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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

New methods for the preparation and dielectric properties of La{sub 2−x}Sr{sub x}NiO{sub 4} (x = 1/8) ceramic

Highlights: • A new fuel in solution combustion synthesis of fine powder La{sub 15/8}Sr{sub 1/8}NiO{sub 4}. • Changes in the morphology of the ceramic La{sub 15/8}Sr{sub 1/8}NiO{sub 4} after thermobaric treatment. • Changes in structural parameters of the La{sub 15/8}Sr{sub 1/8}NiO{sub 4} after thermobaric treatment. • Increase of the dielectric constant of the thermobaric treated ceramic La{sub 15/8}Sr{sub 1/8}NiO{sub 4}. • Using of dielectric modulus and impedance formalisms, of equivalent circuits method. - Abstract: The perovskite-type oxide La{sub 2−x}Sr{sub x}NiO{sub 4} (x = 1/8) was prepared by a new precursor route. The reaction proceeds in the self-ignition mode. Single-phase powder and gas-tight ceramic samples can be produced by single annealing of decomposition products. It was shown that as a result of thermobaric treatment of La{sub 2−x}Sr{sub x}NiO{sub 4} (x = 1/8) the solid solution La{sub 2−x}Sr{sub x}NiO{sub 4} with a higher concentration of strontium and the second phase La{sub 3}Ni{sub 2}O{sub 7} are formed. Short-term (5 min) thermobaric treatment (P = 2.5 GPa) at t° = 900 °C changes the unit cell parameters, but is not accompanied by structural transitions. At the same time, morphological restructuring of the sample occurs—the agglomerates delaminate into thin plates crystals. It was established that the permittivity of the material exposed to thermobaric treatment is much higher compared to that of the sample annealed at atmospheric pressure and virtually does not depend on frequency in a wide temperature range.

36 MATERIALS SCIENCE↗
DOE OSTI2018

SrV2O6: An ultralow-firing microwave dielectric ceramic for LTCC applications

Highlights: • α-SrV{sub 2}O{sub 6} and β-SrV2O{sub 6} phase were coexisted below 500 °C, and stable α-SrV{sub 2}O{sub 6} phase at 630 °C. • Optimum microwave dielectric properties: ε{sub r} ∼9.66, Q × f ∼23,200 GHz, and τ{sub f} ∼ −205 ppm/°C were obtained. • CaTiO{sub 3} successfully adjusted τ{sub f} value toward to near-zero with −2.7 ppm/°C. • Their chemical compatibility with the aluminum electrodes were evaluated. - Abstract: A novel ultralow-firing microwave dielectric ceramic SrV{sub 2}O{sub 6} was prepared at 630 °C through the solid-state method. Phase evolution and crystal structure were analyzed by XRD and Raman spectroscopy. Results show that α-SrV{sub 2}O{sub 6} and β-SrV{sub 2}O{sub 6} phase coexisted when fired at lower temperatures (α-SrV{sub 2}O{sub 6} phase was obtained at 550 °C and remained stable up to 660 °C. Optimum microwave dielectric properties with a quality factor ∼23,200 GHz, a low dielectric constant ∼9.66, and a temperature coefficient of resonant frequency ∼−205 ppm/°C was obtained. SrV{sub 2}O{sub 6} ceramic possessed chemical compatibility with aluminum electrodes when cofired at 630 °C. The temperature stability of SrV{sub 2}O{sub 6} was adjusted by forming composite ceramics with CaTiO{sub 3} and a near-zero τ{sub f} ∼−2.7 ppm/°C was achieved in the 0.75SrV{sub 2}O{sub 6}-0.25CaTiO{sub 3} ceramic. All the results show that the SrV{sub 2}O{sub 6} ceramic might be a promising candidate as substrates in ultra-low temperature cofired (ULTCC) ceramics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2015

Improved Rhenium Thrust Chambers

Radiation-cooled bipropellant thrust chambers are being considered for ascent/ descent engines and reaction control systems on various NASA missions and spacecraft, such as the Mars Sample Return and Orion Multi-Purpose Crew Vehicle (MPCV). Currently, iridium (Ir)-lined rhenium (Re) combustion chambers are the state of the art for in-space engines. NASA's Advanced Materials Bipropellant Rocket (AMBR) engine, a 150-lbf Ir-Re chamber produced by Plasma Processes and Aerojet Rocketdyne, recently set a hydrazine specific impulse record of 333.5 seconds. To withstand the high loads during terrestrial launch, Re chambers with improved mechanical properties are needed. Recent electrochemical forming (EL-Form"TM") results have shown considerable promise for improving Re's mechanical properties by producing a multilayered deposit composed of a tailored microstructure (i.e., Engineered Re). The Engineered Re processing techniques were optimized, and detailed characterization and mechanical properties tests were performed. The most promising techniques were selected and used to produce an Engineered Re AMBR-sized combustion chamber for testing at Aerojet Rocketdyne.

