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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Reversible Iron Oxyfluoride (FeOF)–Graphene Composites as Sustainable Cathodes for High Energy Density Lithium Batteries

Two large barriers are impeding the wide implementation of electric vehicles, namely driving-range and cost, primarily due to the low specific energy and high cost of mono-valence cathodes used in lithium-ion batteries. Iron is the ideal element for cathode materials considering its abundance, low cost and toxicity. However, the poor reversibility of (de)lithiation and low electronic conductivity prevent iron-based high specific energy multi-valence conversion cathodes from practical applications. In this work, a sustainable FeOF nanocomposite is developed with extraordinary performance. The specific capacity and energy reach 621 mAh g –1 and 1124 Wh kg –1 with more than 100 cycles, which triples the specific capacity, and doubles the specific energy of current mono-valence intercalation LiCoO 2 . This is the result of an effective approach, combing the nanostructured FeOF with graphene, realized by making the (de)lithiation reversible by immobilizing FeOF nanoparticles and the discharge products over the graphene surface and providing the interparticle electric conduction. Importantly, it demonstrates that introducing small amount of graphene can create new materials with desired properties, opening a new avenue for altering the (de)lithiation process. Finally, such extraordinary performance represents a significant breakthrough in developing sustainable conversion materials, eventually overcoming the driving range and cost barriers.

25 ENERGY STORAGE↗

Metal Monolithic Amine-grafted Zeolite for CO2 Captu re

The solid amine sorbent for CO 2 capture process has advantages of simplicity and low operating cost compared to the MEA (monoethanolamine) process. Solid amine sorbents reported so far suffered from either low CO 2 capture capacity or low stability. The solid amine sorbent developed in this project exhibited more than 3.2 mmol/g and degraded less than 10% even after 500 cycles of heating and cooling in absence of steam. The presence of steam further enhanced CO 2 capture capacity. The cost of the sorbent is estimated to be less than $\$$7.00/lb. This sorbent was developed using the results of in situ infrared spectroscopic study. Infrared results showed that CO 2 adsorbs on TEPA (tetraethylenepentamine)/PEG (polyethylene glycol) as carbamates and bicarbonates. The CO 2 adsorption capacity and oxidation resistance of the amine sorbent can be enhanced by the interactions between NH 2 of TEPA molecules with the OH group of PEG molecules. PEG was also found to be effectively disperse and immobilize the aromatic amines for SO 2 adsorption. The infrared study also showed that SiO 2 is a significantly better support than zeolites due to its proper hydrophobicity. The results of this study led to the development of a high performance solid amine sorbent under simulated gas flow condition in a fixed bed, a fluidized bed, and a metal monolith unit. This study showed heat transfer could become a major technical issue in scaling up a fixed bed adsorber. The use of the fluidized bed and metal monoliths can alleviate the heat transfer issue. The metal monolith could be suitable for small scale applications due to the high cost of manufacturing; the fluidized bed mode would be most suitable for large scale applications. Preliminary economic analysis suggested that the Akron solid amine process would cost 45% less than that of MEA process.

20 FOSSIL-FUELED POWER PLANTS↗

Review of advanced radiator technologies for spacecraft power systems and space thermal control

A two-part overview of progress in space radiator technologies is presented. The first part reviews and compares the innovative heat-rejection system concepts proposed during the past decade, some of which have been developed to the breadboard demonstration stage. Included are space-constructable radiators with heat pipes, variable-surface-area radiators, rotating solid radiators, moving-belt radiators, rotating film radiators, liquid droplet radiators, Curie point radiators, and rotating bubble-membrane radiators. The second part summarizes a multielement project including focused hardware development under the Civil Space Technology Initiative (CSTI) High Capacity Power program carried out by the NASA Lewis Research Center and its contractors to develop lightweight space radiators in support of Space Exploration Initiative (SEI) power systems technology.

