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NASA's Astromaterials Database: Enabling Research Through Increased Access to Sample Data, Metadata and Imagery

The Astromaterials Acquisition & Curation Office at NASA's Johnson Space Center (JSC) is the designated facility for curating all of NASA's extraterrestrial samples. Today, the suite of collections includes the lunar samples from the Apollo missions, cosmic dust particles falling into the Earth's atmosphere, meteorites collected in Antarctica, comet and interstellar dust particles from the Stardust mission, asteroid particles from Japan's Hayabusa mission, solar wind atoms collected during the Genesis mission, and space‐exposed hardware from several missions. To support planetary science research on these samples, JSC's Astromaterials Curation Office hosts NASA's Astromaterials Curation digital repository and data access portal [http://curator.jsc.nasa.gov/], providing descriptions of the missions and collections, and critical information about each individual sample. Our office is designing and implementing several informatics initiatives to better serve the planetary research community. First, we are re‐hosting the basic database framework by consolidating legacy databases for individual collections and providing a uniform access point for information (descriptions, imagery, classification) on all of our samples. Second, we continue to upgrade and host digital compendia that summarize and highlight published findings on the samples (e.g., lunar samples, meteorites from Mars). We host high resolution imagery of samples as it becomes available, including newly scanned images of historical prints from the Apollo missions. Finally we are creating plans to collect and provide new data, including 3D imagery, point cloud data, micro CT data, and external links to other data sets on selected samples. Together, these individual efforts will provide unprecedented digital access to NASA's Astromaterials, enabling preservation of the samples through more specific and targeted requests, and supporting new planetary science research and collaborations on the samples.

Evans, Cindy↗

Improving the Discoverability and Availability of Sample Data and Imagery in NASA's Astromaterials Curation Digital Repository Using a New Common Architecture for Sample Databases

The Astromaterials Acquisition and Curation Office at NASA's Johnson Space Center (JSC) is the designated facility for curating all of NASA's extraterrestrial samples. The suite of collections includes the lunar samples from the Apollo missions, cosmic dust particles falling into the Earth's atmosphere, meteorites collected in Antarctica, comet and interstellar dust particles from the Stardust mission, asteroid particles from the Japanese Hayabusa mission, and solar wind atoms collected during the Genesis mission. To support planetary science research on these samples, NASA's Astromaterials Curation Office hosts the Astromaterials Curation Digital Repository, which provides descriptions of the missions and collections, and critical information about each individual sample. Our office is implementing several informatics initiatives with the goal of better serving the planetary research community. One of these initiatives aims to increase the availability and discoverability of sample data and images through the use of a newly designed common architecture for Astromaterials Curation databases.

Todd, N. S.↗

Experimental Report: Multi-Instrument Comparison of AAF Size Distribution Instruments

Aerosols are particles suspended in the atmosphere, ranging in size from nanometers to micrometers. Their size distribution affects key atmospheric processes, including nucleation, coagulation, scavenging, activation, and radiative properties (Seinfeld and Pandis 2016). Aerosol size distribution is a critical parameter in atmospheric science, influencing processes such as cloud formation and radiative forcing. Accurate representation of aerosol size distributions is essential for understanding their impact on climate, air quality, and human health. However, aerosol size and composition vary significantly across time and space due to meteorological conditions and natural or anthropogenic sources. (Wu and Boor 2021). Various instruments are used to measure aerosol size distributions, each with distinct principles, advantages, and limitations. This report begins with an in-depth overview of aerosol size-distribution comparison studies, focusing on the passive cavity aerosol spectrometer probe (PCASP), portable optical particle spectrometer (POPS), ultra-high-sensitivity aerosol spectrometer (UHSAS), aerodynamic particle sizer (APS), and scanning mobility particle sizer (SMPS). All of these instruments are used by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) Aerial Facility (AAF), which commissioned this comparison and report. The report evaluates the strengths and weaknesses of these instruments, highlights their applications, and discusses efforts to merge data from multiple instruments for comprehensive analysis.