O'Dell, John Scott↗
NASA NTRS2015

Mechanical Properties and Real-Time Damage Evaluations of Environmental Barrier Coated SiC/SiC CMCs Subjected to Tensile Loading Under Thermal Gradients

SiC/SiC ceramic matrix composites (CMCs) require new state-of-the art environmental barrier coatings (EBCs) to withstand increased temperature requirements and high velocity combustion corrosive combustion gasses. The present work compares the response of coated and uncoated SiC/SiC CMC substrates subjected to simulated engine environments followed by high temperature mechanical testing to asses retained properties and damage mechanisms. Our focus is to explore the capabilities of electrical resistance (ER) measurements as an NDE technique for testing of retained properties under combined high heat-flux and mechanical loading conditions. Furthermore, Acoustic Emission (AE) measurements and Digital Image Correlation (DIC) were performed to determine material damage onset and accumulation.

Ceramic matrix composites↗
DOE OSTI2019

Predicting combustion characteristics in externally heated micro-tubes

Here this study employs a simplified analytical model to obtain qualitative predictions of transitions between non-adiabatic combustion regimes found in non-catalytic tubular micro-flow reactors, i.e. normal stable flames, flames with repetitive extinction and ignition (FREI), and weak flames that are stabilized by wall heat transfer. Assuming large activation energy for single-step kinetics, a comparison of exact solutions for constant and variable wall temperature profiles reveals that while a non-zero wall temperature gradient introduces a temperature lag, it has no impact on the structure of the flame solution itself. This result is significant as it establishes a link to quenching characteristics within heated micro-tubes, and further facilitates a simplified micro-flow reactor analysis. Predictions for sweeps of wall temperatures are combined to S-curves, which allow for a combustion regime classification for a given combination of micro-flow reactor geometry and mixture properties. A variation of parameters such as tube diameter or mixture stoichiometry yields predictions of shifts in regime transitions, thus providing insights on interactions between heat transfer and first order effects of chemical kinetics. A comparison to experimental data illustrates that the theoretical framework, - within inherent limitations, - captures qualitatively correct trends that reflect experimental observations, thus providing valuable insights for micro-flow reactor design and operation.

42 ENGINEERING↗
DOE OSTI2016

Structural and photoluminescence investigations of Sm{sup 3+} doped BaY{sub 2}ZnO{sub 5} nanophosphors

Highlights: • BaY{sub 2(1−x)}Sm{sub 2x}ZnO{sub 5} nanophosphors have been synthesized via solution combustion. • The nanophosphors have been characterized by XRD, TEM and PL spectroscopy. • The crystal structure reveals influence of doping on lattice parameters. • This nanophosphor executes orange–red emission under near UV excitation. - Abstract: BaY{sub 2}ZnO{sub 5}:Sm{sup 3+} nanophosphor was successfully synthesized using solution combustion process. XRD and photoluminescence (PL) techniques were used to analyze the structural and photoluminescence properties. Morphological study of the thermally stable powder was carried out using transmission electron microscope (TEM). Rietveld refinement technique has been used to analyze the samples qualitatively as well as quantitatively. X-Ray diffraction analysis confirms that the highly crystalline single phased Sm{sup 3+} doped BaY{sub 2}ZnO{sub 5} nanophosphor crystallizes in orthorhombic lattice with Pbnm space group. The average particle size lies in the range 80–90 nm with spherical morphology. The photoluminescence excitation at 411 nm yields an intense orange–red emission centered at 610 nm due to {sup 4}G{sub 5/2}–{sup 6}H{sub 7/2} transition. The concentration dependent luminescent behavior of BaY{sub 2(1−x)}Sm{sub 2x}ZnO{sub 5} nanophosphor shows that the optimum concentration for best luminescence is 3 mol%. These results indicate that these nanophosphors find potential applications in the field of phosphor-converted white LED systems.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Fire effects on the persistence of soil organic matter and long-term carbon storage