Juhasz, Albert J.↗

Gyrokinetic Particle Simulation of Turbulent Transport in Burning Plasmas (GPS - TTBP) Final Report

The goal of this project is the development of the Gyrokinetic Toroidal Code (GTC) Framework and its applications to problems related to the physics of turbulence and turbulent transport in tokamaks,. The project involves physics studies, code development, noise effect mitigation, supporting computer science efforts, diagnostics and advanced visualizations, verification and validation. Its main scientific themes are mesoscale dynamics and non-locality effects on transport, the physics of secondary structures such as zonal flows, and strongly coherent wave-particle interaction phenomena at magnetic precession resonances. Special emphasis is placed on the implications of these themes for rho-star and current scalings and for the turbulent transport of momentum. GTC-TTBP also explores applications to electron thermal transport, particle transport; ITB formation and cross-cuts such as edge-core coupling, interaction of energetic particles with turbulence and neoclassical tearing mode trigger dynamics. Code development focuses on major initiatives in the development of full-f formulations and the capacity to simulate flux-driven transport. In addition to the full-f -formulation, the project includes the development of numerical collision models and methods for coarse graining in phase space. Verification is pursued by linear stability study comparisons with the FULL and HD7 codes and by benchmarking with the GKV, GYSELA and other gyrokinetic simulation codes. Validation of gyrokinetic models of ion and electron thermal transport is pursed by systematic stressing comparisons with fluctuation and transport data from the DIII-D and NSTX tokamaks. The physics and code development research programs are supported by complementary efforts in computer sciences, high performance computing, and data management.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Development of a Low-Pressure Helium Compression Control System Strategy

Cryogenics is now widely used in large accelerator projects using applied superconductivity. Economic considerations require an increase in the performance of superconducting devices. One way to achieve this is by lowering their operating temperature and cooling with superfluid helium. For this reason, large cryogenic systems operating at 1.8 K and capable of producing refrigeration capacity in the kW range have to be developed and implemented. These cryogenic systems require a large pumping capacity at very low pressure using integral cold compression or mixed cold-warm compression. This paper describes the different cooling methods using cold and hybrid cycles, describes the cycle operational capabilities, and reviews the low-pressure helium compression control strategy for these cycles developed at Fermi National Accelerator Laboratory.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Programmatic status of NASA's CSTI high capacity power Stirling space power converter program

An overview is presented of the NASA Lewis Research Center Free-Piston Stirling Space Power Converter Technology Development Program. This work is being conducted under NASA's Civil Space Technology Initiative (CSTI). The goal of the CSTI High Capacity Power element is to develop the technology base needed to meet the long duration, high capacity power requirements for future NASA space initiatives. Efforts are focused upon increasing system thermal and electric energy conversion efficiency at least fivefold over current SP-100 technology, and on achieving systems that are compatible with space nuclear reactors. The status of test activities with the Space Power Research Engine (SPRE) is discussed. Design deficiencies are gradually being corrected and the power converter is now outputting 11.5 kWe at a temperature ratio of 2 (design output is 12.5 kWe). Detail designs were completed for the 1050 K Component Test Power Converter (CTPC). The success of these and future designs is dependent upon supporting research and technology efforts including heat pipes, gas bearings, superalloy joining technologies and high efficiency alternators. An update of progress in these technologies is provided.

Dudenhoefer, James E.↗

Mars Technology Program (MTP) Communications and Tracking Technologies for Mars Exploration

The MTP Communications and Tracking Technology Development Program aims to develop critical enabling technology components and products that will make the future high capacity communications links from Mars possible. It comprises ten technology development tasks. This paper briefly describes each task and gives a summary of the current state of the research and future recommendations.

X-band↗

Capacity and cutoff rate calculations for a concatenated coding system

A model is developed for a concatenated coding system, and from it the overall channel cutoff rate and capacity is found using random coding arguments. The effects of interleaving between the inner and outer codes and of the availability of side information to the outer decoder are considered. The performance of several specific concatenated coding systems is calculated and used for comparison with the random coding results. From the analysis, a number of general conclusions regarding the design of concatenated coding systems are presented. All the results are derived assuming a block inner code.

