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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Fungi and Bacteria

Spacecraft equipment is usually protected from fungi and bacteria by incorporating a fungicide-bactericide in the material, by a fungicide-bactericide spray, or by reducing the relative humidity to a degree where growth will not take place. A unique method to protect delicate, expensive bearings in equipment was to maintain a pressure (with dry air or nitrogen) slightly above the outside atmosphere (few millibars) within the working parts of the equipment, thus preventing fungi from entering equipment.

Glenn E Daniels↗

Simple Test For Organic Material In Gas

Dried enzymes and color indicators test sensitively and selectively. Dehydrated enzymes used in convenient method for analyzing gases for specific organic substances, outside laboratory. Method used to detect alcohol in breath or formaldehyde in gas streams. Used for simple semiquantitative detection or for precise quantitative measurement.

Barzana, Eduardo↗

Diffractive optics fabricated by direct write methods with an electron beam

State-of-the-art diffractive optics are fabricated using e-beam lithography and dry etching techniques to achieve multilevel phase elements with very high diffraction efficiencies. One of the major challenges encountered in fabricating diffractive optics is the small feature size (e.g. for diffractive lenses with small f-number). It is not only the e-beam system which dictates the feature size limitations, but also the alignment systems (mask aligner) and the materials (e-beam and photo resists). In order to allow diffractive optics to be used in new optoelectronic systems, it is necessary not only to fabricate elements with small feature sizes but also to do so in an economical fashion. Since price of a multilevel diffractive optical element is closely related to the e-beam writing time and the number of etching steps, we need to decrease the writing time and etching steps without affecting the quality of the element. To do this one has to utilize the full potentials of the e-beam writing system. In this paper, we will present three diffractive optics fabrication techniques which will reduce the number of process steps, the writing time, and the overall fabrication time for multilevel phase diffractive optics.

Kress, Bernard↗

Flow Visualization by Elastic Light Scattering in the Boundary Layer of a Supersonic Flow

We demonstrate instantaneous flow visualization of the boundary layer region of a Mach 2.5 supersonic flow over a flat plate that is interacting with an impinging shock wave. Tests were performed in the Unitary Plan Wind Tunnel (UPWT) at NASA Langley Research Center. The technique is elastic light scattering using 10-nsec laser pulses at 532 nm. We emphasize that no seed material of any kind, including water (H2O), is purposely added to the flow. The scattered light comes from a residual impurity that normally exists in the flow medium after the air drying process. Thus, the technique described here differs from the traditional vapor-screen method, which is typically accomplished by the addition of extra H2O vapor to the airflow. The flow is visualized with a series of thin two-dimensional light sheets (oriented perpendicular to the streamwise direction) that are located at several positions downstream of the leading edge of the model. This geometry allows the direct observation of the unsteady flow structure in the spanwise dimension of the model and also allows the indirect observation of the boundary layer growth in the streamwise dimension.

Herring, G. C.↗

Efficient volatile metal removal from low rank coal in gasification, combustion, and processing systems and methods

Efficient coal pre-processing systems (69) integrated with gasification, oxy-combustion, and power plant systems include a drying chamber (28), a volatile metal removal chamber (30), recirculated gases, including recycled carbon dioxide (21), nitrogen (6), and gaseous exhaust (60) for increasing the efficiencies and lowering emissions in various coal processing systems.

01 COAL, LIGNITE, AND PEAT↗

Method for the synthesis of iron hexacyanoferrate

A method is provided for synthesizing iron hexacyanoferrate (FeHCF). The method forms a first solution of a ferrocyanide source [A4Fe(CN)6.PH2O] material dissolved in a first solvent, where “A” is an alkali metal ion. A second solution is formed of a Fe(II) source dissolved in a second solvent. A reducing agent is added and, optionally, an alkali metal salt. The first and second solutions may be purged with an inert gas. The second solution is combined with the first solution to form a third solution in a low oxygen environment. The third solution is agitated in a low oxygen environment, and AX+1Fe2(CN)6.ZH2O is formed, where X is in the range of 0 to 1. The method isolates the AX+1Fe2(CN)6.ZH2O from the third solution, and dries the AX+1Fe2(CN)6.ZH2O under vacuum at a temperature greater than 60 degrees C.

