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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Cellulose Nanofibrils Dewatered with Poly(Lactic Acid) for Improved Bio-Polymer Nanocomposite Processing

Cellulose nanofibrils (CNFs) have theoretically ideal properties for bio-based composite applications; however, the incorporation of these materials into polymers is made challenging by the strong binding of water to CNFs and the irreversible agglomeration of CNFs during drying. Previous methods used “contact dewatering”, wherein the addition of wood flour (WF) to CNFs facilitated the mechanical removal of water from the system via cold pressing, which showed potential in producing dried CNF fibrils attached to wood fibers for biocomposite applications. In this work, the viability of contact dewatering with poly(lactic) acid (PLA) powder for PLA/CNF composites was evaluated. The energy efficiency of dewatering, preservation of nanoscale CNF morphology, and mechanical properties were examined by mixing wet CNFs with pulverized PLA at various loading levels, pressing water out of the system, and compression molding and shear mixing composites for testing. The most impressive results from this dewatering method were the preservation of micron-to-nanoscale fibers with high aspect ratios in PLA-CNF composites; increased strength and modulus of 1.7% and 4.2%, respectively, compared to neat PLA; equivalent or better properties than spray-dried nanocellulose at similar loading levels; and an 11-194x reduction in drying energy compared to spray-drying CNFs.

Chemistry↗

HOW AGN JETS HEAT THE INTRACLUSTER MEDIUM—INSIGHTS FROM HYDRODYNAMIC SIMULATIONS

Feedback from active galactic nuclei (AGNs) is believed to prevent catastrophic cooling in galaxy clusters. However, how the feedback energy is transformed into heat, and how the AGN jets heat the intracluster medium (ICM) isotropically, still remain elusive. In this work, we gain insights into the relative importance of different heating mechanisms using three-dimensional hydrodynamic simulations including cold gas accretion and momentum-driven jet feedback, which are the most successful models to date in terms of reproducing the properties of cool cores. We find that there is net heating within two “jet cones” (within ∼30° from the axis of jet precession) where the ICM gains entropy by shock heating and mixing with the hot thermal gas within bubbles. Outside the jet cones, the ambient gas is heated by weak shocks, but not enough to overcome radiative cooling, therefore, forming a “reduced” cooling flow. Consequently, the cluster core is in a process of “gentle circulation” over billions of years. Within the jet cones, there is significant adiabatic cooling as the gas is uplifted by buoyantly rising bubbles; outside the cones, energy is supplied by the inflow of already-heated gas from the jet cones as well as adiabatic compression as the gas moves toward the center. In other words, the fluid dynamics self-adjusts such that it compensates and transports the heat provided by the AGN, and hence no fine-tuning of the heating profile of any process is necessary. Throughout the cluster evolution, turbulent energy is only at the percent level compared to gas thermal energy, and thus turbulent heating is not the main source of heating in our simulation.

79 ASTRONOMY AND ASTROPHYSICS↗

Union through UNITY: Cosmology with 2000 SNe Using a Unified Bayesian Framework

Type Ia supernovae (SNe Ia) were instrumental in establishing the acceleration of the Universe’s expansion. By virtue of their combination of distance reach, precision, and prevalence, they continue to provide key cosmological constraints, complementing other cosmological probes. Individual SN surveys cover only over about a factor of 2 in redshift, so compilations of multiple SN data sets are strongly beneficial. We assemble an up-to-date “Union” compilation of 2087 cosmologically useful SNe Ia from 24 data sets (“Union3”). We take care to put all SNe on the same distance scale and update the light-curve fitting with SALT3 to use the full rest-frame optical. Over the next few years, the number of cosmologically useful SNe Ia will increase by more than a factor of 10, and keeping systematic uncertainties subdominant will be more challenging than ever. We discuss the importance of treating outliers, selection effects, light-curve shape/color populations/standardization relations, unexplained dispersion, and heterogeneous observations simultaneously. We present an updated Bayesian framework, called UNITY1.5 (Unified Nonlinear Inference for Type-Ia cosmologY), that incorporates significant improvements in our ability to model selection effects, standardization, and systematic uncertainties compared to earlier analyses. As an analysis byproduct, we also recover the posterior of the SN-only peculiar-velocity field, although we do not interpret it in this work. We compute updated cosmological constraints with Union3 and UNITY1.5, finding weak 1.7σ–2.6σ tension with flat cold dark matter and possible evidence for thawing dark energy (w0 > − 1, wa < 0). We release our SN distances, light-curve fits, and UNITY1.5 framework to the community.

