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At least 721 records · Page 40

Cross-correlation of Planck CMB lensing with DESI-like LRGs

ABSTRACT Cross-correlations between the lensing of the cosmic microwave background (CMB) and other tracers of large-scale structure provide a unique way to reconstruct the growth of dark matter, break degeneracies between cosmology and galaxy physics, and test theories of modified gravity. We detect a cross-correlation between Dark Energy Spectroscopic Instrument (DESI)-like luminous red galaxies (LRGs) selected from DECam Legacy Survey imaging and CMB lensing maps reconstructed with the Planck satellite at a significance of S/N = 27.2 over scales ℓmin = 30, ℓmax = 1000. To correct for magnification bias, we determine the slope of the LRG cumulative magnitude function at the faint limit as s = 0.999 ± 0.015, and find corresponding corrections of the order of a few per cent for $C^{\kappa g}_{\ell }, C^{gg}_{\ell }$ across the scales of interest. We fit the large-scale galaxy bias at the effective redshift of the cross-correlation zeff ≈ 0.68 using two different bias evolution agnostic models: a HaloFit times linear bias model where the bias evolution is folded into the clustering-based estimation of the redshift kernel, and a Lagrangian perturbation theory model of the clustering evaluated at zeff. We also determine the error on the bias from uncertainty in the redshift distribution; within this error, the two methods show excellent agreement with each other and with DESI survey expectations.

79 ASTRONOMY AND ASTROPHYSICS↗

The Effects of an Applied Transverse Field in a Graphene-Like Ising Bilayer Film with Nonequivalent Planes

Using the effective field theory with correlations, we have studied the phase diagrams and the thermal variations of total magnetization (m{sub T}) in a graphene-like Ising bilayer film with nonequivalent planes, consisting of two A (spin-1/2) and B (spin-1) planes with an applied transverse field in the B plane. We have investigated the effects of an applied transverse field and the interplane exchange interaction on the magnetic properties. Many interesting behaviors, such as various types of m{sub T} curves and the re-entrant phenomena, have been obtained, depending on the selections of physical parameters.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Ultraluminous infrared galaxies and the radio-optical correlation for quasars

Through analysis of available optical spectrophotometric data and radio flux density measurements in the literature, it is demonstrated that a good correlation exists between the radio power and bolometric luminosity of the optically-selected OSOs in the Bright Quasar Sample (BOS) of Schmidt and Green (1983). We have recently used VLBI measurements of a sample of ultraluminous infrared galaxies to infer the likely existence of radio-quiet Active Galactic Nuclei (AGNs) deeply enshrouded in dust within their nuclei (Lonsdale, Smith, and Lonsdale 1993). We employ the radio-bolometric luminosity correlation for the BQS quasars to test whether these hypothetical buried AGNs can be energetically responsible for the observed far-infrared luminosities of the ultraluminous infrared galaxies. The ultraluminous infrared galaxies are shown to follow the same relation between radio core power and bolometric luminosity as the radio-quiet QSOs, suggesting that buried AGNs can account for essentially all the observed infrared luminosity, and raising the possibility that any starburst which may be in progress may not be energetically dominant. The broader implications of the radio-optical correlation in quasars for AGNs and luminous infrared galaxy models and the use of radio astronomy as a probe of the central powerhouse in radio quiet AGNs and luminous infrared galaxies are briefly discussed.

Lonsdale, Carol J.↗

Trigonal symmetry breaking and its electronic effects in the two-dimensional dihalides MX 2 and trihalides MX 3

