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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

The yield and post-yield behavior of high-density polyethylene

An experimental and analytical evaluation was made of the yield and post-yield behavior of high-density polyethylene, a semi-crystalline thermoplastic. Polyethylene was selected for study because it is very inexpensive and readily available in the form of thin-walled tubes. Thin-walled tubular specimens were subjected to axial loads and internal pressures, such that the specimens were subjected to a known biaxial loading. A constant octahederal shear stress rate was imposed during all tests. The measured yield and post-yield behavior was compared with predictions based on both isotropic and anisotropic models. Of particular interest was whether inelastic behavior was sensitive to the hydrostatic stress level. The major achievements and conclusions reached are discussed.

Semeliss, M. A.↗

Evidence for Ni-56 yields Co-56 yields Fe-56 decay in type Ia supernovae

In the prevailing picture of Type Ia supernovae (SN Ia), their explosive burning produces Ni-56, and the radioactive decay chain Ni-56 yields Co-56 yields Fe-56 powers the subsequent emission. We test a central feature of this theory by measuring the relative strengths of a (Co III) emission feature near 5900 A and a (Fe III) emission feature near 4700 A. We measure 38 spectra from 13 SN Ia ranging from 48 to 310 days after maximum light. When we compare the observations with a simple multilevel calculation, we find that the observed Fe/Co flux ratio evolves as expected when the Fe-56/Co-56 abundance ratio follows from Ni-56 yields Co-56 yields Fe-56 decay. From this agreement, we conclude that the cobalt and iron atoms we observe through SN Ia emission lines are produced by the radioactive decay of Ni-56, just as predicted by a wide range of models for SN Ia explosions.

Kuchner, Marc J.↗

Yield strength dependence on strain rate of molybdenum-alloy nanofibers

The yield strength dependence on strain rate was studied for molybdenum-alloy nanofibers with varying initial dislocation density at three different pre-strain levels. In-situ tensile experiments at three displacement rates were carried out in a scanning electron microscope. Yield strength and its scatter decreased as a function of the pre-strain level for different displacement rates. A statistical model was used to analyze the results, and a negative strain rate dependence was inferred from the yield experiments. This finding suggests the need for theoretical investigations since classical models such as dynamic strain aging may have limitations at such nanoscales.

36 MATERIALS SCIENCE↗

The Importance of Vane Configuration on Yield Stress Measurements of Cement Slurry

Vane methods combined with direct shear tests are widely applied to measure the yield stress $τ_0$ in concentrated suspensions such as cement slurries. This report reviews three different vanes with different shapes and sizes, and examines the relationship between the yield stress versus the torque and the shear rate versus the angular velocity. This research shows that vanes with conical shapes or reduced height/diameter ratio $(H/D)$ result in larger yield stress values.

36 MATERIALS SCIENCE↗

Winter Wheat Yield Assessment from Landsat 8 and Sentinel-2 Data: Incorporating Surface Reflectance, Through Phenological Fitting, into Regression Yield Models

A combination of Landsat 8 and Sentinel-2 offers a high frequency of observations (3–5 days) at moderate spatial resolution (10–30 m), which is essential for crop yield studies. Existing methods traditionally apply vegetation indices (VIs) that incorporate surface reflectances (SRs) in two or more spectral bands into a single variable, and rarely address the incorporation of SRs into empirical regression models of crop yield. In this work, we address these issues by normalizing satellite data (both VIs and SRs) derived from NASA’s Harmonized Landsat Sentinel-2 (HLS) product, through a phenological fitting. We apply a quadratic function to fit VIs or SRs against accumulated growing degree days (AGDDs), which affects the rate of crop development. The derived phenological metrics for VIs and SRs, namely peak, area under curve (AUC), and fitting coefficients from a quadratic function, were used to build empirical regression winter wheat models at a regional scale in Ukraine for three years, 2016–2018. The best results were achieved for the model with near infrared (NIR) and red spectral bands and derived AUC, constant, linear, and quadratic coefficients of the quadratic model. The best model yielded a root mean square error (RMSE) of 0.201 t/ha (5.4%) and coefficient of determination R2 = 0.73 on cross-validation.

phenological fitting↗

Imitating the “breeder's eye”: Predicting grain yield from measurements of non‐yield traits

