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At least 721 records · Page 40

Partial melting of the St. Severin (LL) and Lost City (H) ordinary chondrites: One step backwards and two steps forward

This study looks at partial melting in H and LL chondrites at nearly one atmosphere of total pressure as part of a continuing study of the origins of basaltic achondrites. Previously, melting experiments on anhydrous CM and CV chondrites showed that, near its solidus, the CM chondrite produced melts having major element chemistries similar to the Sioux County eucrite; but, the pyroxenes in the residuum were too iron-rich to form diogenites. Our preliminary results from melting experiments on ordinary (H, LL) chondrites suggested that, although the melts did not look like any known eucrites, pyroxenes from these charges bracketed the compositional range of pyroxenes found in diogenites. We had used the Fe/Mg exchange coefficients calculated for olivine, pyroxene, and melt in these charges to evaluate the approach to equilibrium, which appeared to be excellent. Unfortunately, mass balance calculations later indicated to us that, unlike our CM and CV charges, the LL and H experimental charges had lost significant amounts of iron to their (Pt or PtRh) supports. Apparently, pyroxene stability in chondritic systems is quite sensitive to the amount of FeO, and it was this unrecognized change in the bulk iron content which had stabilized the high temperature, highly magnesian pyroxenes. Accordingly, this work reinvestigates the phase equilibria of ordinary chondrites, eliminating iron and nickel loss, and reports significant differences. It also looks closely at how the iron and sodium in the bulk charge affect the stability of pyroxene, and it comments on how these new results apply to the problems of diogenite and eucrite petrogenesis.

Jurewicz, A. J. G.↗

One-Dimensional, Two-Phase Flow Modeling Toward Interpreting Motor Slag Expulsion Phenomena

Aluminum oxide slag accumulation and expulsion was previously shown to be a player in various solid rocket motor phenomena, including the Space Shuttle's Reusable Solid Rocket Motor (RSRM) pressure perturbation, or "blip," and phantom moment. In the latter case, such un ]commanded side accelerations near the end of burn have also been identified in several other motor systems. However, efforts to estimate the mass expelled during a given event have come up short. Either bulk calculations are performed without enough physics present, or multiphase, multidimensional Computational Fluid Dynamic analyses are performed that give a snapshot in time and space but do not always aid in grasping the general principle. One ]dimensional, two ]phase compressible flow calculations yield an analytical result for nozzle flow under certain assumptions. This can be carried further to relate the bulk motor parameters of pressure, thrust, and mass flow rate under the different exhaust conditions driven by the addition of condensed phase mass flow. An unknown parameter is correlated to airflow testing with water injection where mass flow rates and pressure are known. Comparison is also made to full ]scale static test motor data where thrust and pressure changes are known and similar behavior is shown. The end goal is to be able to include the accumulation and flow of slag in internal ballistics predictions. This will allow better prediction of the tailoff when much slag is ejected and of mass retained versus time, believed to be a contributor to the widely-observed "flight knockdown" parameter.

Kibbey, Timothy P.↗

Comparing the Volatile Contents of Basaltic Rocks Through the Inner Solar System

Volatiles in planetary interiors play important roles in magma genesis, crust formation, eruption style, and even habitability of planetary surfaces. Allan Treiman’s career has touched on volatiles in the Moon, Mars, HED-parent body, the Earth, Venus, and other planetary bodies through studies of igneous rocks, volatile-bearing igneous minerals within these rocks, and the secondary alteration products produced from these rocks and minerals. His seminal work in many of these fields has inspired our careers and many others in our field. Here, we will build on and summarize what we know of the volatile content of basaltic rocks in the inner solar system. Specifically, this talk will focus on using volatile-bearing minerals (amphibole and apatite) along with bulk compositions to constrain the pre-eruptive, and potentially predegassed, volatile content of the magma and their source regions. We will then use these estimates to compare the volatile content of the Earth, Moon, Mars, Venus, and Mercury and what open questions there are for each planetary body.