54 ENVIRONMENTAL SCIENCES↗

A composition analyzer for microparticles using a spark ion source

Iron microparticles were fired onto a capacitor-type microparticle detector which responded to an impact with a spark discharge. Ion currents were extracted from the spark and analyzed in a time-of-flight mass spectrometer. The mass spectra showed the element of both detector and particle materials. The total extracted ion currents was typically 10A within a period of 100ns, indicating very efficient vaporization of the particle and ionization of the vapor. Potential applications include research on cosmic dust, atmospheric aerosols and cloud droplets, particles ejected by rocket or jet engines, by machining processes, or by nuclear bomb explosions.

Auer, S. O.↗

Composition analyzer for microparticles using a spark ion source

Iron microparticles were fired onto a capacitor-type microparticle detector which responded to an impact with a spark discharge. Ion currents were extracted from the spark and analyzed in a time-of-flight mass spectrometer. The mass spectra showed the elements of both detector and particle materials. The total extracted ion current was typically 10 A within a period of 100 nsec, indicating very efficient vaporization of the particle and ionization of the vapor. Potential applications include research on cosmic dust, atmospheric aerosols and cloud droplets, particles ejected by rocket or jet engines, by machining processes or by nuclear bomb explosions.

Auer, S.↗

A Multi-Instrument Cloud Condensation Nuclei Spectrum Product (Final Technical Report)

A wealth of observational data exists on the characteristics of atmospheric particulate matter, over multiple years, at the DOE ARM Southern Great Plains (SGP) Central Facility site. This site is located in a region of the country that frequently experiences weather extremes, and that is removed from many local sources of pollution but is affected by transported smoke, dust, and urban emissions. The relationships between particulate matter, cloud formation and evolution, and precipitation are therefore of strong interest, and are being explored via modeling on a variety of scales. These models require as input detailed information on the characteristics of particles capable of serving as the nuclei for cloud formation. Sufficient data exist to be able to put together a picture of the nature of the total aerosol and the cloud condensation nuclei (CCN) subset, and their variability, through merged data products. This study was aimed at exploiting the multiple measurement types at SGP to develop the first such multi-year estimates. Further, the resulting data were analyzed to understand temporal patterns ranging from hourly to seasonal, thereby gaining insights into the particle sources affecting the atmosphere in this region. DOE-funded datasets that were analyzed in this study include total particle number concentrations, submicron aerosol scattering coefficients, dry aerosol size distributions, and more recently, time-resolved submicron aerosol chemical composition. Data are also available for the number concentrations of particles that are activated in a cloud condensation nucleus instrument at a series of setpoint supersaturations, providing direct observations of the number concentrations of “CCN”. This variable is the quantity that is generally desired for inclusion in numerical models that seek to represent and predict the impacts of varying aerosol characteristics on the formation and microphysical properties of clouds. One limitation of the use of direct CCN observations is that they are not available for supersaturations larger than about 1%, which is insufficient for deep convection and may be insufficient even for shallow convection, depending on the nature of the available CCN and the dynamics of the cloud. We developed a data-based approach to representing the full aerosol size spectrum with size-dependent hygroscopicity, and used this to extrapolate CCN spectra beyond the limited measurements. Five years of SGP aerosol data (2009 -2013) were analyzed. As a side product of our work, we identified and communicated several previously-unflagged data quality issues. The resulting merged aerosol distributions, along with fits for seasonal averages, were published and submitted to the ARM archive as a special value-added product (VAP; submitted as a PI product). CCN spectra were computed for the same data period and will similarly be published and submitted to the archive for use by the community. We also note that our methodologies and findings have been discussed at several Joint ARM User Facility/Atmospheric System Research (ASR) Principal Investigators Meetings and that recent ARM/ASR aerosol data reporting strategies have included similar ideas for data merging, indicating that this work has had a lasting impact on ARM aerosol data acquisition and reporting. The proposed work advances the science of the interactions of aerosols, clouds and precipitation, with direct application to improve representation of such interactions for clouds in regional and global climate models. The archived data will continue to serve research studies in the future.