Rubin, David↗

Liquid-fuel valve with precise throttling control

Prototype liquid-fuel valve performs on-off and throttling functions in vacuum without component cold-welding or excessive leakage. Valve design enables simple and rapid disassembly and parts replacement and operates with short working stroke, providing maximum throttling sensitivity commensurate with good control.

Mcdougal, A. R.↗

Diurnal and Seasonal Cold Lands Signatures in SSM/I-scale Microwave Radiometry of the North Slope of Alaska

In this paper, we explore scaling and data assimilation-related issues associated with utilizing passive microwave satellite observations of Cold Lands-in this case, the climatologically and ecologically sensitive arctic tundra. Our approach expands on our earlier work using a one-year dataset from the Radiobrightness Energy Balance Experiment-3 (REBEX-3). REBEX-3 featured a tower-based SSM/I (Special Sensor Microwave/Imager) simulator deployed on the North Slope of Alaska in 1994-95. Two findings are significant here. First, a comparison of tower and satellite signatures at 19 and 37 GHz strongly suggested that the North Slope is radiometrically homogeneous for spatial scales up to SSM/I footprints (approximately 25 km), an unusual and valuable characteristic for monitoring and retrieving land surface conditions. And second, at the plot scale, signatures of snow/no-snow and freeze/thaw transitions were identifiable for tussock tundra land cover, so that even snow-free frozen tundra could be unambiguously distinguished from tundra covered with dry snow, another unusual and valuable characteristic. We present results from analyzing satellite brightness signatures of selected North Slope pixels corresponding to instrumented sites along a transect from the Brooks Range to the Arctic Ocean. A custom EASE (Equal Area Scalable Earth)-Grid processor was used to extract SSMJI data for every orbit with observations of this region during the 1994-95 year. The resulting high temporal-resolution (4-8 points/day), gridded data were then analyzed for evidence of the same diurnal and seasonal signatures seen at the plot scale (through micrometeorological and/or brightness data). Differences between satellite and tower brightness observations are quantified for various conditions at the REBEX-3 site. Such differences from the less-frequent and/or larger-scale satellite observations represent a form of input 'noise' in data assimilation applications. For the other sites, the performance of snow/no-snow and freeze/thaw discriminators vs. ground truth represents an opportunity to gauge the homogeneity of other pixels.

Kim, Edward J.↗

Development of Oxidation Resistant Coatings on GRCop-84 Substrates by Cold Spray Process

GRCop-84, a Cu-CR-Nb alloy, has been developed for rocket engine liner applications. For maximum life additional oxidation protection is required to prevent blanching. NiCrAlY was identified as a suitable coating, and efforts were initiated to develop suitable coating techniques. Cold spray is one technique under consideration. Efforts at ASB Industries to produce dense, adherent coatings are detailed. The work culminated in the production of samples for testing at NASA Glenn Research Center.

Karthikeyan, J.↗

Photoionization in Ultraviolet Processing of Astrophysical Ice Analogs at Cryogenic Temperatures

Two recent experimental studies have demonstrated that amino acids or amino acid precursors are generated when astrophysical ice analogs are subjected to ultraviolet (UV) irradiation at cryogenic temperatures. Understanding the complete phenomenology of photoprocessing is critical to elucidating chemical reaction mechanisms that can function within an ice matrix under very cold conditions. Pushing beyond the much better characterized study of photolytic dissociation of chemical bonds through electronic excitation, this work explored the ability of UV radiation present in the interstellar medium to ionize small molecules embedded in ices. Quantum chemical calculations, including bulk solvation effects, were used to study the ionization of hydrogen (H2), water, and methanol (CH3OH) bound in small clusters of water. Ionization potentials were found to be much smaller in the condensed phase than in the gas phase; even a small cluster can account for large changes in the ionization potentials in ice, as well as the known formation of an OH--H3O+ pair in the case of H2O photoionization. To gauge the impact of photoionization on subsequent grain chemistry, the reaction between OH and CO in the presence of H3O+ was studied and compared with the potential energy surface without hydronium present, which is relevant to chemistry following photolysis. The differences indicate that the reaction is somewhat more likely to proceed to products (H + CO2) in the case of photoionization.