Justin Filiberto↗

Analysis of Ryugu Fluid Inclusions: An Update

The most direct and convincing evidence for the presence of water and organic molecules on protoplanetary bodies is provided by fluid inclusions trapped in secondary minerals. Our previous work has demonstrated that early solar system fluids have survived as fluid inclusions in a Ryugu pyrrhotite crystal [2]. We hypothesize that the bulk molecular and isotopic composition of individual Ryugu fluid inclusions can be measured to provide ground truth for exploring and thermochemical modeling of the compositional and isotopic evolution of fluids in protoplanetary bodies including asteroids, comets and icy moons. This presentation is an update on our efforts to make measurements of elemental, molecular and, in particular, isotopic compositions of individual aqueous fluid inclusions in Ryugu samples. The measurements we plan will permit us to (1) understand elemental composition of the aqueous fluids present on Ryugu’s progenitor body, (2) track changes in the chemical and stable isotopic composition of altering fluids in small bodies over time, (3) verify the presence of organics in Ryugu fluids, (4) verify the reported significant CO 2 in Ryugu fluids, (5) measure O and H isotopes in preserved Ryugu fluids, (6) provide constraints on temperature range calculations for the mineralizing reactions being performed by other groups using mineral pairs, (7) measure sulfur/chloride and chloride/phosphorus ratios of Ryugu fluids. We note here that recent results from Enceladus reveal the importance of phosphorus in small body aqueous brines, indicating that our proposed research will benefit studies of all current ocean worlds.

Andrei Dolocan↗

Expanding the Measurement Capabilities of the mARC II Arc-Jet to Map the Operating Envelope for High-Enthalpy Air Flows

The mARC II is a 30 kW arc-jet facility at NASA Ames Research Center developed to produce high-enthalpy flows for low-cost technology development purposes. In this work, we introduce new measurement capabilities following the latest facility upgrades and begin characterizing the operating envelope for the two-disk arc-heater configuration with air as the working gas. The lower bound of the envelope corresponds to the lowest set current and the farthest sensor distance from the nozzle (𝐼set = 40 A, 𝑧 = 69 mm), while the upper bound corresponds to the highest current and closest sensor distance (𝐼set = 200 A, 𝑧 = 2 mm). Stagnation point heat flux was measured using a water-cooled Gardon gauge (⌀4.76 mm, 3/16" hemispherical), with values ranging from 15 ≤ q̇₀ ≤ 900 W/cm 2 . Stagnation pressure was measured using a water-cooled Pitot probe (⌀4.76 mm, 3/16" hemispherical), with values ranging from 18 ≤ p₀ ≤ 1100 Pa. The upgraded vacuum system is demonstrated to significantly extend the lower end of the operating envelope of the mARC II. Additionally, measurements of bulk enthalpy (3 ≤ h ≤ 13 MJ/kg) and stagnation enthalpy (4 ≤ h₀ ≤ 34 MJ/kg) demonstrate the mARC II facility's high-enthalpy capabilities. Completion of the operating envelope characterization is ongoing in tandem with the development of complementary diagnostic capabilities and numerical simulations.

instrumentation↗

Architecture and performance of Perlmutter's 35 PB ClusterStor E1000 all-flash file system

NERSC's newest system, Perlmutter, features a 35 PB all-flash Lustre file system built on HPE Cray ClusterStor E1000. Here, we present its architecture, early performance figures, and performance considerations unique to this architecture. We demonstrate the performance of E1000 OSSes through low-level Lustre tests that achieve over 90% of the theoretical bandwidth of the SSDs at the OST and LNet levels. We also show end-to-end performance for both traditional dimensions of I/O performance (peak bulk-synchronous bandwidth) and nonoptimal workloads endemic to production computing (small, incoherent I/Os at random offsets) and compare them to NERSC's previous system, Cori, to illustrate that Perlmutter achieves the performance of a burst buffer and the resilience of a scratch file system. Finally, we discuss performance considerations unique to all-flash Lustre and present ways in which users and HPC facilities can adjust their I/O patterns and operations to make optimal use of such architectures.

97 MATHEMATICS AND COMPUTING↗

NASA Tech Briefs, November 2013

Topics include: Cryogenic Liquid Sample Acquisition System for Remote Space Applications; 5 Spatial Statistical Data Fusion (SSDF); GPS Estimates of Integrated Precipitable Water Aid Weather Forecasters; Integrating a Microwave Radiometer into Radar Hardware for Simultaneous Data Collection Between the Instruments; Rapid Detection of Herpes Viruses for Clinical Applications; High-Speed Data Recorder for Space, Geodesy, and Other High-Speed Recording Applications; Datacasting V3.0; An All-Solid-State, Room-Temperature, Heterodyne Receiver for Atmospheric Spectroscopy at 1.2 THz; Stacked Transformer for Driver Gain and Receive Signal Splitting; Wireless Integrated Microelectronic Vacuum Sensor System; Fabrication Method for LOBSTER-Eye Optics in <110> Silicon; Compact Focal Plane Assembly for Planetary Science; Fabrication Methods for Adaptive Deformable Mirrors; Visiting Vehicle Ground Trajectory Tool; Workflow-Based Software Development Environment; Mobile Thread Task Manager; A Kinematic Calibration Process for Flight Robotic Arms; Magnetostrictive Alternator; Bulk Metallic Glasses and Composites for Optical and Compliant Mechanisms; Detection of Only Viable Bacterial Spores Using a Live/Dead Indicator in Mixed Populations; and Intravenous Fluid Generation System.

