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At least 721 records · Page 40

Partial glass isosymmetry transition in multiferroic hexagonal ErMn O 3

Ferroelectric transitions of a hexagonal multiferroic, ErMnO 3 , are studied by x-ray scattering techniques. An isosymmetry transition, similar to that previously observed for YMnO 3 , approximately 300 K below the well-known ferroic transition temperature is investigated. The partial glassy behavior of the isosymmetry transition is identified by appearance of quasi-elastic scattering lines in high-energy-resolution scans. The glassy behavior is further supported by the increased interlayer decorrelation of (√3×√3)R30º ordering below the isosymmetry transition. The transition behavior is considered for possible hidden sluggish modes and two-step phase transitions theoretically predicted for the stacked triangular antiferromagnets. The in-plane azimuthal (orientational) ordering behaviors were also compared to the theoretical predictions. Coherent x-ray speckle measurements show unambiguously that the domain sizes decrease anomalously near both the isosymmetry and ferroic transitions. However, domain boundary fluctuations increase monotonically with an Arrhenius form with an activation energy of 0.54(5) eV through both transitions.

36 MATERIALS SCIENCE↗

On the equations governing the electromagnetic perturbations of the Kerr black hole

Teukolsky's (1973) radial wave equation for electromagnetic perturbations about a rotating black hole is transformed into a one-dimensional wave equation with a real and short-range potential. A general technique for transforming one wave equation into another is described, and it is shown how an equation with a complex potential can be transformed into one with a purely real potential. These general techniques are then used to transform Teukolsky's equation into a wave equation whose potential is purely real and of short range. This equation is found to provide a simple formulation of the concepts of superradiant scattering and the conservation of energy underlying the present electromagnetic perturbations. It is noted that the techniques employed are general enough to be applicable when the spin weight is plus or minus 2, making a 'real-potential' formulation of the problem of gravitational perturbations about a Kerr black hole most likely.

Detweiler, S.↗

A combined finite element-boundary element formulation for solution of two-dimensional problems via CGFFT

A method for the computation of electromagnetic scattering from arbitrary two-dimensional bodies is presented. The method combines the finite element and boundary element methods leading to a system for solution via the conjugate gradient Fast Fourier Transform (FFT) algorithm. Two forms of boundaries aimed at reducing the storage requirement of the boundary integral are investigated. It is shown that the boundary integral becomes convolutional when a circular enclosure is chosen, resulting in reduced storage requirement when the system is solved via the conjugate gradient FFT method. The same holds for the ogival enclosure, except that some of the boundary integrals are not convolutional and must be carefully treated to maintain O(N) memory requirement. Results for several circular and ogival structures are presented and shown to be in excellent agreement with those obtained by traditional methods.

Collins, Jeffery D.↗

Error analysis of image reconstruction by a synthetic aperture interferometric radiometer

An error analysis is presented for the image reconstruction algorithm currently employed by the electronically steered thinned array radiometer aircraft instrument. This instrument samples components of the Fourier transform of the brightness temperature distribution at 1.4 GHz. Sources of error are identified, including systematic offsets and stochastic noise in the measurements, errors in the interference pattern antenna calibration, multipath scattering from the antenna support structure, mutual coupling between nearby array elements, and variations in the antenna patterns of the array elements. These errors are shown to produce artifacts in the image which appear as 'streaks' running along the instrument flight line. Possible hardware corrections are discussed. These include a reduction in the profile of the antenna support structure and a decoupling of adjacent and other nearby array elements using corrugated 'skirts'. Also discussed are several image enhancement techniques which detect and correct for some of the streaking. These techniques include a renormalization of the interference patterns based on the measured element patterns, a perturbation based interpretation of image contrast, and a covariance analysis of noise present in the image.

