (CaCO 3 ) is one of the most common minerals in geologic and engineered systems. It is often in contact with aqueous solutions, causing chemically assisted fracture that is critical to understanding the stability of subsurface systems and manmade structures. Calcite fracture was evaluated with reactive molecular dynamics simulations, including the impacts of crack tip geometry (notch), the presence of water, and surface hydroxyl groups. Chemo-mechanical weakening was assessed by comparing the loads where fracture began to propagate. Our analyses show that in the presence of a notch, the load at which crack growth begins is lower, compared to the effect of water or surface hydroxyls. Additionally, the breaking of two adjacent Ca–O bonds is the kinetic limitation for crack initiation, since transiently broken bonds can reform, not resulting in crack growth. In aqueous environments, fresh (not hydroxylated) calcite surfaces exhibited water strengthening. Manual addition of H + and/or OH – species on the (104) calcite surface resulted in chemo-mechanical weakening of calcite by 9%. Achieving full hydroxylation of the calcite surface was thermodynamically and kinetically limited, with only 0.17–0.01 OH/nm 2 surface hydroxylation observed on the (104) surface at the end of the simulations. In conclusion, the limited reactivity of pure water with the calcite surface restricts the chemo-mechanical effects and suggests that reactions between physiosorbed water and localized structural defects may be dominating the chemo-mechanical process in the studies where water weakening has been reported.

Calcite↗

DOE OSTI2024

Effects of Urbanization in China on the East Asian Summer Monsoon as Revealed by Two Global Climate Models

Abstract The East Asian summer monsoon (EASM), vulnerable to anthropogenic activities, exerts profound impacts on precipitation in East Asia. In recent decades, China has been experiencing rapid urbanization. It has not yet reached a consensus on its influences on EASM. Here, we introduce satellite‐derived urban impervious areas of China during 1985–2017 into two global climate models with contrasting biases of climatological EASM simulation. Both models consistently show that urbanization weakens EASM by increasing surface friction drag. The increased surface roughness reduces climatological southerly winds in the concentrated urbanization area. As a result, moisture convergence occurs south of the concentrated urbanization area with ascending motion, while moisture divergence with descending motion appears to the north, resulting in the precipitation anomalies of “southern flood and northern drought.” The dominant role of urban dynamic forcing in regulating EASM is confirmed by reducing urban roughness to the level of croplands in sensitivity experiments. As urban dynamic forcing is largely mitigated, the urbanization impact mainly driven by urban thermal forcing conversely strengthens EASM due to enhanced land‐sea thermal contrast via urbanization‐induced warming. Spatial patterns and magnitudes of the urbanization‐induced EASM weakening vary between the two models due to disparities in their simulations of urban thermodynamic forcing and atmospheric adjustments. These results underscore the robust weakening effect of urbanization on EASM by urban friction drag and document uncertainties in the related spatial pattern and magnitude resulting from model discrepancies.

Meteorology & Atmospheric Sciences↗

DOE OSTI2023

Decoupling of Arctic variability from the North Pacific in a warmer climate

The sea level pressure variability in the North Pacific modulates the climate of the Arctic and surrounding continents, substantially impacting ecosystems and indigenous communities. Our analysis based on data from the CESM2 Large Ensemble and different Model Intercomparison Project datasets reveals that the interannual variability of Arctic surface air temperature (SAT) gradually decouples from the contemporaneous atmospheric conditions over the North Pacific as external forcing increases in intensity in the future. Future projections show that the North Pacific-Arctic relationship during the fall season consistently weakens in magnitude until the end of this century, and in the 22nd and 23rd centuries, the relationship is negligible throughout the year. We show that under increased greenhouse gas emissions, the regional heat fluxes extensively control the Arctic temperature variability, and the strength of the projected North Pacific-Arctic relationship is strongly dependent on the Arctic sea ice extent. Our results suggest that under future warming, a strong coupling of Arctic SAT with the underlying ocean and a weakening of the meridional pressure gradient driven by an enhanced rate of sea ice retreat will weaken the interannual footprint of North Pacific variability on Arctic SAT. Therefore, we propose that the alarming rate of sea-ice decline over recent decades and projected in the near future could accelerate the rate of decoupling. Further, we suggest that mitigation strategies for the Arctic should focus on regional mechanisms operating on interannual and seasonal timescales.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Deficiency in transmitter release triggers homeostatic transcriptional changes that increase presynaptic excitability