We study the consequences of the approximately trigonal (D 3d ) point symmetry of the transition metal (M) site in two-dimensional van der Waals MX 2 dihalides and MX 3 trihalides. The trigonal symmetry leads to a 2-2-1 orbital splitting of the transition metal d shell, which is best represented by d orbitals that describe the trigonal rather than Oh symmetry. The ligand-ligand bond length differences (rather than metal-ligand) take the role of a Jahn-Teller-like mode and in combination with interlayer distances and dimensionality effects tune the crystal field splittings and bandwidths. These effects, in turn, are amplified by electronic correlation effects—leading to crystal field splittings of the order of 0.1–1 eV between the singlet and the lowest orbital doublet—as opposed to the often assumed degenerate 3 t 2g states. Our calculations explain why most of the materials in this family are insulating, and why these considerations have to be taken into account in realistic models of them. Further, orbital order coupled to various lower symmetry lattice modes may lift the remaining orbital degeneracies, and we explain how these may support unique electronic states using ZrI 2 and CuCl 2 as examples, and offer a brief overview of possible electronic configurations in this class of materials. By building and analyzing Wannier models adapted to the appropriate symmetry we examine how the interplay among trigonal symmetry, electronic correlation effects, and – d orbital charge transfer leads to insulating, orbitally polarized magnetic and/or orbital-selective Mott states, and we provide a simple framework and numerical tool for others. Our paper establishes a rigorous framework to understand, control, and tune the electronic states in low-dimensional correlated halides. Furthermore, our analysis shows that trigonal symmetry and its breaking is a key feature of the two-dimensional halides that needs to be accounted for in search of novel electronic states in materials ranging from CrI 3 to α–RuCl 3 .

2-dimensional systems↗

Fractional correlated insulating states at one-third filled magic angle twisted bilayer graphene

Abstract The observation of superconductivity and correlated insulating states in twisted bilayer graphene has motivated much theoretical progress at integer fillings. However, little attention has been given to fractional fillings. Here we show that the three-peak structure of Wannier orbitals, dictated by the symmetry and topology of flat bands, facilitates the emergence of a state we name a “fractional correlated insulator” at commensurate fractional filling of ν = n ± 1/3. Specifically for the filling of 1/3 electrons per moiré unit cell, we show that short-range interactions lead to an extensive entropy due to the “breathing” degree of freedom of an irregular honeycomb lattice that emerges through defect lines. The leading further-range interaction lifts this degeneracy and selects a ferromagnetic nematic state that breaks AB/BA sublattice symmetry. The proposed fractional correlated insulating state might underlie the suppression of superconductivity at ν = 2 − 1/3 filling observed in ref. 1 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stability of the interorbital-hopping mechanism for ferromagnetism in multi-orbital Hubbard models

The emergence of insulating ferromagnetic phase in iron oxychalcogenide chain system has been recently argued to be originated by interorbital hopping mechanism. However, the practical conditions for the stability of such mechanism still prevents the observation of ferromagnetic in many materials. Here, we study the stability range of such ferromagnetic phase under modifications in the crystal fields and electronic correlation strength, constructing a theoretical phase diagram. We find a rich emergence of phases, including a ferromagnetic Mott insulator, a ferromagnetic orbital-selective Mott phase, together with antiferromagnetic and ferromagnetic metallic states. We characterize the stability of the ferromagnetic regime in both the Mott insulator and the ferromagnetic orbital-selective Mott phase forms. We identify a large stability range in the phase diagram at both intermediate and strong electronic correlations, demonstrating the capability of the interorbital hopping mechanism in stabilizing ferromagnetic insulators. Our results may enable additional design strategies to expand the relatively small family of known ferromagnetic insulators.

36 MATERIALS SCIENCE↗

Probing the role of carbon in the interstellar ultraviolet extinction

We probe the role of carbon in the ultraviolet (UV) extinction by examining the relations between the amount of carbon required to be locked up in dust [C/H]{sub dust} with the 2175 A-ring extinction bump and the far-UV extinction rise, based on an analysis of the extinction curves along 16 Galactic sightlines for which the gas-phase carbon abundance is known and the 2175 A-ring extinction bump exhibits variable strengths and widths. We derive [C/H]{sub dust} from the Kramers–Kronig relation which relates the wavelength-integrated extinction to the total dust volume. This approach is less model-dependent since it does not require the knowledge of the detailed optical properties and size distribution of the dust.We also derive [C/H]{sub dust} from fitting the observed UV/optical/near-infrared extinction with a mixture of amorphous silicate and graphite. We find that the carbon depletion [C/H]{sub dust} tends to correlate with the strength of the 2175 A-ring bump, while the abundance of silicon depleted in dust shows no correlation with the 2175 A-ring bump. This supports graphite or polycyclic aromatic hydrocarbon molecules as the possible carrier of the 2175 A-ring bump. We also see that [C/H]{sub dust} shows a trend of correlating with 1/R{sub V}, where R{sub V} is the total-to-selective extinction ratio, suggesting that the far-UV extinction is more likely produced by small carbon dust than by small silicate dust.