Ruf, Christopher S.↗

Far Infrared Measurements of Cirrus

Improved techniques for remote sensing of cirrus are needed to obtain global data for assessing the effect of cirrus in climate change models. Model calculations show that the far infrared/sub-millimeter spectral region is well suited for retrieving cirrus Ice Water Path and particle size parameters. Especially useful cirrus information is obtained at frequencies below 60 cm-1 where single particle scattering dominates over thermal emission for ice particles larger than about 50 m. Earth radiance spectra have been obtained for a range of cloud conditions using an aircraft-based Fourier transform spectrometer. The Far InfraRed Sensor for Cirrus (FIRSC) is a Martin-Puplett interferometer which incorporates a polarizer for the beamsplitter and can be operated in either intensity or linear polarization measurement mode. Two detector channels span 10 to 140 cm-1 with a spectral resolution of 0.1 cm-1; achieving a Noise Equivalent Temperature of approximately 1K at 30 cm-1 in a 4 sec scan. Examples are shown of measured and modeled Earth radiance for a range of cloud conditions from 1998 and 1999 flights.

Nolt, I. G.↗

Information theory optimization of signals from small-angle scattering measurements

Small-angle X-ray scattering (SAXS) of particles in solution informs on the conformational states and assemblies of biological macromolecules (bioSAXS) outside of cryo- and solid-state conditions. In bioSAXS, the SAXS measurement under dilute conditions is resolution limited, and through an inverse Fourier transform, the measured SAXS intensities directly relate to the physical space occupied by the particles via the P (r)-distribution. Yet, this inverse transform of SAXS data has been historically cast as an ill-posed, ill-conditioned problem requiring an indirect approach. Here, we show that through the applications of matrix and information theories, the inverse transform of SAXS intensity data is a well-conditioned problem. The so-called ill-conditioning of the inverse problem is directly related to the Shannon number. By exploiting the oversampling enabled by modern detectors, a direct inverse Fourier transform of the SAXS data is possible, provided the recovered information does not exceed the Shannon number. The Shannon limit corresponds to the maximum number of significant singular values that can be recovered in a SAXS experiment, suggesting this relationship is a fundamental property of band-limited inverse integral transform problems. This correspondence reduces the complexity of the inverse problem to the Shannon limit and maximum dimension. We propose a hybrid scoring function using an information theory framework that assesses both the quality of the model-data fit as well as the quality of the recovered P (r)-distribution. The hybrid score utilizes the Akaike information criteria and Durbin-Watson statistic that considers parameter-model complexity, i.e., degrees of freedom, and the randomness of the model-data residuals. The described tests and findings extend the boundaries for bioSAXS by completing the information theory formalism initiated by Peter B. Moore to enable a quantitative measure of resolution in SAXS, robustly determine maximum dimension, and more precisely define the best parameter model appropriately representing the observed scattering data.

Rambo, Robert P. [Science and Technology Facilitie↗

Signature extraction of ocean pollutants by eigenvector transformation of remote spectra

Spectral signatures of suspended matter in the ocean are being extracted through characteristic vector analysis of remote ocean color data collected with MOCS (Multichannel Ocean Color Sensor). Spectral signatures appear to be obtainable through analyses of 'linear' clusters that appear on scatter diagrams associated with eigenvectors. Signatures associated with acid waste, sewage sludge, oil, and algae are presented. The application of vector analysis to two acid waste dumps overflown two years apart is examined in some detail. The relationships between eigenvectors and spectral signatures for these examples are analyzed. These cases demonstrate the value of characteristic vector analysis in remotely identifying pollutants in the ocean and in determining the consistency of their spectral signatures.

