SEARCH · Search NASA

Results for “MULTIPLE PRODUCTION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 721 records · Page 40

All sources NASA NTRS DOE OSTI

DOE OSTI2026

Impact of DMP-30 catalyst concentration on the degradation and kinetics of bisphenol A epoxy thermosets cured with linear amine hardener

Epoxy thermosets are a crucial component in carbon-fiber composites, serving as the organic binding matrix. Catalysts are commonly used in prepolymer formulations to accelerate curing of the thermosets. However, the impact of catalysts on the thermal stability, degradation pathways, and kinetics of the final thermoset is poorly understood. Here, in this work, Product-Specific Kinetics (PSK) analysis was utilized with isoconversional kinetics to provide a first look into the degradation kinetics of major pyrolysis pathways in bisphenol A (BPA) epoxy resins and determine the impact of altering catalysis concentrations on these kinetic pathways. Results revealed new insights into previously identified degradation pathways, provided evidence of multiple degradation pathways for some products, and showed that use of excess catalyst results in polymer network alterations and reduced thermal stability of the thermosets.

Bisphenol A↗

DOE OSTI2013

GROUND-BASED INFRARED DETECTIONS OF CO IN THE CENTAUR-COMET 29P/SCHWASSMANN-WACHMANN 1 AT 6.26 AU FROM THE SUN

We observed Comet 29P/Schwassmann-Wachmann 1 (hereafter, 29P) in 2012 February and May with CRIRES/VLT and NIRSPEC/Keck-II, when the comet was at 6.26 AU from the Sun and about 5.50 AU from Earth. With CRIRES, we detected five CO emission lines on several nights in each epoch, confirming the ubiquitous content and release of carbon monoxide from the nucleus. This is the first simultaneous detection of multiple lines from any (neutral) gaseous species in comet 29P at infrared wavelengths. It is also the first extraction of a rotational temperature based on the intensities of simultaneously measured spectral lines in 29P, and the retrieved rotational temperature is the lowest obtained in our infrared survey to date. We present the retrieved production rates ({approx}3 Multiplication-Sign 10{sup 28} molecules s{sup -1}) and remarkably low ({approx}5 K) rotational temperatures for CO, and compare them with results from previous observations at radio wavelengths. Along with CO, we pursued detections of other volatiles, namely H{sub 2}O, C{sub 2}H{sub 6}, C{sub 2}H{sub 2}, CH{sub 4}, HCN, NH{sub 3}, and CH{sub 3}OH. Although they were not detected, we present sensitive upper limits. These results establish a new record for detections by infrared spectroscopy of parent volatiles in comets at large heliocentric distances. Until now considered to be a somewhat impossible task with IR ground-based facilities, these discoveries demonstrate new opportunities for targeting volatile species in distant comets.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRSDate not supplied

Why Near Real-time/Low Latency is Important to Monitor the Changing World

An essential factor for remote sensing data products in impacting decision making is latency, or the time between earth observation and data are available to users. In many applications areas, latency plays an important or even decisive role where low latency earth observations help people to make timely, data-based decisions. Within the open and free NASA resources, NASA’s Land, Atmosphere Near real-time Capability for Earth Observing System (EOS) (LANCE) supports users interested in monitoring a wide variety of natural and man-made phenomena using near real-time (NRT) data products that are made available much quicker than routine processing allows. The combination of all available LANCE satellite products provides global coverage at multiple times per day, which makes it possible to meet user needs in various areas of applications including water resources, agriculture, air quality, wildland fire and many other disasters monitoring and management. As one of the prime users of LANCE, NASA’s Earth Science Applied Sciences Program promotes the use of LANCE data products to demonstrate applications in decision making and facilitates the end-user feedback to the science team to improve data products. One of the most critical applications that we expect data to be processed as close to the user as possible is wildland file response and management. User feedback indicates that LANCE NRT fire data products within 3 hours latency would meet the needs of the wildland fire community. Other examples of earth science application areas for which low latency is particularly important include detecting volcanic eruptions, early warning of disasters, tracking extreme weather events, and monitoring air quality.