54 ENVIRONMENTAL SCIENCES↗

A new approach for measuring the carbon and oxygen content of atmospherically relevant compounds and mixtures

Abstract. Due to its complexity, gas- and particle-phase organic carbon in the atmosphere is often classified by its bulk physicochemical properties. However, there is a dearth of robust, moderate-cost approaches to measure the bulk chemical composition of organic carbon in the atmosphere. This is particularly true for the degree of oxygenation, which critically affects the properties and impacts of organic carbon but for which routine measurement approaches are lacking. This gap has limited the understanding of a wide range of atmospheric components, including particulate matter, the mass of which is monitored worldwide due to its health and environmental effects but the chemical characterization of which requires relatively high capital costs and complex operation by highly trained technical personnel. In this work, we demonstrate a new approach to estimate the mass of carbon and oxygen in analytes and mixtures that relies only on robust, moderate-cost detectors designed for use with gas chromatography. Organic compounds entering a flame ionization detector were found to be converted with approximately complete efficiency to CO2, which was analyzed downstream using an infrared detector to measure the mass of carbon analyzed. The ratio of the flame ionization detector (FID) signal generated to CO2 formed (FID∕CO2) was shown to be strongly correlated (R2=0.89) to the oxygen-to-carbon ratio (O∕C) of the analyte. Furthermore, simple mixtures of analytes behaved as the weighted average of their components, indicating that this correlation extends to mixtures. These properties were also observed to correlate well with the sensitivity of the FID estimated by structure activity relationships (quantified as the relative effective carbon number). The relationships between measured FID∕CO2, analyte O∕C, and FID sensitivity allow the estimation of one property from another with <15 % error for mixtures and <20 % error for most individual analytes. The approach opens the possibility of field-deployable, autonomous measurement of the carbon and oxygen content of particulate matter using time-tested, low-maintenance detectors, though such an application would require some additional testing on complex mixtures. With some instrumental modifications, similar measurements on gas-phase species may be feasible. Moreover, the potential expansion to additional gas chromatography detectors may provide concurrent measurement of other elements (e.g., sulfur, nitrogen).

42 ENGINEERING↗

Molecular understanding of the suppression of new-particle formation by isoprene

Nucleation of atmospheric vapours produces more than half of global cloud condensation nuclei and so has an important influence on climate. Recent studies show that monoterpene ( C 10 H 16 ) oxidation yields highly oxygenated products that can nucleate with or without sulfuric acid. Monoterpenes are emitted mainly by trees, frequently together with isoprene ( C 5 H 8 ), which has the highest global emission of all organic vapours. Previous studies have shown that isoprene suppresses new-particle formation from monoterpenes, but the cause of this suppression is under debate. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we show that isoprene reduces the yield of highly oxygenated dimers with 19 or 20 carbon atoms – which drive particle nucleation and early growth – while increasing the production of dimers with 14 or 15 carbon atoms. The dimers (termed C 20 and C 15 , respectively) are produced by termination reactions between pairs of peroxy radicals ( RO 2 • ) arising from monoterpenes or isoprene. Compared with pure monoterpene conditions, isoprene reduces nucleation rates at 1.7 nm (depending on the isoprene / monoterpene ratio) and approximately halves particle growth rates between 1.3 and 3.2 nm. However, above 3.2 nm, C 15 dimers contribute to secondary organic aerosol, and the growth rates are unaffected by isoprene. We further show that increased hydroxyl radical ( OH • ) reduces particle formation in our chemical system rather than enhances it as previously proposed, since it increases isoprene-derived RO 2 • radicals that reduce C 20 formation. RO 2 • termination emerges as the critical step that determines the highly oxygenated organic molecule (HOM) distribution and the corresponding nucleation capability. Species that reduce the C 20 yield, such as NO, HO 2 and as we show isoprene, can thus effectively reduce biogenic nucleation and early growth. Therefore the formation rate of organic aerosol in a particular region of the atmosphere under study will vary according to the precise ambient conditions.