Herro, Mark A.↗

Development of A Non-Explosive Release Device for Aerospace Applications

A simple, non-explosive, high load-capacity release mechanism using shape memory alloy is currently being developed for space flight. This device, the Frangibolt, could replace most pyrotechnic devices in applications where the need for safety, reliability, non-destructive testing, and minimal mechanical shock is more crucial than the need for rapid actuation. Prototype hardware has been designed, tested, and proven in laboratory conditions. Operation and demonstration of these devices evidenced reliable and repeatable performance, clearly indicating that extensive testing for flight qualification is warranted. Here, the Frangibolt design is discussed, recent test results of laboratory units are described, and the work that must be performed in the upcoming months to qualify the device for aerospace applications is addressed.

John D Busch↗

Efficient Removal of Fluoride Using Polypyrrole-Modified Biochar Derived from Slow Pyrolysis of Pomelo Peel: Sorption Capacity and Mechanism

In this study, a novel adsorbent was developed by loading polypyrrole (PPy) onto biochar (BC) prepared by slow pyrolysis of pomelo peel. This PPy-grafted BC mainly exhibited anion-exchange behavior, which dramatically increased fluoride adsorption capacity. The effects of various factors (adsorbent dosage, pyrrole concentration, initial solution pH, co-existing anions and temperature) on the fluoride adsorption were investigated. The adsorbent was characterized by scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and automatic titration methods. Results showed that the optimized adsorbent (BP-0.1) performed excellently at pH 2.8–10.0, and possessed positive charge at pH < 8.6. The adsorption isotherm data were fitted well by the Langmuir model and the maximum adsorption capacity was 18.52 mg/g at 25 ± 2 °C. The adsorption kinetics followed the pseudo-second-order model and adsorption equilibrium was achieved at 24 h. Although both HCO{sub 3}{sup −} and CO{sub 3}{sup 2−} had great influence on F{sup −} adsorption, there was no significant impact in the presence of Cl{sup −}, NO{sub 3}{sup −} and SO{sub 4}{sup 2−}. Real groundwater study showed that 2.5 g/L of BP-0.1 could effectively reduce F{sup −} from 10.0 to 1.4 mg/L at pH 5.0. Thermodynamic parameters confirmed the spontaneous and endothermic nature of the adsorption process. Effect of pH, XPS analysis and the change of amount between Cl{sup −} and F{sup −} in the adsorption process revealed that ion exchange and electrostatic attraction were involved in the adsorption process and ion exchange was the main adsorption mechanism.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Cardiovascular Countermeasures for Exploration-Class Space Flight Missions

Astronaut missions to Mars may be many years or even decades in thc future but current and planned efforts can be extrapolated to required treatments and prophylaxis for delerious efforts of prolonged space flight on the cardiovascular system. The literature of candidate countermeasures was considered in combination with unpublished plans for countermeasure implementation. The scope of cardiovascular countermeasures will be guided by assessments of the efficacy of mechanical, physiological and pharmacological approaches in protecting the cardiovascular capacities of interplanetary crewmembers. Plans for countermeasure development, evaluation and validation will exploit synergies among treatment modalities with the goal of maximizing protective effects while minimizing crew time and in-flight resource use. Protection of the cardiovascular capacity of interplanetary crewmembers will become more effective and efficient over the next few decades, but trade-offs between cost and effectiveness of efficiency are always possible if the increased level of risk can be accepted.

Charles, John B.↗

Carbon-free high-performance cathode for solid-state Li-O 2 battery

The development of a cathode for solid-state lithium-oxygen batteries has been hindered in practice by a low capacity and limited cycle life despite their potential for high energy density. Here, a previously unexplored strategy is proposed wherein the cathode delivers a specific capacity of 200 milliampere hour per gram over 665 discharge/charge cycles, while existing cathodes achieve only ~50 milliampere hour per gram and ~100 cycles. A highly conductive ruthenium-based composite is designed as a carbon-free cathode by first-principles calculations to avoid the degradation associated with carbonaceous materials, implying an improvement in stability during the electrochemical cycling. In addition, water vapor is added into the main oxygen gas as an additive to change the discharge product from growth-restricted lithium peroxide to easily grown lithium hydroxide, resulting in a notable increase in capacity. Thus, the proposed strategy is effective for developing reversible solid-state lithium-oxygen batteries with high energy density.