Woon, David E.↗

Deep Space Observations of Sun Glints from Marine Ice Clouds

The Earth Polychromatic Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) spacecraft takes images of the sunlit face of Earth from a million miles away. Earlier work showed that EPIC detected the specular reflection of sunlight (that is, sun glint) from ice crystals floating in cold clouds over land; here we show that this phenomenon can also be detected over oceans. Furthermore, the results show that - using its observations at Oxygen A-band absorption bands - EPIC can distinguish glints off marine ice clouds from those off the ocean surface. The analysis of more than two years of EPIC data reveals that the two kinds of glints are detected with comparable frequency. Glints off clouds are shown to be generally brighter but smaller in spatial extent. It is also demonstrated that glints off ice clouds have a discernible effect on the regional mean reflectance and that EPIC observations can help constrain the radiative contribution of oriented ice crystals.

Atmosphere↗

2 mm GISMO Observations of the Galactic Center. I. Dust Emission

The central molecular zone, covering the inner 1° of the Galactic plane has been mapped at 2mm using the Goddard-IRAM Superconducting 2-Millimeter Observer (GISMO) bolometric camera on the 30 m IRAM telescope. The 21 resolution maps show abundant emission from cold molecular clouds, from star-forming regions, and from one of the Galactic center nonthermal filaments. In this work we use the Herschel Hi-GAL data to model the dust emission across the Galactic center. We find that a single-temperature fit can describe the 160-500 um emission for most lines of sight, if the long-wavelength dust emissivity scales as with 2.25. This dust model is extrapolated to predict the 2 mm dust emission. Subtraction of the model from the GISMO data provides a clearer look at the 2 mm emission of star-forming regions and the brightest nonthermal filament.

Arendt, Richard G.↗

DOE Zero Energy Ready Home Case Study: Amaris Custom Homes, St.Paul, Minnesota; DOE Zero Energy Ready Home Case Study, Energy Efficiency & Renewable Energy (EERE)

For this project Amaris worked with U.S. Department of Energy (DOE) team, NorthernSTAR Building America Partnership, to approach zero energy in Minnesota's cold climate using reasonable, cost-effective, and replicable construction materials and practices. The result is a passive solar, super-efficient 3542-ft2 walkout rambler with all the creature comforts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Evaluation of Common Thermoplastic Polymers in High-Pressure Cycling Hydrogen Under Ambient and Cold Environments as Applicable to the Hydrogen Infrastructure

Thermoplastic polymers are required to perform unfailingly under stringent conditions of changing pressures (35 MPa to 70 MPa) and temperatures (-40°C to +85°C) in storage and fueling operations. Although diffusivity in glassy polymers appear to be an order of magnitude lower than elastomers, polymer microstructural attributes such as degree of crystallinity and presence of polar and non-polar groups on the main chain with and without branching can play a substantial role in influencing their behaviors in hydrogen environments. In the work described here, the effect of high-pressure hydrogen cycling on PEEK, PTFE, PA11, HDPE, POM (and different commercial grades of these polymers) under ambient and cold (-40°C) conditions is addressed. Ex-situ characterization for polymer changes included density measurements for impact of hydrogen retention, hardness changes using nanoindentation, storage modulus and glass transition changes using dynamic mechanical and thermal analysis (DMTA), degree of crystallization with Differential Scanning Calorimetry (DSC) and tensile testing following ASTM D412. In other evaluations, solid-state nuclear magnetic resonance (NMR), attenuated total reflectance Fourier transform infra-red spectroscopy (ATRFTIR), X-ray diffraction (XRD), and X-ray CT results are presented. The overall impact of these evaluations is to establish a technical basis for the behaviors of common thermoplastics in cycling hydrogen environments under ambient and cold temperatures while establishing the relationship between polymer structure-based properties and hydrogen transport effects.

