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NASA NTRS2017

Coloring Jupiter's Clouds: Radiolysis of Ammonium Hydrosulfide (NH4SH)

Here we present our recent studies on the color and spectral reflectance changes induced by approximately 0.9 megaelectronvolts proton irradiation of ammonium hydrosulfide, NH4SH, a compound predicted to be an important tropospheric cloud component of Jupiter and other giant planets. Ultraviolet-visible spectroscopy was used to observe and identify reaction products in the ice sample and digital photography was used to document the corresponding color changes at 10-160 degrees Kelvin. Our experiments clearly show that the resulting color of the sample depends not only on the irradiation dose but also the irradiation temperature. Furthermore, unlike in our most recent studies of irradiation of NH4SH at 120 degrees Kelvin, which showed that higher irradiation doses caused the sample to appear green, the lower temperature studies now show that the sample becomes red after irradiation. However, comparison of these lower temperature spectra over the entire spectral range observed by HST (Hubble Space Telescope) shows that even though the color and spectrum resemble the color and spectrum of the GRS (Jupiter’s Great Red Spot), there is still enough difference to suggest that another component may be needed to adequately fit spectra of the GRS and other red regions of Jupiter's clouds. Regardless, the presence of NH4SH in the atmosphere of Jupiter and other gas giants, combined with this compound's clear alteration via radiolysis, suggests that its contribution to the ultraviolet-visible spectra of any of these object's clouds is significant.

ultraviolet-visible spectroscopy↗

DOE OSTI2026

Deep Spectroscopy with DESI for Photometric Redshift Training and Calibration

Deep spectroscopic samples can improve photometric redshift (photo-z) estimates and reduce uncertainties on redshift distributions. Such improvements can increase the cosmological constraining power of large imaging-based experiments such as the Vera C. Rubin Observatory’s Legacy Survey of Space and Time (LSST) and mitigate what may be a limiting systematic effect. We present results from the “DESI-Deep pilot” program, which was designed to assess the capability of the Dark Energy Spectroscopic Instrument (DESI) on the 4m Mayall telescope to measure redshifts of galaxies as faint as expected lensing samples for early LSST data (m i ≤ 24.5). We find that DESI is remarkably efficient at this task, with redshift success rates comparable to the results of observations from 10 m class telescopes with only ∼2 × longer integration time (rather than ∼8 × longer as would be expected from aperture-area scaling), while simultaneously achieving ∼30 times larger multiplexing. We also find that the signal-to-noise ratio of the spectra scales as expected for background-limited observations even for the longest exposure times (∼7 hr) and faintest targets in the program. These results demonstrate that DESI could provide the definitive redshift sample for the early years of LSST with a modest investment of observing time. Based upon the results of this program, we provide updated predictions for the time required to collect benchmark samples for photo-z training and calibration using a variety of spectroscopic facilities. Finally, we describe a potential “DESI-Deep” survey designed to train and calibrate photo-z’s for imaging experiments, and provide forecasts of its impact on cosmological inference.

Dey, Biprateep [University of Toronto; University ↗

DOE OSTI2025

Three rate-determining protein roles in photosynthetic O 2 -evolution addressed by time-resolved experiments on genetically modified photosystems

Light-driven water splitting by plants, algae and cyanobacteria is pivotal for global bioenergetics and biomass formation. A manganese cluster bound to the photosystem II proteins catalyzes the complex reaction at high rate, but the rate-determining factors are insufficiently understood. Here we trace the oxygen-evolution transition by time-resolved polarography and infrared spectroscopy for cyanobacterial photosystems genetically modified at two strategic sites, complemented by computational chemistry. Our results highlight three rate-determining roles of the protein environment of the metal cluster: acceleration of proton-coupled electron transfer, acceleration of substrate-water insertion after O 2 -formation, and balancing of rate-determining enthalpic and entropic contributions. Whereas in general the substrate-water insertion step may be unresolvable in time-resolved experiments, here it likely becomes traceable because of deceleration by genetic modification. Our results may stimulate new time-resolved experiments on substrate-water insertion in photosynthesis, clarification of enthalpy-entropy compensation in enzyme catalysis, and knowledge-guided development of inorganic catalyst materials.