25 ENERGY STORAGE↗

Methods of Heat-Exchange Intensification in NPP Equipment

The aims and problems of research on the means for intensifying heat exchange in the equipment of nuclear power plants are examined: nuclear reactors, steam generators, turbine condensers, heat-exchangers of dry water cooling towers, intermediate separators-steam superheaters of turbines, heat-exchange apparatus of safety systems, turbo-electro-generators, oil coolers, feed-water heaters. Methods of identifying heat-exchange are analyzed: different types of finning, turbulence generators and swirlers of one- and two-phase flows, coating on heating surfaces, systems with mixed flow. Computational recommendations are made for determining the intensity of heat emission from promising types of heat-exchange surfaces: bundles of lowfinned tubes and spiral coils.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advanced SMRs Using S-CO2 Power Conversion with Dry Cooling

This report concludes the LDRD entitled "Advanced SMRs using S-CO2 Power Conversion with Dry Cooling." The goal of this project was to demonstrate the feasibility of using sCO 2 as the working fluid in a dry-cooled natural circulation loop. The reason for doing this is to demonstrate that such a loop could be utilized in small modular reactors (SMRs) as a method for (a) passively removing decay heat from the reactor and (b) cooling the reactor without using the copious amounts of water needed for wet-cooled reactors. The dry-cooling aspect of this work is possible due to the working conditions of a sCO 2 Brayton power conversion cycle. The loop was designed, built, and operated over the three-year life of the LDRD project. This report outlines some of the key accomplishments and some of the future work that we are continuing to try to complete in the future. A more comprehensive report will be completed and submitted in the Fall of 2015.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Nonlinear Ultrasonic Diagnosis and Prognosis of ASR Damage in Dry Cask Storage

Alkali-silica reaction (ASR) is a deleterious chemical process that may occur in cement-based materials such as mortars and concretes, where the hydroxyl ions in the highly alkaline pore solution attack the siloxane groups in the siliceous minerals in the aggregates. The reaction produces a cross-linked alkali-silica gel. The ASR gel swells in the presence of water. Expansion of the gel results in cracking when the swelling-induced stress exceeds the fracture toughness of the concrete. As the ASR continues, cracks may grow and eventually coalesce, which results in reduced service life and a decrease safety of concrete structures. Since concrete is widely used as a critical structural component in dry cask storage of used nuclear fuels, ASR damage poses a significant threat to the sustainability of long term dry cask storage systems. Therefore, techniques for effectively detecting, managing and mitigating ASR damage are needed. Currently, there are no nondestructive methods to accurately detect ASR damage in existing concrete structures. The only current way of accurately assessing ASR damage is to drill a core from an existing structure, and conduct microscopy on this drilled cylindrical core. Clearly, such a practice is not applicable to dry cask storage systems. To meet these needs, this research is aimed at developing (1) a suite of nonlinear ultrasonic quantitative nondestructive evaluation (QNDE) techniques to characterize ASR damage, and (2) a physics-based model for ASR damage evolution using the QNDE data. Outcomes of this research will provide a nondestructive diagnostic tool to evaluate the extent of the ASR damage, and a prognostic tool to estimate the future reliability and safety of the concrete structures in dry cask storage systems

42 ENGINEERING↗

Developing generic design alternatives for dry storage of used nuclear fuel at an interim storage facility - 15480

The Department of Energy (DOE) is beginning to lay the groundwork for implementing interim storage of used nuclear fuel (UNF) as recommended by the Blue Ribbon Commission on America's Nuclear Future in their report to the Secretary of Energy published on January 26, 2012. These plans include activities to 1) establish one or more Interim Storage Facilities (ISF) using consent-based siting, and 2) prepare for large-scale transport of UNF. The Administration released its Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste (Strategy) on January 11, 2013. The Strategy includes a phased, adaptive, and consent-based approach to siting and implementing a comprehensive management and disposal system. The Strategy calls for an operational Pilot ISF by 2021, a Larger ISF by 2025, and a geological repository by 2048. The DOE Nuclear Fuels Storage and Transportation Planning Project (NFST) prepared a report in April 2013 titled, -A Project Concept for Nuclear Fuels Storage and Transportation.- This report developed the functions and requirements necessary for development of a Pilot and Larger ISF to meet the framework outlined in the Strategy as follows: - The UNF inventory is limited for the Pilot and Larger ISF as described in the Strategy. - It is assumed that bare fuel will be received in reusable transportation casks in significant quantities for the larger ISF and will not be solely limited to the receipt of fuel in dry storage canister (DSC) as is the Pilot ISF. This assumption was made because the method for accepting UNF from the utilities once the larger ISF begins operating has not yet been decided. - UNF storage alternative concepts identified in previous reports must be more fully developed to support alternative analysis. The purpose of this topic is to report on the development of the generic design alternatives that have been evaluated for the receipt and storage of the UNF at the initial Pilot ISF and Larger ISF. The generic design alternatives have been developed over the past few months by collaboration between the DOE and industry experts experienced in UNF facilities. The design alternatives will enable volunteer host communities to investigate generic design alternatives that could be fully developed for a site-specific location based on their unique design requirements. The design alternatives provide flexibility for additional capabilities to be developed and executed in a modular fashion such that expansion from a Pilot ISF to a Larger ISF could be achieved in an orderly manner. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Comment on 'Shang S. 2012. Calculating actual crop evapotranspiration under soil water stress conditions with appropriate numerical methods and time step. Hydrological Processes 26: 3338-3343. DOI: 10.1002/hyp.8405'