Abstract Plant breeding relies on information gathered from field trials to select promising new crop varieties for release to farmers and to develop genomic prediction models that can enhance the efficiency of genetic improvement in future breeding cycles. However, generating the genetic marker data required to apply genomic prediction at the early stages of a breeding program remains costly for many public‐sector breeding programs as well as for many plant breeders operating in developing countries. As the pace of climate change intensifies, the time lag of developing and deploying new crop varieties requires plant breeders to make selection decisions without knowing the future environments those crop varieties will encounter in farmers’ fields. Therefore, both lower cost and higher accuracy methods for prediction of crop performance are essential for creating and maintaining resilient agricultural systems in the latter half of the 21 st century. To address this challenge, we conducted linked yield trials of 752 public maize ( Zea mays ) genotypes in two distinct environments. We developed and trained a phenotypic prediction model to predict yield from manually scored plant traits. The phenotypic prediction approach we employed outperformed genomic prediction in predicting yields in a second environment, with 8.7%–63% higher R 2 and 4%–13% less root mean square error than the genomic prediction. The phenotypic prediction has the potential to be applied to a wider range of breeding programs, including those that lack the resources to genotype large populations, such as programs in the developing world, breeding programs for specialty crops, and public sector programs.

60 APPLIED LIFE SCIENCES↗

Manipulating Triplet Yield through Control of Symmetry-Breaking Charge Transfer

The efficiency of an organic solar cell depends on the efficacy of exciton diffusion and dissociation processes, and this can be enhanced by reducing the exciton binding energy and increasing the exciton lifetime. Zinc chlorodipyrrin (ZCl) complexes exhibit reduced exciton binding energy due to ultrafast generation of intramolecular charge transfer (ICT) states via symmetry breaking charge transfer in polar media. This paper explores the fate of the ICT states using nanosecond transient absorption. In cyclohexane, ZCl undergoes intersystem-crossing to produce triplets with ~8 ns time constant (~30% yield) and no ICT states are generated. However, in more polar solvents, triplets are generated within 1 ns via ICT state recombination with ~3 times higher yield than produced via ISC. Furthermore, this high triplet yield in toluene (89%) and acetonitrile (76%) via ICT state recombination is a beneficial pathway to spin-protect the excited state decay for additional charge generation from triplet excited states.

14 SOLAR ENERGY↗

Support Induced Control of Surface Composition in Cu–Ni/TiO 2 Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans

5-(hydroxymethyl)furfural (HMF) and furfural (FF) have been confirmed as valuable biomass-derived fuel precursors suitable for catalytic hydrodeoxygenation (HDO) to produce high octane fuel additives such dimethyl furan (DMF) and methyl furan (MF), respectively. In order to realize economically viable production of DMF and MF from biomass, catalytic processes with high yields, low catalyst costs, and process simplicity are needed. In this work, we demonstrate simultaneous co-processing of HMF and FF over Cu-Ni/TiO 2 catalysts, achieving 87.5% yield of DMF from HMF and 88.5% yield of MF from FF in a one pot reaction. The Cu-Ni/TiO 2 catalyst also exhibited improved stability and regeneration compared to Cu/TiO 2 and Cu/Al 2 O 3 catalysts for FF HDO, exhibiting a ~7% loss in FF conversion over 4 sequential recycles, compared to a ~50% loss in FF coversion for Cu/Al 2 O 3 and a ~30% loss in coversion for Cu/TiO 2 . Characterization of the Cu-Ni/TiO 2 catalyst by X-ray Photoelectron Spectroscopy, Scanning Transmission Electron Microscopy, and H 2 -Temperature Programmed Reduction and comparison to monometallic Cu and Ni on Al 2 O 3 and TiO 2 and bimetallic Cu-Ni/Al 2 O 3 catalysts suggest that the unique reactivity and stability of Cu-Ni/TiO 2 derives from support-induced metal segregation in which Cu is selectively enriched at the catalyst surface, while Ni is enriched at the TiO 2 interface. Our findings demonstrate that Cu-Ni/TiO 2 catalysts promise to be a catalyst system capable of integrating directly with a combined HMF and FF product stream from biomass processing to realize lower cost production of liquid fuels from biomass.