One paradigm in biogeochemistry is that frequent disturbance tends to deplete carbon (C) in soil organic matter (SOM) by reducing biomass inputs and promoting losses. However, disturbance by fire has challenged this paradigm because soil C responses to frequent and/or intense fires are highly variable, despite observed declines in biomass inputs. Here, we review recent advances to illustrate that fire-driven changes in decomposition, mediated by altered SOM stability, are an important compensatory process offsetting declines in aboveground biomass pools. Fire alters the stability of SOM by affecting both the physicochemical properties of the SOM and the environmental drivers of decomposition, potentially offsetting C lost via combustion, but the mechanisms affecting the SOM stability differ across ecosystems. Thus, shifting our focus from a top-down view of fire impacting C cycling via changes in plant biomass to a bottom-up view of changes in decomposition may help to elucidate counterintuitive trends in the response of SOM to burning. Finally, given that 70% of global topsoil C is in fire-prone regions, using fire to promote SOM stability may be an important nature-based climate solution to increase C storage.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Mapping ammonia-diesel combustion on a single-cylinder 107 mm bore diesel engine retrofitted for ammonia port-fuel injection

Ammonia is garnering significant interest from the international maritime sector as an alternative fuel. It is attractive as a hydrogen carrier and as a fuel because it has a higher volumetric energy density compared with gaseous or liquid hydrogen, making it easier to store and transport without requiring high pressures or cryogenic storage. Ammonia has significant toxicity concerns, but safe handling procedures have already been established because it is one of the most widely produced chemicals worldwide for use as a fertilizer. Barriers to consuming NH 3 as a fuel in engines include (1) less favorable ignition energy and flame speed compared with conventional fuels; (2) emissions challenges, including potentially high NH 3 , NO X , and N 2 O emissions; and (3) fuel delivery and handling challenges. Although NH 3 has been used to fuel compression-ignition marine engines in limited demonstration projects, technical barriers still exist. The use of NH 3 as a fuel in smaller-bore, high-speed auxiliary engines for large vessels and for smaller inland and coastal marine applications remains unaddressed. This work investigates a late-injection diesel pilot ignition dual-fuel NH 3 strategy using a single-cylinder, high-speed Cummins four-stroke diesel engine platform with a 107 mm bore and 1.1 L displacement per cylinder. The engine was modified for port fuel injection of heated gaseous anhydrous NH 3 . The diesel fuel injection system and the combustion geometry were unmodified to represent a retrofit application, which would minimize additional hardware to maximize diesel fuel displacement with NH 3 . Furthermore, the results show the applicability of a late injection diesel pilot strategy to overcome the challenging fuel properties of NH 3 over the engine operating envelope. Mapping results focusing on emissions are presented, and comparisons are made to a conventional diesel combustion baseline.

Ship engines↗
DOE OSTI2013

Recovery Act: Geologic Sequestration Training and Research

Work under the project entitled "Geologic Sequestration Training and Research," was performed by the University of Alabama at Birmingham and Southern Company from December 1, 2009, to June 30, 2013. The emphasis was on training of students and faculty through research on topics central to further development, demonstration, and commercialization of carbon capture, utilization, and storage (CCUS). The project had the following components: (1) establishment of a laboratory for measurement of rock properties, (2) evaluation of the sealing capacity of caprocks, (3) evaluation of porosity, permeability, and storage capacity of reservoirs, (4) simulation of CO 2 migration and trapping in storage reservoirs and seepage through seal layers, (5) education and training of students through independent research on rock properties and reservoir simulation, and (6) development of an advanced undergraduate/graduate level course on coal combustion and gasification, climate change, and carbon sequestration.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Control of Hybrid Power Unit with a Mechanical Transmission in High-Speed Caterpillar Vehicles

Abstract—: The properties of a hybrid power unit in which a mechanical transmission rigidly connects the internal combustion engine to the driving wheels are considered. In this transmission, the torque created by the parallel electric field is summed with the torque generated by the engine in the event of overloading. The control algorithms developed for the electric power prevent its opposition to the mechanical power under any circumstances.