Bioenergetics↗

NASA NTRS1992

Atmospheric and spectroscopic research in the far infrared

The University of Oregon (UO) has been a major participant in the development of far infrared spectroscopic research of the stratosphere for the purpose of understanding the ozone layer processes. The UO has had a 15-year collaboration with the Italian group of B. Carli, and have participated in the 1978/79 Sub-millimeter Infrared Balloon Experiment (SIBEX), in the Balloon Intercomparison Campaign, (BIC), in the Infrared Balloon Experiment (IBEX), and in the recently concluded Far Infrared Experiment for UARS Correlative Measurements (FIREX). Both IBEX and FIREX programs were conducted in collaboration with NASA Langley, and were designed as validation flights in support of the Upper Atmosphere Research Satellite (UARS) Program. The technique of atmospheric far infrared spectroscopy offers two important advantages. First, many chemically important species can be measured simultaneously and co-spatially in the atmosphere. Second, far infrared atmospheric spectra can be obtained in thermal emission without reference to the sun's position, enabling full diurnal and global coverage. Recent improvements in instrumentation, field measurements, and molecular concentration retrieval techniques are now making the far infrared a mature measurement technology. This work to date has largely focused on balloon-based studies, but the future efforts will focus also on satellite-based experiments. A program of research in the following general areas was proposed: Laboratory Pressure broadening coefficient studies; specialized detector system assembly and testing; and consultation and assistance with instrument and field support. The proposal was approved and a three-year research grant titled 'Atmospheric and Spectroscopic Research in the Far Infrared' was awarded. A summary of technical accomplishments attained during the grant period are presented.

Park, Kwangjai↗

NASA NTRS2000

The Effect of Low Earth Orbit Atomic Oxygen Exposure on Phenylphosphine Oxide-Containing Polymers

Thin films of phenylphosphine oxide-containing polymers were exposed to low Earth orbit aboard a space shuttle flight (STS-85) as part of flight experiment designated Evaluation of Space Environment and Effects on Materials (ESEM). This flight experiment was a cooperative effort between the NASA Langley Research Center (LaRC) and the National Space Development Agency of Japan (NASDA). The thin film samples described herein were part of an atomic oxygen exposure experiment (AOE) and were exposed to primarily atomic oxygen (~1 X 1019 atoms/cm2). The thin film samples consisted of three phosphine oxide containing polymers (arylene ether, benzimidazole and imide). Based on post-flight analyses using atomic force microscopy, X-ray photoelectron spectroscopy, and weight loss data, it was found that atomic oxygen exposure of these materials efficiently produces a phosphate layer at the surface of the samples. This layer provides a barrier towards further attack by AO. Consequently, these materials do not exhibit linear erosion rates which is in contrast with most organic polymers. Qualitatively, the results obtained from these analyses compare favorably with those obtained from samples exposed to atomic oxygen and or oxygen plasma in ground based exposure experiments. The results of the low Earth orbit atomic oxygen exposure on these materials will be compared with those of ground based exposure to AO.

Connell, John W.↗

NASA NTRS2003

Mars Exploration Rovers as Virtual Instruments for Determination of Terrain Roughness and Physical Properties

The two 2003 Mars Exploration Rovers (MERs), in combination with the Athena Payload, will be used as virtual instrument systems to infer terrain properties during traverses, in addition to using the rover wheels to excavate trenches, exposing subsurface materials for remote and in-situ observations. The MERs are being modeled using finite element-based rover system transfer functions that utilize the distribution of masses associated with the vehicle, together with suspension and wheel dynamics, to infer surface roughness and mechanical properties from traverse time series data containing vehicle yaw, pitch, roll, encoder counts, and motor currents. These analyses will be supplemented with imaging and other Athena Payload measurements. The approach is being validated using Sojourner data, the FIDO rover, and experiments with MER testbed vehicles. In addition to conducting traverse science and associated analyses, trenches will be excavated by the MERs to depths of approximately 10-20 cm by locking all but one of the front wheels and rotating that wheel backwards so that the excavated material is piled up on the side of the trench away from the vehicle. Soil cohesion and angle of internal friction will be determined from the trench telemetry data. Emission spectroscopy and in-situ observations will be made using the Athena payload before and after imaging. Trenching and observational protocols have been developed using Sojourner results; data from the FIDO rover, including trenches dug into sand, mud cracks, and weakly indurated bedrock; and experiments with MER testbed rovers. Particular attention will be focused on Mini-TES measurements designed to determine the abundance and state of subsurface water (e.g. hydrated, in zeolites, residual pore ice?) predicted to be present from Odyssey GRS/NS/HEND data.