Tian Yao↗

DOE OSTI2012

A New Structural Form in the SAM/Metal-Dependent O;#8209;Methyltransferase Family: MycE from the Mycinamicin Biosynthetic Pathway

O-linked methylation of sugar substituents is a common modification in the biosynthesis of many natural products and is catalyzed by multiple families of S-adenosyl-l-methionine (SAM or AdoMet)-dependent methyltransferases (MTs). Mycinamicins, potent antibiotics from Micromonospora griseorubida, can be methylated at two positions on a 6-deoxyallose substituent. The first methylation is catalyzed by MycE, a SAM- and metal-dependent MT. Crystal structures were determined for MycE bound to the product S-adenosyl-l-homocysteine (AdoHcy) and magnesium, both with and without the natural substrate mycinamicin VI. This represents the first structure of a natural product sugar MT in complex with its natural substrate. MycE is a tetramer of a two-domain polypeptide, comprising a C-terminal catalytic MT domain and an N-terminal auxiliary domain, which is important for quaternary assembly and for substrate binding. The symmetric MycE tetramer has a novel MT organization in which each of the four active sites is formed at the junction of three monomers within the tetramer. The active-site structure supports a mechanism in which a conserved histidine acts as a general base, and the metal ion helps to position the methyl acceptor and to stabilize a hydroxylate intermediate. A conserved tyrosine is suggested to support activity through interactions with the transferred methyl group from the SAM methyl donor. The structure of the free enzyme reveals a dramatic order-disorder transition in the active site relative to the S-adenosyl-L-homocysteine complexes, suggesting a mechanism for product/substrate exchange through concerted movement of five loops and the polypeptide C-terminus.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2018

Extending Moore's Law via Computationally Error Tolerant Computing.

Dennard scaling has ended. Lowering the voltage supply (V dd ) to sub-volt levels causes intermittent losses in signal integrity, rendering further scaling (down) no longer acceptable as a means to lower the power required by a processor core. However, it is possible to correct the occasional errors caused due to lower V dd in an efficient manner and effectively lower power. By deploying the right amount and kind of redundancy, we can strike a balance between overhead incurred in achieving reliability and energy savings realized by permitting lower V dd . One promising approach is the Redundant Residue Number System (RRNS) representation. Unlike other error correcting codes, RRNS has the important property of being closed under addition, subtraction and multiplication, thus enabling computational error correction at a fraction of an overhead compared to conventional approaches. We use the RRNS scheme to design a Computationally-Redundant, Energy-Efficient core, including the microarchitecture, Instruction Set Architecture (ISA) and RRNS centered algorithms. Finally, from the simulation results, this RRNS system can reduce the energy-delay-product by about 3× for multiplication intensive workloads and by about 2× in general, when compared to a non-error-correcting binary core.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2013

MAIN-BELT COMET P/2012 T1 (PANSTARRS)

We present initial results from observations and numerical analyses aimed at characterizing the main-belt comet P/2012 T1 (PANSTARRS). Optical monitoring observations were made between 2012 October and 2013 February using the University of Hawaii 2.2 m telescope, the Keck I telescope, the Baade and Clay Magellan telescopes, Faulkes Telescope South, the Perkins Telescope at Lowell Observatory, and the Southern Astrophysical Research Telescope. The object's intrinsic brightness approximately doubles from the time of its discovery in early October until mid-November and then decreases by {approx}60% between late December and early February, similar to photometric behavior exhibited by several other main-belt comets and unlike that exhibited by disrupted asteroid (596) Scheila. We also used Keck to conduct spectroscopic searches for CN emission as well as absorption at 0.7 {mu}m that could indicate the presence of hydrated minerals, finding an upper limit CN production rate of Q{sub CN} < 1.5 Multiplication-Sign 10{sup 23} mol s{sup -1}, from which we infer a water production rate of Q{sub H{sub 2O}}<5 Multiplication-Sign 10{sup 25} mol s{sup -1}, and no evidence of the presence of hydrated minerals. Numerical simulations indicate that P/2012 T1 is largely dynamically stable for >100 Myr and is unlikely to be a recently implanted interloper from the outer solar system, while a search for potential asteroid family associations reveals that it is dynamically linked to the {approx}155 Myr old Lixiaohua asteroid family.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2020

Status, Challenges, and Plans for Consistent Modeling and Evaluation of Fission Data: Nubar, PFNS, and FPY [Slides]

This presentation discusses the importance of consistent evaluations for fission observables. Currently, prompt fission quantities (e.g., neutron multiplicity, neutron energy spectrum, and fission product yields) are evaluated independently of one another, either with separate models or data-only/non-model evaluations (few – if any – shared model inputs) and inconsistencies can arise in evaluated data (e.g. NSE 190, 258 (2018)). They have found that consistent, model-based evaluations lead to more physical constraints on free parameters in the model, more robust predictions for other observables and other isotopes, that there are correlations between the uncertainties on different observables, and that uncertainties can be propagated to unmeasured quantities. They are working on developing models to the point where fission observables are calculated at the quality needed for an evaluation. They are striving to consistently calculate fission observables, such as $\bar{v}$, PFNS, and FPY, to a quality suitable for an evaluation. Current evaluations for fission observables use separate models for each observable (with minimal shared input) or are purely data driven. LANL models, such as the Monte Carlo CGMF and deterministic BeoH, have different strengths; the similar fission fragment initial conditions and decay models leads to consistency between the two codes (FPY can be connected to $\bar{v}$ and PFNS, even when calculated by different codes). Work is underway by Lovell to optimize the models and Neudecker is working to perform detailed uncertainty quantification. The PFNS, in particular, presents a significant challenge.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA NTRSDate not supplied