54 ENVIRONMENTAL SCIENCES↗

CM-like Interplanetary Dust Particles in Lower Stratosphere During 1989 October and 1991 June/July

The stratospheric interplanetary dust particles L2005T12 and L2011O3 are linked to CM chondrite matrix. Particle L2005T12 is dominated by tabular grains of partially dehydrated greenalite-rich serpentine. Its amorphous matrix contains abundant smectite nanocrystals and annular Fe,Ni,S units. A uniquely stratified (partial) maghemite rim occurs only on S-rich parts of the matrix. Formation of this rim and Mg depletions in the matrix occurred during atmospheric entry heating of this particle. Particle L2011O3 has large iron sulfide and magnesiowustite grains in an amorphous low-Al, ferromagnesiosilica matrix. Hydrous crystallisation of this matrix produced ultrafine-grained smectites and disseminated iron sulfides. Atmospheric entry heating of both particles is indicated by the partial iron oxide rim, vesicular sulfides, and the scatter of matrix compositions due to loss of Mg. While many uncertainties remain, the high incidence of chondritic rough particles, which include an unknown amount of CM-like particles, in the lower stratosphere during 1984, 1989, and 1991 suggests annual variations in their abundances. The timing of lower stratospheric dust samplings is critical to collect these particles.

Rietmeijer, Frans J. M.↗

Reducing Exposures to Airborne Particles Through Improved Filtration: A High-Level Modeling Analysis

Indoor airborne particulates are well-known health hazards and filtration is one common method of reducing exposures. Based on our previously developed Regional Shelter Analysis methodology and parameters that characterize the existing US building stock, we perform a high-level assessment of the potential benefits of upgrading existing filters in furnace and in heating, ventilation, and air conditioning systems using off-the-shelf filters. We use three metrics to assess the improvement: Building Transmission Factor (a measure of protection against outdoor airborne particles), Indoor Normalized Time and Space Integrated Air Concentration (a measure of indoor exposure to indoor-origin airborne particles), and Building Exit Fraction (fraction of indoor airborne particles that are released to the outdoor atmosphere). We also discuss the potential reduction in regional exposures due to particles exiting the building and exposing downwind building occupants. Our modeling indicates that while buildings provide their occupants passive protection against airborne particulate hazards, including but not limited to PM 2.5 , PM 10 , and wildfire smoke; improving particle filtration efficiency may further improve this protection. The degree of improvement varies with particle size and building type. Of the building types studied, apartments are predicted to benefit most, with greater than a factor of 2 improvement (≥50% reduction in exposures) for 1 µm particle exposures when using MERV 7 to 12 rated filters. Non-residential buildings were notably less responsive to improved filtration but had the highest Building Exit Fractions with 30% to 40% of indoor airborne particles released to the outdoor atmosphere (apartment buildings only released 6% to 9%). Improvements predicted for single family homes were intermediate between apartments and non-residential buildings. Improvements in the Regional Exposure metric are larger, ranging from a factor of 2.5x to 10x for residences (when using MERV 7 to 12 rated filters) and up to 25x for large apartments with MERV 14 or 15 rated filters. The results of our modeling analysis are broadly consistent with the limited experimental data and modeling results available in the literature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The nitrogen cycle: Atmosphere interactions