42 ENGINEERING↗
NASA NTRS1985

Study of high performance alloy electroforming

The nickel-manganese experimental electrolyte was hydrogen peroxide treated and carbon purified for removal of residual sodium saccharin and related organic decomposition products from the plating of previous test panels. The saccharin additive was used to reduce stress where high concentrations of manganese and high pulse peak current densities were used. A large quantity of nickel-manganese alloy plates containing 0.35 to 0.40 percent by weight manganese was electroformed for testing to supply data for a mechanical property data table. The aluminum billet required for the machining of the subscale SSME main combustion chamber was acquired.

Malone, G. A.↗
NASA NTRS2003

Propulsion Research at the Propulsion Research Center of the NASA Marshall Space Flight Center

The Propulsion Research Center of the NASA Marshall Space Flight Center is engaged in research activities aimed at providing the bases for fundamental advancement of a range of space propulsion technologies. There are four broad research themes. Advanced chemical propulsion studies focus on the detailed chemistry and transport processes for high-pressure combustion, and on the understanding and control of combustion stability. New high-energy propellant research ranges from theoretical prediction of new propellant properties through experimental characterization propellant performance, material interactions, aging properties, and ignition behavior. Another research area involves advanced nuclear electric propulsion with new robust and lightweight materials and with designs for advanced fuels. Nuclear electric propulsion systems are characterized using simulated nuclear systems, where the non-nuclear power source has the form and power input of a nuclear reactor. This permits detailed testing of nuclear propulsion systems in a non-nuclear environment. In-space propulsion research is focused primarily on high power plasma thruster work. New methods for achieving higher thrust in these devices are being studied theoretically and experimentally. Solar thermal propulsion research is also underway for in-space applications. The fourth of these research areas is advanced energetics. Specific research here includes the containment of ion clouds for extended periods. This is aimed at proving the concept of antimatter trapping and storage for use ultimately in propulsion applications. Another activity in this involves research into lightweight magnetic technology for space propulsion applications.

Blevins, John↗
NASA NTRS2003

Effect Of Gravity On Porous Tricalcium Phosphate And Nonstoichiometric Titanium Carbide Produced Via Combustion Synthesis

Novel processing techniques, such as self-propagating high temperature synthesis (SHS), have the capability to rapidly produce advanced porous materials that are difficult to fabricate by other methods. This processing technique is also capable of near net shape synthesis, while variable gravity allows the manipulation of the structure and composition of the material. The creation of porous tricalcium phosphate (TCP) is advantageous in the biomaterials field, since it is both a biocompatible material and an osteoconductive material. Porous tricalcium phosphate produced via SHS is an excellent candidate for bone scaffold material in the bone regeneration process. The porosity allows for great vascularization and ingrowth of tissue. Titanium Carbide is a nonstoichiometric biocompatible material that can be incorporated into a TiC-Ti composite system using combustion synthesis. The TiC-Ti composite exhibits a wide range of mechanical and chemical properties. Both of these material systems (TCP and TiC-Ti) can be used to advantage in designing novel bone replacement materials. Gravity plays an important role in both the pore structure and the chemical uniformity of these composite systems and offers considerable potential in advanced bone engineering.

Castillo, M.↗
DOE OSTI2015

Light Absorption Properties and Radiative Effects of Primary Organic Aerosol Emissions

Organic aerosols (OAs) in the atmosphere affect Earth's energy budget by not only scattering but also absorbing solar radiation due to the presence of the so-called "brown carbon" (BrC) component. However, the absorptivities of OAs are not represented or are poorly represented in current climate and chemical transport models. In this study, we provide a method to constrain the BrC absorptivity at the emission inventory level using recent laboratory and field observations. We review available measurements of the light-absorbing primary OA (POA), and quantify the wavelength-dependent imaginary refractive indices (k(OA), the fundamental optical parameter determining the particle's absorptivity) and their uncertainties for the bulk POA emitted from biomass/biofuel, lignite, propane, and oil combustion sources. In particular, we parametrize the k(OA) of biomass/biofuel combustion sources as a function of the black carbon (BC)-to-OA ratio, indicating that the absorptive properties of POA depend strongly on burning conditions. The derived fuel-type-based k(OA) profiles are incorporated into a global carbonaceous aerosol emission inventory, and the integrated k(OA) values of sectoral and total POA emissions are presented. Results of a simple radiative transfer model show that the POA absorptivity warms the atmosphere significantly and leads to similar to 27% reduction in the amount of the net global average POA. cooling compared to results from the nonabsorbing assumption.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2002