R E Arvidson↗

DOE OSTI2024

Ionic Pairs-Engineered Fluorinated Covalent Organic Frameworks Toward Direct Air Capture of CO 2

The covalent organic frameworks (COFs) possessing high crystallinity and capability to capture low-concentration CO 2 (400 ppm) from air are still underdeveloped. The challenge lies in simultaneously incorporating high-density active sites for CO 2 insertion and maintaining the ordered structure. Herein, a structure engineering approach is developed to afford an ionic pair-functionalized crystalline and stable fluorinated COF (F-COF) skeleton. The ordered structure of the F-COF is well maintained after the integration of abundant basic fluorinated alcoholate anions, as revealed by synchrotron X-ray scattering experiments. The breakthrough test demonstrates its attractive performance in capturing (400 ppm) CO 2 from gas mixtures via O$-$C bond formation, as indicated by the in situ spectroscopy and operando nuclear magnetic resonance spectroscopy using 13 C-labeled CO 2 sources. Both theoretical and experimental thermodynamic studies reveal the reaction enthalpy of ≈-40 kJ mol -1 between CO 2 and the COF scaffolds. This implies weaker interaction strength compared with state-of-the-art amine-derived sorbents, thus allowing complete CO 2 release with less energy input. The structure evolution study from synchrotron X-ray scattering and small-angle neutron scattering confirms the well-maintained crystalline patterns after CO 2 insertion. In conclusion, the as-developed proof-of-concept approach provides guidance on anchoring binding sites for direct air capture (DAC) of CO 2 in crystalline scaffolds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

One Beam, Dual Insights: Simultaneous Chemical and Structural Changes in Nanopatterned Ceria under Reaction Conditions

Ceria’s interaction with hydrogen can proceed through multiple chemical forms (hydride, hydroxyl, and oxyhydroxide-like), with consequences for the oxidation state, density, and morphology that are rarely tracked in the same evolving state. Here, in this work, we show that under mild H 2 (and H 2 and CO 2 ) environments nanopatterned ceria undergoes oxidation-state changes accompanied by hydrogen incorporation that increases the effective electron density, establishing the following order: CeO 2 Hy > CeO 2 > CeO 2–x Hy > CeO 2–x . In parallel, the surface roughens in a chemically specific manner, with the largest changes coinciding with conditions where incorporated hydrogen is driven to react with oxygen supplied either by air exposure between experiments or by added CO 2 . We obtained these insights by using a single X-ray beam to simultaneously perform ambient-pressure X-ray photoelectron spectroscopy and grazing-incidence X-ray scattering on the same sample spot. Single-mode measurements can miss key ceria–H 2 transformations relevant to optimizing ceria-based hydrogenation catalysts and supports.

anions↗

DOE OSTI2026

Modulating Mid-Gap Electronic States Through Site-Selective Modification in B-Pbx/B'-CuyV2O5/CdS Heterostructures for Photocatalytic Hydrogen Evolution