36 MATERIALS SCIENCE↗

A Technical and Economic Assessment of LWR Flexible Operation for Generation and Demand Balancing to Optimize Plant Revenue

With increased penetration of subsidized variable renewable energy (VRE) resources and competition from low natural gas prices, existing light water reactor (LWR) nuclear power plants (NPPs) are struggling to remain economically competitive. This work examines the potential economic competitiveness of various thermal energy storage (TES) technologies when coupled directly or indirectly with a NPP. To highlight their relative economic competitiveness, we contrast several energy storage solutions in stochastic dispatch optimization. We leverage data from recent work analyzing a range of TES technologies with varying capital costs, performance, and technology readiness level (TRL) to establish our case. We explore inserting these technologies into an electricity market with existing nuclear generation and large projected variable renewable energy (VRE) penetration. Although these technologies' projected capital costs may make them unlikely candidates in their current state, this analysis demonstrates a high-fidelity techno-economic analysis of energy storage. Furthermore, as the projected cost of energy storage technologies evolves, this analysis sets a precedent for similar future investigations. One region with projected trends that may be unfavorable for existing nuclear capacity is the New York Independent System Operator (NYISO) market. New York state’s baseload generation has been historically provided by fossil-fired and nuclear assets. However, amid economic pressures from subsidized VREs and low natural gas prices, the state has recently deactivated Indian Point nuclear power plant units 2 and 3. Furthermore, the state plans to meet its zero-emission generation target by 2040 by replacing fossil-fired capacity with significant investments in VRE resources like wind and solar photovoltaic (PV) and battery storage. Increased intermittent resource penetration lowers the baseload power requirement, adding further economic pressure to the state’s three remaining NPPs still in operation. With three NPPs still in operation in New York, this work analyzes potential economic benefits to NPPs on the New York grid when directly or indirectly coupled with various TES technologies. This work requires two modeling steps to analyze the potential economic benefits of various system configurations of the TES directly or indirectly coupled with nuclear. First, this analysis leverages capacity expansion modeling by experts at the Electric Power Research Institute (EPRI). Using their deterministic capacity expansion model, U.S. Regional Economy, Greenhouse Gas, and Energy (US-REGEN), EPRI analysts evaluated the capacity and generation evolution of the New York state energy market under four projection scenarios. These four projection scenarios were developed to represent the potential evolution of the capacity and generation in NYISO from 2015 to 2050 under various economic, technology, and policy constraints. The results from these capacity expansion models are then used as boundary conditions in the second modeling step. The second modeling step uses the Holistic Energy Resource Optimization Network (HERON) for a set of stochastic techno-economic analyses (STEAs) to investigate the potential increase in the economic viability of various configurations of the TES. With no current capacity expansion capabilities, HERON takes the data generated from US-REGEN for 2050 to generate synthetic load, solar, and wind data. Then HERON economically optimizes the capacity and dispatch of the various TES configurations. The potential economic benefit is the differential net present value (NPV) of the TES configurations from the no-TES baseline. As a stochastic techno-economic analysis package, HERON introduces uncertainty into the economic metrics, while US-REGEN trades resolution for reduced computational complexity. Using HERON also allows the modeling of direct thermal coupling, a feature not common in capacity and dispatch models. As expected, with high capital costs, the costs of introducing energy storage for all the technologies considered outweighed the potential economic benefit of this strategy for flexible plant operation. The benefit of this analysis is primarily in demonstrating a workflow that examines innovative solutions to increase NPP revenue via TES coupling. HERON’s stochastic capacity and dispatch optimization process used in this work has proven an effective tool in observing and evaluating the impact of introducing storage technologies in a grid energy system.