Grew, G. W.↗

Effective dielectric function of TiO{sub 2} nanoparticles under laser pumping in the fundamental absorption band

A nonlinear optical response of TiO{sub 2} nanoparticles under pumping by 355-nm laser radiation is experimentally investigated. Using the data obtained by z -scanning with simultaneous measurement of the scattering intensity, the effective permitivity of particles is reconstructed as a function of the pump intensity. It is found that graphical mapping of the relationship between the real and imaginary parts of the permitivity can be obtained using an affine transformation of a similar map of the frequency-dependent dielectric function for the Lorentz model. It is shown that an increase in the pump intensity should lead to a red shift of the absorption maximum of nanoparticles and a rise in the plasma frequency, which is estimated (using a single-oscillator Lorenz model) from the obtained values of the real and imaginary parts of the effective permitivity for the probe radiation wavelength in use. (paper)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Suppressing Molecular Charging, Nanochemistry, and Optical Rectification in the Tip-Enhanced Raman Geometry

Classical vs quantum plasmons are operative in tapping vs contact mode tip-enhanced Raman scattering (TERS) and lead to distinct observables. Under otherwise identical experimental conditions, we illustrate the concept through tapping and contact mode TERS mapping of chemically functionalized silver nanocubes. Whereas molecular charging, chemical transformations, and optical rectification are prominent observables in contact mode TERS, the same effects are suppressed using tapping mode feedback. In effect, this work demonstrates that nanoscale physical and chemical processes can be accessed/suppressed on-demand in the TERS geometry. Further, the advantages of tapping mode TERS are otherwise highlighted with the latter in mind.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ultrathin Porous Hydrocarbon Membranes Templated by Nanoparticle Assemblies

Porous polymer membranes are widely desired as catalyst supports, sensors, and active layers for separation membranes. We demonstrate that electron beam irradiation of freely suspended gold or Fe 3 O 4 nanoparticle (NP) monolayer sheets followed by wet chemical etching is a high-fidelity strategy to template two-dimensional (2D) porous crosslinked hydrocarbon membranes. This approach, which relies on secondary electrons generated by the NP cores, can further be used to transform three-dimensional (3D) terraced gold NP supercrystals into 3D porous hydrocarbon membranes. We utilize electron tomography to show how the number of NP layers (monolayer to pentalayer) controls attenuation and scattering of the primary e-beam, which in turn determines ligand crosslink density and 3D pore structure. Furthermore, electron tomography also reveals that many nanopores are vertically continuous due to preferential sintering of NPs. This work demonstrates new routes for the construction of functional nanoporous media.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A machine learning approach to galaxy properties: joint redshift–stellar mass probability distributions with Random Forest

We demonstrate that highly accurate joint redshift–stellar mass probability distribution functions (PDFs) can be obtained using the Random Forest (RF) machine learning (ML) algorithm, even with few photometric bands available. As an example, we use the Dark Energy Survey (DES), combined with the COSMOS2015 catalogue for redshifts and stellar masses. We build two ML models: one containing deep photometry in the griz bands, and the second reflecting the photometric scatter present in the main DES survey, with carefully constructed representative training data in each case. We validate our joint PDFs for 10 699 test galaxies by utilizing the copula probability integral transform and the Kendall distribution function, and their univariate counterparts to validate the marginals. Benchmarked against a basic set-up of the template-fitting code bagpipes, our ML-based method outperforms template fitting on all of our predefined performance metrics. In addition to accuracy, the RF is extremely fast, able to compute joint PDFs for a million galaxies in just under 6 min with consumer computer hardware. Such speed enables PDFs to be derived in real time within analysis codes, solving potential storage issues. As part of this work we have developed galpro 1, a highly intuitive and efficient python package to rapidly generate multivariate PDFs on-the-fly. galpro is documented and available for researchers to use in their cosmology and galaxy evolution studies.

79 ASTRONOMY AND ASTROPHYSICS↗

The DEHVILS survey overview and initial data release: high-quality near-infrared Type Ia supernova light curves at low redshift