Laminar Soot Processes (LSP)

This is the final report of a research program considering the structure and the soot surface reaction properties of laminar nonpremixed (diffusion) flames. The study was limited to ground-based measurements of buoyant laminar jet diffusion flames at pressures of 0.1-1.0 atm. The motivation for the research is that soot formation in flames is a major unresolved problem of combustion science that influences the pollutant emissions, durability and performance of power and propulsion systems, as well as the potential for developing computational combustion. The investigation was divided into two phases considering the structure of laminar soot-containing diffusion flames and the soot surface reaction properties (soot surface growth and oxidation) of these flames, in turn. The first phase of the research addressed flame and soot structure properties of buoyant laminar jet diffusion flames at various pressures. The measurements showed that H, OH and O radical concentrations were generally in superequilibrium concentrations at atmospheric pressure but tended toward subequilibrium concentrations as pressures decreased. The measurements indicated that the original fuel decomposed into more robust compounds at elevated temperatures, such as acetylene (unless the original fuel was acetylene) and H, which are the major reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. The second phase of the research addressed soot surface reaction properties, e.g., soot surface growth and surface oxidation. It was found that soot surface growth rates in both laminar premixed and diffusion flames were in good agreement, that these rates were relatively independent of fuel type, and that these rates could be correlated by the Hydrogen-Abstraction/Carbon-Addition (HACA) mechanisms of Colket and Hall (1994), Frenklach et al. (1990,1994), and Kazakov et al. (1995). It was also found that soot surface oxidation rates were relatively independent of fuel type, were not correlated with O2, CO2, H2O and O collision rates but were correlated with the collision rates of OH with a collision efficiency of 0.14, in agreement with the early measurements in premixed flames of Neoh et al. (1980), after allowing for oxidation by O2 via the classical rate expression of Nagle and Strickland-Constable (1962).

Dai, Z.↗
DOE OSTI2018

Production of Nanoscale Detonation Carbon using a Pulse Gas-Detonation Device

Combustion and thermal decomposition of hydrocarbon fuels are used to produce different forms of carbon. Combustion in the detonation mode is of particular interest, as nanocarbon obtained under these conditions differs in properties from products synthesized by other techniques. A pulsed gas-detonation device designed on the basis of a CCDS2000 detonation spraying facility opens up new possibilities for manufacturing of nanocarbon. The device operates in a flow mode of gas supply into the reactor at the atmospheric pressure, which ensures high productivity and industrial safety of this method. Using detonation of acetylene-oxygen mixtures rich in acetylene, nanoscale carbon was obtained with particle morphology depending on the ratio of the components in the gaseous mixture.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Optical Properties of Laboratory & Ambient Biomass Burning Aerosols: Elucidating Black, Brown, & Organic Carbon Components & Mixing Regimes

Biomass burning (BB) is an important global source of aerosol and trace gases that degrade air quality, decrease visibility, and impact climate and human health. Refractory black carbon (rBC), brown carbon (BrC), and organic aerosol (OA) are major components of BB emissions. BB aerosol composition is highly variable at the source and depends on fuel composition and combustion phase. Atmospheric aging alters fresh BB aerosol through processes that are complex and dynamic. To better understand the variability in optical properties, we report fresh aerosol laboratory measurements from burning southwestern U.S. fuels and compare them to aged ambient BB aerosol from wildfires over a range of atmospheric timescales. Our BB aerosol analysis uses the relationship between the absorption Ångström exponent (AAE) and single scattering albedo (SSA) to identify rBC, BrC, and OA–dominated regimes that are defined using Mie theory. This model framework is used to interpret the large variability in optical properties measured in laboratory burns. In contrast, we find the observed AAE–SSA relationship for ambient BB aerosol to be less variable and more clustered together with increased atmospheric aging. This transition from fresh to aged behavior is attributed to the homogenization of the BB aerosol from mixing and aging over several hours. As a result, BB aerosol in ambient fire plumes that have aged for several hours exhibit larger SSAs than laboratory flaming burns. We conclude that BrC/OC mixtures play a larger role than rBC in the positive climate forcing of BB aerosol than what would be projected from laboratory results.

09 BIOMASS FUELS↗