25 ENERGY STORAGE↗

Development of TRPN dendrimer-modified disordered mesoporous silica for CO{sub 2} capture

Highlights: • A novel series of TRPN dendrimers are synthesized. • Structurally disordered mesoporous silica was used to develop the CO{sub 2} adsorbent. • The CO{sub 2} adsorption capacity is relatively high. • The sorbent exhibits a high stability after 12 cycling runs. • The sorbent achieves complete desorption at low temperature (60 °C). - Abstract: A novel series of tri(3-aminopropyl) amine (TRPN) dendrimers were synthesized and impregnated on structurally disordered mesoporous silica (DMS) to generate CO{sub 2} adsorbents (TS). The physicochemical and adsorption properties of the adsorbents before and after dendrimer modification were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and N{sub 2} adsorption–desorption (N{sub 2}-BET) techniques. CO{sub 2} adsorption–desorption tests indicated that the sorbent demonstrates high CO{sub 2} adsorption capacity (138.1 mg g{sup −1} for G1 sample TS-G1-3CN-50 and 91.7 mg g{sup −1} for G2 sample TS-G2-6CN-50), and can completely desorb CO{sub 2} under vacuum at 60 °C. Its CO{sub 2} adsorption capacity at 25 °C increases with the amine loading, achieving the highest adsorption capacity (140.6 mg g{sup −1} for TS-G1-3CN) at 60%. The developed TS materials exhibited excellent cycling stability. After 12 consecutive adsorption–desorption runs, TS-G1-3CN-50 shows an adsorption capacity of 136.0 mg g{sup −1}, retaining 98.5% of its original value.

36 MATERIALS SCIENCE↗

Re-Architecting the NASA Wire Derating Approach for Space Flight Applications

Mr. Steve Rickman, NASA Technical Fellow for Passive Thermal, proposed a pathfinder study to develop an apparatus for wire and wire bundle thermal testing to measure their performance, and to support development of thermal analytical models. Development of such capability would enable wire and wire bundle amperage capacity. The goal of this study was to assess the feasibility of developing physics-based and regression thermal models of single wires and wire bundles. This report contains the outcome of the NESC assessment.

Steven L Rickman↗

FIELD TEST INSTRUCTION 100-NR-2 OPERABLE UNIT DESIGN OPTIMIZATION STUDY FOR SEQUESTRATION OF SR-90 SATURATED ZONE APATITE PERMEABLE REACTIVE BARRIER EXTENSION

The objective of this field test instruction is to provide technical guidance for aqueous injection emplacement of an extension apatite permeable reactive barrier (PRE) for the sequestration of strontium-90 (Sr-90) using a high concentration amendment formulation. These field activities will be conducted according to the guidelines established in DOE/RL-2010-29, 100-NR-2 Design Optimization Study, hereafter referred to as the DOS. The DOS supports the Federal Facility Agreement Consent Order (EPA et al., 1989), Milestone M-16-06-01, and 'Complete Construction of a Permeable Reactive Barrier at 100-N.' Injections of apatite precursor chemicals will occur at an equal distance intervals on each end of the existing PRE to extend the PRB from the existing 91 m (300 ft) to at least 274 m (900 ft). Field testing at the 100-N Area Apatite Treatability Test Site, as depicted on Figure 1, shows that the barrier is categorized by two general hydrologic conceptual models based on overall well capacity and contrast between the Hanford and Ringold hydraulic conductivities. The upstream portion of the original barrier, shown on Figure 1, is characterized by relatively low overall well specific capacity. This is estimated from well development data and a lower contrast in hydraulic conductivity between the Hanford formation and Ringold Formations. Comparison of test results from these two locations indicate that permeability contrast between the Hanford formation and Ringold Formation is significantly less over the upstream one-third of the barrier. The estimated hydraulic conductivity for the Hanford formation and Ringold Formation over the upstream portion of the barrier based on observations during emplacement of the existing 91 m (300 ft) PRB is approximately 12 and 10 m/day (39 and 32 ft/day), respectively (PNNL-17429). However, these estimates should be used as a rough guideline only, as significant variability in hydraulic conductivity is likely to be observed in the barrier extension wells, particularly those in the Ringold formation. The downstream portion of the original barrier, shown on Figure 1, is characterized by generally higher well specific capacity and a larger hydraulic conductivity contrast between the Hanford formation and Ringold Formation. Hydraulic conductivity rates for the Hanford formation and Ringold Formation over the downstream portion of the barrier were estimated at 29 and 9 m/day (95 and 29 ft/day), respectively (with the Hanford formation hydraulic conductivity being greater in the downstream portion than the upstream portion). Once again, it should be noted that the actual conductivities may vary significantly, and the values state above should only be used as a rough initial estimates. Optimum apatite emplacement has been shown to occur when injections targeting the Hanford formation and the Ringold Formation are performed separately. The remainder of this test instruction provides details for conducting these formation-targeted injections.