Source record↗

Electron lithography STAR design guidelines. Part 3: The mosaic transistor array applied to custom microprocessors. Part 4: Stores logic arrays, SLAs implemented with clocked CMOS

The Mosaic Transistor Array is an extension of the STAR system developed by NASA which has dedicated field cells designed to be specifically used in semicustom microprocessor applications. The Sandia radiation hard bulk CMOS process is utilized in order to satisfy the requirements of space flights. A design philosophy is developed which utilizes the strengths and recognizes the weaknesses of the Sandia process. A style of circuitry is developed which incorporates the low power and high drive capability of CMOS. In addition the density achieved is better than that for classic CMOS, although not as good as for NMOS. The basic logic functions for a data path are designed with compatible interface to the STAR grid system. In this manner either random logic or PLA type structures can be utilized for the control logic.

Trotter, J. D.↗

Modeling Pb(II) Adsorption on Mineral Surfaces: Bridging Density Functional Theory and Experiment with Thermodynamic Insights

Despite decades of work on aqueous lead (Pb) adsorption on a-Fe2O3 (hematite) and a-Al2O3 (alumina), gaps between measurements and modeling obscure molecular-level understanding. Achieving well-matched geometries between theory and experimental for mineral-water interfaces is a hurdle, as surface functional group type and distribution must be accounted for in determining mechanisms. Additionally, computational methods that can describe the substrate are often not appropriate to capture aqueous effects. Progress requires focusing on well-studied and relevant systems, such as key facets (001),(012), and (110) of hematite and alumina, and ubiquitous contaminants such as aqueous Pb. In the past, bulk-parametrized bond-valence principles were used to rationalize Pb(II) adsorption trends. These approaches can break down at surfaces, where flexible bonding environments and adsorption-induced surface relaxations play a critical role. Here, we adapt and apply a density functional theory (DFT) and thermodynamics framework, integrating DFT-calculated energies with experimental data and electrochemical principles, to predict Pb(II) adsorption. Our model results capture trends across the full set of surfaces and predict that inner-sphere Pb(II) sorption on (001) alumina varies from unfavorable to weakly favorable across a range of pH conditions. This aligns with experiment insights that Pb(II) interacts at that surface through outer-sphere interactions. Extending to Fe(II) adsorption, we demonstrate a coverage-dependent site preference, potentially explaining disorder in overlayers grown by the oxidative adsorption of Fe(II) on hematite (001).

lead contamination↗

Facile Synthesis of Rhodium‐Based Nanocrystals in a Metastable Phase and Evaluation of Their Thermal and Catalytic Properties

Abstract Controlling the polymorphism of metal nanocrystals is a promising strategy for enhancing properties and discovering new phenomena. However, previous studies on Rh nanocrystals have focused on their thermodynamically stable face‐centered‐cubic (fcc) phase. Herein, a facile synthesis of Rh‐based nanocrystals featuring the metastable hexagonal close‐packed (hcp) phase is reported by using Ru seeds in their native hcp phase to template the deposition of Rh atoms. The success of such phase‐controlled synthesis relies on the templating effect promoted by the small lattice mismatch between Ru and Rh and the slow dropwise titration of the precursor at an elevated temperature, ensuring the layer‐by‐layer growth mode and thus the formation of a conformal hcp‐Rh shell. Faster injection rate of Rh(III) precursor leads to the formation of a rough Rh shell in the conventional fcc phase due to accelerated reaction kinetics. Considering both thermodynamic and kinetic aspects of this system, the hcp‐Rh phase is favored when the low surface energy from smooth overlayers balances the high bulk energy of the metastable phase, achieved through tight control of reaction rates and deposition patterns. These Ru hcp @Rh hcp core–shell nanocrystals demonstrate thermal stability up to 400 °C, while exhibiting higher catalytic activity toward ethanol oxidation reaction compared to Ru hcp @Rh fcc counterparts.