79 ASTRONOMY AND ASTROPHYSICS↗

Experimental Verification of Buffet Calculation Procedure Using Unsteady Pressure-Sensitive Paint

Typically, a limited number of dynamic pressure sensors is employed to determine the unsteady aerodynamic forces on large, slender aerospace structures. This paper describes a robust calculation procedure based on frequency-specific correlation lengths and validation from an experiment conducted on a flat panel coated with fast response pressure-sensitive paint. The first part of the paper describes the procedure used to analyze the pressure sensitive paint images and a calibration method using dynamic pressure transducers. Excellent comparison in spectra, coherence, and phase, measured via pressure-sensitive paint and dynamic pressure sensors, validates the pressure-sensitive paint data. The second part of the paper describes the buffet validation process, the first step of which was to use pressure histories from all pixels to determine the true force fluctuations. In the next step, only a selected number of pixels was chosen as virtual sensors, and a correlation-length-based buffet calculation procedure was applied to determine modeled force fluctuations. By progressively decreasing the number of virtual sensors, it was observed that the present calculation procedure was able to make a close estimate of the true unsteady forces only from eight sensors. It is believed that the present work provides the first validation of a buffet calculation procedure.

Buffet↗

Metal Oxide Nanoarrays for Chemical Sensing: A Review of Fabrication Methods, Sensing Modes, and Their Inter-correlations

In recent years, engineered nanostructure assemblies such as nanowire arrays have attracted much research attention due to their unique chemical and functional characteristics collectively. The engineered nano-assemblies usually carry the characteristics distinct from bulk as a result of a size effect in their comprised elemental building blocks. The nanoscale size induced high surface-to-volume ratio is a fundamental attribute responsible for various chemical and physical properties required in various technologically important applications such as catalysts and sensors. This review article surveys the latest progress in engineered metal oxide nanostructure arrays, i.e., nanoarrays, for advanced chemical sensors' design and application. It starts with an overview of gaseous chemical sensors followed by surveys of various fabrication methods and routes for metal oxide nanoarrays. Different sensing modes and corresponding applications have been highlighted in the mixed gaseous chemical sensing, which provides new approaches and perspectives to meet the challenges of selective gas sensing, such as the cross-sensitivity and inter-correlation of multiple sensing signals.

36 MATERIALS SCIENCE↗

Separation of lithospheric, external, and core components of the south polar geomagnetic field at satellite altitudes

We present a new approach to producing scalar Magsat magnetic anomaly maps based on correlation coefficient filtering and the use of almost all of the available orbits. Our method differs from earlier techniques with respect to the following: (1) Passes are selected based on their variance properties rather than planetary indices such as Kp. (2) The core field model is least squares fit to individual passes and subsequently removed instead of substracting the model directly. This technique replaces band pass filtering or polynomial trend removal methods. (3) Each selected pass is sorted geographically and by local time, placed into one of four different altitude bands, and correlation coefficient filtered with the two adjacent passes. The filtering is the second step toward isolating the static lithospheric signal from the more dynamic external field signals. (4) Least squares collocation is used to grid the correlated passes; subsequently, the dawn and dusk maps are also correlation filtered providing another step toward removal of external fields. (5) The four resultant total field maps are continued to a common altitude and again correlation filtered for the static lithospheric anomalies. (6) The filtered results are then averaged together to provide a new total field map of the lithosphere south of 40 deg S latitude. Our total field map differs from previous efforts over the crustal blocks of West Antarctica. We obtained a positive anomaly over Edward VII Peninsula, extending into the Byrd subglacial basin and obtained a negative anomaly over the Ellsworth Mountains and parts of the Byrd subglacial basin. Also, a positive anomaly extending from the Ross Sea to offshore Wilkes Land is present in our map; however, this feature is absent in other maps. Positive anomalies marking the Weddell Sea in previous efforts are not present in our map. Prominent external field anomalies in the quadrant offshore of Wilkes Land are present in all previous efforts; however, these signatures are reduced in our total field map. This map significantly advances efforts for the identification and interpretation of magnetic anomalies of the south polar lithosphere.