58 GEOSCIENCES↗

Regenerative Carbonate-Based Thermochemical Energy Storage System for Concentrating Solar Power

Southern Research has developed a thermochemical energy storage (TCES) technology that utilizes the endothermic-exothermic reversible carbonation of calcium oxide (lime) to store thermal energy at high-temperatures, such as those achieved by next generation concentrating solar power (CSP) facilities. The major challenges addressed in the development of this system include refining a high capacity, yet durable sorbent material and designing a low thermal resistance low-cost heat exchanger reactor system to move heat between the sorbent and a heat transfer fluid under conditions relevant for CSP operation (e.g., energy density, reaction kinetics, heat flow). The proprietary stabilized sorbent was developed by Precision Combustion, Inc. (PCI). A factorial matrix of sorbent compositions covering the design space was tested using accelerated high throughput screening in a thermo-gravimetric analyzer. Several promising formulations were selected for more thorough evaluation and one formulation with high capacity (0.38 g CO 2 /g sorbent) and durability (>99.7% capacity retention over 100 cycles) was chosen as a basis for further development of the energy storage reactor system. In parallel with this effort, a full range of currently available commercial and developmental heat exchange reactor systems and sorbent loading methods were examined through literature research and contacts with commercial vendors. Process models were developed to examine if a heat exchange reactor system and balance of plant can meet required TCES performance and cost targets, optimizing tradeoffs between thermal performance, exergetic efficiency, and cost. Reactor types evaluated included many forms, from microchannel reactor, to diffusion bonded heat exchanger, to shell and tube heat exchangers. The most viable design for application to a supercritical CO 2 power cycle operating at 200-300 bar pressure and >700°C was determined to be a combination of a diffusion bonded heat exchanger with a shell and tube reactor. A bench scale reactor system was then designed and constructed to test sorbent performance under more commercially relevant conditions. This system utilizes a tube-in tube reactor design containing approximately 250 grams sorbent and is able to operate under a wide range of temperature, pressure and flow conditions as needed to explore system performance under a variety of operating conditions. A variety of sorbent loading methods may be tested using the reactor design. Initial bench test results over 25 cycles showed very high sorbent stability (>99%) and sufficient capacity (>0.28 g CO 2 /g sorbent) for an economical commercial-scale system. Initial technoeconomic evaluation of the proposed storage system show that the sorbent cost should not have a significant impact on overall system cost, and that the largest cost impacts come from the heat exchanger reactor and balance of plant equipment, including compressors and gas storage, due to the high temperatures for sCO 2 cycles. Current estimated system costs are $47/kWhth based on current material and equipment cost estimates.

14 SOLAR ENERGY↗

Toward a Concept of Operations for Aviation Weather Information Implementation in the Evolving National Airspace System

The capacity of the National Airspace System is being stressed due to the limits of current technologies. Because of this, the FAA and NASA are working to develop new technologies to increase the system's capacity which enhancing safety. Adverse weather has been determined to be a major factor in aircraft accidents and fatalities and the FAA and NASA have developed programs to improve aviation weather information technologies and communications for system users The Aviation Weather Information Element of the Weather Accident Prevention Project of NASA's Aviation Safety Program is currently working to develop these technologies in coordination with the FAA and industry. This paper sets forth a theoretical approach to implement these new technologies while addressing the National Airspace System (NAS) as an evolving system with Weather Information as one of its subSystems. With this approach in place, system users will be able to acquire the type of weather information that is needed based upon the type of decision-making situation and condition that is encountered. The theoretical approach addressed in this paper takes the form of a model for weather information implementation. This model addresses the use of weather information in three decision-making situations, based upon the system user's operational perspective. The model also addresses two decision-making conditions, which are based upon the need for collaboration due to the level of support offered by the weather information provided by each new product or technology. The model is proposed for use in weather information implementation in order to provide a systems approach to the NAS. Enhancements to the NAS collaborative decision-making capabilities are also suggested.

McAdaragh, Raymon M.↗