Atmospheric interactions involving the nitrogen species are varied and complex. These interactions include photochemical reactions, initiated by the absorption of solar photons and chemical kinetic reactions, which involve both homogeneous (gas-to-gas reactions) and heterogeneous (gas-to-particle) reactions. Another important atmospheric interaction is the production of nitrogen oxides by atmospheric lightning. The nitrogen cycle strongly couples the biosphere and atmosphere. Many nitrogen species are produced by biogenic processes. Once in the atmosphere nitrogen oxides are photochemically and chemically transformed to nitrates, which are returned to the biosphere via precipitation, dry deposition and aerosols to close the biosphere-atmosphere nitrogen cycle. The sources, sinks and photochemistry/chemistry of the nitrogen species; atmospheric nitrogen species; souces and sinks of nitrous oxide; sources; sinks and photochemistry/chemistry of ammonia; seasonal variation of the vertical distribution of ammonia in the troposphere; surface and atmospheric sources of the nitrogen species, and seasonal variation of ground level ammonia are summarized.

Levine, J. S.↗

The Integrated Science Investigation of the Sun (ISIS): Energetic Particle Measurements for the Solar Probe Plus Mission

One of the major goals of NASA's Solar Probe Plus (SPP) mission is to determine the mechanisms that accelerate and transport high-energy particles from the solar atmosphere out into the heliosphere. Processes such as coronal mass ejections and solar flares, which peak roughly every 11 years around solar maximum, release huge quantities of energized matter, magnetic fields and electromagnetic radiation into space. The high-energy particles, known as solar energetic particles or SEPs, present a serious radiation threat to human explorers living and working outside low-Earth orbit and to technological assets such as communications and scientific satellites in space. This talk describes the Integrated Science Investigation of the Sun (ISIS) - Energetic Particle Instrument suite. ISIS measures key properties such as intensities, energy spectra, composition, and angular distributions of the low-energy suprathermal source populations, as well as the more hazardous, higher energy particles ejected from the Sun. By making the first-ever direct measurements of the near-Sun regions where the acceleration takes place, ISIS will provide the critical measurements that, when integrated with other SPP instruments and with solar and interplanetary observations, will lead to a revolutionary new understanding of the Sun and major drivers of solar system space weather.

McComas, D. J.↗

Martian surface properties indicated by the opposition effect

Radiative transfer expressions are used to derive average surface particle single-scattering albedos, phase functions and porosities from a photometric comparison of Viking Orbiter opposition measurements of the Martian Arabia, Syrtis Major and Elysium Planitia regions with several generic features. The best functional fit to the data includes consideration of atmospheric scattering, two-particle populations and surface roughness. It is found that (1) the presence of high albedo, high porosity surface particles is ubiquitous, (2) opposition surge is absent in the Syrtis Major region, and (3) the Chryse areas possess the largest surface roughness.

Thorpe, T. E.↗

Evolution of Io's volatile inventory

Voyager data are used to make crude estimates of the rate at which Io loses volatiles, by a variety of processes, to the surrounding magnetosphere, for the case of both the current, SO2-dominated atmosphere and hypothetical paleoatmospheres in which such other gases as N2 may have been the dominant constituent. Among the mechanisms making significant contributions to the prodigious rate at which Io is losing volatiles are: the interaction of the magnetospheric plasma with volcanic plume particles and the background atmosphere; the sputtering of ices on the surface, if the nightside atmospheric pressure is low enough; and Jeans' escape of O as a dissociation product of SO2 gas. It is also argued that in the case of paleoatmospheres only the first two alternatives would have been possible and, nevertheless, insufficient to account for N2 loss over the life of the satellite.

Pollack, J. B.↗

Neutrons and Gamma Rays from Solar Flares

The theory of neutron and gamma-ray production in flares is reviewed and comparisons of the calculations with data are made. The principal conclusions pertain to the accelerated proton and electron numbers and spectra in flares and to the interaction site of these particles in the solar atmosphere. For the June 21, 1980 flare, from which high-energy neutrons and high-energy ( MeV) photons were seen, the electron-to-proton ratio is energy dependent and much smaller than unity at energies greater than 1 MeV. The interaction site of these particles appears to be the solar chromosphere.