Alsdorf, Douglas E.↗

Forward-backward multiplicity correlations in pp collisions at $\sqrt{s}$ = 0.9, 2.76 and 7 TeV

The strength of forward-backward (FB) multiplicity correlations is measured by the ALICE detector in proton-proton (pp) collisions at $\sqrt{s}$ = 0.9, 2.76 and 7 TeV. The measurement is performed in the central pseudorapidity region (|η| < 0.8) for the transverse momentum p T > 0.3 GeV/c. Two separate pseudorapidity windows of width ($\delta$η) ranging from 0.2 to 0.8 are chosen symmetrically around η = 0. The multiplicity correlation strength (b corr ) is studied as a function of the pseudorapidity gap (η gap ) between the two windows as well as the width of these windows. The correlation strength is found to decrease with increasing η gap and shows a non-linear increase with $\delta$η. A sizable increase of the correlation strength with the collision energy, which cannot be explained exclusively by the increase of the mean multiplicity inside the windows, is observed. The correlation coefficient is also measured for multiplicities in different configurations of two azimuthal sectors selected within the symmetric FB η-windows. Two different contributions, the short-range (SR) and the long-range (LR), are observed. The energy dependence of b corr is found to be weak for the SR component while it is strong for the LR component. Moreover, the correlation coefficient is studied for particles belonging to various transverse momentum intervals chosen to have the same mean multiplicity. Both SR and LR contributions to b corr are found to increase with p T in this case. Results are compared to PYTHIA and PHOJET event generators and to a string-based phenomenological model. In conclusion, the observed dependencies of b corr add new constraints on phenomenological models.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Evolution-guided engineering of small-molecule biosensors

Allosteric transcription factors (aTFs) have proven widely applicable for biotechnology and synthetic biology as ligand-specific biosensors enabling real-time monitoring, selection and regulation of cellular metabolism. However, both the biosensor specificity and the correlation between ligand concentration and biosensor output signal, also known as the transfer function, often needs to be optimized before meeting application needs. Here, we present a versatile and high-throughput method to evolve prokaryotic aTF specificity and transfer functions in a eukaryote chassis, namely baker's yeast Saccharomyces cerevisiae. From a single round of mutagenesis of the effector-binding domain (EBD) coupled with various toggled selection regimes, we robustly select aTF variants of the cis,cis-muconic acid-inducible transcription factor BenM evolved for change in ligand specificity, increased dynamic output range, shifts in operational range, and a complete inversion-of-function from activation to repression. Importantly, by targeting only the EBD, the evolved biosensors display DNA-binding affinities similar to BenM, and are functional when ported back into a prokaryotic chassis. The developed platform technology thus leverages aTF evolvability for the development of new host-agnostic biosensors with user-defined small-molecule specificities and transfer functions.

59 BASIC BIOLOGICAL SCIENCES↗

Spiral arms and massive star formation: Analysis of the CO face-on pictures of the galaxy

The face-on distribution of molecular gas in the first Galactic quadrant, derived from the Massachusetts-Stony Brook Galactic Plane CO Survey, was compared to the Galactic distribution of giant radio HII regions. The HII regions were found to preferentially select gas regions of higher than average density (more than twice the mean) and showed a strong correlation with the second power of the gas density. Systematic effects were tested with a Monte Carlo simulated HII region distribution and found to be negligible. The 135 HII regions were selected from the radio catalogs of Downes et at. (1980) and Wink et al. (1982). The HII regions were required to be within the CO survey 1 and b limits, within the solar circle, and not part of the 3 kpc expanding arm. The velocities of the HII regions were tabulated by the catalog authors and obvious associations with known objects and H2CO absorptions were used by them to assign distances. The distance assignments were here grouped into two categories; (1) those HII regions with definite distance assignments (85 objects); and (2) those HII regions with less secure distance assignments and those for which no near-far assignment was possible (50 objects).