ABSTRACT While the sample of optical Type Ia supernova (SN Ia) light curves (LCs) usable for cosmological parameter measurements surpasses 2000, the sample of published, cosmologically viable near-infrared (NIR) SN Ia LCs, which have been shown to be good ‘standard candles,’ is still ≲ 200. Here, we present high-quality NIR LCs for 83 SNe Ia ranging from 0.002 < z < 0.09 as a part of the Dark Energy, H0, and peculiar Velocities using Infrared Light from Supernovae (DEHVILS) survey. Observations are taken using UKIRT’s WFCAM, where the median depth of the images is 20.7, 20.1, and 19.3 mag (Vega) for Y, J, and H-bands, respectively. The median number of epochs per SN Ia is 18 for all three bands (Y,J, and H) combined and 6 for each band individually. We fit 47 SN Ia LCs that pass strict quality cuts using three LC models, SALT3, snoopy, and B ayeSN and find scatter on the Hubble diagram to be comparable to or better than scatter from optical-only fits in the literature. Fitting NIR-only LCs, we obtain standard deviations ranging from 0.128 to 0.135 mag. Additionally, we present a refined calibration method for transforming 2MASS magnitudes to WFCAM magnitudes using HST CALSPEC stars that results in a 0.03 mag shift in the WFCAM Y-band magnitudes.

Astronomy & Astrophysics↗

Cleanroom air sampler counts, categorizes, and records particle data

Light scattering particle counter monitors particles in a clean room. It categorizes and records the particles according to size and functions simultaneously in three separate areas. The counter uses a transducer head to transform light signals into electric signals.

Nelson, M. B.↗

NASA Tech Briefs, January 2013

Topics include: Single-Photon-Sensitive HgCdTe Avalanche Photodiode Detector; Surface-Enhanced Raman Scattering Using Silica Whispering-Gallery Mode Resonators; 3D Hail Size Distribution Interpolation/Extrapolation Algorithm; Color-Changing Sensors for Detecting the Presence of Hypergolic Fuels; Artificial Intelligence Software for Assessing Postural Stability; Transformers: Shape-Changing Space Systems Built with Robotic Textiles; Fibrillar Adhesive for Climbing Robots; Using Pre-Melted Phase Change Material to Keep Payloads in Space Warm for Hours without Power; Development of a Centrifugal Technique for the Microbial Bioburden Analysis of Freon (CFC-11); Microwave Sinterator Freeform Additive Construction System (MS-FACS); DSP/FPGA Design for a High-Speed Programmable S-Band Space Transceiver; On-Chip Power-Combining for High-Power Schottky Diode-Based Frequency Multipliers; FPGA Vision Data Architecture; Memory Circuit Fault Simulator; Ultra-Compact Transputer-Based Controller for High-Level, Multi-Axis Coordination; Regolith Advanced Surface Systems Operations Robot Excavator; Magnetically Actuated Seal; Hybrid Electrostatic/Flextensional Mirror for Lightweight, Large-Aperture, and Cryogenic Space Telescopes; System for Contributing and Discovering Derived Mission and Science Data; Remote Viewer for Maritime Robotics Software; Stackfile Database; Reachability Maps for In Situ Operations; JPL Space Telecommunications Radio System Operating Environment; RFI-SIM: RFI Simulation Package; ION Configuration Editor; Dtest Testing Software; IMPaCT - Integration of Missions, Programs, and Core Technologies; Integrated Systems Health Management (ISHM) Toolkit; Wind-Driven Wireless Networked System of Mobile Sensors for Mars Exploration; In Situ Solid Particle Generator; Analysis of the Effects of Streamwise Lift Distribution on Sonic Boom Signature; Rad-Tolerant, Thermally Stable, High-Speed Fiber-Optic Network for Harsh Environments; Towed Subsurface Optical Communications Buoy; High-Collection-Efficiency Fluorescence Detection Cell; Ultra-Compact, Superconducting Spectrometer-on-a-Chip at Submillimeter Wavelengths; UV Resonant Raman Spectrometer with Multi-Line Laser Excitation; Medicine Delivery Device with Integrated Sterilization and Detection; Ionospheric Simulation System for Satellite Observations and Global Assimilative Model Experiments - ISOGAME; Airborne Tomographic Swath Ice Sounding Processing System; flexplan: Mission Planning System for the Lunar Reconnaissance Orbiter; Estimating Torque Imparted on Spacecraft Using Telemetry; PowderSim: Lagrangian Discrete and Mesh-Free Continuum Simulation Code for Cohesive Soils; Multiple-Frame Detection of Subpixel Targets in Thermal Image Sequences; Metric Learning to Enhance Hyperspectral Image Segmentation; Basic Operational Robotics Instructional System; Sheet Membrane Spacesuit Water Membrane Evaporator; Advanced Materials and Manufacturing for Low-Cost, High-Performance Liquid Rocket Combustion Chambers; Motor Qualification for Long-Duration Mars Missions.