Ramaty, R.↗

Searches for neutrinos from cosmic-ray interactions in the Sun using seven years of IceCube data

Cosmic-ray interactions with the solar atmosphere are expected to produce particle showers which in turn produce neutrinos from weak decays of mesons. These solar atmospheric neutrinos (SAνs) have never been observed experimentally. A detection would be an important step in understanding cosmic-ray propagation in the inner solar system and the dynamics of solar magnetic fields. SAνs also represent an irreducible background to solar dark matter searches and a detection would allow precise characterization of this background. In this work, we present the first experimental search based on seven years of data collected from May 2010 to May 2017 in the austral winter with the IceCube Neutrino Observatory. An unbinned likelihood analysis is performed for events reconstructed within 5 degrees of the center of the Sun. No evidence for a SAν flux is observed. After inclusion of systematic uncertainties, we set a 90% upper limit of 1.02 +0.20 -0.18 ·10 -13 GeV-1cm -2 s -1 at 1 TeV.

79 ASTRONOMY AND ASTROPHYSICS↗

Observations of joule and particle heating in the auroral zone

Observational data from the Chatanika, Alaska incoherent scatter radar have been used to deduce atmospheric heating rates associated with particle precipitation and joule dissipation. During periods when Chatanika is in the vicinity of the auroral oval the height-integrated heat input to the lower thermosphere can be as large as 100 ergs per sq cm per sec with joule and particle heating rates of comparable magnitude. Altitude profiles of these heat inputs are also obtained, showing that the energy liberated by joule dissipation tends to peak at a substantially higher altitude (about 130 km) than that due to particles (100-120 km). As a consequence, it follows that joule heating can be expected to provide a rapid means for creating thermospheric disturbances. It is also pointed out that joule and particle heating are permanent features of the auroral oval and polar cap. As such, expansion of the auroral oval leads to an increase in the total global heating and, hence, to the close relationship between magnetic disturbances and thermospheric perturbation.

Banks, P. M.↗

Asteroidal versus cometary meteoroid impacts on the Long Duration Exposure Facility (LDEF)

Meteoroids that enter the Earth's atmosphere at low velocities will tend to impact the apex side (that surface facing the spacecraft direction of motion) of a spacecraft at a very high rate compared to the rate with which they will impact an antapex-facing surface. This ratio -- apex to antapex impact rates -- will become less as meteoroid entry velocities increase. The measured ratio, apex to antapex, for 500 micron diameter impact craters in 6061-T6 aluminum on LDEF seems to be about 20 from the work of the meteoroid SIG group and from the work of Humes that was presented at the first LDEF symposium. Such a ratio is more consistent with the meteoroid velocity distributions derived by Erickson and by Kessler, than it is with others that have been tested. These meteoroid velocity distributions have mean entry velocities into the Earth's atmosphere of 16.5 to 16.9 km/s. Jackson and Zook (in a paper submitted to Icarus) have numerically simulated the orbital evolution of small dust grains emitted from asteroids and comets. For those asteroidal grains small enough (below about 100 microns diameter) to drift from the asteroid belt to the orbit of the Earth, under P-R and solar wind drag, without suffering collisional destruction, the following results are found: as their ascending or descending nodes cross the Earth's orbit (and when they might collide with the Earth), their orbital eccentricities and inclinations are quite low (e less than 0.3, i less than 20 degrees), and their mean velocity with respect to the Earth is about 5 or 6 km/s. When gravitational acceleration of the Earth is taken into account, the corresponding mean velocities relative to the top of the Earth's atmosphere are 12 to 13 km/s. This means that, at best, these small asteroidal particles can not comprise more than 50 percent of the particles entering the Earth's atmosphere. And when gravitational focusing is considered, they cannot comprise more than a few percent of those in heliocentric orbit at 1 AU. The rest are presumably of cometary origin.

Zook, Herbert A.↗