Weakening of synaptic transmission at theDrosophilalarval neuromuscular junction triggers two forms of homeostatic compensation, one that increases the probability of glutamate release per action potential (P r ) and another that increases motoneuron (MN) activity. We investigated the molecular changes in MNs that underlie the increase in MN activity. RNA sequencing (RNA-seq) analysis on MNs whose glutamate release is weakened by knockdown of components of the MN transmitter release machinery reveals a reduction in expression of a group of genes that encode potassium channels and their positive modulators. These results identify a mechanism of compensation for weakened synaptic transmission by MNs, which engages a transcriptional program in those cells to increase firing and, thereby, ensure sufficient locomotory drive.

Science & Technology - Other Topics↗

DOE OSTI2025

Behavioral resilience via dynamic circuit firing homeostasis

Homeostatic regulation ensures stable neural circuit output under changing conditions. We find that in Drosophila larvae, either presynaptic weakening due to perturbation of transmitter release or postsynaptic weakening due to perturbation of glutamate receptors at synapses between motor neuron (MN) and muscle has little impact on locomotion, suggesting a nonsynaptic compensatory mechanism. In vivo imaging shows that five different forms of synaptic weakening increase the duration of activity bouts in type I MNs. Strikingly, this compensation is input selective: occurring only in the tonic type Ib MN, not the phasic type Is MN that innervates the same muscle. Moreover, an inhibitory class of central pre-MNs that innervates the tonic—but not phasic—input decreases in activity. The adjustment in activity occurs remarkably quickly: within minutes of synapse perturbation. We propose that MN firing is dynamically regulated by two coordinated mechanisms: a cell-autonomous adjustment of MN excitability and a circuit adjustment of inhibitory central drive. The input selectivity of this process suggests homeostatic adjustment to maintain tonic drive but hold constant the phasic drive that organizes locomotory wave patterns.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

AMOC stability and diverging response to Arctic sea ice decline in two climate models

This study compares the impacts of Arctic sea ice decline on the Atlantic meridional overturning circulation (AMOC) in two configurations of the Community Earth System Model with different horizontal resolution. In a suite of model experiments, we impose radiative imbalance at the ice surface, replicating a loss of sea ice cover comparable to that observed during 1979–2014, and we find dramatic differences in the AMOC response between the two models. In the lower-resolution configuration, the AMOC weakens by about one-third over the first 100 years, approaching a new quasi-equilibrium. By contrast, in the higher-resolution configuration, the AMOC weakens by ~10% during the first 20–30 years followed by a full recovery driven by invigorated deep water formation in the Labrador Sea and adjacent regions. We investigate these differences using a diagnostic AMOC stability indicator, which reflects the AMOC freshwater transport in and out of the basin and hence the strength of the basin-scale salt-advection feedback. This indicator suggests that the AMOC in the lower-resolution model is less stable and more sensitive to surface perturbations, as confirmed by hosing experiments mimicking Arctic freshening due to sea ice decline. Differences between the models’ mean states, including the Atlantic Ocean mean surface freshwater fluxes, control the differences in AMOC stability. Our results demonstrate that the AMOC stability indicator is indeed useful for evaluating AMOC sensitivity to perturbations. We emphasize that, despite the differences in the long-term adjustment, both models simulate a multidecadal AMOC weakening caused by Arctic sea ice decline, relevant to climate change.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Dust semi-direct effects: low-level cloud response to free-tropospheric dust-induced longwave radiation over the North Atlantic Ocean