BioNutrients: Microbial on-demand production of short shelf-life micronutrients in space

Long duration deep space missions pose a significant challenge when considering adequate nutrition for human spaceflight. Many micronutrients supplied in pre-packaged foods for low Earth orbit flights have a short shelf life and will degrade over multi-year missions. One strategy to mitigate the risk of micronutrient malnutrition is to grow fresh foods to supplement a pre-packaged diet. The BioNutrients project aims to develop systems for growing edible microorganisms that are genetically engineered to produce short shelf life micronutrients. BioNutrients-1 (BN-1) is a five-year spaceflight project currently underway on the International Space Station (ISS) that tests long-term storage and production of two carotenoids, β-carotene and zeaxanthin, in genetically engineered yeast strains. BN-1 on-orbit and ground control activities indicate that the nutrient production system will be stable for at least two years in ambient storage conditions. BN-1 is also testing the effects of long-term ISS storage on viability and gene expression using “stasis packs” containing a series of microorganisms useful in food and biomanufacturing processes. Stasis pack analysis is distinguishing microorganisms with full viability after two years of storage from other species that lose viability rapidly. In parallel, BioNutrients-2 (BN-2) is being developed as a six-month flight experiment that will expand the range of foods produced on ISS to include yogurt, kefir, and probiotic yeast. BN-2 will improve upon hardware design by transitioning from a hard-shell polycarbonate bioreactor to a flexible fluorinated ethylene propylene (FEP) bag. This change reduces the mass and volume required to store production packs. The long-term goal of BioNutrients is to develop the capability for rapid and safe delivery of multiple micronutrients in single-use production packs. We expect synthetic biology approaches similar to BioNutrients will play an important role for astronaut health in future NASA missions to the Moon and Mars.

Synthetic Biology↗

NASA NTRS2014

Integration of RGB "Dust" Imagery to Operations at the Albuquerque Forecast Office

The NASA/Short‐term Prediction, Research, and Transition (SPoRT) Program has been providing unique Red‐Green‐Blue (RGB) composite imagery to its operational partners since 2005. In the early years of activity these RGB products were related to a True Color RGB, showing what one's own eyes would see if looking down at earth from space, as well as a Snow‐Cloud RGB (i.e. False Color), separating clouds from snow on the ground. More recently SPoRT has used the EUMETSAT Best Practices standards for RGB composites to transition a wide array of imagery for multiple uses. A "Dust" RGB product has had particular use at the Albuquerque, New Mexico WFO. Several cases have occurred where users were able to isolate dust plume locations for mesoscale and microscale events during day and night time conditions. In addition the "Dust" RGB can be used for more than just detection of dust as it is sensitive to the changes in density due to atmospheric moisture content. Hence low‐level dry boundaries can often be discriminated. This type of imagery is a large change from the single channel imagery typically used by operational forecast staff and hence, can be a challenge to interpret. This presentation aims to discuss the integration of such new imagery into operational use as well as the benefits assessed by the Albuquerque WFO over several documented events.

Fuell, Kevin↗

NASA NTRS2014

Integration of RGB "Dust" Imagery to Operations at the Albuqueque Forecast Office

Fuell, Kevin↗

DOE OSTI2022

Variation on a theme: the structures and biosynthesis of specialized fatty acid natural products in plants

SUMMARY Plants are able to construct lineage‐specific natural products from a wide array of their core metabolic pathways. Considerable progress has been made toward documenting and understanding, for example, phenylpropanoid natural products derived from phosphoenolpyruvate via the shikimate pathway, terpenoid compounds built using isopentyl pyrophosphate, and alkaloids generated by the extensive modification of amino acids. By comparison, natural products derived from fatty acids have received little attention, except for unusual fatty acids in seed oils and jasmonate‐like oxylipins. However, scattered but numerous reports show that plants are able to generate many structurally diverse compounds from fatty acids, including some with highly elaborate and unique structural features that have novel bioproduct functionalities. Furthermore, although recent work has shed light on multiple new fatty acid natural product biosynthesis pathways and products in diverse plant species, these discoveries have not been reviewed. The aims of this work, therefore, are to (i) review and systematize our current knowledge of the structures and biosynthesis of fatty acid‐derived natural products that are not seed oils or jasmonate‐type oxylipins, specifically, polyacetylenic, very‐long‐chain, and aromatic fatty acid‐derived natural products, and (ii) suggest priorities for future investigative steps that will bring our knowledge of fatty acid‐derived natural products closer to the levels of knowledge that we have attained for other phytochemical classes.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2011