A previous study analyzed errors in the numerical calculation of actual crop evapotranspiration (ET(sub a)) under soil water stress. Assuming no irrigation or precipitation, it constructed equations for ET(sub a) over limited soil-water ranges in a root zone drying out due to evapotranspiration. It then used a single crop-soil composite to provide recommendations about the appropriate usage of numerical methods under different values of the time step and the maximum crop evapotranspiration (ET(sub c)). This comment reformulates those ET(sub a) equations for applicability over the full range of soil water values, revealing a dependence of the relative error in numerical ET(sub a) on the initial soil water that was not seen in the previous study. It is shown that the recommendations based on a single crop-soil composite can be invalid for other crop-soil composites. Finally, a consideration of the numerical error in the time-cumulative value of ET(sub a) is discussed besides the existing consideration of that error over individual time steps as done in the previous study. This cumulative ET(sub a) is more relevant to the final crop yield.

Time step↗

Optimized Slurries for Spray Drying: Different Approaches to Obtain Homogeneous and Deformable Alumina-Zirconia Granules

Spray drying is widely used for producing granulated feed materials for compaction process, which is the current industrial method for manufacturing alumina-zirconia femoral heads. The optimization of the granules compaction behavior requires the control of the slurry rheology. Moreover, for a dual-phase ceramic suspension, the even phase distribution has to be kept through the atomization step. Here we present two approaches addressing the key issues involved in the atomization of a composite system. Alumina-10 vol % zirconia powders were prepared by either a powder mixing route, or by the surface modification of a commercial α-alumina powder with a zirconium salt. Slurries from both powders were spray dried. The correlation between slurry rheology and pH, granules morphology and sintered microstructures was here investigated and discussed on the ground of the two feed materials characteristics. The processing conditions were optimized to obtain dense and homogeneous alumina-zirconia micro-nano composites by both processing routes.

36 MATERIALS SCIENCE↗

A Novel Laser 3D Printing Method for the Advanced Manufacturing of Protonic Ceramics

Protonic ceramics (PCs) with high proton conductivity at intermediate temperatures (300–600 °C) have attracted many applications in energy conversion and storage devices such as PC fuel/electrolysis cells, PC membrane reactors, hydrogen pump, hydrogen or water-permeable membranes, and gas sensors. One of the essential steps for fulfilling the practical utilization of these intermediate-temperature PC energy devices is the successful development of advanced manufacturing methods for cost-effectively and rapidly fabricating them with high energy density and efficiency in a customized demand. In this work, we developed a new laser 3D printing (L3DP) technique by integrating digital microextrusion-based 3D printing and precise and rapid laser processing (sintering, drying, cutting, and polishing), which showed the capability of manufacturing PCs with desired complex geometries, crystal structures, and microstructures. The L3DP method allowed the fabrication of PC parts such as pellets, cylinders, cones, films, straight/lobed tubes with sealed endings, microchannel membranes, and half cells for assembling PC energy devices. The preliminary measurement of the L3DP electrolyte film showed a high proton conductivity of ≈7 × 10−3 S/cm. This L3DP technique not only demonstrated the potential to bring the PCs into practical use but also made it possible for the rapid direct digital manufacturing of ceramic-based devices.