Clemens, D. P.↗

Space Systems - Safety and Compatibility of Materials - Method to Determine the Flammability Thresholds of Materials

Spacecraft fire safety emphasizes fire prevention, which is achieved primarily through the use of fire-resistant materials. Materials selection for spacecraft is based on conventional flammability acceptance tests, along with prescribed quantity limitations and configuration control for items that are non-pass or questionable. ISO 14624-1 and -2 are the major methods used to evaluate flammability of polymeric materials intended for use in the habitable environments of spacecraft. The methods are upward flame-propagation tests initiated in static environments and using a well-defined igniter flame at the bottom of the sample. The tests are conducted in the most severe flaming combustion environment expected in the spacecraft. The pass/fail test logic of ISO 14624-1 and -2 does not allow a quantitative comparison with reduced gravity or microgravity test results; therefore their use is limited, and possibilities for in-depth theoretical analyses and realistic estimates of spacecraft fire extinguishment requirements are practically eliminated. To better understand the applicability of laboratory test data to actual spacecraft environments, a modified ISO 14624 protocol has been proposed that, as an alternative to qualifying materials as pass/fail in the worst-expected environments, measures the actual upward flammability limit for the material. A working group established by NASA to provide recommendations for exploration spacecraft internal atmospheres realized the importance of correlating laboratory data with real-life environments and recommended NASA to develop a flammability threshold test method. The working group indicated that for the Constellation Program, the flammability threshold information will allow NASA to identify materials with increased flammability risk from oxygen concentration and total pressure changes, minimize potential impacts, and allow for development of sound requirements for new spacecraft and extravehicular landers and habitats. Furthermore, recent research has shown that current normal gravity materials flammability tests do not correlate with flammability in ventilated, micro- or reduced-gravity conditions. Currently, the materials selection for spacecraft is based on the assumption of commonality between ground flammability test results and spacecraft environments, which does not appear to be valid. Materials flammability threshold data acquired in normal gravity can be correlated with data obtained in microgravity or reduced-gravity experiments, and consequently a more accurate assessment of the margin of safety of the material in the real environment can be made. In addition, the method allows the option of selecting better or best space system materials, as opposed to what would be considered just acceptable from a flammability point of view and realistic assessment of spacecraft fire extinguishment needs, which could result in significant weight savings. The knowledge afforded by this technique allows for limited extrapolations of flammability behavior to conditions not specifically tested and that could potentially result in significant cost and time savings. The intent of this Technical Specification is to bring to the attention of International Aerospace Community the importance of correlating laboratory test data with real-life space systems applications. The method presented is just one of the possibilities that are believed will lead to better understanding the applicability of laboratory aerospace materials flammability test data. International feedback on improving the proposed method, as well as suggestions for correlating other laboratory aerospace test data with real-life applications relevant to space systems are being sought.

Hirsch, David↗

The influence of random packed column parameters on the liquid holdup and interfacial area

Abstract Carbon dioxide capture via solvent absorption in packed columns has emerged as a potential technology to mitigate coal‐fired power plant CO 2 emissions. Parameters, including packing types, solvent properties, and operating conditions, could potentially affect the packed column CO 2 capture efficiency. To understand the importance of those parameters and help packed column optimization, a design of experiments (DoEs) method was proposed to generate input parameter matrix. Combined with multiphase computational fluid dynamics (CFD), the random packed column parameter influence on the liquid holdup and interfacial area can be efficiently investigated. Surrogate‐based sensitivity analysis shows that the solvent flow rate and contact angle are key factors dictating liquid holdup and interfacial area. On the other hand, solvent viscosity has a marginal impact on the interfacial area. The sensitivity scores were calculated for each input parameter to guide the selection of dimensionless numbers for the liquid holdup and interfacial area correlation development.