Aerosol semi-direct effect is the adjustment of the radiative budget due to the cloud response to radiation absorption. Although dust accounts for about a third of aerosols' shortwave absorption, our understanding of its semi-direct effect often relies on traditional shortwave-focused mechanisms previously established for biomass-burning aerosols, and implications of dust longwave absorption on clouds have yet to be explored. Here, we assess the low-level cloud cover (LLCC) response to changes in properties and characteristics of the free-tropospheric dust layer over the North Atlantic Ocean (May–August, 2007–2017). We find that, consistent with previous studies, LLCC typically responds positively (increases in clouds) to an overlying dust layer. However, this response weakens with increasing dust optical depth (DOD), dust geometric thickness (DGT), and dust-layer base height (DBH). Specifically, we find that the LLCC response weakens by 4.3 ± 1.04 % and 1.6 ± 0.65 %, respectively, for a one-standard-deviation increase in DOD and DGT, and a smaller response to DBH (0.19 ± 0.45 %). We also find that the weakened LLCC response is primarily due to enhanced dust-induced longwave-dominated cloud-top warming, which counteracts the mean cloud-top cooling by as much as 19 % (mean of 9 %). Sensitivity analysis further indicates that the variability in dust properties, influenced by dust size distribution and refractive index, dominates the changes in dust-induced cloud-top warming, rather than variabilities in cloud properties or thermodynamic profiles. Our result adds to the traditional understanding of LLCC enhancement through shortwave-driven atmospheric stability, often associated with aerosol semi-direct effects, and highlights the role of dust-induced cloud-top longwave warming in dust semi-direct effects.

Pandey, Satyendra K. [Univ. of California, Merced,↗

DOE OSTI2025

Factors controlling injection-induced rupture of intersecting faults during geological sequestration of CO 2

This study addresses coupled multiphase fluid flow and geomechanics effects on potential fault activation associated with subsurface CO 2 injection around intersecting faults. An enhanced fault-representation model is used to capture geomechanical responses of two intersecting faults with finite length during CO 2 injection. The faults are embedded in a strike-slip stress regime of a caprock-reservoir-basement system with the faults represented by zero-thickness interfaces with adjacent finite-thickness damage zones. A sensitivity analysis is conducted to study the effect of fault permeability, slip-weakening behavior, well location relative to the orientation of faults, and well placement (the number and location of injection wells). Five metrics (pressure, CO 2 plume, shear state on the fault, as well as shear displacement and stress path at selected fault monitoring points) are selected to assess CO 2 migration and reactivation of intersecting faults. The results show that induced ruptures are favored by low permeability faults due to high pressure buildup and by slip-weakening behavior resulting from fault strength reduction. The location of one injection well relative to fault orientation determines the magnitude of changes in effective normal stress and shear stress, affecting the location of induced ruptures. Well placement (two injection wells used in the paper) dominates pressure diffusion around the intersection and tips of faults. This redistributes changes in effective normal stress caused by each injection well, influencing the spatial distribution of ruptures along faults. A larger injection volume induces far-field ruptures that are controlled by stress transfer within the injection layer. The findings presented here can provide valuable insights into engineering operations for a long-term, safe, and reliable geologic CO 2 storage.

Fault permeability↗

DOE OSTI2020

Impact of equilibrium radial electric field on energy loss process after pedestal collapse

An impact of the equilibrium radial electric field on energy loss processes after pedestal collapse is numerically investigated using the BOUT++ framework. Using linear stability analysis, the resistive ballooning mode is shown to be stabilized by the radial shear of the equilibrium radial electric field. On the other hand, the energy loss level after the pedestal collapse increases if the equilibrium radial electric field is taken into account. The spatio-temporal and phase diagram analyses show that the equilibrium radial electric field partially cancels the fluctuation-driven toroidally axisymmetric radial electric field and weakens the E × B shearing rate after pedestal collapse, weakening the turbulence suppression by vortex shearing. Finally, the equilibrium radial electric field therefore increases turbulence intensity in nonlinear cyclic oscillations among pressure gradient, E × B shearing rate, and turbulence intensity, which gives rise to subsequent bursts of turbulent transport and increases the energy loss level.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2020