08 HYDROGEN↗

Surface-induced brightness temperature variations and their effects on detecting thin cirrus clouds using IR emission channels in the 8-12 micrometer region

A method for detecting cirrus clouds in terms of brightness temperature differences between narrow bands at 8, 11, and 12 mu m has been proposed by Ackerman et al. (1990). In this method, the variation of emissivity with wavelength for different surface targets was not taken into consideration. Based on state-of-the-art laboratory measurements of reflectance spectra of terrestrial materials by Salisbury and D'Aria (1992), we have found that the brightness temperature differences between the 8 and 11 mu m bands for soils, rocks and minerals, and dry vegetation can vary between approximately -8 K and +8 K due solely to surface emissivity variations. We conclude that although the method of Ackerman et al. is useful for detecting cirrus clouds over areas covered by green vegetation, water, and ice, it is less effective for detecting cirrus clouds over areas covered by bare soils, rocks and minerals, and dry vegetation. In addition, we recommend that in future the variation of surface emissivity with wavelength should be taken into account in algorithms for retrieving surface temperatures and low-level atmospheric temperature and water vapor profiles.

Gao, Bo-Cai↗

Processing of sintered alpha SiC

Processing methods of sintered alpha SiC for engine applications are developed in a cost effective manner, using a submicron sized powder blended with sintering aids (boron and carbon). The processes for forming a green powder compact, such as dry pressing, cold isostatic pressing and green machining, slip casting, aqueous extrusion, plastic extrusion, and injection molding, are described. Dry pressing is the simplest route to component fabrication, and is carried out at approximately 10,000 psi pressure, while in the cold isostatic method the pressure could go as high as 20,000 psi. Surfactants are added to control settling rates and casting characteristics in the slip casting. The aqueous extrusion process is accomplished by a hydraulic ram forcing the aqueous mixture through a die. The plastic forming processes of extrusion and injection molding offer the potential of greater diversity in shape capacity. The physical properties of sintered alpha SiC (hardness, Young's modulus, shear modulus, and thermal diffusivity) are extensively tested. Corrosion resistance test results of silicon carbide are included.

Storm, R. S.↗

A Facile Degumming Method of Kenaf Fibers Using Deep Eutectic Solution

An eco-friendly and effective degumming method needed to be developed for producing kenaf bast fibers. As such, this study devised a novel deep eutectic solvent (DES) method coupled with microwave and alkaline-ultrasonic treatment. The novel method could effectively remove the gummy matters, providing a smooth and clean fiber surface. The properties of the fibers were assessed including chemical compositions, surface structure, crystallinity index (66.68%) and thermal properties. The residual gum content (9.419%), fiber fineness (4.125tex), breaking tenacity (13.650 cn/tex) of the refined dry fibers produced by the novel treatment were comparable with the fibers produced by the traditional two-step alkali boiling method. Besides, the novel method could reduce the usage of chemical, water and time by 48.9%, by 66.7% and 66.8%, respectively. These results revealed that the novel combined DES pretreatment is a practical and feasible pretreatment method for kenaf bast degumming, demonstrating its facile, green energy-saving and fast properties in the degumming process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Estimating Canopy Water Content of Chaparral Shrubs Using Optical Methods

California chaparral ecosystems are exceptionally fire adapted and typically are subject to wildfire at decadal to century frequencies. The hot dry Mediterranean climate summers and the chaparral communities of the Santa Monica Mountains make wildfire one of the most serious economic and life-threatening natural disasters faced by the region. Additionally, the steep fire-burned hillsides are subject to erosion, slumpage, and mud slides during the winter rains. The Santa Monica Mountain Zone (SMMZ) is a 104,000 ha eastwest trending range with 607 m of vertical relief and located in the center of the greater Los Angeles region. A series of fires in the fall of 1993 burned from Simi Valley to Santa Monica within a few hours. Developing techniques to monitor fire hazard and predict the spread of fire is of major concern to the region. One key factor in the susceptibility to fire is the water content of the vegetation canopy. The development of imaging spectrometry and remote sensing techniques may constitute a tool to provide this information.

Ustin, Susan L.↗

Estimating Canopy Water Content of Chaparral Shrubs Using Optical Methods

California chaparral ecosystems are exceptionally fire adapted and typically are subject to wildfire at decadal to century frequencies. The hot dry Mediterranean climate summers and the chaparral communities of the Santa Monica Mountains make wildfire one of the most serious economic and life-threatening natural disasters faced by the region.

ecosystems↗