09 BIOMASS FUELS↗

Enhancing Quantum Yield via Local Symmetry Distortion in Lanthanide-Based Upconverting Nanoparticles

Lanthanide-based upconverting nanoparticles exhibit significant promise for solar energy generation, biological imaging, and security technologies but have not seen widespread adoption due to the prohibitively low efficiencies of current materials. Weak transition dipole moments between 4f orbitals hinder both photon absorption and emission. Here, we introduce a novel way to increase the radiative transition rates in Yb,Er-based upconverting nanoparticles based on local symmetry distortion. Beginning from a host matrix of the well-studied hexagonal (β)-phase NaYF 4 , we incrementally remove Y 3+ ions and cosubstitute for them a 1:1 mixture of Gd 3+ and Lu 3+ . These two ions act to expand and contract the lattice, respectively, inducing local-level distortion while maintaining the average host structure. We synthesize a range of β-NaY 0.8-2 x Gd x Lu x F 4 :Yb 0.18 Er 0.02 nanoparticles and experimentally confirm that particle size, phase, global structure, and Yb 3+ and Er 3+ concentrations remain constant as x is varied. Upconversion quantum yield is probed as the degree of cosubstitution is varied from x = 0 to x = 0.24. We achieve a maximum quantum yield value of 0.074% under 63 W/cm 2 of excitation power density, representing a 1.6× enhancement over the unmodified particles and the highest measured value for near-infrared-to-visible upconversion in sub-25 nm unshelled nanoparticles. We also investigate upconversion emission at the single-particle level and report record improvements in emission intensity for sub-50 nm particles. Radiative rate enhancements are confirmed by measuring excited-state lifetimes. The approach described herein can be used in combination with more established methods of efficiency improvement, such as adding passivating shells or coupling to plasmonic nanoattenas, to further boost the upconversion quantum yield.

36 MATERIALS SCIENCE↗

Yield and Emplacement Depth Effects on Acoustic Signals from Buried Explosions in Hard Rock

Subterranean energy releases such as explosions and earthquakes may disturb the Earth-atmosphere interface, creating acoustic waves that can travel great distances. These waves provide a record of the ground motion directly above the event. The information they encode may provide critical insight into the depth and size of underground explosions, the sequence of events immediately before volcanic eruptions, and the magnitude of strong motion resulting from earthquakes. However, the effect of event size and burial depth on the resulting acoustic wave has not been explored in detail. The relationship between acoustic amplitude, frequency, and energy is investigated for a series of well-characterized underground chemical explosions in granite. Acoustic amplitude was found to vary linearly with explosive yield divided by emplacement depth. Peak acoustic frequency appears to be a function of explosive yield alone. The ratio of radiated acoustic energy to source energy had a relatively poor fit to yield, depth, and combinations thereof. These relationships suggest that acoustic analysis can be used to determine the size and depth of a buried explosion. The results presented here have particular relevance to the nuclear monitoring community, because depth is difficult to determine with seismic methods.

58 GEOSCIENCES↗

Yields and Cavity Radii of Underground Nuclear Tests with Specified Yields Reported in DOE/NV -- 209-REV 15 (2000)

The letter report provides a compilation of yield and cavity radius information for all underground nuclear tests with specified yields reported in DOE/NV -- 209-REV 15 (2000). Yield data were taken directly from DON/NV -- 209-REV 15 (2000). Cavity radius information was taken from a personal computer based database resident at Lawrence Livermore National Laboratory. This database is associated with the written report by Miller et al. (2002).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

BLUP and mean yields of selected top 25 high yielding half-sib families

BLUP and mean yields of selected top 25 high yielding half-sib families. The yield BLUP were estimated using mixed linear models. The family column indicates the families with progeny column showing the corresponding progenies to selected families. ‘Wat’ here has been used to denote Watkinsville, ‘Tif’ for Tifton and ‘TN’ for Tennessee.

09 BIOMASS FUELS↗

The relation of the yield stress of high-pressure anvils to the pressure attained at yielding and the ultimate attainable pressure

A sensitive microprofilometer was used to determine the onset of yielding in the anvils of a supported opposed anvil device for the case of 3% cobalt-cemented tungsten carbide as the anvil material. In addition, it is shown how the commencement of yielding in boron carbide pistons, the yield strength being known, can be used to obtain the transition pressure to a conducting phase in gallium phosphide. The transition pressures of bismuth and gallium phosphide are obtained and it is found that these transitions are extremely close to the maximum attainable pressure in, respectively, a maraging steel and a 3% cobalt-cemented tungsten carbide.

Panda, P. C.↗