Understanding Irrigation Impacts on Low-Level Jets over the Great Plains

Low-level jets (LLJs) over the Great Plains are well-known for their importance in transporting moisture from the Gulf of Mexico and forming precipitation in the Central US. However, the impact of irrigation practice on LLJs is rarely studied. To understand the irrigation impact on the Great Plains LLJs, the Weather Research and Forecasting (WRF) model is employed with and without an irrigation scheme. The simulated wind field is evaluated against the observed wind from Midlatitude Continental Convective Clouds Experiment (MC3E). The results show that adding irrigation improves the simulated wind, especially at lower altitudes below 800 hPa. Irrigation reduces the LLJ frequency over the Great Plains, mainly by reducing the intense LLJ frequency. The reduced LLJ frequency is caused by the irrigation-induced weakening of meridional wind. The favorable conditions for LLJs have been identified by examining the mechanism associated with LLJs: a ridge-like pattern with weak and calm synoptic-scale conditions in the mid-levels and a strong west-east temperature gradient at lower levels that promote meridional winds. Irrigation-induced cooling leads to a baroclinic pattern with high pressure at lower altitudes over the irrigation region and low pressure in the mid- and upper levels in the downstream region, resulting in a northerly component that hinders the formation of LLJs. Low-level surface cooling also decreases the west-east temperature gradient and hence weakens the thermal wind forcing. The irrigation-induced mid-level low and weaker west-east temperature gradient are responsible for the reduced meridional winds and the reduced LLJ frequencies.

Yang, Zhao↗

DOE OSTI2022

Greenhouse-gas forced changes in the Atlantic meridional overturning circulation and related worldwide sea-level change

Abstract The effect of anthropogenic climate change in the ocean is challenging to project because atmosphere-ocean general circulation models (AOGCMs) respond differently to forcing. This study focuses on changes in the Atlantic Meridional Overturning Circulation (AMOC), ocean heat content ( $$\Delta$$ Δ OHC), and the spatial pattern of ocean dynamic sea level ( $$\Delta \zeta$$ Δ ζ ). We analyse experiments following the FAFMIP protocol, in which AOGCMs are forced at the ocean surface with standardised heat, freshwater and momentum flux perturbations, typical of those produced by doubling $$\hbox {CO}_{{2}}$$ CO 2 . Using two new heat-flux-forced experiments, we find that the AMOC weakening is mainly caused by and linearly related to the North Atlantic heat flux perturbation, and further weakened by a positive coupled heat flux feedback. The quantitative relationships are model-dependent, but few models show significant AMOC change due to freshwater or momentum forcing, or to heat flux forcing outside the North Atlantic. AMOC decline causes warming at the South Atlantic-Southern Ocean interface. It does not strongly affect the global-mean vertical distribution of $$\Delta$$ Δ OHC, which is dominated by the Southern Ocean. AMOC decline strongly affects $$\Delta \zeta$$ Δ ζ in the North Atlantic, with smaller effects in the Southern Ocean and North Pacific. The ensemble-mean $$\Delta \zeta$$ Δ ζ and $$\Delta$$ Δ OHC patterns are mostly attributable to the heat added by the flux perturbation, with smaller effects from ocean heat and salinity redistribution. The ensemble spread, on the other hand, is largely due to redistribution, with pronounced disagreement among the AOGCMs.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Towards understanding the robust strengthening of ENSO and more frequent extreme El Niño events in CMIP6 global warming simulations

The El Niño Southern Oscillation (ENSO) has profound impacts on weather patterns across the globe, yet there is no consensus on its response to global warming. Several modelling studies find a stronger ENSO in global warming scenarios, while other studies suggest ENSO weakening. Using a broad range of models from the Coupled Model Intercomparison Project phase 6 (CMIP6) and four types of warming experiments, here we show that the majority of the models predict a stronger ENSO by century-end in Shared Social Pathway (SSP) experiments, and in idealized 1pctCO 2 and abrupt 4xCO 2 experiments. Several models, however, do predict no change or ENSO weakening, especially in the idealized experiments. Critically, the strongest forcing (abrupt-4xCO 2 ) does not induce the strongest ENSO response, while differences between the models are much greater than those between warming scenarios. For the long-term response (over 1000 years) the models disagree even on the sign of change. Furthermore, changes in ENSO sea surface temperature (SST) variability are only modestly correlated with the tropical Pacific mean state change. The highest correlation for ENSO SST amplitude is found with the mean zonal SST gradient in the SSP5-8.5 experiment (R = –0.58). In contrast, changes in ENSO rainfall variability correlate well with changes in the mean state, as well as with changes in ENSO SST variability. When evaluating the Bjerknes Stability Index for a subset of models, we find that it is not a reliable predictor of ENSO strengthening, as this index tends to predict greater stability with warming. We argue that the enhanced ENSO stability is offset by increases in atmospheric noise or/and potential nonlinear effects. However, a robust inter-model mechanism that can explain a stronger ENSO simulated with global warming is still lacking. Therefore, caution should be exercised when considering ENSO changes based on a single model or warming scenario.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Atmospheric and oceanic energy transport during North Atlantic freshening events: influences of moisture transport and hydrologic cycle feedbacks