Kshort and Λ production in p p interactions at s = 0.9 and 7 TeV measured with the ATLAS detector at the LHC

CERN-LHC. Measurements of the production cross sections for KS and LAMBDA hadrons in proton-proton collisions at centre-of-mass energies of 7 TeV and 0.9 TeV using data samples with total integrated luminosities of 190 mub-1 and 7 mub-1 respectively. The data, corrected to the |pseudorapidity| < 2.5 and PT > 100 MeV phase space regions, are presented as transverse momentum, rapidity and multiplicity distributions as well as production ratios between LAMBDABAR and LAMBDA baryons.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2012

Degradation of CYANEX 301 in Contact with Nitric Acid Media

The nature of the degradation product obtained upon contacting CYANEX 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid) with nitric acid has been elucidated and found to be a disulfide derivative. The first step to the degradation of CYANEX 301 in toluene has been studied using 31P{1H} NMR after being contacted with nitric acid media. The spectrum of the degradation product exhibits a complex multiplet around dP = 80 ppm. A succession of purifications of CYANEX 301 has resulted in single crystals of the acidic form and the corresponding ammonium salt. Unlike the original CYANEX 301, which consists of a complex diastereomeric mixture displaying all possible combinations of chiral orientations at the 2-methyl positions, the purified crystals were shown by single-crystal X-ray diffraction to be racemates, containing 50:50 mixtures of the [R;R] and [S;S] diastereomers. The comparison between the 31P {1H} NMR spectra of the degradation products resulting from the diastereomerically pure CYANEX 301 and the original diastereomeric mixture has elucidated the influence of the isomeric composition on the multiplicity of the 31P {1H} NMR peak. These NMR data indicate the initial degradation leads to a disulfide-bridged condensation product displaying multiple resonances due to phosphorus–phosphorus coupling, which is caused by the inequivalence of the two P atoms as a result of their different chirality. A total of nine different NMR resonances, six of which display phosphorus–phosphorus coupling, could be assigned, and the identity of the peaks corresponding to phosphorus atoms coupled to each other was confirmed by 31P {1H} homodecoupled NMR analysis.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2019

Small system studies: A theory overview

There is now a substantial body of evidence that a deconfined quark-gluon plasma is created in ultrarelativistic collisions of heavy nuclei. Some key observables which are used to gauge the production of the quark-gluon plasma are the hadronic spectra and multiplicities across many species, azimuthal anisotropies in the production of various hadrons, jet quenching, photon/dilepton production, and heavy quarkonium suppression. A key question in the study of the quark-gluon plasma is what happens to these observables as one changes the system size. In particular, it is very interesting to study collisions of “small systems” such as pp, dA, pA, and e + e - since naively one does not expect to produce a QGP in these cases. One of the surprises from such studies was the existence of sizable azimuthal anisotropies in the hadron spectra in the highest multiplicity classes, which led to speculations that one can generate a QGP in such relatively rare events. This interpretation, however, is complicated by the fact that there can be multiple sources of azimuthal anisotropy. I will discuss our current understanding of the different sources of azimuthal anisotropies and the multiplicity windows in which each mechanism is expected to dominate. I will also provide a critical discussion of the reliability of hydrodynamic models applied to small systems. Finally, I will briefly discuss jet quenching and heavy quarkonium suppression in small systems and discuss whether or not these observables show any indication of the production of a small QGP droplet.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2012

THE SOURCES OF HCN AND CH{sub 3}OH AND THE ROTATIONAL TEMPERATURE IN COMET 103P/HARTLEY 2 FROM TIME-RESOLVED MILLIMETER SPECTROSCOPY