Source record↗

Mapping transformations for broadband atmospheric radiation calculations

Two methods of mapping the line-by-line absorption coefficient (k) spectrum onto a new variable to produce a set of k coefficients which can be used for accurate and efficient broadband radiative transfer calculations in vertically inhomogeneous, nongray scattering atmospheres are described. These methods are intended for applications for which the less accurate correlated-k method is inadequate. These methods are tested for model atmospheres containing CO2 and H2O, with pressure in the range 0.05-0.9 bar. The results obtained differed by no more than 1 or 2 percent from the line-by-line results if the number of k coefficients was about 100 times less than the number required for the line-by-line calculation. These algorithms can be used for gas mixtures and for a variety of pressure-temperature profiles.

West, Robert↗

SU-E-I-29: Generalized Relative Object Detectability (G-ROD): A Metric for Comparing X-Ray Imaging Detector Systems

Purpose: To determine the relative task-specific performance of two x-ray imaging detectors including the effect of other components of the imaging chain. Methods: The relative object detectability (ROD) was defined as the ratio of the integral of the detective-quantum efficiency (DQE) of a detector weighted by the square of the Fourier Transform (or frequency spectrum) of the object to the same integral for a second detector. The generalized ROD (G-ROD) is calculated by replacing DQE by the generalized DQE (GDQE) which includes geometric unsharpness and scatter to evaluate the total imaging chain. The G-ROD was calculated for the micro-angiographic fluoroscope (MAF) relative to a flat-panel detector (FPD) for low (1.05) and high (1.2) magnifications with two focal-spot sizes, small (0.3 mm) and medium (0.5 mm), and for the same value of scatter fraction. Solid spheres from 50 to 600 microns were simulated as the objects for this evaluation. The G-ROD results were compared with those of the ROD which considers the detectors alone. Results: For 50-micron spheres, the ROD is 7.93 and, for the small [medium] focus, the G-ROD is 6.74 [5.22] at low magnification and 3.03 [1.66] at high magnification, indicating superior performance of the MAF particularly at low magnification. Both ROD and G-ROD decrease monotonically with size and remain around one above 400-microns. The G-ROD decreases more dramatically with low compared to high magnification for both focal spots. Conclusion: In all cases, the MAF performs better than the FPD and the decreasing trend of the G-ROD indicates that the performance of both detectors becomes similar as the object size increases and becomes nearly equal above 400-micron diameter sphere size. Finally, increased magnification and focal-spot size decrease the G-ROD, indicting that they degrade the performance of the MAF more than that of the FPD for a small-object viewing task. Supported by NIH Grant: 2R01EB002873 and an equipment grant from Toshiba Medical Systems Corporation.

60 APPLIED LIFE SCIENCES↗

An in-situ neutron diffraction study of a multi-phase transformation and twinning-induced plasticity steel during cyclic loading

In-situ neutron diffraction during cyclic tension-compression loading (∼+3.5% to −2.8%) of a 17Mn-3Al-2Si-1Ni-0.06C steel that exhibits concurrent transformation and twinning -induced plasticity effects indicated a significant contribution of intragranular back stresses to the observed Bauschinger effect. Rietveld analysis revealed a higher rate of martensitic transformation during tension compared to compression. Throughout cycling, α′-martensite exhibited the highest phase strains such that it bears an increasing portion of the macroscopic load as its weight fraction evolves. On the other hand, the ε-martensite strain remained compressive as it accommodated most of the internal strains caused by the shape misfit associated with the γ→ε and/or ε→α′ transformations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