Analogs of present-day rapid ice melt can be found in episodic discharges of icebergs that occurred during glacial periods called Heinrich events. This introduces excess meltwater into the North Atlantic and weakens the Atlantic thermohaline circulation (AMOC), triggering a hydrologic cycle–AMOC collapse feedback as the atmospheric energy transport compensates for reduced northward heat transport. Here we employ a novel series of 100-year North Atlantic “hosing” simulations to investigate atmospheric and oceanic energy transport response from freshwater forcing, focusing in particular on the role of atmospheric rivers (ARs) within atmospheric energy transport. Importantly, we use an “overwriting” methodology that allow us to attribute AMOC weakening to added North Atlantic meltwater and subsequent hydrologic cycle responses, respectively. In contrast to far-reaching response of transient eddies, our results show a substantial increase in moisture convergence from ARs that is geographically constrained to the North Atlantic midlatitudes. Such AR changes nevertheless comprise an important component of net precipitation changes over the Euro-Atlantic sector, with the amount being comparable to that from transient eddies over the subpolar Atlantic. Over the course of the century-long simulations, we demonstrate that hydrologic cycle responses to North Atlantic freshening and subsequent feedbacks, including those from ARs, account for approximately half of the simulated AMOC collapse. Furthermore, our work highlights the dynamics of atmospheric moisture transport response to North Atlantic freshening events and elucidates how intensifying moisture transport may accelerate AMOC collapse in the future.

Atmospheric Science↗

DOE OSTI2025

Characterization of Recrystallized Grains During Static Recrystallization of Hot-Compressed Mg–Zn–Ca Alloys Using In Situ Far-Field High-Energy Diffraction Microscopy

In this study, we explored the effect of Zn content on the static recrystallization of three 80 pct hot-compressed alloys, Mg–0.5Zn–0.1Ca wt pct (ZX050), Mg–1Zn–0.1Ca wt pct (ZX10), and Mg–3.2Zn–0.1Ca wt pct (ZX30), using far-field high-energy microscopy (ff-HEDM). Individual recrystallized grains were tracked and their 3D centroid, relative volume, and grain-averaged crystallographic orientation were measured during annealing. These measurements were used to compare the recrystallization kinetics and texture evolution of recrystallized grains in ZX alloys as a function of the Zn content. Fully recrystallized microstructures were observed for the ZX30 and the ZX10 alloys after annealing at 230 °C and 330 °C, respectively. In contrast, only a partially recrystallized microstructure for the ZX050 alloy was observed after > 1 hour of annealing at 430 °C. The resistance to recrystallization with decreasing Zn content was also confirmed by detecting faster growth rates of recrystallized grains in the ZX10 and ZX30 alloys, and slower growth rates in the ZX050 alloy. The significant recrystallization texture weakening of the ZX10 and ZX30 alloys and the development of a basal texture in the ZX05 alloy were described based on the orientation dependency of nucleation and growth of recrystallized grains. The analysis demonstrated that texture weakening was associated with increasing Zn content in Mg–Zn–Ca alloys.

Roumina, Reza [Univ. of Michigan, Ann Arbor, MI (U↗

DOE OSTI2022

Low temperature dry reforming of methane using Ru-Ni-Mg/ceria-zirconia catalysts: Effect of Ru loading and reduction temperature

Dry reforming catalysts, especially those with activity at moderate temperatures, have been intensely investigated to enhance the conversion of biogas. Here, Ru is evaluated as a promoter for Ni-Mg based catalysts. Catalysts based on 1.4 wt%Ni-1.0 wt%Mg-Ce 0.6 Zr 0.4 O 2 with Ru (0.02–0.32 wt%) were prepared using incipient wetness. The reducibility of the catalysts and conversions increased with increasing Ru content. Increases in conversions with increasing Ru loading was attributed to the additional active sites and synergistic effect between Ru and Ni, which weakened Ni-Mg interactions. Samples showed dry reforming activity at low temperatures (450–510 °C). Reaction rates and activation energies of higher loading Ru samples (1.4 wt%Ni-1.0 wt%Mg/Ce 0.6 Zr 0.4 O 2 with 0.16 and 0.32 wt%Ru) decreased when the reduction temperature was raised from 300 to 400 °C. A 20 h TOS study showed stable catalytic activity with minimal coke deposition. Furthermore, the results suggest that Ru is an alternative to Pt in promoting low temperature dry reforming of methane.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