We interfaced ..beta..-Pbx/..beta..'-CuyV2O5 compounds, with varying stoichiometries of precisely positioned Pb-ions (x) and Cu-ions (y) in interstitial sites along a tunnel-structured ?-V2O5 framework, with cysteine-capped CdS (cysCdS) quantum dots (QDs) to yield heterostructured photocatalysts. ..beta..-Pbx/..beta..'-CuyV2O5 compounds exhibit midgap electronic states with orbital contributions from both Cu 3d and stereochemically active Pb 6s states that show distinctive light-initiated reactivity with photoexcited QDs. ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures were prepared by linker-assisted assembly (LAA). Scanning and transmission electron microscopy, energy-dispersive X-ray spectroscopy, and Raman spectroscopy revealed that cysCdS QDs were deposited onto surfaces of ..beta..-Pbx/..beta..'-CuyV2O5 via LAA. HAXPES revealed that the site-selective positioning of Pb-ions and Cu-ions promoted close energetic alignment of the midgap states of ..beta..-Pbx/..beta..'-CuyV2O5 compounds with the valence-band maximum of cysCdS QDs. Transient absorption spectroscopy revealed that photogenerated holes were transferred from CdS QDs to midgap states of ..beta..-Pbx/..beta..'-CuyV2O5 compounds on time scales <50 ps. Finally, photoelectrochemical and photochemical experiments revealed that ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures promoted the photocatalytic reduction of H+ to H2. In photoelectrochemical experiments, under oxidative conditions, for all ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures, H2 was evolved at a Pt counter electrode while a sacrificial donor was oxidized at the heterostructure-functionalized working electrode. In contrast, under reductive conditions, for ..beta..-Pb0.152V2O5/CdS and ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures, H2 was evolved at the working electrode. In photochemical experiments, dispersed ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures promoted the reduction of H+ to H2 under white-light illumination; ..beta..'-Cu0.55V2O5/CdS and ..beta..-Pbx/..beta..'-CuyV2O5/CdS heterostructures, for which midgap states have Cu 3d orbital character, generated 2-fold more H2 than ..beta..-Pb0.152V2O5/CdS heterostructures. Cu-ion insertion thus appends additional acceptor surface states that improve ligand-mediated hole transfer from photoexcited QDs, but such states are intrinsically limited in mediating hole transport to the substrate as a result of the low mobility of holes in narrow Cu 3d-states. Our results reveal that the density and orbital character of midgap states of ..beta..-Pbx/..beta..'-CuyV2O5 compounds, tunable through recently developed site-selective ion insertion strategies, determine efficiencies of charge-transfer and charge-transport mechanisms that underpin photocatalysis.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Larmor power limit for cyclotron radiation of relativistic particles in a waveguide

Cyclotron radiation emission spectroscopy (CRES) is a modern technique for high-precision energy spectroscopy, in which the energy of a charged particle in a magnetic field is measured via the frequency of the emitted cyclotron radiation. The He6-CRES collaboration aims to use CRES to probe beyond the standard model physics at the TeV scale by performing high-resolution and low-background beta-decay spectroscopy of 6 He and 19 Ne. Having demonstrated the first observation of individual, high-energy (0.1–2.5 MeV) positrons and electrons via their cyclotron radiation, the experiment provides a novel window into the radiation of relativistic charged particles in a waveguide via the time-derivative (slope) of the cyclotron radiation frequency, df c /dt. We show that analytic predictions for the total cyclotron radiation power emitted by a charged particle in circular and rectangular waveguides are approximately consistent with the Larmor formula, each scaling with the Lorentz factor of the underlying e ± as γ 4 . This hypothesis is corroborated with experimental CRES slope data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2024

The hypernuclear physics program at Jefferson Lab

Missing mass spectroscopy of Λ hypernuclei using the (e, e' K⁺) re action has been performed in the past at the Thomas Jefferson National Accelerator Facility (Jefferson Lab) by several experiments in Halls A and C. A new experimen tal campaign is expected to start running in 2026 in Hall C and to provide the first study of the isospin dependence in medium-mass hyperisotopes by populating $^{40}_Λ{K}$ and $^{48}_Λ{K}$ using isotopically enriched calcium targets [E12-15-008]. During this cam paign, it will be possible to study Λ interactions in nuclear matter using a lead target [E12-20-013]. Solid-state targets made of lithium, beryllium, boron [LOI12-23-013], and aluminum [LOI12-23-016] are considered to be included in the campaign. The use of the HKS and HES spectrometers together with thin target foils and high beam currents leads to a sub-MeV energy resolution, significantly better than in hadron beam experiments. Valuable information on few-body hyperon systems would be gained if helium targets were used [E12-19-002]. Using an additional spectrometer for measuring the decay-pion spectra could give access to the binding energies of light hyperfragments [LOI12-23-011]. The measurement of precise and accurate en ergy spectra of different hyperisotopes probes the Λ-N interaction in nuclei including the Λ-N-N interaction. The latter is assumed to play a key role for the stiffness of the nuclear equation of state relevant for the stability of neutron stars.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2024

Data for: Competitive and Cooperative Effects of Chloride on Palladium(II) Adsorption to Iron (Oxyhydr)oxides: Implications for Mobility During Weathering

Data package for manuscript "Competitive and Cooperative Effects of Chloride on Palladium(II) Adsorption to Iron (Oxyhydr)oxides: Implications for Mobility During Weathering" by Emily G. Wright, Xicheng He, Elaine D. Flynn, Daniel E. Giammar, and Jeffrey G. Catalano. The manuscript will be submitted to Geochimica et Cosmochimica Acta. This dataset contains adsorption results from experiments designed to investigate the effect of chloride on Pd(II) adsorption to hematite and 2-line ferrihydrite. This includes lab experiments reacting suspensions of the minerals with various amounts of Pd and chloride at pH 4. We also characterized adsorbed Pd with X-ray absorption fine structure spectroscopy.