42 ENGINEERING↗

Computational investigation of hydrogen-induced phonon changes in carbon fiber

Optical vibrational spectroscopy has shown promise as a noninvasive means of monitoring the mechanical properties of carbon fiber (CF), which is increasingly used for industrial and consumer purposes. However, interpretation of optical vibrational spectra for solid materials is inferential, particularly when defects are present. Because inelastic neutron scattering (INS) spectroscopy is not subject to selection rules, the full vibrational spectra can be measured. And, identifying correlations between INS features and tensile properties can assist in the interpretation of spectra from more commonly used optical vibrational spectroscopic techniques, such as Raman and infrared (IR) spectroscopy. Recent INS experiments on high-performance commercial carbon fibers showed features near 900 and 1100 cm –1 in addition to a broad feature near 3000 cm –1 that increased in intensity with decreasing tensile strength. These features were assigned to hydrogen defects. Here, we use density functional theory to simulate the INS spectra of several hydrogen defect geometries in graphite as a model for carbon fiber structure units, confirming the experimental assignment of these peaks to hydrogen modes and providing insights into the structure and lattice dynamics of the defects.

36 MATERIALS SCIENCE↗

Machine learning models of intermittent operation of RO wellhead water treatment for salinity reduction and nitrate removal

Machine learning models were developed for intermittent multi-mode operation of a wellhead reverse osmosis water purification and desalination system to predict salt passage, nitrate passage, and permeate flux. The models, based on long short-term memory (LSTM) recurrent neural network (RNN) architecture, included an attention mechanism to increase model performance in proximity of the regulatory limit for nitrate. Training and testing of the models for the Startup, Production, Shutdown and Flushing operational modes were based on operational data (consisting of 22 process variables per data sample) acquired every 2–5 s over a six-month period. The significant sets of model input attributes for the different operational modes were assessed via Spearman ranking correlation, Self-Organizing Map (SOM) analysis and feed forward feature selection (FFFS). Although the variability of nitrate passage, salt passage and permeate flux was significant over the four operational modes, prediction performance for the three outcomes were with R2 and Average Absolute Relative Error (AARE) of 0.78–0.95 and 2.96–6.16 %, respectively. Model updates post membrane elements replacement demonstrated similar levels of prediction accuracy. The study results suggest that there is merit in exploring the utility of multi-mode models for sensor fault detection, data imputation, and for potential use in model-predictive control.

Intermittent RO operation↗

Long-term nitrogen dioxide exposure assessment using back-extrapolation of satellite-based land-use regression models for Australia

Highlights: • We assessed how well a year-2006 satellite-based LUR model captures historical NO{sub 2}. • We used three methods to estimate annual mean NO{sub 2} during 1990–2005. • We measured their performance using standard LUR validation techniques. • Back-extrapolated 2006 levels captured up to 76% of spatial variability (90–05). Assessing historical exposure to air pollution in epidemiological studies is often problematic because of limited spatial and temporal measurement coverage. Several methods for modelling historical exposures have been described, including land-use regression (LUR). Satellite-based LUR is a recent technique that seeks to improve predictive ability and spatial coverage of traditional LUR models by using satellite observations of pollutants as inputs to LUR. Few studies have explored its validity for assessing historical exposures, reflecting the absence of historical observations from popular satellite platforms like Aura (launched mid-2004). We investigated whether contemporary satellite-based LUR models for Australia, developed longitudinally for 2006–2011, could capture nitrogen dioxide (NO{sub 2}) concentrations during 1990–2005 at 89 sites around the country. We assessed three methods to back-extrapolate year-2006 NO{sub 2} predictions: (1) ‘do nothing’ (i.e., use the year-2006 estimates directly, for prior years); (2) change the independent variable ‘year’ in our LUR models to match the years of interest (i.e., assume a linear trend prior to year-2006, following national average patterns in 2006–2011), and; (3) adjust year-2006 predictions using selected historical measurements. We evaluated prediction error and bias, and the correlation and absolute agreement of measurements and predictions using R{sup 2} and mean-square error R{sup 2} (MSE-R{sup 2}), respectively. We found that changing the year variable led to best performance; predictions captured between 41% (1991; MSE-R{sup 2} = 31%) and 80% (2003; MSE-R{sup 2} = 78%) of spatial variability in NO{sub 2} in a given year, and 76% (MSE-R{sup 2} = 72%) averaged over 1990–2005. We conclude that simple methods for back-extrapolating prior to year-2006 yield valid historical NO{sub 2} estimates for Australia during 1990–2005. These results suggest that for the time scales considered here, satellite-based LUR has a potential role to play in long-term exposure assessment, even in the absence of historical predictor data.

54 ENVIRONMENTAL SCIENCES↗