Menon, Nalini C.↗

Jovian Plasma Torus Interaction with Europa: 3D Hybrid Kinetic Simulation. First results

The hybrid kinetic model supports comprehensive simulation of the interaction between different spatial and energetic elements of the Europa-moon-magnetosphere system with respect to variable upstream magnetic field and flux or density distributions of plasma and energetic ions, electrons, and neutral atoms. This capability is critical for improving the interpretation of the existing Europa flyby measurements from the Galileo orbiter mission, and for planning flyby and orbital measurements, (including the surface and atmospheric compositions) for future missions. The simulations are based on recent models of the atmosphere of Europa (Cassidy etal.,2007;Shematovichetal.,2005). In contrast to previous approaches with MHD simulations, the hybrid model allows us to fully take into account the finite gyro radius effect and electron pressure, and to correctly estimate the ion velocity distribution and the fluxes along the magnetic field (assuming an initial Maxwellian velocity distribution for upstream background ions).Non-thermal distributions of upstream plasma will be addressed in future work. Photoionization,electron-impact ionization, charge exchange and collisions between the ions and neutrals are also included in our model. We consider two models for background plasma:(a) with O(++) ions; (b) with O(++) and S(++) ions. The majority of O2 atmosphere is thermal with an extended cold population (Cassidyetal.,2007). A few first simulations already include an induced magnetic dipole; however, several important effects of induced magnetic fields arising from oceanic shell conductivity will be addressed in later work.

Lipatov, A. S.↗

High-heat transfer lithium-ion batteries: A new era in battery thermal management

Despite advances in lithium-ion battery technology, critical challenges remain that must be addressed to accelerate electric vehicle (EV) adoption and global energy transformation. Significantly improved battery thermal management (BTM) is key to overcoming these challenges. BTM approaches focus on increasing heat transfer coefficients via air, liquid, or refrigerant cooling, but less attention is given to reducing the battery's thermal resistance, a major bottleneck for heat transfer. This work introduces a novel approach to reduce battery thermal resistance by integrating in-plane heat transfer with optimized cell geometry, minimized thermal resistances, and reduced interfacial resistances, representing a departure from previous methods. The standard prismatic can cell incorporating this technology is referred to as the high heat transfer (HHT) battery. An equivalent resistance battery thermal model is developed for speed and accuracy, validated against experimental data in the literature, demonstrating strong correlation and ensuring reliable predictions for real-world performance. Thermal performance metrics of the conventional and HHT batteries are compared using a parametric study with air, liquid, and refrigerant boundary conditions across a range of aspect ratios. The HHT battery shows a heat removal rate up to 20 times higher than a conventional battery. These findings suggest that HHT technology could be transformative for EV battery performance, enabling fast charging, mitigating thermal runaway, extending battery life, reducing cold-weather power loss, increasing reliability, lowering costs, and enabling higher energy density, all critical for EV adoption and energy transformation. Future work will focus on prototyping and real-world testing to refine these findings for commercial-scale applications.

25 ENERGY STORAGE↗

Cooling Design and Thermal Analysis for Thermal Shields of a Cryocooler-Cooled Superconducting ECR Ion Source MARS-D Magnet

Here, a demonstrative NbTi based Mixed Axial and Radial field System (MARS-D) is being developed for a next-Generation Electron Cyclotron Resonance Ion Source (ECRIS) at Lawrence Berkeley National Laboratory (LBL), which employs a novel closed-loop coil design scheme that more efficiently utilizes conductor fields and extend the application of NbTi for high frequency (up to 45 GHz) ECR operation. The NbTi MARS-D magnet consists of a single hexagonally shaped closed-loop coil and a set of auxiliary solenoids. A cryostat for cooling the MARS-D magnet is under design at LBL. The MARS-D magnet working around 4.2 K will be bath-cooled in liquid helium using multiple two-stage cryocoolers. An intermediate temperature thermal radiation shield is adopted to reduce the heat leakage imposed on 4.2 K coil cold mass from room temperature. The thermal shield is conduction-cooled by the first-stage cold heads of four two-stage cryocoolers and the cold head of a single-stage cryocooler shared with nine binary leads. The temperature in the area of the shield that warm ends of HTS leads are mounted on is expected no higher than 60 K, which is limited by maximum allowable working temperature of HTS leads. The paper presents thermal analysis on the thermal radiation shield including heat loads and effects of eddy current induced during quench on its material selection.