CO 2 hydrogenation: Selectivity control of CO versus CH 4 achieved using Na doping over Ru/m-ZrO 2 at low pressure

By doping 1%Ru/m-ZrO 2 with sodium, selectivity tuning between CO and CH 4 during CO 2 hydrogenation was achieved by controlling the relative rates of reverse water-gas shift and CO methanation. By increasing basicity through Na loading: (1) the formate C-H bond is weakened in DRIFTS of adsorbed CO, accelerating C-H bond formation of formate and promoting CO formation at the Ru/m-ZrO 2 interface; and (2) the coverage of Na increases on ensembles of Ru atoms responsible for methanation. Increasing Na content shifts selectivity from CH 4 (useful for synthetic natural gas) to CO, which can be used for Fischer-Tropsch synthesis or methanol-to-gasoline. Electronic modification of formate is likely due to enhanced basicity (strengthening bonding between catalyst and the-CO 2 function of formate and weakening C-H). In conclusion, no electron transfer from Na to Ru was detected in XANES. DRIFTS as a function of time and XPS results showed that Na exacerbates site blocking and deactivation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Low temperature ethanol steam reforming: Selectivity control with lithium doping of Pt/m-ZrO 2

Lithium promoted 2%Pt/m-ZrO 2 catalysts previously observed to exhibit higher rates for the low temperature water-gas shift (LTS) were tested for the ethanol steam reforming with the aim of exploring the potential tuning of the selectivity. Characterization of catalysts having optimized Li content (0.5–0.75%Li) for LTS exhibited (a) weakened C—H bonding of formate, a proposed intermediate in the LTS mechanism, as shown by a shift in the ν(CH) band to lower wavenumbers, (b) a relatively low extent of blocking of Pt, as measured by the ν(CO) band intensity of Pt-CO, (c) increased basicity as measured by CO 2 temperature-programmed desorption with mass spectrometry, but not so high as to strongly inhibit CO 2 product removal, and finally (d) no evidence of electron transfer from Li to Pt. Here, for this study, the same catalysts were tested for ethanol steam reforming (ESR). Results show that Li could likewise weaken the C—C bond of the acetate intermediate, the analog of formate in LTS, and facilitate decarboxylation over decarbonylation altering the selectivity in favor of methanation. This trend was confirmed by fixed bed reaction testing, in-situ infrared spectroscopy experiments of transient ESR, and temperature-programmed ESR using MS. The Li-doped catalysts may be used to pre-reform ethanol prior to feeding to a methane steam reformer to increase the overall H 2 selectivity of the process. DRIFTS of steady state ESR revealed that deactivation occurs through losses in the Pt-support interface, thereby hindering the turnover of the acetate intermediate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Unraveling disadhesion mechanism of epoxy/CSH interface under aggressive conditions

Almost all FRP-reinforced concrete exposed to the marine environment are susceptible to durability deficiencies due to failure of the FRP/epoxy/concrete interface, especially the vulnerable epoxy/concrete interface, which is frequently attacked by water and ions. Herein, molecular dynamics simulations of epoxy/CSH interface under different environmental exposures are utilized to specifically elucidate the degradation principles of water and ions on the bonding properties and mechanical responses of the epoxy/concrete interface. The environmental sequences associated with the interfacial bonding degradation are arranged as Na{sub 2}SO{sub 4} + NaCl>NaCl>Na{sub 2}SO{sub 4} > Water>Dry. Remarkably, water molecules weaken the interaction between the epoxy and CSH by robbing interfacial H- and Ca-O bonds, thereby reducing the energy barrier to interfacial peel and shear failure. The weakening effects are exacerbated by the presence of aggressive ions, as Na{sup +} ions attracted to the CSH surface accumulate more water molecules in the interfacial region by forming hydrated ions clusters, which ultimately accelerates the epoxy/CSH interfacial degradation.

36 MATERIALS SCIENCE↗