Nguyen, Quynh N.↗

Use of friction stir processing to synthesize nanocrystalline, grain boundary segregating Fe-Ti alloys

Grain boundary segregating alloys, a class of alloys designed such that nanocrystalline grain sizes are thermodynamically stabilized by the presence of high segregation energy solutes at the grain boundaries, are typically produced through geometrically limited processing techniques such as equal channel angular extrusion or thin film sputtering. Here, this study explores the use of friction stir processing (FSP) as a novel means of studying and producing these alloys using a test system of Fe-6at%Ti. Spot FSPs with a range of processing parameter sets were produced on bulk, coarse grained bars of material and optimal parameters were identified. Microscopy identified a range of processed materials which achieved nanocrystalline grains on the order of 100 nm, delineating a critical window of processing parameters which limit heat input while inducing sufficient plastic deformation for grain refinement. The finest grained nanocrystalline Fe-Ti achieved a hardness of 7.68 GPa, a significant increase in hardness over pure Fe with a similar microstructure due to increased dislocation density from FSP as well as several strengthening mechanisms produced through the presence and segregation of Ti. These results demonstrated the feasibility of using FSP to produce nanocrystalline grain boundary segregating alloys.

Fe alloys↗

A review of fluids under nanoconfinement: Reactivity, geomechanics, phase transitions, and flow

Due to its many industrial applications, the physics associated with the nanoconfinement of fluids has garnered great attention from the scientific community in roughly the last fifteen years. One pioneer of that research has been the Multi-Scale Fluid-Solid Interactions in Architected and Natural Materials (MUSE) Energy Frontier Research Center, which produced more than 50 journal articles from 2018 to 2023. We structure the findings of MUSE into four categories and contextualize the work with the broader literature. Here, the four categories are (1) the dependence of chemical reactions on the degree of confinement, which given the lower freedom of motion of molecules yet improved availability of reaction sites generally lead to enhancement from bulk reactions; (2) the mechanical properties of the porous matrix, which are dependent on the heterogeneity of the system in terms of both composition and structure; (3) the phase transitions under nanoconfinement, which are influenced by the pore size and morphology, surface chemistry, and substrate composition; and (4) the physical controls of slip flow, which demonstrate the importance of several factors, such as wettability. These aspects of nanoconfinement are becoming clearer, but there are other elements such as mathematical theory that are still being developed.

58 GEOSCIENCES↗

Altermagnetic polar metallic phase in ultrathin epitaxially strained RuO 2 films

Altermagnetism refers to a wide class of magnetic orders featuring magnetic sublattices with opposite spins related by rotational symmetries, resulting in nontrivial spin splitting and magnetic multipoles. However, the direct observation of the altermagnetic transition remains elusive. Here, by combining theoretical analysis, electrical transport, X-ray, and optical spectroscopies, we establish a phase diagram in hybrid molecular beam epitaxy-grown RuO 2 /TiO 2 (110) films, mapping symmetries along with altermagnetic/electronic/structural phase transitions as functions of film thickness and temperature. This features an altermagnetic metallic polar phase in epitaxially strained 2 nm films, suggesting a potential link between polar metals and altermagnetic materials. Such a clear signature of a magnetic phase transition at ~500 K is observed exclusively in ultrathin strained films, unlike in bulk RuO 2 single crystals. These results highlight the power of epitaxial heterostructure engineering to induce altermagnetism in systems initially nonmagnetic, opening avenues for realizing emergent quantum phases with multifunctional properties.

RuO2 thin film↗

Infrared fixed point in the massless twelve-flavor SU(3) gauge-fermion system

We present strong numerical evidence for the existence of an infrared fixed point in the renormalization group flow of the SU(3) gauge-fermion system with twelve massless fermions in the fundamental representation. Our numerical simulations using nHYP-smeared staggered fermions with Pauli-Villars improvement do not exhibit any first-order bulk phase transition in the investigated parameter region. We utilize an infinite volume renormalization scheme based on the gradient flow transformation to determine the renormalization group β function. The gradient flow β function exhibits a zero at g GF ⋆ 2 = 6.60 ( 62 ) , implying that the system is infrared conformal. We calculate the leading irrelevant critical exponent γ g ⋆ = 0.199 ( 32 ) . Our prediction for γ g ⋆ is consistent with available literature at the 1 − 2 σ level. Published by the American Physical Society 2024