58 GEOSCIENCES↗

DOE OSTI2024

Synthesis of Zeolites LiX and LiAgX

In this work, we produced approximately 50 grams of zeolite LiX and 50 grams of zeolite LiAgX from commercially available zeolite X. The production of the two specialized zeolite phases was accomplished via a series of ion exchange steps followed by washing, drying, and calcining to produce the final materials. The ion exchange was confirmed by several methods including inductively-coupled plasma emission spectroscopy of exchange solution aliquots, gravimetric analysis, energy dispersive x-ray spectroscopy, and X-ray diffraction. We synthesized approximately 115 grams of zeolite LiX in a large-scale production step after completing a proof-of-concept experiment demonstrating the methodology. The production of zeolite LiX from zeolite X yielded an ion exchange (Li + →Na + ) of approximately 82%. The production of zeolite LiAgX from the previously synthesized zeolite LiX was targeted to exchange approximately 20% of the Li + ions with Ag + ions. We first performed a proof-of-concept experiment demonstrating the reaction pathway and selectivity of the Ag + ion, and then performed a large-scale synthesis of zeolite LiAgX using approximately 50 grams of the zeolite LiX. Our final exchange percentage of silver into the zeolite LiX matrix was approximately 20.8%.

36 MATERIALS SCIENCE↗

NASA NTRS1977

Ultraviolet spectroscopy of the zodiacal light at 20-deg elongation

The zodiacal light at 20-deg elongation and 10-deg inclination was observed by rocket ultraviolet spectrometers at 10-15-A resolution in the spectral range 1200-3200 A during an experiment designed to observe comet Kohoutek (1973 XII). The data were obtained above 180 km when scattered horizon light in the startracker caused a loss of tracking on the comet. Airglow emission due to NO and O(+), identified spectroscopically and by its variation with altitude, is significant between 1900 and 2500 A. Longward of 2600 A, the spectrum matches that of the sun, and the derived value of the color ratio, relative to the visible, is 0.90 + or - 0.20. At 1600 A, an upper limit on the zodiacal-light emission of 0.07 R per A or 7 hundred-millionths erg/s per sq cm/sterad per A is obtained.

Feldman, P. D.↗

NASA NTRS1995

SIMS chemical and isotopic analysis of impact features from LDEF experiments AO187-1 and AO187-2

Previous secondary ion mass spectrometry (SIMS) studies of extended impact features from LDEF capture cell experiment AO187-2 showed that it is possible to distinguish natural and man-made particle impacts based on the chemical composition of projectile residues. The same measurement technique has now been applied to specially prepared gold target impacts from experiment AO187-1 in order to identify the origins of projectiles that left deposits too thin to be analyzed by conventional energy-dispersive x-ray (EDX) spectroscopy. The results indicate that SIMS may be the method of choice for the analysis of impact deposits on a variety of sample surfaces. SIMS was also used to determine the isotopic compositions of impact residues from several natural projectiles. Within the precision of the measurements all analyzed residues show isotopically normal compositions.

Stadermann, Frank J.↗

NASA NTRS1994

The use of multispectral thermal infrared image data to estimate the sulfur dioxide flux from volcanoes: A case study from Mount Etna, Sicily, July 29, 1986