ECRIS↗

New Whole-House Solutions Case Study: Affordable Cold Climate Infill Housing with Hybrid Insulation Approach, Wyandotte, Michigan

Even builders who are relatively new to energy-efficient construction can consistently reach a target whole house airtightness of 1.5 air changes per hour at 50 Pascals (ACH50) with high R-value enclosures that use a hybrid insulation approach. In 2010, the City of Wyandotte, Michigan, started construction to build affordable, energy-efficient homes on lots in existing neighborhoods. A goal was to engage local builders in energy-efficient construction and be able to deliver the new houses for less than $100/ft2. By the end of 2012, approximately 25 new houses were built by five local builders under this program. To help builders consistently achieve the airtightness target, a local architect worked with researchers from Building Science Corporation, a Building America team, to develop a technology specification with several key pieces. A high R-value wall and roof assembly made use of 2 ×6 advanced framing and a hybrid insulation approach that included insulating sheathing to control thermal bridging and closed cell spray polyurethane foam insulation (ccSPF) for its airtightness and vapor control benefits. This approach allows the air barrier to be completed and tested before any finishing work occurs, ensuring that problems are spotted and corrected early in the construction process.

BSC↗

Design guidelines for avoiding thermo-acoustic oscillations in helium piping systems

Thermo-acoustic oscillations are a commonly observed phenomenon in helium cryogenic systems, especially in tubes connecting hot and cold areas. The open ends of these tubes are connected to the lower temperature (typically at 4.2 K), and the closed ends of these tubes are connected to the high temperature (300K). Cryogenic instrumentation installations provide ideal conditions for these oscillations to occur due to the steep temperature gradient along the tubing. These oscillations create errors in measurements as well as an undesirable heat load to the system. The work presented here develops engineering guidelines to design oscillation-free helium piping. This work also studies the effect of different piping inserts and shows how the proper geometrical combinations have to be chosen to avoid thermo-oscillations. The effect of an 80 K intercept is also studied and shows that thermo-oscillations can be dampened by placing the intercept at an appropriate location.

43 PARTICLE ACCELERATORS↗

Formation of 1 H -Phenalene (C 13 H 10 ) in the Taurus Molecular Cloud via Methylidyne Addition-Cyclization-Aromatization (MACA)

The formation of 1H-phenalene (C 13 H 10 ) in cold molecular clouds, such as the Taurus Molecular Cloud-1 (TMC-1), presents a significant challenge to traditional astrochemical models, which predominantly suggest high-temperature pathways for polycyclic aromatic hydrocarbon (PAH) formation. In this study, we explore computationally the Methylidyne Addition-Cyclization-Aromatization (MACA) mechanism as a viable, barrierless pathway for phenalene synthesis under low-temperature conditions. Through electronic structure calculations and Rice–Ramsperger–Kassel–Marcus (RRKM) statistical methods, we demonstrate that the reaction of 1-vinylnaphthalene (C 10 H 7 C 2 H 3 ) with the methylidyne radical (CH) leads to the formation of 1H-phenalene via a bimolecular reaction, a process that is exoergic and without entrance barrier. The MACA mechanism facilitates the growth of the aromatic carbon backbone via a [5 + 1] ring annulation, providing a new insight into PAH formation in cold molecular clouds. Notably, the MACA mechanism has previously been shown to form indene (C9H8), which was detected in TMC-1 as well, via a [4 + 1] annulation, demonstrating its potential to produce a variety of complex PAHs by addition of a five- and six-membered ring to a benzene moiety via [4 + 1] and [5 + 1] annulation, respectively. As a result, this work highlights the importance of barrierless, exoergic reactions involving MACA in the synthesis of complex aromatic molecules in space, expanding our physicochemical understanding of carbon-rich chemistry in cold molecular clouds.

Aromatic compounds↗

Progress toward positron-electron pair plasma experiments

Electron-positron plasmas have been of theoretical interest for decades, due to the unique plasma physics that arises from all charged particles having precisely identical mass. It is only recently, though, that developments in non-neutral plasma physics (both in linear and toroidal geometries) and in the flux of sources for cold positrons have brought the goal of conducting electron-positron pair plasma experiments within reach. The APEX/PAX collaboration is working on a number of projects in parallel toward that goal; this paper provides an overview of recent, current, and upcoming activities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