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

CHESS 2025: Orthorectified airborne RGB imagery from NEON AOP surveys

This dataset provides Level 1 (L1) and Level 3 (L3) orthorectified Red-Green-Blue (RGB) imagery collected for the 2025 Colorado Headwaters Ecological Spectroscopy Study (CHESS). This high-resolution imagery is a photographic record of red, green, and blue visible light from sunlight reflected off of the Earth’s surface. The data comprise full-color images of the ground surface and are primarily intended to provide context to imaging spectroscopy and light detection and ranging (LiDAR) data. The data were acquired over three study domains in the Upper Gunnison river basin: the upper East River watershed (CRBU); Almont Triangle and Taylor Canyon (ALMO); and Upper Taylor River watershed (UPTA) between 2025-06-13 and 2025-07-15. RGB images were acquired using the PhaseOne IXM-RS150F high-resolution digital camera onboard the National Ecological Observatory Network (NEON) Airborne Observation Platform (AOP). The package data include both an L1 product comprising one camera frame per file and an L3 mosaic aligned to the Universal Transverse Mercator (UTM) Zone 13N grid and the World Geodetic System (WGS) 84 projection. Both products are provided in geotif (.tif) format at 0.1 m ground resolution. The bulk of the imagery was collected during the main CHESS field campaign from June 13 to July 15, 2025. Additional images of a portion of the Upper Taylor (UPTA) domain were collected on September 18, 2025, to fill gaps in imagery identified after the main campaign was complete. RGB camera imagery is not radiometrically calibrated, and therefore pixel values should not be exploited for scientific analysis. Pixel values have undergone a manual adjustment to enhance feature identification. The imagery is rigorously geolocated which does allow for reliable geometric information to be retrieved. To generate the orthorectified imagery, the NEON AOP camera captured visible spectrum in red, green, and blue bands. The raw images were then processed using NEON’s camera orthorectification workflow. A boresight calibration flight was made to build a complete camera, distortion, and alignment model. Color balance/white balance and exposure correction were applied to the raw RGB images. The corrected images were orthorectified by ray-tracing image pixels to a lidar-derived digital surface model (DSM) mesh using the refined camera model, outputting orthorectified raster pixels on a regular grid. Flightline-level data were mosaicked by selecting per-pixel contributions from overlapping orthorectified images using line-of-sight (LOS) zenith angle minimization to reduce edge distortions. CHESS Project Description: The Colorado Headwaters Ecological Spectroscopy Study (CHESS) comprised a multi-week airborne remote sensing and field observation campaign in the Upper Gunnison Basin, Colorado, conducted in June and July of 2025. Airborne remote sensing was conducted by the National Ecological Observatory Network Airborne Observation Platform (NEON AOP), concurrent with a field campaign run by the Rocky Mountain Biological Laboratory (RMBL), the Lawrence Berkeley National Laboratory (LBNL) and SLAC National Accelerator Laboratory Watershed Function Science Focus Area (SFA), and NASA-JPL (Jet Propulsion Laboratory) Earth Surface Mineral Dust Source Investigation (EMIT) program. Between June 10 and July 18, 2025, the NEON AOP flight team collected high-resolution aerial imaging spectroscopy and Light Detection and Ranging (LiDAR) data over three domains: the Upper East River (CRBU), Almont Triangle (ALMO), and the Upper Taylor Basin (UPTA). In coordination with the flights, a field campaign acquired ground-truth observations, including observations of vegetation composition, foliar traits, forest demography, and subsurface properties in 18 core sampling areas within the domains. Additional surface water observations were taken at over 380 point locations. All CHESS campaign datasets can be found within the CHESS ESS-DIVE data portal: https://data.ess-dive.lbl.gov/portals/chess. Funding Acknowledgement: Field and remote-sensing data acquisition was performed under a grant from the National Aeronautics and Space Administration (80NSSC24K1005). This work was also supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

2018 NEON and 2025 CHESS Campaigns↗

Establishing Data Analysis Pipeline for Bulk ATAC-Seq Datasets

We developed an analysis pipeline for transposase-accessible chromatin sequencing (ATAC-Seq) data derived from bulk samples, which brings together publicly available R packages in addition to command-line tools designed for analysis of bulk ATAC-Seq data and can be run on any computer running a Linux-like operating system such as Ubuntu or Apple OSX.

97 MATHEMATICS AND COMPUTING↗

Transportation concepts for space industrialization

Space shuttle and heavy lift launch vehicle concepts are described with attention to transportation cost trends. Chemical (LOX/LH2), nuclear, and electric propulsion systems are considered. Suggested space shuttle projects include the support of manned geosynchronous missions and the transfer of bulk cargo and large-delicate space structures from fabrication/assembly orbits to their operational locations. It is thought that development of the space shuttle will stimulate interest in space industrialization.

Murphy, J. T.↗