We have found that image data acquired with NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) can be used to make estimates of the SO2 content of volcanic plumes. TIMS image data are most applicable to the study of partially transparent SO2 plumes, such as those released during quiescent periods or nonexplosive eruptions. The estimation procedure is based on the LOWTRAN 7 radiative transfer code, which we use to model the radiance perceived by TIMS as it views the ground through an SO2 plume. The input to the procedure includes the altitudes of the aircraft and ground, the altitude and thickness of the SO2 plume, the emissivity of the ground, and altitude profiles of the atmospheric pressure, temperature, and relative humidity. We use the TIMS data to estimate both ground temperatures beneath a plume and SO2 concentrations within a plume. Applying our procedure to TIMS data acquired over Mount Etna, Sicily, on July 29, 1986, we estimate that the SO2 flux from the volcano was approximately 6700 t d(exp -1). The use of TIMS to study SO2 plumes represents a bridge between highly localized methods, such as correlation spectroscopy or direct sampling, and small-scale mapping techniques involving satellite instruments such as the Total Ozone Mapping Spectrometer or Microwave Limb Sounder. We require further airborne experiments to refine our estimation procedure. This refinement is a necessary preparation for the schedueled 1998 launch of the Advanced Spaceborne Thermal Emission and Reflectance Radiometer, which will allow large-scale multispectral thermal infrared image data to be collected over virtually any volcano on Earth at least once every 16 days.

Realmuto, Vincent J.↗

NASA NTRS2002

Investigation of N2O Production from 266 and 532 nm Laser Flash Photolysis of O3/N2/O2 Mixtures

Tunable diode laser absorption spectroscopy has been employed to measure the amount of N2O produced from laser flash photolysis of O3/N2/O2 mixtures at 266 and 532 nm. In the 532 nm photolysis experiments very little N2O is observed, thus allowing an upper limit yield of 7 x 10(exp -8) to be established for the process O3 + N2 yield N2O + O2, where O3 is nascent O3 that is newly formed via O(3P(sub J)) + O2 recombination (with vibrational excitation near the dissociation energy of O3). The measured upper limit yield is a factor of approx. 600 smaller than a previous literature value and is approximately a factor of 10 below the threshold for atmospheric importance. In the 266 nm photolysis experiments, significant N2O production is observed and the N2O quantum yield is found to increase linearly with pressure over the range 100 - 900 Torr in air bath gas. The source of N2O in the 266 nm photolysis experiments is believed to be the addition reaction O(1D(sub 2)) + N2 + M yields (k(sub sigma)) N2O + M, although reaction of (very short-lived) electronically excited O3 with N2 cannot be ruled out by the available data. Assuming that all observed N2O comes from the O(1D(sub 2)) + N2 + M reaction, the following expression describes the temperature dependence of k(sub sigma) (in its third-order low-pressure limit) that is consistent with the N2O yield data: k(sub sigma) = (2.8 +/- 0.1) x 10(exp -36)(T/300)(sup -(0-88+0.36)) cm(sup 6) molecule(sup -2)/s, where the uncertainties are 2(sigma) and represent precision only. The accuracy of the reported rate coefficients at the 95% confidence level is estimated to be 30 - 40% depending on the temperature. Model calculations suggest that gas phase processes initiated by ozone absorption of a UV photon represent about 1.4% of the currently estimated global source strength of atmospheric N2O. However, these processes could account for a significant fraction of the oxygen mass-independent enrichment observed in atmospheric N2O, and they appear to be the first suggested photochemical mechanism that is capable of explaining the altitude dependence of the observed mass -independent isotopic signature.

Estupinan, E. G.↗

NASA NTRS2003

Coherent Anti-Stokes Raman Scattering (CARS) as a Probe for Supersonic Hydrogen-Fuel/Air Mixing

The dual-pump coherent anti-Stokes Raman spectroscopy (CARS) method was used to measure temperature and the absolute mole fractions of N2, O2 and H2 in a supersonic non-reacting fuel-air mixing experiment. Experiments were conducted in NASA Langley Research Center s Direct Connect Supersonic Combustion Test Facility. Under normal operation of this facility, hydrogen and air burn to increase the enthalpy of the test gas and O2 is added to simulate air. This gas is expanded through a Mach 2 nozzle and into a combustor model where fuel is then injected, mixes and burns. In the present experiment the O2 of the test gas is replaced by N2. The lack of oxidizer inhibited combustion of the injected H2 fuel jet allowing the fuel/air mixing process to be studied. CARS measurements were performed 427 mm downstream of the nozzle exit and 260 mm downstream of the fuel injector. Maps were obtained of the mean temperature, as well as the N2, O2 and H2 mean mole fraction fields. A map of mean H2O vapor mole fraction was also inferred from these measurements. Correlations between different measured parameters and their fluctuations are presented. The CARS measurements are compared with a preliminary computational prediction of the flow.

Danehy, P. M.↗