One of the least understood properties of comets is the compositional structure of their nuclei, which can either be homogeneous or heterogeneous. The nucleus structure can be conveniently studied at millimeter wavelengths, using velocity-resolved spectral time series of the emission lines, obtained simultaneously for multiple molecules as the body rotates. Using this technique, we investigated the sources of CH{sub 3}OH and HCN in comet 103P/Hartley 2, the target of NASA's EPOXI mission, which had an exceptionally favorable apparition in late 2010. Our monitoring with the IRAM 30 m telescope shows short-term variability of the spectral lines caused by nucleus rotation. The varying production rates generate changes in brightness by a factor of four for HCN and by a factor of two for CH{sub 3}OH, and they are remarkably well correlated in time. With the addition of the velocity information from the line profiles, we identify the main sources of outgassing: two jets, oppositely directed in a radial sense, and icy grains, injected into the coma primarily through one of the jets. The mixing ratio of CH{sub 3}OH and HCN is dramatically different in the two jets, which evidently shows large-scale chemical heterogeneity of the nucleus. We propose a network of identities linking the two jets with morphological features reported elsewhere and postulate that the chemical heterogeneity may result from thermal evolution. The model-dependent average production rates are 3.5 Multiplication-Sign 10{sup 26} molecules s{sup -1} for CH{sub 3}OH and 1.25 Multiplication-Sign 10{sup 25} molecules s{sup -1} for HCN, and their ratio of 28 is rather high but not abnormal. The rotational temperature from CH{sub 3}OH varied strongly, presumably due to nucleus rotation, with the average value being 47 K.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRSDate not supplied

Interannual to Decadal Variability in Subarctic Atlantic Ocean Primary Productivity Historical Variability, Dynamics, and Response to Warming

Phytoplankton primary productivity in the Subarctic Atlantic Ocean sustains valuable fisheries and exports anthropogenic atmospheric carbon dioxide, but multiple Earth system models show that this productivity declines substantially in 21st century global warming scenarios. Prior studies have investigated the spatial and temporal dynamics of the seasonal cycle of the phytoplankton, which exhibit a prominent but spatially variable spring bloom that is caused by the closely related seasonal cycles in solar radiation and vertical mixing that modulate both phytoplankton growth and loss rates. However, recent work indicates that multi-decade declines in this spring bloom with global warming in multiple Earth system models are driven by reductions in circulation of nutrients from the subtropical and tropical thermocline, rather than local changes in vertical mixing or shortwave radiation in the Subarctic. It is unclear if current models of how phytoplankton productivity varies seasonally or over a century in global warming can be interpolated to explain the interannual to decadal variability. In this poster, I will quantify the interannual to decadal variability of phytoplankton chlorophyll using historical satellite ocean color observations and model simulations with the Community Earth System Model. I will then use the observations and model simulations to elucidate the mechanisms of interannual to decadal variability and how that variability is restructured in 21st century global warming scenarios.

nterannual↗

DOE OSTI2021

Reliability-Informed Economic and Energy Evaluation for Design for Remanufacturing: A Case Study on a Hydraulic Manifold

Design for Remanufacturing (DfRem) is an attractive approach for sustainable product development. Evaluation of DfRem strategies, from both economic and environmental perspectives, at an early design stage can allow the designers to make informed decisions when choosing the best design option. Studying the long-term implications of a particular design scenario requires quantifying the benefits of remanufacturing for multiple life cycles while considering the reliability of the product. In addition to comparing designs on a one-to-one basis, we find that including reliability provides a different insight into comparing design strategies. We present a reliability-informed cost and energy analysis framework that accounts for product reliability for multiple remanufacturing cycles within a certain warranty policy. The variation of reuse rate over successive remanufacturing cycles is formulated using a branched power-law model which provides probabilistic scenarios of reusing or replacing with new units. To demonstrate the utility of this framework, we use the case study of a hydraulic manifold, which is a component of a transmission used in some agricultural equipment, and use real-world field reliability data to quantify the transmission’s reliability. Three design improvement changes are proposed for the manifold and we quantify the costs and energy consumption associated with each of the design changes for multiple remanufacturing cycles.

design for remanufacturing↗

DOE OSTI2022

Energy Dependent Fission Product Yields

Since 2011, the LLNL-LANL-TUNL collaboration has undertaken experimental measurements of the energy evolution of the chain fission product yields (FPY) from neutron-induced fission of 235 U, 238 U, and 239 Pu using quasi-monoenergetic neutrons produced at the TUNL 10 MV Van de Graaff accelerator. Our method relies on direct, post-irradiation γ-ray spectroscopy of γ-rays emitted by fission products in actinide targets, with multiple γ-ray spectra taken continuously for a period from a half-hour to three months from the end of irradiation. The main experimental results of this study have been published for eight incident neutron energies of En = 0.58, 1.37, 2.37, 3.6, 4.6, 5.5, 8.9 and 14.8 MeV [1–4]. For each incident energy, approximately 16 cumulative FPYs were determined, nearly all being high-yield fission products, i.e., those occurring in the peaks of the mass distributions. As will be described in this report, our FPY analysis has been significantly improved in every step of the process, reducing the overall systematic uncertainties compared to previously published data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